July 2023 - 50 articles
Relative equilibrium populations of the five lowest-energy isolated-pentagon-rule (IPR) isomeric structures of Pr@C82 under high-temperature fullerene synthesis conditions were calculated with the Gibbs energy terms based on molecular characteristics...
Water oxidation (WO) is the first step in the water-splitting process aiming at the production of hydrogen as a green renewable fuel. To successfully perform WO, potent strategies for overcoming the high energetic barrier and slow kinetics of this re...
In the vitrification of high-level radioactive liquid waste (HLW), the separation of sodium-molybdate melts is a problem because it reduces the chemical durability of the vitrified waste. A glass with both high MoO3 solubility and chemical durability...
Understanding the complex mechanisms underlying redox-mediated biological processes is a fundamental pillar of cellular biology. We describe the identification and quantification of disulfide formation and reduction in response to phosphine–bor...
Biogenic nanoparticles are considered effective alternatives to chemical pesticides for the management of pathogenic plant diseases. This study was focused on the synthesis of stable silver nanoparticles (AgNPs) to control challenging plant pathogeni...
The preparation of ammine complexes of transition metals having oxidizing anions such as permanganate and perrhenate ions is a great challenge due to possible reactions between ammonia and oxidizing anions during the synthesis of these materials. How...
A predictable type of coordination is a key property of tripodal ligands. Homo- and heteroleptic lanthanide complexes with tripodal ligands are a representative class of compounds. However, despite the fact that many of them are paramagnetic, their m...
Over the past decade, inorganic fillers and sol–gel-based flame-retardant technologies for textile treatments have gained increasing research interest as useful alternatives to hazardous chemicals previously employed in textile coating and fini...
The electrochemical performance of lithium–sulfur batteries (LiSBs) has been hampered by the slow redox kinetics and shuttle effect of lithium polysulfides (LiPSs), which require the rational design and synthesis of highly active electrocatalys...
In this article, the performance and design considerations of the planar structure of germanium on silicon avalanche photodiodes are presented. The dependences of the breakdown voltage, gain, bandwidth, responsivity, and quantum efficiency on the rev...
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