To elucidate the role of environmentally friendly oxide additives in a molybdenum disulfide (MoS
2)-based solid lubricant, this study investigates the tribological behavior of a MoS
2–TiO
2 coating deposited via a spray-bonding process and compares it with a commercial Sb
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To elucidate the role of environmentally friendly oxide additives in a molybdenum disulfide (MoS
2)-based solid lubricant, this study investigates the tribological behavior of a MoS
2–TiO
2 coating deposited via a spray-bonding process and compares it with a commercial Sb
2O
3-containing formulation (Everlube 620C). Interfacial characteristics and wear-related mechanisms were systematically analyzed using scanning electron microscopy (SEM), focused ion beam (FIB), Raman spectroscopy, and X-ray diffraction (XRD). The MoS
2–TiO
2 coating exhibited a higher steady-state coefficient of friction (0.35–0.45) and wear compared to the baseline. Its wear behavior was governed by fracture-induced three-body abrasion, driven by the hard and brittle nature of TiO
2, which promotes stress concentration at particle–matrix interfaces, crack initiation, particle pull-out, and debris generation. These processes suppress the formation of a desirable MoS
2-rich tribo/transfer film, leading to deformation-dominated friction. Overall, the findings indicate that the intrinsic mechanical properties and interfacial behavior of TiO
2 limit its effectiveness as an additive in MoS
2-based coatings, highlighting the importance of additive selection and compatibility in achieving optimal tribological performance. Notably, this study was performed at an additive volume fraction equivalent to that of Sb
2O
3 in Everlube 620C, serving as a foundation and indicating that further optimization of TiO
2 particle size and concentration is required to achieve comparable performance.
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