Lubricants

To enhance the abrasion resistance of TC4 titanium alloy and meet the demand for wear-resistant and corrosion-resistant friction pair materials for water-hydraulic components of marine equipment, the tribological properties of the material subsequent to ultrasonic rolling extrusion surface strengthening under seawater-lubricated conditions were investigated. The process of ultrasonic rolling machining was simulated and analyzed by the finite element method. The influence of process parameters on surface residual stress and surface roughness of TC4 was studied, and the appropriate range of process parameters was determined. The effects of key process parameters such as rolling times, static pressure, amplitude, and rotational speed on the surface properties of TC4 were investigated by the single-factor test method. Based on the response surface methodology, a prediction model of surface hardness and roughness of TC4 was constructed, and the process parameters were optimized and analyzed. The friction coefficient, wear amount, and wear rate of TC4 and CFRPEEK under seawater lubrication before and after strengthening were studied by wear tests. The wear morphologies of the specimens prior to and subsequent to strengthening were analyzed, and the friction and wear mechanisms were explored in depth. The results indicate that ultrasonic rolling extrusion surface strengthening process facilitates grain refinement in the surface layer of TC4, enhances surface hardness, and optimizes surface roughness, thereby improving its wear resistance. This is of guiding significance to the design and use of hydraulic components in seawater and has a promoting effect on the development of marine equipment.

The paper proposes a pavement safety index, the estimated available friction at the expected travel speed, FRS(v), to model the composed effect of low-slip speed friction and macrotexture on roadway crashes. This index seems to capture the relative contributions of microtexture and macrotexture across different operating speeds. Speed-dependent available friction at 40, 55, and 70 mph was estimated using the speed-correction procedure in ASTM E1960-07 and integrated into Safety Performance Function (SPF) development. Comparison of the resulting SPF models suggests that FRS values corresponding to typical operating speeds can capture the combined influence of SFN (40) and macrotexture on expected crashes for freeways and rural two-lane, two-way highways. For freeways, the estimated available friction at 70 mph (FRS113) produced the most appropriate SPF, evidenced by the lowest AIC. For rural two-lane, two-way highways, the estimated available friction at 40 mph (FRS65) resulted in the lowest AIC value, consistent with the typical operating speeds on these facilities. In contrast, none of the speed-specific friction estimates produced satisfactory model performance for urban and suburban arterials, likely due to the wide variation in traveling speeds and geometric characteristics on these facilities. The applicability of the proposed metric was demonstrated through the development of illustrative investigatory friction levels based on observed crash data, and the identification of candidate roadway segments for friction improvement interventions, and the estimation of the corresponding return on investment for these interventions.

In this work, we produced a new polyurea (PU)-based thickener based on serine derivatives (ethanolamine or L-Serine ethyl ester) and 1,5 pentamethylene diisocyanate (PDI), using castor oil as base oil and methylene diphenyl diisocyanate (MDI) as a reference. Polymerization was carried out in a planetary ball mill at room temperature for 75 min. The polymerization degree of the PU thickener was examined via ¹H NMR, which ranged between 1.8 and 14.6 repeating units after the extraction of the base oil. Rheological analysis showed gel formation for ten out of twelve samples, which was strongly dependent on the polymerization degree and thickener amount. The decomposition temperature of the MDI-based PU greases was consistently roughly 20 °C higher than that of PDI-based systems. The lubricants were further evaluated through rheology experiments before and after the gels underwent an annealing process at 100 °C for 1 h (amplitude and frequency test), indicating a strong increase in the storage modulus G’, whereas the yield point γ_F remained constant or decreased.