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Catalysts, Volume 9, Issue 10

2019 October - 90 articles

Cover Story: In this paper (Catalysts 2019, 9, 826), a collaborative study between Demchenko and Daniellou and co-workers led to the identification of the prerequisites for the enzymatic remote activation of commonly used chemical glycosyl donors. Indeed, using multidisciplinary approaches, we have been able to understand and rationalize how thioiomidoyl glycosides can act as substrates for glycoside hydrolases. Remarkably, this work paves the way for broadening bioacatalytic applications using such unnatural enzymatic substrates with mutant enzymes like thioligases. View this paper.
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Articles (90)

  • Review
  • Open Access
98 Citations
12,073 Views
35 Pages

Biocatalytic Synthesis of Natural Green Leaf Volatiles Using the Lipoxygenase Metabolic Pathway

  • Sophie Vincenti,
  • Magali Mariani,
  • Jean-Christophe Alberti,
  • Sabrina Jacopini,
  • Virginie Brunini-Bronzini de Caraffa,
  • Liliane Berti and
  • Jacques Maury

22 October 2019

In higher plants, the lipoxygenase enzymatic pathway combined actions of several enzymes to convert lipid substrates into signaling and defense molecules called phytooxylipins including short chain volatile aldehydes, alcohols, and esters, known as g...

  • Article
  • Open Access
12 Citations
5,143 Views
13 Pages

Screening and Comparative Characterization of Microorganisms from Iranian Soil Samples Showing ω-Transaminase Activity toward a Plethora of Substrates

  • Najme Gord Noshahri,
  • Jamshid Fooladi,
  • Christoph Syldatk,
  • Ulrike Engel,
  • Majid M. Heravi,
  • Mohammad Zare Mehrjerdi and
  • Jens Rudat

22 October 2019

In this study, soil microorganisms from Iran were screened for ω-transaminase (ω-TA) activity based on growth on minimal media containing (rac)-α-methylbenzylamine (rac-α-MBA) as a sole nitrogen source. Then, for the selection of strains with high en...

  • Article
  • Open Access
19 Citations
4,806 Views
20 Pages

21 October 2019

In this study, the photocatalytic degradation of azo dye “Food Black 1” (FB1) was investigated using TiO2 and ZnO nanoparticles under ultraviolet (UV) light. The performances of the two photocatalysts were evaluated in terms of key parame...

  • Article
  • Open Access
32 Citations
7,026 Views
27 Pages

21 October 2019

Fischer–Tropsch (FT) synthesis was carried out in a 3D printed stainless steel (SS) microchannel microreactor using bimetallic Co-Ru catalysts on three different mesoporous silica supports. CoRu-MCM-41, CoRu-SBA-15, and CoRu-KIT-6 were synthesi...

  • Review
  • Open Access
33 Citations
8,318 Views
18 Pages

Cofactor F420-Dependent Enzymes: An Under-Explored Resource for Asymmetric Redox Biocatalysis

  • Mihir V. Shah,
  • James Antoney,
  • Suk Woo Kang,
  • Andrew C. Warden,
  • Carol J. Hartley,
  • Hadi Nazem-Bokaee,
  • Colin J. Jackson and
  • Colin Scott

20 October 2019

The asymmetric reduction of enoates, imines and ketones are among the most important reactions in biocatalysis. These reactions are routinely conducted using enzymes that use nicotinamide cofactors as reductants. The deazaflavin cofactor F420 also ha...

  • Article
  • Open Access
5 Citations
5,306 Views
18 Pages

20 October 2019

For decades the steric effect was still ambiguously understood in catalytic benzylation reactions of arenes with benzyl alcohol, which limited the green synthesis of phenylmethane derivates in industrial scale. This research applies a series of silic...

  • Article
  • Open Access
6 Citations
5,330 Views
14 Pages

Fe Speciation in Iron Modified Natural Zeolites as Sustainable Environmental Catalysts

  • Fernando Chávez Rivas,
  • Inocente Rodríguez-Iznaga,
  • Gloria Berlier,
  • Daria Tito Ferro,
  • Beatriz Concepción-Rosabal and
  • Vitalii Petranovskii

19 October 2019

Natural purified mordenite from Palmarito de Cauto (ZP) deposit, Cuba, was subjected to a hydrothermal ion exchange process in acid medium with Fe2+ or Fe3+ salts (Fe2+ZP and Fe3+ZP). The set of samples was characterized regarding their textural prop...

  • Article
  • Open Access
45 Citations
6,234 Views
14 Pages

Overcoming Stability Problems in Microwave-Assisted Heterogeneous Catalytic Processes Affected by Catalyst Coking

  • Ignacio Julian,
  • Christoffer M. Pedersen,
  • Kostiantyn Achkasov,
  • Jose L. Hueso,
  • Henrik L. Hellstern,
  • Hugo Silva,
  • Reyes Mallada,
  • Zachary J. Davis and
  • Jesus Santamaria

19 October 2019

Microwave-assisted heterogeneous catalysis (MHC) is gaining attention due to its exciting prospects related to selective catalyst heating, enhanced energy-efficiency, and partial inhibition of detrimental side gas-phase reactions. The induced tempera...

  • Article
  • Open Access
9 Citations
3,817 Views
15 Pages

18 October 2019

Several organic templates were introduced during acid or alkaline treatment to optimize pore structures of hierarchical HY zeolites. The influences of category and concentration of templates on the pore structures and acidity of hierarchical HY zeoli...

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Catalysts - ISSN 2073-4344