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Molecules, Volume 29, Issue 11

2024 June-1 - 304 articles

Cover Story: A series of iridium(III) triimine complexes incorporating 2,2′:6′,2′′-terpyridine (terpy) and 2,6-bis(thiazol-2-yl)pyridine (dtpy) derivatives were successfully designed and synthesized to investigate the impact of the peripheral rings (pyridine, thiazole) and substituents (thiophene, bithiophene, EDOT) attached to the triimine skeleton on their photophysical properties. The Ir(III) complexes were fully characterized using IR, 1H, elemental analysis and single crystal X-ray analysis. The Ir(III) complexes display room-temperature red-orange phosphorescence in solution with quantum yields in the range of 1.27–5.30% and lifetimes of hundreds of nanoseconds to a few microseconds. The structured shape of the emission band at both room and low temperatures indicates a substantial share of the ligand in the emission process. View this paper
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Articles (304)

  • Article
  • Open Access
6 Citations
2,593 Views
20 Pages

UPLC-ESI-MS/MS Profiling of Secondary Metabolites from Methanol Extracts of In Vivo and In Vitro Tissues of Daucus capillifolius Gilli (A Comparative Study)

  • Rehab H. Abdallah,
  • Wafaa H. B. Hassan,
  • Shaza M. Al-Massarani,
  • Wael M. Abdel-Mageed,
  • Samih I. Eldahmy,
  • Omer A. Basudan,
  • Mehtab Parveen,
  • Entesar El Senosy and
  • Sahar Abdelaziz

Daucus capillifolius Gilli is a rare annual wild herb grown in Libya. It belongs to the Apiaceae family, which is one of the largest flowering plant families. Plants of this family are outstanding sources of various secondary metabolites with various...

  • Article
  • Open Access
5 Citations
2,943 Views
18 Pages

Rare tautomeric forms of nucleobases can lead to Watson–Crick-like (WC-like) mispairs in DNA, but the process of proton transfer is fast and difficult to detect experimentally. NMR studies show evidence for the existence of short-time WC-like g...

  • Article
  • Open Access
2 Citations
1,917 Views
12 Pages

Tourmaline, a boron-bearing mineral, has been extensively applied as a geothermometer, provenance indicator, and fluid-composition recorder in geological studies. In this paper, the decomposition capability of an HF-HNO3–mannitol mixture for a...

  • Article
  • Open Access
1 Citations
1,853 Views
16 Pages

Graphene oxide (GO) has attracted huge attention in biomedical sciences due to its outstanding properties and potential applications. In this study, we synthesized GO using our recently developed 1-pyrenebutyric acid-assisted method and assessed how...

  • Article
  • Open Access
27 Citations
9,869 Views
17 Pages

Mechanochemical Synthesis of MOF-303 and Its CO2 Adsorption at Ambient Conditions

  • Sylwia Głowniak,
  • Barbara Szczęśniak,
  • Jerzy Choma and
  • Mietek Jaroniec

Metal–organic structures have great potential for practical applications in many areas. However, their widespread use is often hindered by time-consuming and expensive synthesis procedures that often involve hazardous solvents and, therefore, g...

  • Article
  • Open Access
2 Citations
1,680 Views
14 Pages

In this work, the dispersive solid phase extraction (dSPE) of melatonin using graphene (G) mixtures with sepiolite (SEP) and bentonite (BEN) clays as sorbents combined with fluorescence detection has been investigated. The retention was found to be q...

  • Article
  • Open Access
2 Citations
2,406 Views
15 Pages

Design, Synthesis, and Cytotoxic Assessment of New Haloperidol Analogues as Potential Anticancer Compounds Targeting Sigma Receptors

  • Daniele Zampieri,
  • Maurizio Romano,
  • Sara Fortuna,
  • Emanuele Amata,
  • Maria Dichiara,
  • Giuseppe Cosentino,
  • Agostino Marrazzo and
  • Maria Grazia Mamolo

Sigma receptors (SRs), including SR1 and SR2 subtypes, have attracted increasing interest in recent years due to their involvement in a wide range of activities, including the modulation of opioid analgesia, neuroprotection, and potential anticancer...

  • Article
  • Open Access
2 Citations
2,229 Views
14 Pages

Pickering Emulsion of Oleoresin from Dipterocarpus alatus Roxb. ex G. Don and Its Antiproliferation in Colon (HCT116) and Liver (HepG2) Cancer Cells

  • Piman Pocasap,
  • Kawintra Tamprasit,
  • Thanyathanya Rungsri,
  • Karnchanok Kaimuangpak,
  • Tarapong Srisongkram,
  • Somporn Katekaew,
  • Khanita Kamwilaisak,
  • Ploenthip Puthongking and
  • Natthida Weerapreeyakul

Oleoresin of Dipterocarpus alatus Roxb. ex G. Don (DA) has been traditionally used for local medicinal applications. Several in vitro studies have indicated its pharmacological potential. However, the low water solubility hinders its use and developm...

  • Article
  • Open Access
1 Citations
2,133 Views
12 Pages

Synthesis and Characterization of Cross-Linked Aggregates of Peroxidase from Megathyrsus maximus (Guinea Grass) and Their Application for Indigo Carmine Decolorization

  • Angie V. Perez,
  • Jorge A. Gaitan-Oyola,
  • Diana P. Vargas-Delgadillo,
  • John J. Castillo,
  • Oveimar Barbosa and
  • Roberto Fernandez-Lafuente

We present the synthesis of a cross-linking enzyme aggregate (CLEAS) of a peroxidase from Megathyrsus maximus (Guinea Grass) (GGP). The biocatalyst was produced using 50%v/v ethanol and 0.88%w/v glutaraldehyde for 1 h under stirring. The immobilizati...

  • Article
  • Open Access
11 Citations
2,644 Views
16 Pages

Preparation, Characterization, and Antioxidant Properties of Self-Assembled Nanomicelles of Curcumin-Loaded Amphiphilic Modified Chitosan

  • Qizhou Chen,
  • Yuwei Jiang,
  • Linlan Yuan,
  • Lifen Liu,
  • Xufeng Zhu,
  • Rimeng Chen,
  • Zhuo Wang,
  • Kefeng Wu,
  • Hui Luo and
  • Qianqian Ouyang

Curcumin (Cur) is a phytochemical with various beneficial properties, including antioxidant, anti-inflammatory, and anticancer activities. However, its hydrophobicity, poor bioavailability, and stability limit its application in many biological appro...

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Molecules - ISSN 1420-3049