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C, Volume 9, Issue 3

2023 September - 27 articles

Cover Story: In this work, a statistical evaluation of the main parameters influencing the synthesis of graphite oxides (GrO) using the Tour method is carried out. A screening experimental design is carried out, using temperature, time and the amounts of KMnO4 and H2O2 as variables. Specific surface area (SSA), porosity and carbon content (%C) are chosen as responses, since they are decisive characteristics in adsorption-related applications. After statistical evaluation of all the results (obtained using the Brunauer–Emmett–Teller method, Elemental Analysis, Scanning Electron Microscopy, X-Ray Diffraction and Raman), it is concluded that temperature is the most influential factor. Higher temperatures result in more exfoliated GrO, with higher SSA, smaller crystal size and lower %C. View this paper
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Articles (27)

  • Article
  • Open Access
3 Citations
3,268 Views
20 Pages

10 September 2023

MnO2/nitrogen-containing graphene (x-NGM) composites with varying contents of Mn were used as the electrode materials for flexible asymmetric solid-state supercapacitors. The MnO2 was a two-phase mixture of γ- and α-MnO2. The combination...

  • Article
  • Open Access
5 Citations
3,608 Views
22 Pages

Membranes of Multiwall Carbon Nanotubes in Chitosan–Starch with Mechanical and Compositional Properties Useful in Li-Ion Batteries

  • Yoxkin Estévez-Martínez,
  • Enrique Quiroga-González,
  • Erick Cuevas-Yañez,
  • Sergio Durón-Torres,
  • Daniel Alaníz-Lumbreras,
  • Elizabeth Chavira-Martínez,
  • Rubén Posada-Gómez,
  • Jeremias Bravo-Tapia and
  • Víctor Castaño-Meneses

8 September 2023

This work reports on membranes of a combination of chitosan–starch with lithium-modified multiwall carbon nanotubes. One of the most important contributions of this article is the functionalization of the surface of multiwall carbon nanotubes b...

  • Article
  • Open Access
7 Citations
4,861 Views
17 Pages

4 September 2023

Characterizing materials with low surface areas or with very small sample sizes requires innovative approaches beyond traditional N2 and Ar adsorption measurements. The measurement of Kr adsorption isotherms is often employed to serve this purpose, y...

  • Article
  • Open Access
11 Citations
4,444 Views
15 Pages

Photocatalytic Materials Based on g-C3N4 Obtained by the One-Pot Calcination Method

  • Radik R. Shamilov,
  • Zufar M. Muzipov,
  • Dmitriy O. Sagdeev,
  • Kirill V. Kholin,
  • Alina F. Saifina,
  • Aidar T. Gubaidullin and
  • Yuriy G. Galyametdinov

2 September 2023

Photocatalysts based on graphitic carbon nitride (g-C3N4) attracted considerable attention due to their efficiency in hydrogen production and decomposition of organic pollutants in aqueous solutions. In this work, a new approach to synthesis of g-C3N...

  • Article
  • Open Access
1 Citations
2,132 Views
15 Pages

31 August 2023

The Casimir–Polder force between atoms or nanoparticles and graphene-coated dielectric substrates is investigated in the region of large separations. Graphene coating with any value of the energy gap and chemical potential is described in the f...

  • Article
  • Open Access
7 Citations
3,307 Views
19 Pages

Carbonized Melamine Cyanurate as a Palladium Catalyst Support for the Dehydrogenation of N-heterocyclic Compounds in LOHC Technology

  • Anton P. Koskin,
  • Yurii V. Larichev,
  • Sergey A. Stepanenko,
  • Yury V. Dubinin,
  • Artem B. Ayupov,
  • Andrey A. Saraev,
  • Evgeny A. Suprun and
  • Petr M. Yeletsky

30 August 2023

In this work, the use of graphite-like carbon nitride (g-C3N4) with improved texture characteristics for the synthesis of supported palladium catalysts of dehydrogenation of nitrogen-containing heterocycles was studied. This process is key to the cre...

  • Article
  • Open Access
15 Citations
3,570 Views
14 Pages

Resistive Gas Sensors Based on Porous Sp-Containing Films Obtained by Dehydrohalogenation of PVDC and PVDC-PVC Copolymer

  • Oleg A. Streletskiy,
  • Ilya A. Zavidovskiy,
  • Islam F. Nuriahmetov,
  • Olesya Y. Nishchak,
  • Alexander V. Pavlikov and
  • Natalya F. Savchenko

28 August 2023

Resistive sensing responses of the thin films obtained by dehydrohalogenation of polyvinylidene chloride (PVDC) and polyvinylidene chloride–polyvinyl chloride (PVDC-PVC) copolymer were investigated. The structure of the samples was studied by t...

  • Article
  • Open Access
3 Citations
2,706 Views
15 Pages

Diffusion Behavior of Iodine in the Micro/Nano-Porous Graphite for Nuclear Reactor at High Temperature

  • Ming-Bo Qi,
  • Peng-Fei Lian,
  • Peng-Da Li,
  • He-Yao Zhang,
  • Jin-Xing Cheng,
  • Qing-Bo Wang,
  • Zhong-Feng Tang,
  • T. J. Pan,
  • Jin-Liang Song and
  • Zhan-Jun Liu

26 August 2023

The diffusion behavior of iodine in micro/nano-porous graphite under high-temperature conditions was studied using analysis methods such as Rutherford backscattering Spectrometry, scanning electron microscopy, X-ray diffraction, and Raman spectroscop...

  • Article
  • Open Access
7 Citations
2,559 Views
12 Pages

25 August 2023

Finishing coatings used in the wood-based composite industry play a key role in the final appearance of the finished product. However, the use of such coatings is not only for aesthetic purposes, but also to protect the product against surface damage...

  • Article
  • Open Access
6 Citations
3,112 Views
12 Pages

Divergence in Antiviral Activities of Carbon Dots versus Nano-Carbon/Organic Hybrids and Implications

  • Cristian E. Rodriguez,
  • Audrey F. Adcock,
  • Buta Singh,
  • Subhadra Yerra,
  • Yongan Tang,
  • Ya-Ping Sun and
  • Liju Yang

20 August 2023

Carbon dots (CDots) are generally defined as small carbon nanoparticles (CNPs) with effective surface passivation, for which the classical synthesis is the functionalization of pre-existing CNPs with organic molecules. However, “dot” samp...

  • Article
  • Open Access
1 Citations
2,713 Views
11 Pages

Diamond as Insulation for Conductive Diamond—A Spotted Pattern Design for Miniaturized Disinfection Devices

  • Manuel Zulla,
  • Vera Vierheilig,
  • Maximilian Koch,
  • Andreas Burkovski,
  • Matthias Karl and
  • Stefan Rosiwal

18 August 2023

Boron-doped diamond (BDD) electrodes are well known for the in situ production of strong oxidants. These antimicrobial agents are produced directly from water without the need of storage or stabilization. An in situ production of reactive oxygen spec...

  • Article
  • Open Access
12 Citations
3,443 Views
17 Pages

Effect of Cu on Performance of Self-Dispersing Ni-Catalyst in Production of Carbon Nanofibers from Ethylene

  • Sofya D. Afonnikova,
  • Yury I. Bauman,
  • Vladimir O. Stoyanovskii,
  • Mikhail N. Volochaev,
  • Ilya V. Mishakov and
  • Aleksey A. Vedyagin

14 August 2023

The development of effective catalysts for the pyrolysis of light hydrocarbons with the production of carbon nanomaterials represents a relevant direction. In the present work, the influence of copper addition on performance of a self-dispersed Ni-ca...

  • Article
  • Open Access
1 Citations
2,066 Views
19 Pages

8 August 2023

It is shown that it is possible to adapt the quantum graph model of graphene to some types of nonequilateral graphynes considered in the literature; we also discuss the corresponding nanotubes. The proposed models are, in fact, effective models and a...

  • Article
  • Open Access
10 Citations
3,073 Views
14 Pages

Electrical Resistance Evolution of Graphite and Talc Geological Heterostructures under Progressive Metamorphism

  • Augusto Gonçalves Nobre,
  • Fabio Ramos Dias de Andrade,
  • Andres Fabian Salazar-Naranjo,
  • Josue Neroti Rigue,
  • Ricardo Barreto da Silva,
  • Silvio Roberto Farias Vlach and
  • Romulo Augusto Ando

30 July 2023

The electrical properties of isolated graphene established precedents for studies of electrical superconducting materials at room temperature. After the discovery of stabilized graphene and graphite nanoplatelets in a geological context, the interest...

  • Article
  • Open Access
7 Citations
3,111 Views
8 Pages

Graphene Oxide Membranes: Controlled Laser Reduction for Sensing Applications

  • Aiden Rowley,
  • Yijing Stehle,
  • Luke Kilby and
  • Caleb Bashant

30 July 2023

Reduced graphene oxide (rGO) has attracted attention as an active electrode material for flexible electrochemical devices due to its high electric conductivity and large surface area. Compared to other reduction processes, laser reduction is a precis...

  • Article
  • Open Access
38 Citations
9,907 Views
17 Pages

Graphene Oxide: A Comparison of Reduction Methods

  • Natália Garrote de Barros,
  • Abel Cardoso Gonzaga Neto,
  • Kleber Bitencourt Vaccioli,
  • Hugo Rafael Vallejo Angulo,
  • Leonardo Gondim de Andrade e Silva,
  • Samuel Marcio Toffoli and
  • Ticiane Sanches Valera

27 July 2023

This paper presents a comparison of traditional thermal and chemical reduction methods with more recent ionizing radiation reduction via gamma rays and electron beams (e-beams). For GO, all synthesis protocols were adapted to increase production scal...

  • Review
  • Open Access
3 Citations
11,674 Views
21 Pages

Activated Carbon for Sepsis Prevention and Intervention: A Modern Way of Utilizing Old Therapies

  • Elisaveta Snezhkova,
  • Heinz Redl,
  • Johannes Grillari and
  • Marcin Osuchowski

25 July 2023

(1) Background: Uncontrolled inflammation often contributes to life-threatening sepsis sequela such as multi-organ dysfunction syndrome (MODS), and is accompanied by abnormal levels of pathological and damage-associated molecular patterns (PAMPs &...

  • Article
  • Open Access
13 Citations
3,701 Views
21 Pages

Adsorption of Cobalt and Strontium Ions on Plant-Derived Activated Carbons: The Suggested Mechanisms

  • Irina Ceban (Ginsari),
  • Tudor Lupascu,
  • Sergey Mikhalovsky and
  • Raisa Nastas

21 July 2023

In this study, activated carbons derived from walnut shells (CA-N) and apple wood (CA-M) were used as adsorbents to remove cobalt(II) and strontium(II) ions from aqueous solutions. The novel materials were obtained using nitric acid (CA-Mox) and nitr...

  • Review
  • Open Access
25 Citations
9,270 Views
33 Pages

Recent Advancements in Applications of Graphene to Attain Next-Level Solar Cells

  • Sonal Santosh Bagade,
  • Shashidhar Patel,
  • M. M. Malik and
  • Piyush K. Patel

19 July 2023

This paper presents an intensive review covering all the versatile applications of graphene and its derivatives in solar photovoltaic technology. To understand the internal working mechanism for the attainment of highly efficient graphene-based solar...

  • Article
  • Open Access
2 Citations
4,096 Views
14 Pages

12 July 2023

As the world takes a more strategic approach to the climate crisis, carbon in its various forms has become a key factor in ascertaining the sustainability of the landscape. Landscape has been recognised as a resource and mechanism for addressing the...

  • Feature Paper
  • Article
  • Open Access
4 Citations
3,064 Views
16 Pages

Effect of Carbon Nanoparticles on the Porous Texture of ι-Carrageenan-Based N-Doped Nanostructured Porous Carbons and Implications for Gas Phase Applications

  • Samantha K. Samaniego Andrade,
  • Alfréd Menyhárd,
  • Szilvia Klébert,
  • Miklós Mohai,
  • Balázs Nagy and
  • Krisztina László

12 July 2023

S and N double-doped high surface area biomass-derived carbons were obtained from marine biomass-derived ι-carrageenan. Adding carbon nanoparticles (CNPs), namely graphene oxide (GO) or carbon nanotubes (CNTs), in the early stage of the synthesi...

  • Review
  • Open Access
148 Citations
38,932 Views
30 Pages

7 July 2023

Biochar, a sustainable solid material derived from biomass pyrolysis enriched in carbon, has emerged as a promising solution for soil carbon sequestration. This comprehensive review analyzes the current knowledge on biochar’s application in thi...

  • Article
  • Open Access
18 Citations
3,691 Views
12 Pages

5 July 2023

The raw materials (coals different stages of metamorphism) and technological factors (period and temperature) of the coke-making that determine the carbon structure of blast furnace coke, and its physical and mechanical properties are analyzed. The c...

  • Article
  • Open Access
6 Citations
5,834 Views
23 Pages

Evaluation and Optimization of Tour Method for Synthesis of Graphite Oxide with High Specific Surface Area

  • Hanna Bukovska,
  • Fernando García-Perez,
  • Natalia Brea Núñez,
  • Laura J. Bonales,
  • Andrés Velasco,
  • M. Ángeles Clavero,
  • Javier Martínez,
  • Alberto J. Quejido,
  • Isabel Rucandio and
  • M. Belén Gómez-Mancebo

5 July 2023

Many of the graphene-based structures exhibit an adsorption capacity due to their high specific surface area (SSA) and micropore volume. This capacity makes them competent materials for applications in energy and environmental sectors where efficienc...

  • Article
  • Open Access
3 Citations
2,618 Views
17 Pages

4 July 2023

The Casimir–Polder force acting on atoms and nanoparticles spaced at large separations from real graphene sheets possessing some energy gaps and chemical potentials is investigated in the framework of the Lifshitz theory. The reflection coeffic...

  • Article
  • Open Access
2 Citations
2,631 Views
11 Pages

RF Sensor with Graphene Film for HRP Concentration Detection

  • Fabio Peinetti,
  • Muhammad Yasir and
  • Patrizia Savi

23 June 2023

This paper presents a radio-frequency (RF) antenna as a sensor to detect Horseradish peroxidase (HRP). At the core of the proposed approach is a graphene film deposited on a stub connected to an RF antenna. The graphene film is doctor bladed on the s...

  • Article
  • Open Access
2,299 Views
10 Pages

Single-Bilayer Graphene Test Structures for Kelvin Probe Microscopy

  • Sergey P. Lebedev,
  • Ilya A. Eliseyev,
  • Mikhail S. Dunaevskiy,
  • Ekaterina V. Gushchina and
  • Alexander A. Lebedev

21 June 2023

A new technique for determining the point spread function, which is required for measuring the surface potential using Kelvin probe microscopy (KPM), is presented. The method involves using a silicon carbide substrate coated with single-layer and bil...

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C - ISSN 2311-5629