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Crystals, Volume 7, Issue 11

2017 November - 29 articles

Cover Story: Helicobacter pylori infection can lead to the development of gastric and duodenal ulcers and gastric cancer. The H. pylori genome encodes several periplasmic binding proteins (PBPs), most with unknown function. We describe crystallisation and preliminary X-ray diffraction analysis of the PBP YckK from H. pylori SS1, an important step towards elucidation of its ligand specificity and three-dimensional structure. The cover shows the electron density map of the molecular replacement solution. View the paper here.
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Articles (29)

  • Article
  • Open Access
21 Citations
5,912 Views
9 Pages

Room-Temperature Plastic Deformation of Strontium Titanate Crystals Grown from Different Chemical Compositions

  • Atsutomo Nakamura,
  • Kensuke Yasufuku,
  • Yuho Furushima,
  • Kazuaki Toyoura,
  • K. Peter D. Lagerlöf and
  • Katsuyuki Matsunaga

22 November 2017

Oxide materials have the potential to exhibit superior mechanical properties in terms of high yield point, high melting point, and high chemical stability. Despite this, they are not widely used as a structural material due to their brittle nature. H...

  • Article
  • Open Access
2 Citations
5,764 Views
17 Pages

19 November 2017

Phoxonic crystals, which exhibit simultaneous phononic and photonic bandgaps, are promising artificial materials for optomechanical and acousto-optical devices. In this paper, simultaneous guidance of surface acoustic and surface optical waves in tru...

  • Review
  • Open Access
72 Citations
11,448 Views
15 Pages

17 November 2017

The formation of minerals such as calcite and struvite through the hydrolysis of urea catalyzed by ureolytic bacteria is a simple and easy way to control mechanisms, which has been extensively explored with promising applications in various areas suc...

  • Article
  • Open Access
45 Citations
7,673 Views
13 Pages

15 November 2017

While phononic crystals can be theoretically modeled with a variety of analytical and numerical methods, the practical realization and comprehensive characterization of complex designs is often challenging. This is especially important for the nearly...

  • Article
  • Open Access
18 Citations
6,161 Views
11 Pages

15 November 2017

Graphene’s novel electrical, optical, and mechanical properties are affected both by substrate interaction and processing steps required to fabricate contacts and devices. Annealing is used to clean graphene devices, but this can lead to doping and d...

  • Article
  • Open Access
6 Citations
6,385 Views
13 Pages

Quantitative Imaging of the Stress/Strain Fields and Generation of Macroscopic Cracks from Indents in Silicon

  • Brian K. Tanner,
  • David Allen,
  • Jochen Wittge,
  • Andreas N. Danilewsky,
  • Jorge Garagorri,
  • Eider Gorostegui-Colinas,
  • M. Reyes Elizalde and
  • Patrick J. McNally

14 November 2017

The crack geometry and associated strain field around Berkovich and Vickers indents on silicon have been studied by X-ray diffraction imaging and micro-Raman spectroscopy scanning. The techniques are complementary; the Raman data come from within a f...

  • Article
  • Open Access
3 Citations
6,847 Views
11 Pages

Galloping Reduction of Transmission Lines by Using Phononic Crystal

  • Lin Han,
  • Yan Zhang,
  • Xiaomei Li,
  • Linhua Jiang and
  • Da Chen

13 November 2017

Considering the combination of the transmission lines and phononic crystals (PCs), we propose a new method to solve the problem of the galloping of overhead transmission lines. The method has two key points: attaching the suitable mass-spring system...

  • Article
  • Open Access
2 Citations
6,739 Views
9 Pages

Expression, Purification, Crystallization, and X-ray Structural Analysis of CRISPR-Associated Protein Cas6 from Methanocaldococcus jannaschii

  • Ming-Chang Lee,
  • Shih-Ting Tseng,
  • Juan-Cheng Yang,
  • Tung-Ju Hsieh,
  • Shang-Chuen Wu,
  • Shu-Min Kuan,
  • Ming-Jen Chen,
  • Ming-Chiu Chang,
  • Chun-Chiu Wang and
  • Yeh Chen
  • + 4 authors

10 November 2017

The CRISPR-associated protein 6, Cas6 protein, is an endoribonuclease that cleaves precursor CRISPR RNAs within the repeat sequence to release specific invader-targeting RNAs. Cas6 protein can recognize different sequences by their specific scaffold....

  • Article
  • Open Access
7 Citations
5,704 Views
21 Pages

Dopant Concentration Induced Optical Changes in Ca,Eu-α-Sialon

  • Daniel Michalik,
  • Tomasz Pawlik,
  • Benedykt Kukliński,
  • Agata Lazarowska,
  • Tadeusz Leśniewski,
  • Justyna Barzowska,
  • Sebastian Mahlik,
  • Marek Grinberg,
  • Barbara Adamczyk and
  • Małgorzata Sopicka-Lizer
  • + 1 author

8 November 2017

The phosphor powders of Ca(m/2)−xEuxSi12−(m+n)Alm+nOnN16−n (m = 1.6, n = 0.8, x in the range of 0–0.08) were synthesized by means of a solid state reaction in flowing nitrogen in a carbon resistant furnace and the influence of Eu concentration on the...

  • Article
  • Open Access
18 Citations
6,713 Views
16 Pages

Novel Quaternary TlGaSn2Se6 Single Crystal as Promising Material for Laser Operated Infrared Nonlinear Optical Modulators

  • Oleh V. Parasyuk,
  • Volodymyr S. Babizhetskyy,
  • Oleg Y. Khyzhun,
  • Volodymyr O. Levytskyy,
  • Iwan V. Kityk,
  • Galyna L. Myronchuk,
  • Oksana V. Tsisar,
  • Lyudmyla V. Piskach,
  • Jaroslaw Jedryka and
  • Michal Piasecki
  • + 1 author

7 November 2017

The studies of the laser operated third order nonlinear optical features of novel TlGaSn2Se6 crystal were done. The main efforts were devoted to a search of a possibility to apply these crystals as laser operated optoelectronic material. For this rea...

  • Article
  • Open Access
3 Citations
5,718 Views
13 Pages

6 November 2017

The three mixed-metal oxochromates(VI) Cd(HgI2)2(HgII)3O4(CrO4)2, Cd(HgII)4O4(CrO4), and Zn(HgII)4O4(CrO4) were grown under hydrothermal conditions. Their crystal structures were determined from single-crystal X-ray diffraction data. The crystal-chem...

  • Article
  • Open Access
10 Citations
5,405 Views
14 Pages

Microindentation Hardness of Protein Crystals under Controlled Relative Humidity

  • Takeharu Kishi,
  • Ryo Suzuki,
  • Chika Shigemoto,
  • Hidenobu Murata,
  • Kenichi Kojima and
  • Masaru Tachibana

4 November 2017

Vickers microindentation hardness of protein crystals was investigated on the (110) habit plane of tetragonal hen egg-white lysozyme crystals containing intracrystalline water at controlled relative humidity. The time evolution of the hardness of the...

  • Article
  • Open Access
8 Citations
5,012 Views
9 Pages

Ultrafast Photoalignment: Recording a Lens in a Nanosecond

  • Svetlana V. Serak,
  • Timothy J. Bunning and
  • Nelson V. Tabiryan

3 November 2017

Liquid crystals can be photoaligned with a single nanosecond pulse acting on thin photoanisotropic coatings on the cell substrates. This phenomenon was demonstrated for pulses of 532 nm and 355 nm wavelengths (second and the third harmonics of a Nd:Y...

  • Review
  • Open Access
13 Citations
9,198 Views
21 Pages

Brief Review of Epitaxy and Emission Properties of GaSb and Related Semiconductors

  • Shouzhu Niu,
  • Zhipeng Wei,
  • Xuan Fang,
  • Dengkui Wang,
  • Xinwei Wang,
  • Xian Gao and
  • Rui Chen

2 November 2017

Groups III–V semiconductors have received a great deal of attention because of their potential advantages for use in optoelectronic and electronic applications. Gallium antimonide (GaSb) and GaSb-related semiconductors, which exhibit high carrier mob...

  • Article
  • Open Access
10 Citations
6,495 Views
22 Pages

2 November 2017

This paper develops a framework to obtain the flow stress of nickel-based superalloys as a function of γ-γ’ morphology. The yield strength is a major factor in the design of these alloys. This work provides additional effects of γ’ morphology in the...

  • Article
  • Open Access
63 Citations
12,919 Views
22 Pages

A Novel Dual Air-Bearing Fixed-χ Diffractometer for Small-Molecule Single-Crystal X-ray Diffraction on Beamline I19 at Diamond Light Source

  • David . R Allan,
  • Harriott Nowell,
  • Sarah A. Barnett,
  • Mark R. Warren,
  • Adrian Wilcox,
  • Jeppe Christensen,
  • Lucy K. Saunders,
  • Andrew Peach,
  • Mark T. Hooper and
  • Ron W. Wooley
  • + 12 authors

2 November 2017

Herein, we describe the development of a novel dual air-bearing fixed-χ diffractometer for beamline I19 at Diamond Light Source. The diffractometer is designed to facilitate the rapid data collections possible with a Dectris Pilatus 2M pixel-array ph...

  • Article
  • Open Access
9 Citations
4,892 Views
11 Pages

1 November 2017

Single-crystal germanium is a semiconductor material which shows complicated phase transformation under high pressure. In this study, new insight into the phase transformation of diamond-cubic germanium (dc-Ge) was attempted by controlled cyclic nano...

  • Article
  • Open Access
23 Citations
6,177 Views
9 Pages

Nanoindentation of HMX and Idoxuridine to Determine Mechanical Similarity

  • Alexandra C. Burch,
  • John D. Yeager and
  • David F. Bahr

1 November 2017

Assessing the mechanical behavior (elastic properties, plastic properties, and fracture phenomena) of molecular crystals is often complicated by the difficulty in preparing samples. Pharmaceuticals and energetic materials in particular are often used...

  • Article
  • Open Access
9 Citations
9,570 Views
10 Pages

31 October 2017

High resolution size exclusion chromatography (SEC) coupled with static light scattering (SLS) analyses were conducted to study the effect of the mobile phase ionic strength and protein concentration on the output of SEC experiments. The results high...

  • Article
  • Open Access
9 Citations
5,036 Views
9 Pages

Halogen and Hydrogen Bonding in Multicomponent Crystals of Tetrabromo-1H-Benzotriazole

  • Michele Baldrighi,
  • Pierangelo Metrangolo,
  • Tullio Pilati,
  • Giuseppe Resnati and
  • Giancarlo Terraneo

31 October 2017

4,5,6,7-Tetrabromo-1H-benzotriazole (TBBT) is still considered a reference inhibitor of casein kinase II (CK2), a valuable target for anticancer therapy, even though the poor solubility in water of this active pharmaceutical ingredient (API) has prev...

  • Article
  • Open Access
17 Citations
5,426 Views
12 Pages

31 October 2017

A wavelet-based finite element method (WFEM) is developed to calculate the elastic band structures of two-dimensional phononic crystals (2DPCs), which are composed of square lattices of solid cuboids in a solid matrix. In a unit cell, a new model of...

  • Review
  • Open Access
12 Citations
10,649 Views
13 Pages

29 October 2017

The formation mechanism of metastable crystals from metastable liquids still remains elusive, although controlling the metastability of crystals and liquids already plays a crucial role in designing new materials in physics, chemistry, biology, and m...

  • Communication
  • Open Access
3 Citations
5,824 Views
9 Pages

Crystallisation and Preliminary Crystallographic Analysis of Helicobacter pylori Periplasmic Binding Protein YckK

  • Mohammad Mizanur Rahman,
  • Daniel Phillip Germantsis,
  • Mayra Alejandra Machuca,
  • Abu Iftiaf Salah Ud-Din and
  • Anna Roujeinikova

29 October 2017

Helicobacter pylori infection can lead to the development of gastric and duodenal ulcers and gastric cancer. In recent years, the efficacy of the standard therapy has been falling, necessitating ongoing efforts to identify new drug targets. Due to th...

  • Communication
  • Open Access
14 Citations
4,943 Views
9 Pages

Tetrel, Chalcogen, and Charge-Assisted Hydrogen Bonds in 2-((2-Carboxy-1-(substituted)-2-hydroxyethyl)thio) Pyridin-1-ium Chlorides

  • Firudin I. Guseinov,
  • Mikhail F. Pistsov,
  • Eldar M. Movsumzade,
  • Leonid M. Kustov,
  • Victor A. Tafeenko,
  • Vladimir V. Chernyshev,
  • Atash V. Gurbanov,
  • Kamran T. Mahmudov and
  • Armando J. L. Pombeiro

28 October 2017

Reaction of 2-chloro-2-(diethoxymethyl)-3-substitutedoxirane or 1-chloro-1-(substituted) -3,3-diethoxypropan-2-one with pyridine-2-thiol in EtOH at 25 °C yields 3-(diethoxymethyl)-3-hydroxy-2-substituted-2,3-dihydrothiazolo[3,2-a]pyridin-4-ium chlori...

  • Article
  • Open Access
4 Citations
9,275 Views
12 Pages

High-Pressure Reactivity of Kr and F2—Stabilization of Krypton in the +4 Oxidation State

  • Dominik Kurzydłowski,
  • Magdalena Sołtysiak,
  • Aleksandra Dżoleva and
  • Patryk Zaleski-Ejgierd

28 October 2017

Since the synthesis of the first krypton compound, several other Kr-bearing connections have been obtained. However, in all of them krypton adopts the +2 oxidation state, in contrast to xenon which forms numerous compounds with an oxidation state as...

  • Article
  • Open Access
137 Citations
8,551 Views
19 Pages

High-Throughput Small-Molecule Crystallography at the ‘Belok’ Beamline of the Kurchatov Synchrotron Radiation Source: Transition Metal Complexes with Azomethine Ligands as a Case Study

  • Vladimir A. Lazarenko,
  • Pavel V. Dorovatovskii,
  • Yan V. Zubavichus,
  • Anatolii S. Burlov,
  • Yurii V. Koshchienko,
  • Valery G. Vlasenko and
  • Victor N. Khrustalev

28 October 2017

This paper concisely describes capabilities of the ‘Belok’ beamline at the Kurchatov synchrotron radiation source, related to high-throughput small-molecule X-ray crystallography. As case examples, a series of four novel transition metal complexes wi...

  • Review
  • Open Access
35 Citations
11,301 Views
39 Pages

Indentation Plasticity and Fracture Studies of Organic Crystals

  • Sowjanya Mannepalli and
  • Kiran S. R. N. Mangalampalli

27 October 2017

This review article summarizes the recent advances in measuring and understanding the indentation-induced plastic deformation and fracture behavior of single crystals of a wide variety of organic molecules and pharmaceutical compounds. The importance...

  • Article
  • Open Access
9 Citations
4,772 Views
13 Pages

26 October 2017

We investigate longitudinal near-field coupling between acoustic resonators grafted along a waveguide. Experiments are performed in the audible range with a simple acoustic system composed of a finite aperiodic sequence of air resonators. Transmissio...

  • Article
  • Open Access
7 Citations
4,145 Views
12 Pages

First-Principles Study of the Nonlinear Elasticity of Rare-Earth Hexaborides REB6 (RE = La, Ce)

  • Xianshi Zeng,
  • Yuanxiu Ye,
  • Shenlin Zou,
  • Qingdong Gou,
  • Yufeng Wen and
  • Ping Ou

25 October 2017

The complete set of independent second- and third-order elastic constants of rare-earth hexaborides LaB 6 and CeB 6 are determined by the combination method of first-principles calculations and homogeneous deformation theory. The grou...

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Crystals - ISSN 2073-4352