Crystals 2017, 7(11), 325; https://doi.org/10.3390/cryst7110325
High-Throughput Small-Molecule Crystallography at the ‘Belok’ Beamline of the Kurchatov Synchrotron Radiation Source: Transition Metal Complexes with Azomethine Ligands as a Case Study
Vladimir A. Lazarenko 1
, Pavel V. Dorovatovskii 1, Yan V. Zubavichus 1, Anatolii S. Burlov 2, Yurii V. Koshchienko 2, Valery G. Vlasenko 3 and Victor N. Khrustalev 4,*
, Pavel V. Dorovatovskii 1, Yan V. Zubavichus 1, Anatolii S. Burlov 2, Yurii V. Koshchienko 2, Valery G. Vlasenko 3 and Victor N. Khrustalev 4,*
1
National Research Center “Kurchatov Institute”, Moscow 123182, Russian Federation
2
Institute of Physical and Organic Chemistry of Southern Federal University, Rostov-on-Don 344090, Russian Federation
3
Institute of Physics of Southern Federal University, Rostov-on-Don 344090, Russian Federation
4
Peoples’ Friendship University of Russia (RUDN University), Moscow 117198, Russian Federation
*
Author to whom correspondence should be addressed.
Academic Editor: William Clegg
Received: 10 October 2017 / Revised: 19 October 2017 / Accepted: 24 October 2017 / Published: 28 October 2017
(This article belongs to the Special Issue Advances in Synchrotron Radiation Applications for Crystal Structure Studies)
Abstract
This paper concisely describes capabilities of the ‘Belok’ beamline at the Kurchatov synchrotron radiation source, related to high-throughput small-molecule X-ray crystallography. As case examples, a series of four novel transition metal complexes with azomethine ligands were selected. The complexes demonstrate somewhat unexpected changes in the coordination geometry and nuclearity in response to the introduction of substituents in the ligand’s periphery. View Full-TextKeywords:
Kurchatov synchrotron radiation source; transition metals; azomethine ligands; secondary interactions; crystal structure
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Lazarenko, V.A.; Dorovatovskii, P.V.; Zubavichus, Y.V.; Burlov, A.S.; Koshchienko, Y.V.; Vlasenko, V.G.; Khrustalev, V.N. High-Throughput Small-Molecule Crystallography at the ‘Belok’ Beamline of the Kurchatov Synchrotron Radiation Source: Transition Metal Complexes with Azomethine Ligands as a Case Study. Crystals 2017, 7, 325.
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