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Catalysts, Volume 3, Issue 4

December 2013 - 14 articles

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Articles (14)

  • Article
  • Open Access
13 Citations
7,928 Views
20 Pages

13 December 2013

In this work, the results of gas phase cyclohexane photocatalytic oxidative dehydrogenation on MoOx/SO4/TiO2 catalysts with DRIFTS analysis are presented. Analysis of products in the gas-phase discharge of a fixed bed photoreactor was coupled with in...

  • Article
  • Open Access
14 Citations
9,098 Views
12 Pages

Influence of Gold on Hydrotalcite-like Compound Catalysts for Toluene and CO Total Oxidation

  • Eric Genty,
  • Renaud Cousin,
  • Sylvie Capelle and
  • Stéphane Siffert

12 December 2013

X6Al2HT500 hydrotalcites, where X represents Mg, Fe, Cu or Zn were synthetized and investigated before and after gold deposition for toluene and CO total oxidation reactions. The samples have been characterized by specific areas, XRD measurements and...

  • Article
  • Open Access
47 Citations
28,883 Views
12 Pages

3 December 2013

A variety of primary alcohols and phenols were reacted with acetic anhydride at room temperature in the presence of sodium bicarbonate to produce corresponding esters in good to excellent yields. The acetylation of 4-nitrobenzyl alcohol was also carr...

  • Article
  • Open Access
3 Citations
7,277 Views
20 Pages

15 November 2013

Deconvolution of the evolved isobutene data obtained from temperature-programmed, low-pressure steady-state conversion of isobutane over HZSM-5 has yielded apparent activation energies for isobutane dehydrogenation, isobutene dimerization and desorp...

  • Review
  • Open Access
201 Citations
16,900 Views
12 Pages

15 November 2013

This short review paper shows the significance of recombination of a photoexcited electron and a hole in conduction and valence bands, respectively, of a titania photocatalyst, since recombination has not yet been fully understood and has not been ev...

  • Article
  • Open Access
22 Citations
9,792 Views
8 Pages

An Ionic Liquid Solution of Chitosan as Organocatalyst

  • Tatjana Heckel,
  • Dagny Dagmara Konieczna and
  • René Wilhelm

11 November 2013

Chitosan, which is derived from the biopolymer chitin, can be readily dissolved in different ionic liquids. The resulting homogeneous solutions were applied in an asymmetric Aldol reaction. Depending on the type of ionic liquid used, high asymmetric...

  • Article
  • Open Access
8 Citations
7,403 Views
12 Pages

Formic Acid Oxidation over Hierarchical Porous Carbon Containing PtPd Catalysts

  • Angélica M. Baena-Moncada,
  • Gustavo M. Morales,
  • Cesar Barbero,
  • Gabriel A. Planes,
  • Jonathan Florez-Montaño and
  • Elena Pastor

31 October 2013

The use of high surface monolithic carbon as support for catalysts offers important advantage, such as elimination of the ohmic drop originated in the interparticle contact and improved mass transport by ad-hoc pore design. Moreover, the approach dis...

  • Article
  • Open Access
13 Citations
7,211 Views
14 Pages

Palladium-Catalyzed Polyfluorophenylation of Porphyrins with Bis(polyfluorophenyl)zinc Reagents

  • Noriaki Sugita,
  • Satoshi Hayashi,
  • Sawa Ishii and
  • Toshikatsu Takanami

22 October 2013

A facile and efficient method for the synthesis of pentafluorophenyl- and related polyfluorophenyl-substituted porphyrins has been achieved via palladium-catalyzed cross-coupling reactions of brominated porphyrins with bis(polyfluorophenyl)zinc reag...

  • Review
  • Open Access
71 Citations
14,536 Views
25 Pages

Catalysts Supported on Carbon Materials for the Selective Hydrogenation of Citral

  • Esther Bailón-García,
  • Francisco J. Maldonado-Hódar,
  • Agustín F. Pérez-Cadenas and
  • Francisco Carrasco-Marín

22 October 2013

The heterogeneously catalyzed selective-hydrogenation of citral is one of the more feasible ways for obtaining its appreciated unsaturated-alcohols, nerol and geraniol, which are present in over 250 essential oils. Thus, citral has very recently come...

  • Review
  • Open Access
74 Citations
11,507 Views
24 Pages

Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

  • Weiguo Cheng,
  • Qian Su,
  • Jinquan Wang,
  • Jian Sun and
  • Flora T.T. Ng

22 October 2013

This review presents the synergistic effect in the catalytic system of ionic liquids (ILs) for the synthesis of cyclic carbonate from carbon dioxide and epoxide. The emphasis of this review is on three aspects: the catalytic system of metal-based ion...

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Catalysts - ISSN 2073-4344