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Palladium-Catalyzed Intermolecular Oxidative Amination of Alkenes with Amines, Using Molecular Oxygen as Terminal Oxidant

Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan
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Catalysts 2013, 3(4), 794-810; https://doi.org/10.3390/catal3040794
Received: 25 July 2013 / Revised: 29 September 2013 / Accepted: 8 October 2013 / Published: 16 October 2013
(This article belongs to the Special Issue Palladium Catalysts for Cross-Coupling Reaction)
In this review, we summarize recent progress from our group with regard to Pd-catalyzed oxidative amination of alkenes with amines. Intermolecular oxidative amination of alkenes with secondary anilines was induced using a palladium-complex catalyst combined with molybdovanadophosphate as a co-catalyst under dioxygen, leading to allylic amines and enamines in good yields with high selectivities. The reaction proceeded efficiently, using molecular oxygen as the terminal oxidant. In addition, palladium-catalyzed oxidative amination of alkenes with anilines as primary amines was achieved using molecular oxygen as the sole oxidant, producing (Z)-N-alkenyl-substituted anilines in high yields. View Full-Text
Keywords: amination; enamine; allylic amine; molybdovanadophosphate; oxidative coupling; alkenes amination; enamine; allylic amine; molybdovanadophosphate; oxidative coupling; alkenes
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Obora, Y.; Ishii, Y. Palladium-Catalyzed Intermolecular Oxidative Amination of Alkenes with Amines, Using Molecular Oxygen as Terminal Oxidant. Catalysts 2013, 3, 794-810.

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