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19 Results Found

  • Article
  • Open Access
25 Citations
4,612 Views
16 Pages

Broadband Dielectric Spectroscopy Study of Biobased Poly(alkylene 2,5-furanoate)s’ Molecular Dynamics

  • Michelina Soccio,
  • Daniel E. Martínez-Tong,
  • Giulia Guidotti,
  • Beatriz Robles-Hernández,
  • Andrea Munari,
  • Nadia Lotti and
  • Angel Alegria

16 June 2020

Poly(2,5-alkylene furanoate)s are bio-based, smart, and innovative polymers that are considered the most promising materials to replace oil-based plastics. These polymers can be synthesized using ecofriendly approaches, starting from renewable source...

  • Article
  • Open Access
1 Citations
868 Views
15 Pages

Eco-Friendly Membrane Separators Based on Furanoate Polymers for Li-Ion Batteries

  • Sofia Santi,
  • Luca Bargnesi,
  • Giulia Fredi,
  • Michelina Soccio,
  • Nadia Lotti,
  • Catia Arbizzani and
  • Andrea Dorigato

18 October 2025

Conventional lithium-ion battery separators made from petroleum-based polymers pose environmental concerns due to their non-renewable origin and energy-intensive production. Novel bio-based alternatives, such as poly(alkylene 2,5-furanoate)s (PAFs),...

  • Article
  • Open Access
35 Citations
4,375 Views
15 Pages

Block Copolyesters Containing 2,5-Furan and trans-1,4-Cyclohexane Subunits with Outstanding Gas Barrier Properties

  • Giulia Guidotti,
  • Laura Genovese,
  • Michelina Soccio,
  • Matteo Gigli,
  • Andrea Munari,
  • Valentina Siracusa and
  • Nadia Lotti

Biopolymers are gaining increasing importance as substitutes for plastics derived from fossil fuels, especially for packaging applications. In particular, furanoate-based polyesters appear as the most credible alternative due to their intriguing phys...

  • Article
  • Open Access
2 Citations
2,275 Views
18 Pages

Study on Impact of Monomers Towards High Molecular Weight Bio-Based Poly(ethylene Furanoate) via Solid State Polymerization Technique

  • Johan Stanley,
  • Eleftheria Xanthopoulou,
  • Margaritis Kostoglou,
  • Lidija Fras Zemljič,
  • Dimitra A. Lambropoulou and
  • Dimitrios N. Bikiaris

26 November 2024

In recent years, bio-based poly(ethylene furanoate) has gained the attention of packaging industries owing to its remarkable properties as a promising alternative to fossil-based polymers. It is necessary to synthesize high-molecular-weight polymers...

  • Article
  • Open Access
20 Citations
6,019 Views
26 Pages

Effect of Monomer Type on the Synthesis and Properties of Poly(Ethylene Furanoate)

  • Johan Stanley,
  • Zoi Terzopoulou,
  • Panagiotis A. Klonos,
  • Alexandra Zamboulis,
  • Eleftheria Xanthopoulou,
  • Savvas Koltsakidis,
  • Dimitrios Tzetzis,
  • Lidija Fras Zemljič,
  • Dimitra A. Lambropoulou and
  • Apostolos Kyritsis
  • + 2 authors

16 June 2023

This work aimed to produce bio-based poly(ethylene furanoate) (PEF) with a high molecular weight using 2,5-furan dicarboxylic acid (FDCA) or its derivative dimethyl 2,5-furan dicarboxylate (DMFD), targeting food packaging applications. The effect of...

  • Article
  • Open Access
41 Citations
6,606 Views
17 Pages

12 June 2020

Environmentally friendly polymer blends between post-consumer PET-G and bio-based poly(ethylene 2,5 furanoate) (PEF) have been prepared. The PET-G granules were obtained from the post-consumer glycol-modified poly(ethylene terephthalate) PET-G foils...

  • Feature Paper
  • Article
  • Open Access
20 Citations
4,319 Views
16 Pages

Towards High Molecular Weight Furan-Based Polyesters: Solid State Polymerization Study of Bio-Based Poly(Propylene Furanoate) and Poly(Butylene Furanoate)

  • Lazaros Papadopoulos,
  • Eleftheria Xanthopoulou,
  • George N. Nikolaidis,
  • Alexandra Zamboulis,
  • Dimitris S. Achilias,
  • George Z. Papageorgiou and
  • Dimitrios N. Bikiaris

30 October 2020

In the era of polymers from renewable resources, polyesters derived from 2,5 furan dicarboxylic acid (FDCA) have received increasing attention due to their outstanding features. To commercialize them, it is necessary to synthesize high molecular weig...

  • Article
  • Open Access
1,594 Views
14 Pages

2 October 2025

Polyethylene furanoate (PEF) and TritanTM copolyester are sustainable polyester polymers. PEF is made from biobased resources, whereas Tritan is mainly used for reusable food contact articles. Both polyesters are alternatives for polyethylene terepht...

  • Article
  • Open Access
1 Citations
925 Views
25 Pages

Ecofriendly PEF- and PBF-Based Blends with Epoxidized Natural Rubber: Unraveling the Structure–Property Relationship

  • Sandra Paszkiewicz,
  • Konrad Walkowiak,
  • Izabela Irska,
  • Jakub Śmigielski,
  • Elżbieta Piesowicz,
  • Aleksander Hejna,
  • Beata Dudziec and
  • Mateusz Barczewski

28 August 2025

Two series of environmentally friendly polymer blends of bio-based poly(ethylene 2,5 furanoate) (PEF) and poly(butylene 2,5 furanoate) (PBF) with epoxidized natural rubber (epNR) have been prepared. Both bio-based polyesters were synthesized from dim...

  • Review
  • Open Access
174 Citations
32,205 Views
32 Pages

The Road to Bring FDCA and PEF to the Market

  • Ed de Jong,
  • Hendrikus (Roy) A. Visser,
  • Ana Sousa Dias,
  • Clare Harvey and
  • Gert-Jan M. Gruter

26 February 2022

Biobased polymers and materials are desperately needed to replace fossil-based materials in the world’s transition to a more sustainable lifestyle. In this article, Avantium describes the path from invention towards commercialization of their Y...

  • Article
  • Open Access
981 Views
15 Pages

Synthesis of Lignocellulose-Based Poly(Butylene 3-Propyladipate-Co-Furanoate): Replacing Adipate

  • Ruijia Hu,
  • Weihao Li,
  • Xi Zhou,
  • Shunmin Yi,
  • Xingfu Zheng,
  • Qiufeng Mo and
  • Wanyu Liu

14 February 2025

A novel lignocellulose-based poly(butylene 3-propyladipate-co-furanoate) (PBApF) was synthesized from lignocellulose-derived 3-propyladipic acid (3PAA), 1,4-butanediol (BDO), and 2,5-furandicarboxylic acid (FDCA). The copolyesters were characterized...

  • Review
  • Open Access
406 Citations
60,215 Views
35 Pages

Bio-Based Packaging: Materials, Modifications, Industrial Applications and Sustainability

  • Corina L. Reichert,
  • Elodie Bugnicourt,
  • Maria-Beatrice Coltelli,
  • Patrizia Cinelli,
  • Andrea Lazzeri,
  • Ilaria Canesi,
  • Francesca Braca,
  • Belén Monje Martínez,
  • Rafael Alonso and
  • Lodovico Agostinis
  • + 11 authors

14 July 2020

Environmental impacts and consumer concerns have necessitated the study of bio-based materials as alternatives to petrochemicals for packaging applications. The purpose of this review is to summarize synthetic and non-synthetic materials feasible for...

  • Article
  • Open Access
25 Citations
6,763 Views
14 Pages

Poly(Ethylene Furanoate) along Its Life-Cycle from a Polycondensation Approach to High-Performance Yarn and Its Recyclate

  • Tim Höhnemann,
  • Mark Steinmann,
  • Stefan Schindler,
  • Martin Hoss,
  • Simon König,
  • Antje Ota,
  • Martin Dauner and
  • Michael R. Buchmeiser

23 February 2021

We report on the pilot scale synthesis and melt spinning of poly(ethylene furanoate) (PEF), a promising bio-based fiber polymer that can heave mechanical properties in the range of commercial poly(ethylene terephthalate) (PET) fibers. Catalyst optimi...

  • Article
  • Open Access
32 Citations
4,626 Views
22 Pages

Biobased Poly(ethylene furanoate) Polyester/TiO2 Supported Nanocomposites as Effective Photocatalysts for Anti-inflammatory/Analgesic Drugs

  • Anastasia Koltsakidou,
  • Zoi Terzopoulou,
  • George Z. Kyzas,
  • Dimitrios N. Bikiaris and
  • Dimitra A. Lambropoulou

4 February 2019

In the present study, polymer supported nanocomposites, consisting of bio-based poly(ethylene furanoate) polyester and TiO2 nanoparticles, were prepared and evaluated as effective photocatalysts for anti-inflammatory/analgesic drug removal. Nanocompo...

  • Article
  • Open Access
1 Citations
1,435 Views
20 Pages

Sustainable Production of 2,5-Furandicarboxylic Acid via Nickel-Based Heterogeneous Catalysis from 5-Hydroxymethylfurfural

  • Celso Luiz de Aquino Santos,
  • João Paulo Alves Silva,
  • Solange I. Mussatto and
  • Livia Melo Carneiro

26 June 2025

2,5-Furandicarboxylic acid (FDCA) is a bio-based platform chemical with high potential to replace terephthalic acid in polymer production, particularly for polyethylene furanoate (PEF), a biopolymer with superior thermal and barrier properties. This...

  • Article
  • Open Access
2,506 Views
25 Pages

Meltblow Processing of Poly (Ethylene Furanoate)–Bio-Based Polyester Nonwovens

  • Tim Hiller,
  • Hagen J. Altmann,
  • Iris Elser,
  • Mehdi Azimian and
  • Michael R. Buchmeiser

24 January 2025

Poly(ethylene furanoate) (PEF) has been identified as a bio-based alternative or supplement to poly(ethylene terephthalate) (PET) for various applications such as food packaging and bottles as well as technical- and high-performance fibers and yarns....

  • Article
  • Open Access
4 Citations
2,364 Views
18 Pages

Fabrication of Poly(ethylene furanoate)/Silver and Titanium Dioxide Nanocomposites with Improved Thermal and Antimicrobial Properties

  • Johan Stanley,
  • Eleftheria Xanthopoulou,
  • Lidija Fras Zemljič,
  • Panagiotis A. Klonos,
  • Apostolos Kyritsis,
  • Dimitra A. Lambropoulou and
  • Dimitrios N. Bikiaris

1 April 2024

Poly(ethylene furanoate) (PEF)-based nanocomposites were fabricated with silver (Ag) and titanium dioxide (TiO2) nanoparticles by the in-situ polymerization method. The importance of this research work is to extend the usage of PEF-based nanocomposit...

  • Review
  • Open Access
78 Citations
16,028 Views
26 Pages

Chemical Recycling of PET in the Presence of the Bio-Based Polymers, PLA, PHB and PEF: A Review

  • Mohammad Nahid Siddiqui,
  • Halim Hamid Redhwi,
  • Abdulrahman A. Al-Arfaj and
  • Dimitris S. Achilias

23 September 2021

The great increase in the production and consumption of plastics has resulted in large amounts of plastic wastes, creating a serious problem in terms of their environmentally friendly disposal. The need for the production of more environmentally frie...

  • Feature Paper
  • Article
  • Open Access
19 Citations
3,633 Views
23 Pages

Mechanical and Functional Properties of Novel Biobased Poly(decylene-2,5-furanoate)/Carbon Nanotubes Nanocomposite Films

  • Giulia Fredi,
  • Andrea Dorigato,
  • Mauro Bortolotti,
  • Alessandro Pegoretti and
  • Dimitrios N. Bikiaris

23 October 2020

The present work investigates the microstructural, thermo-mechanical, and electrical properties of a promising, but still not thoroughly studied, biobased polymer, i.e., poly(decylene furanoate) (PDeF), and its performance when multi-walled carbon na...