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Fuels, Volume 7, Issue 2 (June 2026) – 23 articles

Cover Story (view full-size image): The maritime industry’s transition towards low- and zero-carbon fuels is an essential step in achieving global decarbonization goals, but it also introduces new safety-related challenges. Alternative fuels possess distinct physical and chemical properties that require adapted risk assessment approaches. The Methodology for Alternative fuels Hazard Identification (MAHI) is a hybrid framework that combines established hazard identification and risk evaluation techniques to support the systematic assessment of emerging marine fuels. The methodology helps identify critical hazards, improve decision-making processes, and facilitate the safe and sustainable implementation of alternative fuels in maritime applications. View this paper
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10 pages, 932 KB  
Article
Effect of Gadolinium-Doped Ceria (GDC) Promoter on the Catalytic Activity of Ni/Al2O3 in Methane Dry Reforming
by Yang Li, Seyed Bahram Nourani Najafi, P. V. Aravind and Anatoli Mokhov
Fuels 2026, 7(2), 41; https://doi.org/10.3390/fuels7020041 - 17 Jun 2026
Viewed by 235
Abstract
Dry reforming of methane (DRM) is an attractive route for H2 production and simultaneous CO2 utilization, but its practical implementation is limited by catalyst deactivation. This study experimentally investigates the catalytic performance of Ni/Al2O3 and Gd-doped ceria-promoted Ni/GDC–Al [...] Read more.
Dry reforming of methane (DRM) is an attractive route for H2 production and simultaneous CO2 utilization, but its practical implementation is limited by catalyst deactivation. This study experimentally investigates the catalytic performance of Ni/Al2O3 and Gd-doped ceria-promoted Ni/GDC–Al2O3 catalysts for DRM in a fixed-bed quartz reactor over 400–800 °C at gas residence times of 0.1 s and 0.4 s. Increasing temperature and residence time enhanced CH4 and CO2 conversion as well as H2 and CO yields for both catalysts. The GDC-promoted catalyst exhibited markedly improved activity, achieving conversions and product yields at 0.1 s comparable to those of Ni/Al2O3 at 0.4 s and reaching complete CH4 conversion at about 650 °C, approximately 100 °C lower than the Ni/Al2O3 catalyst. Long-term testing at 650 °C showed stable catalytic behavior of the Ni/GDC–Al2O3 catalyst, while operational observations qualitatively suggested the absence of significant carbon deposition, consistent with equilibrium calculations. Full article
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14 pages, 1842 KB  
Article
Integrated Thermochemical Conversion of Plastics to Circular Refinery Feedstocks: A System-Level Analysis
by Maria Laura Mastellone
Fuels 2026, 7(2), 40; https://doi.org/10.3390/fuels7020040 - 17 Jun 2026
Viewed by 143
Abstract
Plastics pyrolysis is increasingly pursued as a pathway for producing circular hydrocarbon feedstocks for petrochemical integration. However, non-integrated reactor configurations often exhibit limited heat-transfer control, significant char-handling requirements, and variable product distributions. This work presents a system-level interpretation of the MLM-R™ process, an [...] Read more.
Plastics pyrolysis is increasingly pursued as a pathway for producing circular hydrocarbon feedstocks for petrochemical integration. However, non-integrated reactor configurations often exhibit limited heat-transfer control, significant char-handling requirements, and variable product distributions. This work presents a system-level interpretation of the MLM-R™ process, an integrated pyrolysis–combustion loop in which a circulating solid heat carrier enables continuous thermal supply through internal oxidation of carbonaceous residues. Material Flow Analysis (MFA) was applied to reconcile mass, elemental carbon, and chemical energy distributions across the defined process boundary. For the representative case study (1000 kg polyolefin basis), ~81% of feed carbon and ~83% of feed chemical energy (HHV basis) were recovered in the condensed liquid product, while ~7% of feed carbon was internally combusted to sustain autothermal operation. Simulated distillation analysis indicates that removal—aimed at further reprocessing—of a ~15 wt% C34+ heavy fraction from the pyrolysis vapor stream enables compliance with refinery-relevant boiling range targets (≥95% below 480 °C). The MFA results, supported by the physicochemical interpretation, suggest that integrated control of solids circulation and heat transfer contributes to product selectivity and process scalability in circular feedstock production. Full article
(This article belongs to the Special Issue Sustainability Assessment of Renewable Fuels Production)
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24 pages, 3238 KB  
Article
A Novel Permeability Evolution Model for Gas Flow in Coal Seams
by Ruguo Dong, Yongli Liu and Lixin Li
Fuels 2026, 7(2), 39; https://doi.org/10.3390/fuels7020039 - 13 Jun 2026
Viewed by 182
Abstract
The permeability of coal seams plays a critical role in the efficiency of coalbed methane extraction and gas disaster prevention. Traditional permeability models often overlook the anisotropic and dynamic evolution characteristics of coal under varying stress and gas adsorption conditions. This paper proposes [...] Read more.
The permeability of coal seams plays a critical role in the efficiency of coalbed methane extraction and gas disaster prevention. Traditional permeability models often overlook the anisotropic and dynamic evolution characteristics of coal under varying stress and gas adsorption conditions. This paper proposes a novel permeability evolution model that integrates the effects of effective stress variation and gas sorption-induced deformation on coal permeability. Starting from the concept of face porosity and utilizing a representative voxel approach, the model incorporates the anisotropy of mechanical parameters and adsorption expansion strain to derive the evolution of permeability in three dimensions. The model is validated against experimental permeability data from two distinct coal samples (Sulcis and Sydney), demonstrating its ability to accurately capture permeability changes under different boundary conditions. Furthermore, the concept of “internal expansion strain coefficient” is introduced to quantify the impact of adsorption-induced matrix deformation on permeability. The model provides a theoretical foundation for predicting gas flow behavior in coal seams under complex in-situ conditions and offers significant insights into the optimization of gas extraction strategies. Full article
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20 pages, 1040 KB  
Article
Long-Term Storage Stability: Density of Jet A and Camelina Biodiesel Blends for UAV Micro-Turbojet Applications
by Anca-Iuliana Dumitru, Sibel Osman, Grigore Cican, Bartosz Ciupek and Łukasz Brodzik
Fuels 2026, 7(2), 38; https://doi.org/10.3390/fuels7020038 - 12 Jun 2026
Viewed by 259
Abstract
This study evaluates the impact of long-term storage on aviation fuel blends composed of Jet A and camelina-derived biodiesel. The physicochemical properties of the pure biodiesel were assessed according to EN 14214 and ASTM D6751 standards, while the resulting Jet A–biodiesel blends were [...] Read more.
This study evaluates the impact of long-term storage on aviation fuel blends composed of Jet A and camelina-derived biodiesel. The physicochemical properties of the pure biodiesel were assessed according to EN 14214 and ASTM D6751 standards, while the resulting Jet A–biodiesel blends were evaluated against ASTM D1655 aviation fuel specifications. Particular attention was given to the evolution of density during storage as an indicator of fuel stability. The results show that camelina methyl esters exhibit generally satisfactory physicochemical characteristics; however, the iodine value remains a critical limitation. The measured value of approximately 155 significantly exceeds the maximum limit of 120 established by European standards, reflecting the high degree of unsaturation of the feedstock. Long-term monitoring of the blends revealed a clear relationship between biodiesel concentration and the rate of fuel degradation. Increasing the biodiesel fraction led to more pronounced variations in density during storage, indicating reduced stability of the fuel system. Consequently, instability risks increase proportionally with the biodiesel-to-Jet A ratio, highlighting the need for appropriate storage strategies and technological optimization when considering higher concentrations of camelina-derived biodiesel in aviation fuel blends. Full article
(This article belongs to the Special Issue Sustainable Jet Fuels from Bio-Based Resources)
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28 pages, 20347 KB  
Review
Green Hydrogen in Integrated Multi-Energy Systems: Technological Pathways, Policy and Market Perspectives, and the Role of Artificial Intelligence
by Hassan Niazi, Kamran Taghizad-Tavana, Ali Esmaeel Nezhad, Afshin Canani, Mehrdad Tarafdar Hagh and Pouya Paidar
Fuels 2026, 7(2), 37; https://doi.org/10.3390/fuels7020037 - 12 Jun 2026
Viewed by 303
Abstract
Green hydrogen is increasingly discussed as an energy carrier that can link electricity, gas, heat, and transport sectors. However, many existing reviews address this topic from separate viewpoints, such as hydrogen production technologies, Artificial Intelligence (AI) applications, or system integration, with less attention [...] Read more.
Green hydrogen is increasingly discussed as an energy carrier that can link electricity, gas, heat, and transport sectors. However, many existing reviews address this topic from separate viewpoints, such as hydrogen production technologies, Artificial Intelligence (AI) applications, or system integration, with less attention to how policy and market conditions affect deployment. This review brings these related aspects together in one structured discussion. The paper first reviews the hydrogen supply chain, including production, storage, transport, and utilization. It then discusses an integrated multi-energy architecture in which hydrogen interacts with electricity, natural gas, heat, and cooling networks. Policy instruments in five major economies, including the European Union, the United States, China, Japan, and India, are compared. The review also summarizes the main barriers to large-scale deployment, including high production costs, limited infrastructure, technological challenges, regulatory uncertainty, and supply-chain constraints. In addition, the current market structure and selected large-scale hydrogen projects planned in the United States are reviewed. The paper also examines the role of artificial intelligence in green hydrogen systems. AI applications are grouped into four main stages of the hydrogen value chain: forecasting renewable energy generation, improving electrolyzer design and operation, optimizing storage and distribution, and supporting system-level techno-economic assessment. Recent Machine Learning (ML) studies are compared based on their methods and their contributions to operation and planning. Overall, this review highlights the role of AI in enabling green hydrogen integration within multi-energy systems. Full article
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16 pages, 973 KB  
Article
Microbial Dynamics in Two-Stage Anaerobic Digester Integrating ADM1 Simulation with Functional Microbial Kinetics for Food Waste Valorization
by Jasim Al Shehihi and Nitin Raut
Fuels 2026, 7(2), 36; https://doi.org/10.3390/fuels7020036 - 8 Jun 2026
Viewed by 226
Abstract
Two-Stage Anaerobic Digesters (TSADs) have emerged as an effective strategy for improving the stability and efficiency of biogas production from high-strength substrates such as food waste. The separation of acidogenic and methanogenic phases enables better environmental control for distinct microbial communities, thereby enhancing [...] Read more.
Two-Stage Anaerobic Digesters (TSADs) have emerged as an effective strategy for improving the stability and efficiency of biogas production from high-strength substrates such as food waste. The separation of acidogenic and methanogenic phases enables better environmental control for distinct microbial communities, thereby enhancing methane yield and reducing process instability. This study investigates the dynamics of microbial populations of acidogens, acetogens, and methanogens in a TSAD using an extended Anaerobic Digester Model No. 1 framework incorporating stage-specific microbial growth kinetics. Simulation scenarios were performed across a range of operational parameters, including OLR (1–8 kg VS/m3 day), pH (5.0–8.0), temperature (35 °C and 45 °C), and HRT (10–30 days). The results demonstrate that balanced microbial population dynamics and syntrophic interactions strongly influence methane production and overall digester performance. Optimal methane yields were achieved within an OLR range of 3.5–4.5 kg VS/m3 day under mesophilic conditions. Elevated loading rates led to VFA accumulation and pH decline, resulting in the inhibition of methanogenic populations and reduced methane output. Preliminary parametric analysis suggests that the acetoclastic methanogen growth rate and ammonia inhibition constants are influential parameters affecting system performance. The findings highlight the importance of integrating microbial population dynamics into AD models to enhance predictive accuracy and support the development of intelligent control strategies for sustainable waste-to-energy systems. Full article
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17 pages, 11980 KB  
Article
Effect and Analysis of Mixed Non-Ionic Surfactants on Viscosity Reduction in Heavy Oil
by Rui Liu, Kang Liu, Meiming He, Mingqi Sun, Yuxuan Yang and Wanfen Pu
Fuels 2026, 7(2), 35; https://doi.org/10.3390/fuels7020035 - 8 Jun 2026
Viewed by 236
Abstract
This study investigates improving the flowability of heavy crude oil using non-ionic surfactants that modify interfacial properties, thereby enhancing emulsification and dispersion. A mixture of Span 85 (HLB = 1.8) and Tween 20 (HLB = 16.7) was selected to meet the affinity requirements [...] Read more.
This study investigates improving the flowability of heavy crude oil using non-ionic surfactants that modify interfacial properties, thereby enhancing emulsification and dispersion. A mixture of Span 85 (HLB = 1.8) and Tween 20 (HLB = 16.7) was selected to meet the affinity requirements of both oil and water phases. Experiments were conducted on five different densities of heavy crude oil, evaluating viscosity reduction, emulsion droplet size distribution, and interfacial tension. Notably, this work presents the first systematic examination of interactions between various heavy crude oil densities and mixed emulsifiers. Results show that aligning the HLB value of the mixed emulsifier with that of the heavy crude oil enhances electrostatic repulsion between droplets, reducing droplet size and optimizing surfactant arrangement at the interface. The optimal HLB value for viscosity reduction was determined to be 8.0, at which a viscosity reduction rate of over 89% was achieved for high-density heavy crude oil. A quantitative relationship between emulsion droplet size and viscosity reduction rate was also established, leading to improved emulsion stability and significant viscosity reduction. These findings provide a theoretical framework for applying non-ionic mixed surfactants to enhance heavy crude oil flowability, and deliver experimental data to support field applications in petroleum engineering. Full article
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21 pages, 717 KB  
Article
Renewable Energy Convergence and Global Fuel Transition Regimes: Evidence from Heterogeneous Energy Systems
by Constantinos Katrakylidis and Dimitrios Dimitriadis
Fuels 2026, 7(2), 34; https://doi.org/10.3390/fuels7020034 - 30 May 2026
Viewed by 220
Abstract
This study investigates whether countries converge toward common long-run paths in renewable energy consumption and examines the implications for global fuel transition dynamics. Using a balanced panel of 108 countries over the period 1990–2022, we implement an integrated econometric framework that combines stochastic [...] Read more.
This study investigates whether countries converge toward common long-run paths in renewable energy consumption and examines the implications for global fuel transition dynamics. Using a balanced panel of 108 countries over the period 1990–2022, we implement an integrated econometric framework that combines stochastic convergence tests, β- and σ-convergence analysis, the Phillips–Sul club convergence methodology, ordered logit modelling, and heterogeneous panel causality tests. The results reject global stochastic convergence, indicating that countries do not share a common transition trajectory. However, evidence of β- and σ-convergence suggests the presence of partial and bounded catch-up dynamics. The Phillips–Sul approach identifies four distinct convergence regimes, implying multiple steady-state equilibria in global energy systems. Structural analysis shows that income and governance quality increase the probability of belonging to higher-renewable-energy regimes, while carbon intensity constrains upward transitions. Regime-specific causality results further reveal that the drivers of renewable energy dynamics differ across structural contexts. Overall, the findings demonstrate that global energy transitions are characterized by persistent heterogeneity and regime-dependent adjustment processes rather than uniform convergence. This study contributes by integrating convergence analysis with structural modelling and regime-based interpretation, offering a more comprehensive framework for understanding differentiated decarbonization pathways. The results carry important policy implications, highlighting that effective energy transition strategies must be tailored to regime-specific conditions rather than relying on uniform policy approaches. Full article
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18 pages, 4627 KB  
Article
Experimental Study on Water Injection Removal of Ammonium Chloride Particles to Enhance Hydrotreatment Air Cooler Reliability
by Xiaofei Liu, Xin Chen, Zhengwei Zhang, Huayu Wen, Dongbo Chen, Haoyu Yin, Haozhe Jin, Chao Wang and Lite Zhang
Fuels 2026, 7(2), 33; https://doi.org/10.3390/fuels7020033 - 15 May 2026
Viewed by 472
Abstract
Hydrotreatment is vital for producing high-quality liquid fuels in petroleum refining and its air coolers are critical components prone to severe corrosion under high-temperature and high-pressure conditions. Ammonium salts from NH3-HCl and NH3-H2S reactions, particularly ammonium chloride [...] Read more.
Hydrotreatment is vital for producing high-quality liquid fuels in petroleum refining and its air coolers are critical components prone to severe corrosion under high-temperature and high-pressure conditions. Ammonium salts from NH3-HCl and NH3-H2S reactions, particularly ammonium chloride precipitated during cooling, readily deposit on tube surfaces. Strong temperature gradients and complex flow conditions may severely affect air cooler inlets and front sections. To enhance the refining process reliability, an experimental setup was established to investigate the water injection removal of ammonium chloride particle deposits in air cooler tube bundles. Results show that water injection effectively removes ammonium chloride particles. Particle size has a minor influence, whereas inlet velocity, temperature, and water injection rate significantly affect removal efficiency. Increasing inlet velocity from 2 to 5 m/s, temperature from 80 to 110 °C, and water injection rate all enhance removal efficiency. Furthermore, differences between two-row tubes were also observed: the second-row tube exhibits a higher removal ratio due to liquid film formation, which increases Reynolds number and shear force, thereby enhancing dissolution. These findings provide experimental support for optimizing water injection strategies to mitigate corrosion, improving hydrotreatment unit reliability and safety, ensuring the continuous operation of the petroleum and fuel processing industry. Full article
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15 pages, 1539 KB  
Article
Study on the Impact of Naphtha and Light Fuel Oil on Key Quality Indicators of Gasoline and Diesel
by Wang Yubin, Tang Lingjun, Jiang Luxin, Li Zhengbing and Chen Lei
Fuels 2026, 7(2), 32; https://doi.org/10.3390/fuels7020032 - 14 May 2026
Viewed by 368
Abstract
The blending of naphtha and light fuel oil with gasoline and diesel during pipeline batch transportation poses risks of quality non-compliance. This study experimentally investigates the impact of these contaminants on key quality indicators to establish quantitative blending thresholds. Based on a volume-gradient [...] Read more.
The blending of naphtha and light fuel oil with gasoline and diesel during pipeline batch transportation poses risks of quality non-compliance. This study experimentally investigates the impact of these contaminants on key quality indicators to establish quantitative blending thresholds. Based on a volume-gradient experimental design (0–50 vol% for naphtha, 0–15 vol% for light fuel oil), diesel blends were tested for pour point, flash point, and 95% recovery temperature, while gasoline blends were tested for final boiling point, all in accordance with Chinese national standards. Results demonstrate that light fuel oil contamination in gasoline causes a linear increase in the final boiling point (y = 18.77x + 185.09, R2 = 0.91), exceeding the 205 °C limit at concentrations above 1.2 vol%. Naphtha contamination in diesel leads to a sharp linear decline in flash point (y = −13.20x + 101.83, R2 = 0.84), falling below the 60 °C threshold at concentrations above 3.0 vol%. Diesel pour point increases linearly with light fuel oil concentration (y = 0.39x − 26.41, R2 = 0.88) but remains within specification up to 15 vol%. These quantitative thresholds, derived from statistically significant regression models, provide a scientific basis for optimizing cut-point strategies and mitigating safety risks in product oil pipeline operations. Full article
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40 pages, 5496 KB  
Article
Hybrid Methodology for Alternative Fuels Risk Assessment
by José Miguel Mahía-Prados, Ignacio Arias-Fernández, Manuel Romero Gómez and Sandrina Pereira
Fuels 2026, 7(2), 31; https://doi.org/10.3390/fuels7020031 - 13 May 2026
Viewed by 553
Abstract
The transition towards alternative marine fuels introduces new safety challenges related to onboard storage, distribution, and fuel management, due to the markedly different physical and chemical properties of methane, methanol, ammonia, and hydrogen. While numerous studies address the risks of individual fuels, there [...] Read more.
The transition towards alternative marine fuels introduces new safety challenges related to onboard storage, distribution, and fuel management, due to the markedly different physical and chemical properties of methane, methanol, ammonia, and hydrogen. While numerous studies address the risks of individual fuels, there is a lack of structured and comparable risk-assessment methodologies to support early-stage fuel selection and preliminary system design under a unified framework. This study introduces the Methodology to Alternative-fuels Hazardous Identification, a hybrid framework that integrates HAZOP-based deviation analysis with HAZID-style risk classification to enable a consistent qualitative–quantitative comparison of alternative marine fuel systems. The methodology is applied to representative storage and distribution architectures for methane, methanol, ammonia, compressed hydrogen, and liquefied hydrogen, allowing the identification of dominant risk drivers and system-level vulnerabilities across fuel options. The results reveal distinct fuel-specific risk profiles. Methane and methanol are mainly associated with moderate risks linked to operational temperature deviations and system controllability. Ammonia exhibits the most severe risk profile due to the high consequences of toxic releases, particularly under pressure-related failures. Compressed hydrogen is dominated by high-risk scenarios driven by extreme storage pressures, while liquefied hydrogen presents a mixed profile governed by the interaction between cryogenic temperature control and pressure regulation. By providing a comparative and scalable risk-assessment framework, the Methodology to Alternative-fuels Hazardous Identification (MAHI) supports informed decision-making in early design phases and complements existing regulatory safety analyses, contributing to a safer energy transition in maritime transport. Full article
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14 pages, 4929 KB  
Article
Weld Seam Failure Analysis of a Natural Gas Pipeline Reducer: Implications for Oil and Gas Transportation Safety
by Kangkai Xu, Peng Wang, Shuai Wang, Shuyi Xie and Bohong Wang
Fuels 2026, 7(2), 30; https://doi.org/10.3390/fuels7020030 - 6 May 2026
Viewed by 511
Abstract
Ensuring the integrity of weld seams in pipeline components is critical for the safe and reliable transportation of oil and natural gas. This paper presents a systematic failure investigation of a cracked weld in a reducer located at a natural gas transmission station [...] Read more.
Ensuring the integrity of weld seams in pipeline components is critical for the safe and reliable transportation of oil and natural gas. This paper presents a systematic failure investigation of a cracked weld in a reducer located at a natural gas transmission station in Western China, aiming to identify the failure mechanism and assess its implications for pipeline safety management. A comprehensive analysis was conducted using macroscopic examination, chemical composition analysis, mechanical property testing, metallographic observation, and microscopic fracture characterization. The results reveal that the heat-affected zone (HAZ) exhibited abnormally high hardness (up to 588 HV0.1), indicating insufficient toughness that made it susceptible to cracking. The base metal showed a high carbon equivalent (CEV), placing it in the “difficult-to-weld” category and increasing its sensitivity to improper welding thermal cycles. On-site investigation further identified significant deficiencies in welding process control, including inadequate preheating, improper interpass temperature management, and insufficient post-weld heat treatment (PWHT). These deficiencies allowed welding residual stresses to persist and failed to mitigate the hardened HAZ microstructure. The combination of poor material weldability and inadequate on-site welding practices ultimately led to brittle fracture under service conditions. This failure highlights a critical vulnerability in pipeline transportation infrastructure and underscores the necessity of strict adherence to qualified welding procedures for high-carbon-equivalent steels. The findings provide practical guidance for enhancing welding quality control and ensuring the long-term operational safety of natural gas pipeline systems. Full article
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30 pages, 5292 KB  
Article
Study on the Mixture Patterns and Dynamic Growth Rate of Sequential Transport of Refined Oil and Liquid Ammonia Based on Their Low Solubility Characteristics
by Jiong Wang, Zihan Wang, Gang Liu and Lei Chen
Fuels 2026, 7(2), 29; https://doi.org/10.3390/fuels7020029 - 5 May 2026
Viewed by 288
Abstract
Ammonia, as a hydrogen carrier and clean fuel, has an increasingly urgent demand for large-scale transportation. Utilizing the existing refined oil pipeline network for sequential transportation of ammonia and refined oil is an economically and efficiently feasible solution. However, the unique micro-solubility characteristics [...] Read more.
Ammonia, as a hydrogen carrier and clean fuel, has an increasingly urgent demand for large-scale transportation. Utilizing the existing refined oil pipeline network for sequential transportation of ammonia and refined oil is an economically and efficiently feasible solution. However, the unique micro-solubility characteristics of ammonia and refined oil can cause significant differences in the mixing mechanism of the two substances during sequential transportation in the pipeline compared to traditional oil products. This study conducts transient flow numerical simulation and mechanism research on the mixing problem during the sequential transportation process of ammonia and refined oil under the influence of micro-solubility transfer. Using the ANSYS Fluent platform and combining it with the dynamic mesh technology, a sequential transportation pipeline model was constructed. In the VOF multiphase flow model framework, the Fick diffusion and convective transfer theories were coupled. Through the development of user-defined functions, a transfer model was established to describe the ammonia dissolution process in refined oil during sequential transportation. This model characterizes the axial transfer process of the two-phase flow and the dissolution transfer in the pipeline. Then, the correctness and accuracy of the transfer model were verified, proving that the model has reliable simulation capabilities. To evaluate the comprehensive influence of various engineering factors on the mixing law, this study selected seven key parameters. It then designed and simulated multiple sets of comparative conditions. The influence of each parameter on the development of the mixing section was analyzed, and a sensitivity analysis was conducted. Subsequently, using the growth rate of the mixing length (dL/dt) as the dependent variable to represent the dynamic development of the mixing process, and using the above seven parameters as independent variables, a semi-empirical fitting formula was established. This formula can comprehensively reflect the coupling effect of multiple factors. The results show that the model has good generalization ability and extrapolation robustness. It provides a prediction model and theoretical tool with certain engineering practical value. This can be used for predicting the amount of mixing and optimizing operating parameters in actual pipeline sequential transportation systems. Full article
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21 pages, 898 KB  
Article
The Modelling and Optimization of a Sustainable Biofuel Supply Chain from Pomegranate Agricultural Waste
by Vidhi Saini, Anubhav Pratap Singh, Anand Chauhan, Ankit Agrawal and Vinay Kumar
Fuels 2026, 7(2), 28; https://doi.org/10.3390/fuels7020028 - 5 May 2026
Cited by 1 | Viewed by 3183
Abstract
The growing demand for energy and emerging environmental concerns are making it necessary to look for more sustainable alternatives. To address the limitations of first-generation biofuels and reduce dependence on fossil fuels, this study focuses on second-generation bioethanol sourced from non-edible pomegranate waste. [...] Read more.
The growing demand for energy and emerging environmental concerns are making it necessary to look for more sustainable alternatives. To address the limitations of first-generation biofuels and reduce dependence on fossil fuels, this study focuses on second-generation bioethanol sourced from non-edible pomegranate waste. This study develops and analyses a supply chain optimization model for the sustainable production of biofuel from pomegranate waste and solves it using a genetic algorithm. The framework assesses key supply chain elements, including collection centres for pomegranate waste, processing plants, bio-refineries for conversion and distribution centres for final bioethanol. The primary objective of the optimization is to reduce the total cost of the biofuel production system and to maximize positive environmental impact through waste valorization. A numerical example validates the framework, and a sensitivity analysis further evaluates the economic viability of the supply chain under fluctuating market conditions, such as variations in the purchasing cost of waste, the production cost of bioethanol and the opening cost of plants. Biofuel production supports the Sustainable Development Goals (SDG-12 and -13) by transforming waste into renewable energy. This study aims to address gaps in biofuel research by focusing on the underutilized area of pomegranate-based biofuel through an integrated supply chain optimization framework. The findings offer practical values for researchers working on renewable energy solutions, policymakers and business leaders. Full article
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15 pages, 30322 KB  
Article
Co-Hydrothermal Carbonization of Cacao (Theobroma cacao) Shells with LDPE: Hydrochar Characterization, Comparative Pyrolytic Kinetic Study, and Thermodynamic Property Determination
by Mariane Fe A. Abesamis, Alec Paolo V. Dy Pico, Rosanne May E. Marilag, Javinel P. Servano, Queenee Mosera M. Ibrahim, Cymae O. Oguis, Alexander Jr. Q. Bello, Kenth Michael U. Uy, Joevin Mar B. Tumongha, Rodel D. Guerrero, Ralf Ruffel M. Abarca and Alexander O. Mosqueda
Fuels 2026, 7(2), 27; https://doi.org/10.3390/fuels7020027 - 24 Apr 2026
Viewed by 748
Abstract
In the Philippines’ agricultural setup, pre-harvest cacao (Theobroma cacao) fruits are wrapped with low-density polyethylene (LDPE) for moisture retention and damage protection. Responding to the growing concern for its waste volume and scarcity of treatment, this research explores the co-hydrothermal carbonization [...] Read more.
In the Philippines’ agricultural setup, pre-harvest cacao (Theobroma cacao) fruits are wrapped with low-density polyethylene (LDPE) for moisture retention and damage protection. Responding to the growing concern for its waste volume and scarcity of treatment, this research explores the co-hydrothermal carbonization (co-HTC) of cacao shells (CS) and LDPE as a method to convert agricultural waste with plastic into hydrochar for potential energy applications. Thus, observations on the thermal, physicochemical, and morphological changes from feedstocks to hydrochar are carried out. Optimal conditions of 200 °C for 60 min resulted in hydrochar with 21.11 MJ/kg and appreciable thermal properties. SEM micrographs show that hydrochar had increased surface area, a good fuel characteristic, and surface flaking on oversized LDPE film, suggesting relative LDPE degradation. EDX analysis reveals C, K, Ca, and Zn metals that affect chemical pathways. FTIR analysis further supports chemical synergy by preservation of functional groups innate from both parent materials. Kinetic and thermal evolutions are also investigated to reveal the influence of pretreatment on the stability of cacao shell-dominated hydrochar and the effectivity of biomass integration to facilitate relatively easier cracking of LDPE. The findings support co-HTC as a viable technology to enhance the circular economy by valorizing LDPE and cacao shells while promoting energy recovery and solid fuel production. Full article
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18 pages, 974 KB  
Article
Physicochemical and Energy Properties of Charcoal Briquettes Obtained from Pequi (Caryocar brasiliense Camb.) Shells Without Binders: Influence of Moisture Content and Carbonization Temperature
by Bárbara Lôpo de Lima, Antonio José Vinha Zanuncio, Fernando Colen, Talita Baldin, Edy Eime Pereira Baraúna, Marina Donária Chaves Arantes, Alfredo Napoli, Amelia Guimarães Carvalho, Lorena dos Santos Almeida Silva, Eliane Favalessa, Shoraia Germani Winter, Felipe Gomes da Silva and Maria Auxiliadora Drumond
Fuels 2026, 7(2), 26; https://doi.org/10.3390/fuels7020026 - 22 Apr 2026
Viewed by 813
Abstract
Bioenergy production from agro-industrial waste has the potential to contribute to climate change mitigation. In Brazil, the pequi (Caryocar brasiliense Camb.) production chain makes an economic, environmental, and social contribution. However, the collection and processing of the fruit produce large amounts of [...] Read more.
Bioenergy production from agro-industrial waste has the potential to contribute to climate change mitigation. In Brazil, the pequi (Caryocar brasiliense Camb.) production chain makes an economic, environmental, and social contribution. However, the collection and processing of the fruit produce large amounts of waste, such as the peel, whose improper disposal leads to significant environmental impacts. This study evaluated how moisture and carbonization temperature influence the energy properties of charcoal briquettes made from pequi peel waste. Carbonization was performed at two final temperatures (360 °C/480 °C) with a heating rate of 1.5 °C min−1 and residence times of 4 h and 5 h 20 min, respectively. Carbonization yields were calculated based on dry mass. Briquettes were produced from pequi peel at moisture contents of 5%, 7.5%, and 10% (wet basis). After carbonization, the charcoal briquette samples were characterized by proximate analysis, higher heating value (HHV), bulk density, energy density, and mechanical durability. Carbonization temperature exerted a more pronounced effect on the properties of the carbonized briquettes than the initial moisture content. Carbonization at 480 °C increased the fixed carbon content (76.38%, 74.25%, and 75.10% for treatments 1, 2, and 3) and the HHV (25.10–25.31 MJ kg−1), while reducing the gravimetric yield (32.84–33.25%). The influence of moisture content was more evident in carbonizations carried out at 360 °C, indicating a temperature-dependent interaction. The use of pequi peel for solid biofuel production promotes the valorization of agro-industrial residues and supports strategies aimed at the circular bioeconomy and the decarbonization of the energy matrix. Full article
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18 pages, 3349 KB  
Article
Study on Enhanced Coalbed Methane Desorption Characteristics of Hydraulic Fracturing Combined with Hot Water Injection
by Xu Zheng, Bing Liang, Weiji Sun, Zhuang Li, Zipeng Wei and Yan Li
Fuels 2026, 7(2), 25; https://doi.org/10.3390/fuels7020025 - 20 Apr 2026
Viewed by 589
Abstract
To investigate the synergistic effect of hydraulic fracturing and hot water injection on enhancing methane extraction from low-permeability coalbeds and elucidate the underlying thermal-hydraulic coupling mechanism, methane desorption experiments were conducted in coal samples with varying fracture networks using a self-developed multi-field coupling [...] Read more.
To investigate the synergistic effect of hydraulic fracturing and hot water injection on enhancing methane extraction from low-permeability coalbeds and elucidate the underlying thermal-hydraulic coupling mechanism, methane desorption experiments were conducted in coal samples with varying fracture networks using a self-developed multi-field coupling experimental system. Tests were performed under different injection pressures and temperatures to analyze coal temperature evolution and methane desorption-seepage characteristics. The results demonstrate that hydraulic fracturing significantly improves pore structure and connectivity, thereby optimizing methane desorption behavior. The methane migration in the samples is influenced by water injection, exhibiting an initial promotion followed by inhibition. The combined fracturing-thermal injection approach effectively reduces the dynamic viscosity of water, mitigates the water lock effect, and enhances the desorption capacity. The hydraulic fracturing and the hot water injection complement each other, achieving synergistic production enhancement. The optimal injection pressure and water temperature can be selected according to specific reservoir conditions to balance the production increase and cost efficiency. This laboratory-scale study provides theoretical support for optimizing hydraulic measures and thermal injection techniques in coalbed methane extraction, revealing complementary synergies between these two methods and offering new insights into multi-field coupling enhancement mechanisms with practical application guidelines. Full article
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17 pages, 6839 KB  
Article
Numerical Investigation of Jatropha and Castor Biofuel Droplet Evaporation at High Engine Operating Conditions
by Ali Raza, Marva Hadia, Zunaira Tu Zehra, Sajjad Miran, Muhammad Khurram and Ghulam Murtaza
Fuels 2026, 7(2), 24; https://doi.org/10.3390/fuels7020024 - 14 Apr 2026
Viewed by 821
Abstract
Fossil fuel depletion has increased interest in renewable alternatives such as biodiesel derived from non-edible plant oils. Droplet evaporation is a key process influencing fuel–air mixing and combustion efficiency in diesel engines. In this study, the evaporation characteristics of diesel and two non-edible [...] Read more.
Fossil fuel depletion has increased interest in renewable alternatives such as biodiesel derived from non-edible plant oils. Droplet evaporation is a key process influencing fuel–air mixing and combustion efficiency in diesel engines. In this study, the evaporation characteristics of diesel and two non-edible biofuels, Jatropha and Castor, are investigated using computational fluid dynamics (CFD) under high-temperature and high-pressure conditions representative of engine environments. The numerical model incorporates the conservation equations of mass, momentum, and energy, together with the kε turbulence model and a discrete phase model to simulate droplet heating, motion, and mass transfer during evaporation. A comparative CFD analysis is performed to examine how fuel properties, ambient temperature, and droplet size affect the evaporation behaviour of diesel, Jatropha, and Castor droplets under identical engine-like conditions. The evolution of droplet diameter, temperature, velocity, and lifetime is analysed, and the applicability of the classical D2-law is evaluated under different operating conditions. The results indicate that biofuel droplets generally evaporate faster than diesel droplets at lower temperatures, while evaporation trends become similar at higher temperatures. These findings provide insight into the evaporation behaviour of Jatropha and Castor fuels and their potential application in diesel engines. Full article
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20 pages, 881 KB  
Article
Characterization of Residual Woody Biomass for the Production of Densified Solid Biofuels and Their Local Utilization
by Mario Morales-Máximo, Ramiro Gudiño-Macedo, José Guadalupe Rutiaga-Quiñones, Juan Carlos Coral-Huacuz, Luis Fernando Pintor-Ibarra, Luis Bernardo López-Sosa and Víctor Manuel Ruíz-García
Fuels 2026, 7(2), 23; https://doi.org/10.3390/fuels7020023 - 10 Apr 2026
Viewed by 1050
Abstract
The energy utilization of residual woody biomass is a relevant strategy for the decentralized energy transition and local waste management in rural areas. The objective of this study was to characterize (physically, chemically, and energetically) five types of residual biomass: pine branches, huinumo [...] Read more.
The energy utilization of residual woody biomass is a relevant strategy for the decentralized energy transition and local waste management in rural areas. The objective of this study was to characterize (physically, chemically, and energetically) five types of residual biomass: pine branches, huinumo (this material refers to the long, thin pine needles that, after drying and falling, form a layer on the forest floor), cherry branches and leaves, and grass waste generated in the community of San Francisco Pichátaro, Michoacán, Mexico, in order to evaluate its viability for the production of densified solid biofuels. A comprehensive analysis was conducted, including moisture content, higher heating value, proximate characterization, structural chemical analysis (using the Van Soest method), elemental CHONS analysis, ash microanalysis (by ICP-OES), and a multicriteria analysis with normalized energy and compositional indicators. The results showed that huinumo and cherry leaves were the most outstanding biomasses, presenting the highest heating values (20.7 MJ/kg) and low moisture and ash contents. Pine branches obtained the most balanced results, characterized by their equilibrium in fixed carbon and lignin, as well as their low potassium content. The multicriteria analysis showed that there is no absolute optimal biomass; however, it indicates that pine branches and huinumo are the most robust feedstocks for the production of briquettes or pellets. The results confirm the significant technical and environmental potential of local lignocellulosic residues for the production of solid biofuels and for contributing to sustainable energy solutions at the local scale. Full article
(This article belongs to the Special Issue Biofuels and Bioenergy: New Advances and Challenges)
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25 pages, 4161 KB  
Article
Experimental Assessment of Combustion Performance and Emission Characteristics of Ethanol–Jet A1 Blends in a Turboprop Engine for UAV Applications
by Maria Căldărar, Mădălin Dombrovschi, Tiberius-Florian Frigioescu, Gabriel-Petre Badea, Laurentiu Ceatra and Răzvan Roman
Fuels 2026, 7(2), 22; https://doi.org/10.3390/fuels7020022 - 9 Apr 2026
Cited by 2 | Viewed by 1025
Abstract
The increasing need to reduce reliance on fossil-derived aviation fuels and mitigate environmental impacts has intensified research into renewable alternatives for aviation energy systems. The growing interest in ethanol-based fuels is primarily driven by their simple oxygen-rich molecular structure and advantageous physicochemical characteristics, [...] Read more.
The increasing need to reduce reliance on fossil-derived aviation fuels and mitigate environmental impacts has intensified research into renewable alternatives for aviation energy systems. The growing interest in ethanol-based fuels is primarily driven by their simple oxygen-rich molecular structure and advantageous physicochemical characteristics, yet experimental studies examining their application in hybrid power architectures, including micro-turboprop engine-based power sources, are still limited. This study presents an experimental investigation of ethanol–Jet A1 fuel blends used in a micro-turboprop engine operating as a power generation unit for unmanned aerial vehicle applications. Ethanol was blended with Jet A1 at volumetric fractions of 10%, 20% and 30% and the engine was tested under multiple operating regimes corresponding to different electrical power outputs. Exhaust gas temperature, electrical power output and gaseous emissions (CO and NOx) were measured for each operating condition. The results indicate that low ethanol fractions (E10) provide performance comparable to neat kerosene, while higher ethanol fractions lead to a reduction in exhaust gas temperature at low-power regimes due to the lower heating value and high latent heat of vaporization of ethanol. Emission measurements showed a decrease in NOx emissions with increasing ethanol content, associated with lower combustion temperatures, while CO emissions increased at low-power regimes due to incomplete combustion under lean conditions. Additionally, combustion instability was observed during rapid transitions from maximum to idle regime operation for higher ethanol blends, attributed to transient ultra-lean mixtures, evaporative cooling, and reduced reaction rates. The results demonstrate that ethanol–kerosene blends can be used in micro-turboprop systems at low blend ratios without major performance penalties, but transient operating conditions impose stability limits that must be considered in practical UAV power system applications. Full article
(This article belongs to the Special Issue Sustainable Jet Fuels from Bio-Based Resources)
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21 pages, 1713 KB  
Article
Mechanistic Modeling of TEG Dehydrator Emissions in Oil and Gas Industry
by Jacob Mdigo, Arthur Santos, Gerald Duggan, Prajay Vora, Kira Shonkwiler and Daniel Zimmerle
Fuels 2026, 7(2), 21; https://doi.org/10.3390/fuels7020021 - 7 Apr 2026
Viewed by 954
Abstract
This work presents a mechanistic modeling approach for simulating methane emissions from triethylene glycol (TEG) dehydrators used in oil & gas (O&G) operations. The model was developed as a modular component of the Mechanistic Air Emissions Simulator (MAES) tool, incorporating species-specific absorption and [...] Read more.
This work presents a mechanistic modeling approach for simulating methane emissions from triethylene glycol (TEG) dehydrators used in oil & gas (O&G) operations. The model was developed as a modular component of the Mechanistic Air Emissions Simulator (MAES) tool, incorporating species-specific absorption and emission dynamics through two-level, second-order polynomial regression (PR) models trained on ProMax simulation data: (1) species-level regression models that track the transfer rates of individual gas species within the dehydrator unit streams, and (2) outlet flow stream regression models that predict the fraction of inlet gas distributed among the outlet streams of the dehydrator unit. These behaviors were characterized over a range of glycol circulation ratios, wet gas pressures, and temperatures. The model was validated using root mean square error (RMSE) analysis. The species-level PR achieved low root mean square error (RMSE) values (<0.03) for light hydrocarbon species across all dehydrator components, ranging from 0.0009 for methane to 0.029 for normal pentane. Similarly, the outlet-level PR yielded RMSE values below 0.002 for the dry gas fraction, 0.001 for the flash tank fraction, and 0.002 for the still vent fraction, demonstrating strong agreement between predicted and reference ProMax values. When deployed at field facilities, the model significantly improved MAES-simulated dehydrator emissions, revealing that gas-assisted glycol pump emissions are the dominant contributors to both dehydrator-level and site-level methane emissions under uncontrolled conditions. Further analysis of the 154 dehydrator units reported by operators under the AMI 2024 project showed that 54 units (31%) used gas-driven glycol pumps, of which 6 units (11%) operated with uncontrolled flash tanks, and 22 units (40.7%) were identified as potentially oversized. Of the six dehydrator units with uncontrolled gas-assisted pumps, pump emissions accounted for 90.25% of total dehydrator emissions and 63.10% of total site-level emissions. These findings highlight substantial opportunities for emissions mitigation through equipment upgrades. Full article
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22 pages, 5194 KB  
Article
Linking Sandpack Tests and CFD: How Vibration-Induced Permeability Heterogeneity Shapes Waterflood Sweep and Oil Recovery
by Zhengyuan Zhang, Shixuan Lu, Liming Dai and Na Jia
Fuels 2026, 7(2), 20; https://doi.org/10.3390/fuels7020020 - 26 Mar 2026
Viewed by 663
Abstract
Vibration-assisted water flooding (VA-WF) can improve sweep efficiency. However, unclear macro-scale mechanisms limit its wider adoption in heavy oil reservoirs. This study combines previous sandpack experiments with two-dimensional Volume-of-Fluid (VOF) simulations to show how vibrations reshape permeability fields and, in turn, pressure and [...] Read more.
Vibration-assisted water flooding (VA-WF) can improve sweep efficiency. However, unclear macro-scale mechanisms limit its wider adoption in heavy oil reservoirs. This study combines previous sandpack experiments with two-dimensional Volume-of-Fluid (VOF) simulations to show how vibrations reshape permeability fields and, in turn, pressure and production behaviour. Heavy oil sandpacks were water-flooded under conditions of no vibration and 2 Hz and 5 Hz axial excitation. Measured injection pressure histories and oil production were used to calibrate a VOF model in which absolute permeability follows a log-normal distribution with directional anisotropy. Only when axial and radial permeabilities were assigned a negative local correlation did the model reproduce key observations: secondary pressure spikes, irregular viscous-fingering morphologies, delayed production drops, and variability in cumulative recovery. Parameter sweeps quantify the sensitivity of VA-WF performance to the variance and correlation of the permeability field, and multiple runs estimate the variability in outcomes introduced by stochastic heterogeneity. This study proposes a transferable workflow—comprising sample testing, parameter inference, and probabilistic simulation—to screen excitation conditions and forecast VA-WF performance prior to field implementation, enabling operators to optimize vibration frequency based on reservoir-specific permeability characteristics and to anticipate production variability under uncertainty. These results highlight the dominant factors affecting swept volume and oil recovery, supporting data-driven decision making in VA-WF projects. Full article
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22 pages, 1170 KB  
Article
Analysis of Methods for Reducing Fuel Consumption in Shipping, Taking into Account Applicable Legal Regulations
by Cezary Behrendt, Włodzimierz Kamiński and Oleh Klyus
Fuels 2026, 7(2), 19; https://doi.org/10.3390/fuels7020019 - 25 Mar 2026
Viewed by 904
Abstract
The International Maritime Organization’s (IMO) greenhouse gas (GHG) strategy aims for a 40% reduction in carbon intensity by 2030 and a 70% reduction by 2050, relative to 2008 levels. Attainment of these objectives necessitates an integrated strategy encompassing technological advancements, operational optimization, and [...] Read more.
The International Maritime Organization’s (IMO) greenhouse gas (GHG) strategy aims for a 40% reduction in carbon intensity by 2030 and a 70% reduction by 2050, relative to 2008 levels. Attainment of these objectives necessitates an integrated strategy encompassing technological advancements, operational optimization, and the adoption of innovative practices to curtail fuel consumption and enhance vessel performance. The Ship Energy Efficiency Management Plan (SEEMP), mandated by MEPC 62 in 2011, establishes a systematic framework for the continual enhancement of energy efficiency. SEEMP is intrinsically associated with reductions in fuel consumption, enabling maritime organizations to systematically monitor and control energy performance via the Energy Efficiency Operational Indicator (EEOI). This metric enables operators to assess operational energy performance and implement measures such as optimized voyage planning and fuel-saving technologies. However, the effectiveness of SEEMP varies widely across companies and vessel types, often due to limited crew awareness. To enhance daily implementation, it is essential to improve crew training and streamline SEEMP documentation. Simplifying SEEMP structures within ship management companies can further facilitate usability and compliance. By focusing on these areas, the maritime industry can better align with IMO’s GHG reduction targets and promote more sustainable operations and fuel-saving technologies. Full article
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