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Proceedings, 2020, NanoFIS 2020

4th International Conference nanoFIS 2020 - Functional Integrated nanoSystems

Digital Event| 2–4 November 2020

Volume Editors:
Anton Köck, Materials Center Leoben Forschung GmbH (MCL), Austria
Marco Deluca, Materials Center Leoben Forschung GmbH (MCL), Austria

Number of Papers: 44
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Cover Story (view full-size image): This volume comprises papers presented at the 4th International Conference nanoFIS 2020—Functional Integrated nanoSystems, held from 2nd to 4th November 2020. Due to the COVID-19 pandemic [...] Read more.
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1 pages, 125 KiB  
Abstract
Ablative Laser Structuring for Stretchable Multilayer and Multi-Material Electronics and Sensor Systems
by Simon P. Stier and Holger Böse
Proceedings 2020, 56(1), 21; https://doi.org/10.3390/proceedings2020056021 - 17 Dec 2020
Viewed by 1093
Abstract
Conventional machining and shaping processes for polymers and elastomers such as injection molding exhibit significant disadvantages, as specific tools have to be manufactured, the method of machining is highly dependent on the material properties, and the cost of automation is usually high. Therefore, [...] Read more.
Conventional machining and shaping processes for polymers and elastomers such as injection molding exhibit significant disadvantages, as specific tools have to be manufactured, the method of machining is highly dependent on the material properties, and the cost of automation is usually high. Therefore, additive manufacturing processes (3D printing) have established themselves as an alternative. This eliminates the expensive production of tools and the production is individualized. However, the specific (additive) manufacturing process remains highly dependent on the properties of the material. These processes include selective laser sintering (SLS) for powdered thermoplastic polymers and metals, extrusion such as fused deposition modeling (FDM) for thermoplastic polymers in wire form, or optical curing such as digital light processing (DLP) for liquid resins. Especially for elastomer sensors or circuit boards (structure of several alternately constituted approx. 100 µm-thick elastomer films made with different types of liquid silicone rubber), there is no suitable additive manufacturing process that combines liquid, partly non-transparent source materials, multi-component printing, and very fine layer thicknesses. In order to enable a largely automated, computer-aided manufacturing process, we have developed the concept of ablative multilayer and multi-material laser-assisted manufacturing. Here, the layers (conductive and non-conductive elastomers, as well as metal layers for contacting) are first coated over the entire surface (e.g., spray, dip, or doctor blade coating, as well as galvanic coating) and then selectively removed with a CO2 or fiber laser. These steps are repeated several times to achieve a multi-layer structured design. Is it not only possible to adjust and improve the work previously carried out manually, but also to introduce completely new concepts, such as fine through-plating between the layers to enable much more compact structures to be possible. As an exemplary application, we have used the process for manufacturing a thin and surface solderable pressure sensor and a stretchable circuit board. Full article
1 pages, 121 KiB  
Abstract
Electronic Multiscale Hybrid Materials: Sinter-Free Inks, Printed Transparent Grids, and Soft Devices
by Tobias Kraus
Proceedings 2020, 56(1), 24; https://doi.org/10.3390/proceedings2020056024 - 18 Dec 2020
Viewed by 1160
Abstract
Hybrid electronic materials combine the excellent electronic properties of metals and semiconductors with the mechanical flexibility, ease of processing, and optical transparency of polymers. This talk will discuss hybrids that combine organic and inorganic components at different scales. Metallic and semiconductor nanoparticle cores [...] Read more.
Hybrid electronic materials combine the excellent electronic properties of metals and semiconductors with the mechanical flexibility, ease of processing, and optical transparency of polymers. This talk will discuss hybrids that combine organic and inorganic components at different scales. Metallic and semiconductor nanoparticle cores are coated with conductive polymer shells to create “hybrid inks” that can be inkjet-printed and form conductive leads without any sintering step. Transparent electrodes are printed using ultrathin metal nanowires with core diameters below 2 nm. The chemically synthesized wires spontaneously form percolating structures when patterned with a soft stamp; this rapidly yields optically transparent grid electrodes, even on demanding soft substrates. These new hybrid electronic materials enable the fabrication of soft electronics, including flexible sensors on polymer foils, radio-frequency identification (RFID) antennae on cardboard, and soft human–machine interfaces. Selected devices will be covered at the end of the talk. Full article

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3 pages, 493 KiB  
Proceeding Paper
Functionalisation of Multi-Layer Graphene-Based Gas Sensor by Au Nanoparticles
by Laura Morelli, Filiberto Ricciardella, Max Koole, Stefan Persijn and Sten Vollebregt
Proceedings 2020, 56(1), 1; https://doi.org/10.3390/proceedings2020056001 - 7 Dec 2020
Cited by 1 | Viewed by 1624
Abstract
A novel gas sensor based on multi-layered graphene (MLG) functionalised with gold nanoparticles (Au-NPs) is presented. We demonstrate for the first time that: (1) the signal saturates during the analyte exposure, something which does not occur in the pristine material and in graphene-based [...] Read more.
A novel gas sensor based on multi-layered graphene (MLG) functionalised with gold nanoparticles (Au-NPs) is presented. We demonstrate for the first time that: (1) the signal saturates during the analyte exposure, something which does not occur in the pristine material and in graphene-based gas sensors in general; (2) the sign of the device current response is inverted. MLG is grown by chemical vapour deposition on pre-patterned CMOS-compatible Mo catalyst. The sensor is fabricated directly on the growth substrate, without any transfer of MLG. The Au-NPs are later deposited from an aerosol on the sensor at a specific controlled location, mitigating any additional patterning steps. The functionalised sensor is tested with 1 ppm (part-per-million) of NO2 at room temperature. Full article
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3 pages, 620 KiB  
Proceeding Paper
Functionalized SnO2 Sensors on Flexible Substrate for Ammonia Detection at Low Temperature
by Jean-Paul Viricelle, Mohamad Hijazi, Valérie Stambouli, Omar Kassem, Mohamed Saadaoui, Mathilde Rieu and Christophe Pijolat
Proceedings 2020, 56(1), 2; https://doi.org/10.3390/proceedings2020056002 - 7 Dec 2020
Viewed by 1361
Abstract
Ammonia detection at ambient with low-cost sensors is a challenge for various applications like breath analysis and agriculture. Such a challenge can be reached with functionalized SnO2 based gas sensors using silanization by 3-aminopropyltriethoxysilane (APTES) as an intermediate step before grafting with [...] Read more.
Ammonia detection at ambient with low-cost sensors is a challenge for various applications like breath analysis and agriculture. Such a challenge can be reached with functionalized SnO2 based gas sensors using silanization by 3-aminopropyltriethoxysilane (APTES) as an intermediate step before grafting with functional end group providing selectivity for the target gas. Moreover, operation at room temperature gives the opportunity to develop a sensor on a plastic substrate entirely manufactured by inkjet technology, by developing suitable inks, in particular to obtain SnO2 sensing element. Full article
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2 pages, 348 KiB  
Proceeding Paper
Miniaturized Thermal Acoustic Gas Sensor Based on a CMOS Microhotplate and MEMS Microphone
by Richard Hopper, Daniel Popa, Vasileios Tsoutsouras, Florin Udrea and Phillip Stanley-Marbell
Proceedings 2020, 56(1), 3; https://doi.org/10.3390/proceedings2020056003 - 7 Dec 2020
Viewed by 1505
Abstract
In this work, we present a novel thermal acoustic gas sensor, fabricated using a CMOS microhotplate and MEMS microphone. The sensing mechanism is based on the detection of changes in the thermal acoustic conversion efficiency which is dependent on the physical properties of [...] Read more.
In this work, we present a novel thermal acoustic gas sensor, fabricated using a CMOS microhotplate and MEMS microphone. The sensing mechanism is based on the detection of changes in the thermal acoustic conversion efficiency which is dependent on the physical properties of the gas. The gas sensor has all the benefits of CMOS technology, including low cost and miniaturization. Here, we demonstrate its application for CO2 gas detection. Full article
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2 pages, 176 KiB  
Extended Abstract
Superconducting Nanowire Devices for Light Detection at the Single-Photon Level
by Stephan Steinhauer, Samuel Gyger, Ali W. Elshaari, Julien Zichi, Iman Esmaeil Zadeh, Jin Chang, Johannes W. N. Los, Nima Kalhor, Sander Dorenbos and Val Zwiller
Proceedings 2020, 56(1), 4; https://doi.org/10.3390/proceedings2020056004 - 8 Dec 2020
Viewed by 1133
Abstract
Superconducting nanowire single photon detectors (SNSPDs) have become a mature technology for single-photon detection with excellent performance [...] Full article
3 pages, 341 KiB  
Extended Abstract
ChipScope Symposium: Novel Approaches for a Chip-Sized Optical Microscope
by Angel Diéguez, Steffen Bornemann, Katarzyna Kluczyk-Korch, Kateryna Trofymchuk, Viktorija Glembockyte and Stefan Schrittwieser
Proceedings 2020, 56(1), 5; https://doi.org/10.3390/proceedings2020056005 - 9 Dec 2020
Viewed by 1202
Abstract
In the Chipscope project funded by the EU, a completely new strategy towards optical microscopy is explored by a team of researchers from different European institutions. In this workshop, the different researchers of the project will explain the last advances obtained in the [...] Read more.
In the Chipscope project funded by the EU, a completely new strategy towards optical microscopy is explored by a team of researchers from different European institutions. In this workshop, the different researchers of the project will explain the last advances obtained in the project, presenting the microscopes, how light emission is produced, and the detection principles and simulations. Full article
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2 pages, 578 KiB  
Proceeding Paper
An Embedded, Low-Power, Wireless NO2 Gas-Sensing Platform Based on a Single-Walled Carbon Nanotube Transducer
by Stefan Nedelcu, Sebastian Eberle, Cosmin Roman and Christofer Hierold
Proceedings 2020, 56(1), 6; https://doi.org/10.3390/proceedings2020056006 - 10 Dec 2020
Cited by 1 | Viewed by 1214
Abstract
This work proposes a portable, software-defined NO2-sensing platform, which is able to acquire currents ranging from nA to µA from a Single-Walled Carbon Nanotube (SWCNT) gas sensor. It includes an embedded software that steers the system allowing dynamical adjustments of the [...] Read more.
This work proposes a portable, software-defined NO2-sensing platform, which is able to acquire currents ranging from nA to µA from a Single-Walled Carbon Nanotube (SWCNT) gas sensor. It includes an embedded software that steers the system allowing dynamical adjustments of the SWCNT bias levels, measurement range, sampling rate and of measurement time intervals. Further, the embedded functions can post-process the measurement results, log data on an SD card or send data via a wireless connection. Full article
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3 pages, 320 KiB  
Proceeding Paper
Current Perspectives for Autonomous Sensor Nodes
by Marco Deluca and Anton Köck
Proceedings 2020, 56(1), 7; https://doi.org/10.3390/proceedings2020056007 - 10 Dec 2020
Cited by 1 | Viewed by 1230
Abstract
The current technological trends associated with Industry 4.0 and the Internet of Things (IoT) require an interconnected network of sensor nodes providing distributed information on the environment to enable intelligent action to be taken by control systems. Such sensors need to be wireless, [...] Read more.
The current technological trends associated with Industry 4.0 and the Internet of Things (IoT) require an interconnected network of sensor nodes providing distributed information on the environment to enable intelligent action to be taken by control systems. Such sensors need to be wireless, self-powered and energy independent. In this work we provide an overview of possible strategies to realize a positive energy balance in autonomous sensor nodes without the use of batteries. We will first overview different sensors in terms of power consumption. We will then concentrate on energy harvesting and storage, showing state-of-the-art possibilities in both cases. Full article
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3 pages, 411 KiB  
Proceeding Paper
Transparent Wearable Sensor for Early Extravasation Detection
by Hsuan-Chin Lu and Ying-Chih Liao
Proceedings 2020, 56(1), 8; https://doi.org/10.3390/proceedings2020056008 - 10 Dec 2020
Cited by 1 | Viewed by 1274
Abstract
In this work, we present a wearable sensor patch for the early detection of extravasation by using a simple, direct printing process. Interdigitated electrodes are printed on a flexible film, which can be attached to skin. The electrodes are integrated with a top [...] Read more.
In this work, we present a wearable sensor patch for the early detection of extravasation by using a simple, direct printing process. Interdigitated electrodes are printed on a flexible film, which can be attached to skin. The electrodes are integrated with a top electrode to form a flexible pressure-sensing device utilizing an electrical contact resistance (ECR) variation mechanism. The detector possesses good sensitivity and a low detection limit for pressure variation. By adjusting the printing parameters, sensors of millimeter size can be fabricated and allow the potential for multiple detection points in a large area. In addition, by using silver nanowire inks, the sensor becomes nearly transparent to prevent patients’ panic. The possibility and feasibility of this device for early extravasation detection is also evaluated. Full article
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3 pages, 934 KiB  
Proceeding Paper
Chemical Solution Deposition of BaxSr1-xTiO3 Thin Films for Energy Storage Applications
by Federica Benes, Mirela Dragomir, Barbara Malič and Marco Deluca
Proceedings 2020, 56(1), 9; https://doi.org/10.3390/proceedings2020056009 - 10 Dec 2020
Cited by 1 | Viewed by 1228
Abstract
Highly textured Ba0.5Sr0.5TiO3 and Ba0.6Sr0.4TiO3 thin films have been successfully processed using chemical solution deposition (CSD) techniques and annealed at different temperatures to investigate the [...] Read more.
Highly textured Ba0.5Sr0.5TiO3 and Ba0.6Sr0.4TiO3 thin films have been successfully processed using chemical solution deposition (CSD) techniques and annealed at different temperatures to investigate the influence on crystal growth. Microstructure and texture have been evaluated using SEM and XRD techniques. The films showed a homogeneous thickness of ~120 nm and the grain growth seemed to be highly influenced by the annealing temperature. Moreover, by tuning the deposition and annealing conditions, an almost epitaxial growth of Ba0.6Sr0.4TiO3 on the platinized silicon substrate has been achieved. Nevertheless, the samples showed severe cracking due to the strain imposed by the substrate or due to the growing direction. Full article
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3 pages, 951 KiB  
Proceeding Paper
Light-Free Cross-Talk Analysis of a CMOS Infrared Detector Array
by Ying Dai, Syed Zeeshan Ali, Richard Hopper, Claudio Falco, Daniel Popa and Florin Udrea
Proceedings 2020, 56(1), 10; https://doi.org/10.3390/proceedings2020056010 - 10 Dec 2020
Viewed by 1182
Abstract
Low-cost infrared (IR) thermal cameras are powering a rising market of industrial and consumer applications. Complementary metal-oxide-semiconductor (CMOS)-based thermopile arrays are proven thermal imagers that can be monolithically integrated into low-cost and low-power-consumption formats for high-volume manufacturability. Here we present a simple method [...] Read more.
Low-cost infrared (IR) thermal cameras are powering a rising market of industrial and consumer applications. Complementary metal-oxide-semiconductor (CMOS)-based thermopile arrays are proven thermal imagers that can be monolithically integrated into low-cost and low-power-consumption formats for high-volume manufacturability. Here we present a simple method to evaluate the cross-talk of these arrays and propose a numerical model for device optimization. Full article
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2 pages, 267 KiB  
Proceeding Paper
Solidly Mounted Resonator (SMR) Sensors for Biomedical Applications
by Siavash Esfahani, Jan Peter Specht, George Jolly, Marina Cole and Julian W. Gardner
Proceedings 2020, 56(1), 11; https://doi.org/10.3390/proceedings2020056011 - 10 Dec 2020
Cited by 1 | Viewed by 1505
Abstract
Biosensors play a key role in medical diagnostics, and acoustic wave technology such as solidly mounted resonators (SMRs) applied to this field is one of the latest developments with great potential. This study seeks to explore the potential application of SMRs to detect [...] Read more.
Biosensors play a key role in medical diagnostics, and acoustic wave technology such as solidly mounted resonators (SMRs) applied to this field is one of the latest developments with great potential. This study seeks to explore the potential application of SMRs to detect and quantify prostate-specific antigen (PSA) for the screening and diagnosis of prostate cancer. The primary results show promising frequency shift of SMR sensors coated with Polydimethylsiloxane (PDMS) to different liquids. The SMR frequency is 1.082, 1.084 and 1.088 GHz, respectively, to air, deionized water and toluene (liquid) presence. These sensors have great potential as an accurate, low-cost method for measuring PSA and biomarkers for cancer and other diseases. Full article
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3 pages, 398 KiB  
Proceeding Paper
Phase-Modulated Standing Wave Interferometer
by Ingo Ortlepp, Eberhard Manske, Jens-Peter Zöllner and Ivo W. Rangelow
Proceedings 2020, 56(1), 12; https://doi.org/10.3390/proceedings2020056012 - 10 Dec 2020
Cited by 2 | Viewed by 1156
Abstract
Standing wave interferometers (SWIs) show enormous potential for miniaturization because of their simple linear optical set-up, consisting only of a laser source, a measuring mirror and two standing wave sensors for obtaining quadrature signals. To reduce optical influences on the standing wave and [...] Read more.
Standing wave interferometers (SWIs) show enormous potential for miniaturization because of their simple linear optical set-up, consisting only of a laser source, a measuring mirror and two standing wave sensors for obtaining quadrature signals. To reduce optical influences on the standing wave and avoid the need for an exact and long-term stable sensor-to-sensor distance, a single-sensor set-up was developed with a phase modulation by forced oscillation of the measuring mirror. When the correct modulation stroke is applied, the harmonics in the sensor signal can be used for obtaining quadrature signals for phase demodulation and direction discrimination. Full article
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3 pages, 478 KiB  
Proceeding Paper
Fabrication of Diamond Membranes by Femtosecond Laser Ablation for MEMS Sensor Applications
by Johann Zehetner, Alexander Kromka, Tibor Izsák, Gabriel Vanko, Lenka Gajdošová and Stephan Kasemann
Proceedings 2020, 56(1), 13; https://doi.org/10.3390/proceedings2020056013 - 10 Dec 2020
Viewed by 1290
Abstract
We present the feasibility in fabricating membranes and cantilevers made of diamond grown on Si/SiO2 substrates by femtosecond laser ablation. In the ablation process, we generated nano- and microstructures on the membrane surface. Such laser-induced periodic surface structures (LIPSS) are useful in [...] Read more.
We present the feasibility in fabricating membranes and cantilevers made of diamond grown on Si/SiO2 substrates by femtosecond laser ablation. In the ablation process, we generated nano- and microstructures on the membrane surface. Such laser-induced periodic surface structures (LIPSS) are useful in tailoring the surface chemistry. In combination with wet or reactive ion etching, smooth membranes were generated. Full article
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3 pages, 546 KiB  
Proceeding Paper
Bottom-Up Metal/Oxide/Bi2Te3 Heterostructures for Enhanced Thermoelectric Properties
by Zhenhua Wu and Zhiyu Hu
Proceedings 2020, 56(1), 14; https://doi.org/10.3390/proceedings2020056014 - 14 Dec 2020
Viewed by 1135
Abstract
In this paper, metals’ (Cu, Ag, Au)/Al2O3/Bi2Te3 heterostructures have been fabricated to synergistically optimize their carrier concentration and mobility, thereby enhancing their thermoelectric power factor. Metal can be alloyed with Bi2Te3 to reduce [...] Read more.
In this paper, metals’ (Cu, Ag, Au)/Al2O3/Bi2Te3 heterostructures have been fabricated to synergistically optimize their carrier concentration and mobility, thereby enhancing their thermoelectric power factor. Metal can be alloyed with Bi2Te3 to reduce the electron concentration. The introduction of the oxide layer further reduces the electron concentration and leads to an increase in mobility. By adjusting the metal and oxide layer, it is possible to realize the simultaneous optimization of electric conductivity and the Seebeck coefficient. This work will enable the optimal and novel design of heterstructures for thermoelectric materials with further improved performance. Full article
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2 pages, 1156 KiB  
Extended Abstract
Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticle Composites
by Bendix Ketelsen, Patrick P. Tjarks, Ying-Chih Liao and Tobias Vossmeyer
Proceedings 2020, 56(1), 15; https://doi.org/10.3390/proceedings2020056015 - 14 Dec 2020
Viewed by 1104
Abstract
Functional composite nanomaterials are promising candidates for the fabrication of wearable, flexible chemiresistive sensors which can be used [...] Full article
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3 pages, 419 KiB  
Proceeding Paper
Modelling of Evanescent Field Scattering
by Andreas Tortschanoff, Marcus Baumgart and Jaka Pribošek
Proceedings 2020, 56(1), 16; https://doi.org/10.3390/proceedings2020056016 - 14 Dec 2020
Cited by 1 | Viewed by 1232
Abstract
Evanescent field particle scattering is a promising method for single particle detection. In this study, we performed a detailed numerical analysis to show the possibilities and limitations of analytical models for predicting the capabilities of this sensing mechanism. Full article
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2 pages, 569 KiB  
Extended Abstract
Towards Nanomaterials-Based Biocompatible and Biodegradable Strain Sensors for Healthcare and Medical Applications
by Shin-Da Wu, Bendix Ketelsen, Shan-hui Hsu and Tobias Vossmeyer
Proceedings 2020, 56(1), 17; https://doi.org/10.3390/proceedings2020056017 - 14 Dec 2020
Cited by 1 | Viewed by 1173
Abstract
Green electronics is an emerging environment-friendly process of the design and manufacture [...] Full article
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2 pages, 186 KiB  
Proceeding Paper
Vacuum Packaging Requirements for MEMS and Characterization Techniques
by Luca Mauri, Anna Della Porta, Alessio Corazza and Marco Moraja
Proceedings 2020, 56(1), 18; https://doi.org/10.3390/proceedings2020056018 - 15 Dec 2020
Cited by 1 | Viewed by 1657
Abstract
Getter materials are technically proven and industrially well-implemented solutions for maintaining a vacuum inside electronic devices to assure long lifetimes and proper operating conditions. The pressure requirements of some hermetically packaged microelectromechanical systems (MEMS) devices, such as gyroscopes, accelerometers, infrared (IR) bolometers, and [...] Read more.
Getter materials are technically proven and industrially well-implemented solutions for maintaining a vacuum inside electronic devices to assure long lifetimes and proper operating conditions. The pressure requirements of some hermetically packaged microelectromechanical systems (MEMS) devices, such as gyroscopes, accelerometers, infrared (IR) bolometers, and digital mirrors, are very stringent. The internal pressure can be as low as in the 10−3 mbar range. Due to the desorption phenomena of gaseous species from the internal surfaces, the vacuum inside such hermetically sealed electronic devices tends to degrade over time and, in the worst case, can affect the proper operation of the device. The integration of a special nanostructured getter film is an effective way to preserve and guarantee the performance of such devices. In addition to the getter material, there is also the need to develop and customize analytical techniques for post-process vacuum quality control and reliability checks of hermetic bonding, which are extremely important for the assessment of a device’s overall performance, lifetime, and manufacturing process yield. Full article
3 pages, 404 KiB  
Proceeding Paper
Design Considerations of Ultra-Low-Power Polymer Gas Microsensors Based on Noise Analysis
by Rafael Puyol, Sylvain Pétré, Yann Danlée, Thomas Walewyns, Laurent A. Francis and Denis Flandre
Proceedings 2020, 56(1), 19; https://doi.org/10.3390/proceedings2020056019 - 16 Dec 2020
Cited by 1 | Viewed by 1227
Abstract
Current sensing solutions must combine an ultra-low energy consumption trend with high reliability. The challenge lies on a fine setting of the detection threshold with the assurance of a sufficient sensitivity. In this article, the uncertainty introduced on gas sensing applications by the [...] Read more.
Current sensing solutions must combine an ultra-low energy consumption trend with high reliability. The challenge lies on a fine setting of the detection threshold with the assurance of a sufficient sensitivity. In this article, the uncertainty introduced on gas sensing applications by the inherent sensor noise is studied. A 1/f model of the electronic noise in polypyrrole-based ammonia (NH3) sensors is presented and used to estimate the intrinsic signal-to-noise ratio (SNR), giving an effective precision of 10.7 bits, i.e., down to 31.4 ppb in terms of NH3 concentration. No significant improvement in SNR is achieved by increasing the bias voltage and hence the power consumption. Full article
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4 pages, 694 KiB  
Proceeding Paper
Revisiting Colorimetric Gas Sensors: Compact, Versatile and Cost-Effective
by Christian Driau, Olga Casals, Ismael Benito-Altamirano, Joan Daniel Prades and Cristian Fàbrega
Proceedings 2020, 56(1), 20; https://doi.org/10.3390/proceedings2020056020 - 17 Dec 2020
Viewed by 1427
Abstract
We report on an inexpensive and very selective gas sensor implemented by simply combining colorimetric indicators casted on top of acetate-based transparent tape, with a commercial microchip adapted here to measure optical reflectance. This sensor can be easily reproduced (leading to quantitatively consistent [...] Read more.
We report on an inexpensive and very selective gas sensor implemented by simply combining colorimetric indicators casted on top of acetate-based transparent tape, with a commercial microchip adapted here to measure optical reflectance. This sensor can be easily reproduced (leading to quantitatively consistent results), refreshed and reconfigured to sense different target gases replacing only the colorimetric tape. The device may either work as sensor (CO2 and NH3) or dosimeter (Formaldehyde) depending on the targeted gas. Full article
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2 pages, 205 KiB  
Proceeding Paper
Surface Science of Metal Oxides: Examining What Happens at the Atomic Scale
by Ulrike Diebold
Proceedings 2020, 56(1), 22; https://doi.org/10.3390/proceedings2020056022 - 17 Dec 2020
Cited by 1 | Viewed by 1174
Abstract
The atomic-scale phenomena at surfaces and interfaces influence, and often even dominate, the properties of materials and their functioning in nanoscale devices. This contribution discusses recent results of applying the surface science method, where systems are investigated under idealized conditions. Such experiments directly [...] Read more.
The atomic-scale phenomena at surfaces and interfaces influence, and often even dominate, the properties of materials and their functioning in nanoscale devices. This contribution discusses recent results of applying the surface science method, where systems are investigated under idealized conditions. Such experiments directly relate to first-principles calculations and provide insights into mechanisms and processes at a level that cannot be achieved in any other way. The review discusses recent developments with a main emphasis on metal oxides, a versatile and extremely useful class of materials. Full article
2 pages, 384 KiB  
Proceeding Paper
Photoconductivity of Colloidal Quantum Dot Films in Plasmonic Nanogaps
by Dario Grimaldi, Emil Kelderer, Andreas Hohenau, Harald Ditlbacher and Joachim R. Krenn
Proceedings 2020, 56(1), 23; https://doi.org/10.3390/proceedings2020056023 - 17 Dec 2020
Viewed by 1198
Abstract
We investigate the photoconductivity properties of lead sulphide (PbS) quantum dot ensembles in lithographically tailored gold electrodes with smallest gaps of 15 nm. We demonstrate that quantum dots are reliable nanoscale light/current converters and correlate the measured photocurrents to the quantum dot number, [...] Read more.
We investigate the photoconductivity properties of lead sulphide (PbS) quantum dot ensembles in lithographically tailored gold electrodes with smallest gaps of 15 nm. We demonstrate that quantum dots are reliable nanoscale light/current converters and correlate the measured photocurrents to the quantum dot number, the gap voltage and light irradiance. For the latter, we find a photocurrent power law dependence with an exponent of 2/3. Furthermore, we probe the role of plasmonic effects in the gold electrodes and image by scanning photocurrent microscopy the spatial dependence of photocurrent generation. Full article
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3 pages, 316 KiB  
Proceeding Paper
Ordered Porphyrin Arrays on Fe(001): An Enabling Technology for Future Spintronics
by Guglielmo Albani, Alberto Calloni, Madan S. Jagadeesh, Alberto Brambilla, Andrea Picone, Alessandro Lodesani, Lamberto Duò, Franco Ciccacci, Marco Finazzi and Gianlorenzo Bussetti
Proceedings 2020, 56(1), 25; https://doi.org/10.3390/proceedings2020056025 - 19 Dec 2020
Viewed by 1217
Abstract
We give evidence of the formation of an ordered array of tetra-phenyl porphyrins (TPP) when these molecules are deposited on top of oxygen-passivated Fe(001), namely the Fe(001)-p(1 × 1)O surface. We also prove that they are magnetically coupled with the substrate. [...] Read more.
We give evidence of the formation of an ordered array of tetra-phenyl porphyrins (TPP) when these molecules are deposited on top of oxygen-passivated Fe(001), namely the Fe(001)-p(1 × 1)O surface. We also prove that they are magnetically coupled with the substrate. The ordered molecular packing, together with the magnetic coupling, are fundamental conditions for application in organic spintronic devices. The system is studied by means of spin-resolved photoemission spectroscopies and scanning tunneling microscopy. Full article
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3 pages, 603 KiB  
Proceeding Paper
Optofluidic Particle Detection
by Vladislav Agluschewitsch, Mayra Garcés-Schröder and Andreas Waag
Proceedings 2020, 56(1), 26; https://doi.org/10.3390/proceedings2020056026 - 24 Dec 2020
Viewed by 1189
Abstract
The combination of optics and microfluidics for particle detection makes it possible to fabricate small low-cost devices. In such hybrid-on-chip systems with integrated µLEDs, the particles can be close to the light source, which is beneficial for the detection capability according to the [...] Read more.
The combination of optics and microfluidics for particle detection makes it possible to fabricate small low-cost devices. In such hybrid-on-chip systems with integrated µLEDs, the particles can be close to the light source, which is beneficial for the detection capability according to the simulation results. In addition, further advantages and extension possibilities of such devices are discussed. Full article
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2 pages, 358 KiB  
Proceeding Paper
VitaLight—Light to Support Vital Signs
by Stefan Schantl, Andreas Peter Weiss and Franz-Peter Wenzl
Proceedings 2020, 56(1), 27; https://doi.org/10.3390/proceedings2020056027 - 24 Dec 2020
Viewed by 1366
Abstract
The spectral composition of light has a significant influence on human wellbeing, emotion and health. Natural sunlight is often considered as the ideal light source in this regard. Therefore, artificial lighting solutions that mimic natural sunlight are a central research topic in the [...] Read more.
The spectral composition of light has a significant influence on human wellbeing, emotion and health. Natural sunlight is often considered as the ideal light source in this regard. Therefore, artificial lighting solutions that mimic natural sunlight are a central research topic in the lighting industry. Another global trend is the monitoring and evaluation of the vital parameters of human beings to improve their health status and their personal lifestyle. Here, we present VitaLight, a laboratory sample for a smart lighting system that aims to interconnect these global trends and consists of VitaWatch, a wristband with functionally integrated sensors that is comfortable to wear on the body, and VitaLUMI, a lighting unit with access to the internet. Full article
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3 pages, 302 KiB  
Proceeding Paper
Predicting Dielectric Properties of Doped BaTiO3 Using First-Principles and Monte Carlo Simulations
by Florian Mayer, Maxim Popov, Jürgen Spitaler and Marco Deluca
Proceedings 2020, 56(1), 28; https://doi.org/10.3390/proceedings2020056028 - 25 Dec 2020
Viewed by 1122
Abstract
We investigate the dielectric properties of homovalent (M4+)-doped Ba(Ti1−xMx)O3 compositions using a two-dimensional Ising-like network. The model is mainly based on the interaction of permanent and induced dipoles and allows us to simulate the collective behavior [...] Read more.
We investigate the dielectric properties of homovalent (M4+)-doped Ba(Ti1−xMx)O3 compositions using a two-dimensional Ising-like network. The model is mainly based on the interaction of permanent and induced dipoles and allows us to simulate the collective behavior of atoms at finite temperatures. In contrast to previous publications, we also include first-principles calculations to model the local environment and interaction of the B-site atoms. Furthermore, in order to describe the corresponding physics more accurately, we introduce an additional degree of freedom for the polarization direction. Our simulations provide an insight into the formation of polar clusters, the evolution of spontaneous polarization at different concentrations of dopants, and the response to external fields. For the purpose of studying the dielectric properties, the model is used to calculate hysteresis curves and related quantities. Full article
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3 pages, 1347 KiB  
Proceeding Paper
Modelling of Void Collapse with Molecular Dynamics in Pure Sn
by Georg Siroky, Elke Kraker, Dietmar Kieslinger, Lorenz Romaner, Ernst Kozeschnik and Werner Ecker
Proceedings 2020, 56(1), 29; https://doi.org/10.3390/proceedings2020056029 - 26 Dec 2020
Viewed by 1435
Abstract
This work simulates the collapse of a spherical void in pure Sn during melting using molecular dynamics (MD). Simulations were performed for two temperatures with a modified embedded atom method (MEAM) potential, which was reported to be in good agreement with respect to [...] Read more.
This work simulates the collapse of a spherical void in pure Sn during melting using molecular dynamics (MD). Simulations were performed for two temperatures with a modified embedded atom method (MEAM) potential, which was reported to be in good agreement with respect to melting point and elastic constants. Solutions of the Rayleigh–Plesset (RP) equation are used for comparison under the assumption of macroscopic surface tension and liquid viscosity. Despite a qualitative correlation, longer collapse times were observed in MD simulations, which arose from partial solid structures and the incubation time for melting. Full article
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2 pages, 177 KiB  
Proceeding Paper
Aerosol Jet Printed Nanocarbons on Heat Sink Materials
by Reinhard Kaindl, Bernhard C. Bayer, Tushar Gupta, Songfeng Pei, Pengxiang Hou, Jinhong Du, Chang Liu, Wencai Ren, Alexander Blümel, Paul Patter, Karl Popovic, David Dergez and Wolfgang Waldhauser
Proceedings 2020, 56(1), 30; https://doi.org/10.3390/proceedings2020056030 - 28 Dec 2020
Viewed by 2188
Abstract
Graphene- and carbon nanotube (CNT)-based inks have been printed on relevant heat sink materials by Aerosol jet. The thickness of the layers varied between ~100 and ~1.500 nm. The inks’ viscosity ranged from <20 up to 600 cps at a solid content between [...] Read more.
Graphene- and carbon nanotube (CNT)-based inks have been printed on relevant heat sink materials by Aerosol jet. The thickness of the layers varied between ~100 and ~1.500 nm. The inks’ viscosity ranged from <20 up to 600 cps at a solid content between 0.18 and 3% and wide particle sizes from 5 nm up to 5 µm. The printed layers could be interesting for rather high-power and high-temperature applications including thermal heat spreaders, resistive heaters, high-current carrying interconnectors, temperature sensors and ordnance fuze technology. Full article
3 pages, 429 KiB  
Extended Abstract
Looking Inside Micro- and Nano-Mechanical Pillar Resonators: A Picosecond Ultrasonics Approach
by Paul Stritt, Juliane Doster, Thomas Dekorsy, Vitalyi Gusev, Eva Weig and Mike Hettich
Proceedings 2020, 56(1), 31; https://doi.org/10.3390/proceedings2020056031 - 28 Dec 2020
Viewed by 1552
Abstract
Pillar-shaped Gallium arsenide (GaAs) micromechanical resonators are fabricated, and the feasibility to measure the inside of the pillars in the axial direction with laser-induced GHz ultrasound based on picosecond ultrasonics is tested. Measurements on the pillars with head sizes in the µm range [...] Read more.
Pillar-shaped Gallium arsenide (GaAs) micromechanical resonators are fabricated, and the feasibility to measure the inside of the pillars in the axial direction with laser-induced GHz ultrasound based on picosecond ultrasonics is tested. Measurements on the pillars with head sizes in the µm range show excellent agreement with theoretical predictions. Full article
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3 pages, 664 KiB  
Proceeding Paper
In-Situ Spectroelectrochemical Study of Conductive Polyaniline Forms for Sensor Applications
by Anja Korent, Kristina Žagar Soderžnik and Kristina Žužek Rožman
Proceedings 2020, 56(1), 32; https://doi.org/10.3390/proceedings2020056032 - 29 Dec 2020
Cited by 3 | Viewed by 1501
Abstract
Our contribution focuses on a correlative study of polyaniline (PANI) electropolymerisation and UV/VIS spectroscopy. PANI was prepared via electro-oxidation using a potentiodynamic method on commercial gold screen-printed electrodes (Au-SPE). By using an in-situ spectroelectrochemical method, the development of the polymer was observed from [...] Read more.
Our contribution focuses on a correlative study of polyaniline (PANI) electropolymerisation and UV/VIS spectroscopy. PANI was prepared via electro-oxidation using a potentiodynamic method on commercial gold screen-printed electrodes (Au-SPE). By using an in-situ spectroelectrochemical method, the development of the polymer was observed from monomer, monomer oxidation to final polymer formation and its transformations between the oxidation forms. The results confirm the spontaneous doping of the polymer during the polymerisation, the instability of leucoemeraldine form in air and its two-stage oxidation to emeraldine form. The final conductive PANI deposited on Au-SPE will be used as sensor element for the detection of toxic organic compounds. Full article
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3 pages, 187 KiB  
Proceeding Paper
Endohedral Functionalization of Metallicity-Sorted Single-Walled Carbon Nanotubes
by Marianna V. Kharlamova, Christian Kramberger, Oleg Domanov, Andreas Mittelberger, Kazuhiro Yanagi, Thomas Pichler and Dominik Eder
Proceedings 2020, 56(1), 33; https://doi.org/10.3390/proceedings2020056033 - 30 Dec 2020
Cited by 4 | Viewed by 1254
Abstract
We performed endohedral functionalization of high-purity metallicity-sorted semiconducting and metallic single-walled carbon nanotubes (SWCNTs) with a mean diameter of 1.4 nm with silver chloride (AgCl) by the method of capillary filling with the melt. The AgCl-filled SWCNTs were investigated by high-resolution scanning transmission [...] Read more.
We performed endohedral functionalization of high-purity metallicity-sorted semiconducting and metallic single-walled carbon nanotubes (SWCNTs) with a mean diameter of 1.4 nm with silver chloride (AgCl) by the method of capillary filling with the melt. The AgCl-filled SWCNTs were investigated by high-resolution scanning transmission electron microscopy and spectroscopic techniques, such as Raman spectroscopy, X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy, which were combined to study comprehensively the modified electronic properties of the filled SWCNTs. The data revealed a downshift of the Fermi level of the nanotubes upon filling, i.e., a p-doping of SWCNTs. Full article
3 pages, 528 KiB  
Proceeding Paper
Investigations on Long-Range AFM Scans Using a Nanofabrication Machine (NFM-100)
by Jaqueline Stauffenberg, Ingo Ortlepp, Christoph Reuter, Mathias Holz, Denis Dontsov, Christoph Schäffel, Steffen Strehle, Jens-Peter Zöllner, Ivo W. Rangelow and Eberhard Manske
Proceedings 2020, 56(1), 34; https://doi.org/10.3390/proceedings2020056034 - 30 Dec 2020
Cited by 1 | Viewed by 1361
Abstract
The focus of this work lies on investigations on a new Nano Fabrication Machine (NFM-100) with a mounted atomic force microscope (AFM). This installed tip-based measuring system uses self-sensing and self-actuated microcantilevers, which can be used especially for field-emission scanning probe lithography (FESPL). [...] Read more.
The focus of this work lies on investigations on a new Nano Fabrication Machine (NFM-100) with a mounted atomic force microscope (AFM). This installed tip-based measuring system uses self-sensing and self-actuated microcantilevers, which can be used especially for field-emission scanning probe lithography (FESPL). The NFM-100 has a positioning range of Ø 100 mm, which offers, in combination with the tip-based measuring system, the possibility to analyse structures over long ranges. Using different gratings, the accuracy and the reproducibility of the NFM-100 and the AFM-system will be shown. Full article
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3 pages, 375 KiB  
Proceeding Paper
Direct Deposition of CVD Diamond Layers on Top of GaN Membranes
by Tibor Izsák, Gabriel Vanko, Milan Držík, Stephan Kasemann, Johann Zehetner, Marian Vojs, Bohumír Zaťko, Štěpán Potocký and Alexander Kromka
Proceedings 2020, 56(1), 35; https://doi.org/10.3390/proceedings2020056035 - 30 Dec 2020
Cited by 1 | Viewed by 1228
Abstract
We present technological issues in the deposition of diamond films on gallium nitride (GaN) membranes. Many wrinkles and thicker diamond layers were observed at the membrane center and poor quality diamond outside the membrane area. The deflection of the membranes was analyzed by [...] Read more.
We present technological issues in the deposition of diamond films on gallium nitride (GaN) membranes. Many wrinkles and thicker diamond layers were observed at the membrane center and poor quality diamond outside the membrane area. The deflection of the membranes was analyzed by a bulging method using white light interferometry. The membrane bending is discussed in the terms of temperature gradient and mismatch of thermal expansion coefficients of materials. Full article
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3 pages, 284 KiB  
Proceeding Paper
Synthesis and Piezoelectric Characterization of UV-Curable Nanocellulose/ZnO/AlN Polymeric Flexible Films for Green Energy Generation Applications
by Maria Assunta Signore, Giulio Malucelli, Donatella Duraccio, Chiara De Pascali, Ambra Fioravanti, Pietro Siciliano and Luca Francioso
Proceedings 2020, 56(1), 36; https://doi.org/10.3390/proceedings2020056036 - 30 Dec 2020
Viewed by 1172
Abstract
In this work, the fabrication of composites consisting of piezoelectric ZnO ceramic nanostructures and nanocellulose fillers in a UV-cured acrylic matrix has been exploited for the design of new functional coatings for green energy generation. The piezoelectric behavior was investigated at different accelerations [...] Read more.
In this work, the fabrication of composites consisting of piezoelectric ZnO ceramic nanostructures and nanocellulose fillers in a UV-cured acrylic matrix has been exploited for the design of new functional coatings for green energy generation. The piezoelectric behavior was investigated at different accelerations applied to cantilever beams. The piezoelectric signal generated by the different ZnO nanostructures was improved by aluminum nitride film integration on the beam and proof mass insertion at the tip. Full article
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3 pages, 377 KiB  
Proceeding Paper
Temperature Cycled Operation and Multivariate Statistics for Electronic-Nose Applications Using Field Effect Transistors
by Guillem Domènech-Gil, Marius Rodner, Jens Eriksson and Donatella Puglisi
Proceedings 2020, 56(1), 37; https://doi.org/10.3390/proceedings2020056037 - 31 Dec 2020
Viewed by 1201
Abstract
Gas sensitive iridium-gated field effect transistors based on silicon carbide were used to study the response towards formaldehyde, ammonia, carbon monoxide and nitrogen dioxide at concentrations ranging from parts per million to parts per billion diluted in dry synthetic air and under 50% [...] Read more.
Gas sensitive iridium-gated field effect transistors based on silicon carbide were used to study the response towards formaldehyde, ammonia, carbon monoxide and nitrogen dioxide at concentrations ranging from parts per million to parts per billion diluted in dry synthetic air and under 50% of relative humidity. The sensor performance was studied using temperature cycled operation mode from 270 to 390 °C to investigate the capability of these devices to discriminate between the studied gases under different background conditions via pattern recognition algorithms. Full article
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3 pages, 615 KiB  
Proceeding Paper
Nanostructured Materials Based on Thin Films and Nanoclusters for Hydrogen Gas Sensing
by Stanislav Haviar, Nirmal Kumar, Šárka Batková and Jiří Čapek
Proceedings 2020, 56(1), 38; https://doi.org/10.3390/proceedings2020056038 - 5 Jan 2021
Cited by 2 | Viewed by 1210
Abstract
In this paper, we present two approaches to synthesize nanostructured metal oxide semiconductors in a form of multi-layer thin films later assembled as a conductometric gas-sensors. The first approach produces a combination of thin solid film of tungsten trioxide (WO3) with [...] Read more.
In this paper, we present two approaches to synthesize nanostructured metal oxide semiconductors in a form of multi-layer thin films later assembled as a conductometric gas-sensors. The first approach produces a combination of thin solid film of tungsten trioxide (WO3) with nanoclusters of cupric oxide (CuO) prepared by a magnetron-based gas aggregation cluster source (GAS). The second method is a two-step reactive magnetron sputtering forming a nanostructured copper tungstate (CuWO4) on-top of a WO3 film. Both methods lead to synthesis of nanosized hetero-junctions. These greatly improve the sensorial response to hydrogen in comparison with a WO3 thin film alone. Full article
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2 pages, 278 KiB  
Proceeding Paper
Correlating Spatially Resolved Photoconductivity and Luminescence in Colloidal Quantum Dot Films
by Emil Kelderer, Dario Grimaldi, Andreas Hohenau, Harald Ditlbacher and Joachim R. Krenn
Proceedings 2020, 56(1), 39; https://doi.org/10.3390/proceedings2020056039 - 11 Jan 2021
Viewed by 1055
Abstract
We investigated the optoelectronic properties of lead sulphide (PbS) quantum dot films in lithographically tailored gold nanogap electrodes. In particular, we aimed at the correlated measurement of photoconductivity and luminescence as a tool to characterize the charge dynamics from exciton generation to carrier [...] Read more.
We investigated the optoelectronic properties of lead sulphide (PbS) quantum dot films in lithographically tailored gold nanogap electrodes. In particular, we aimed at the correlated measurement of photoconductivity and luminescence as a tool to characterize the charge dynamics from exciton generation to carrier extraction and recombination. Combining these measurements in an optical microscope with laser scanning excitation enabled, as well, the spatially resolved observation of the involved effects. Full article
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3 pages, 541 KiB  
Proceeding Paper
Real-Time Temperature Detection Via Quantum Dots for Photothermal Cellular Actuation
by Wei Yu, Olivier Deschaume, Stijn Jooken, Fanglei Guo, Pengfei Zhang, Jolan Wellens, Christ Glorieux and Carmen Bartic
Proceedings 2020, 56(1), 40; https://doi.org/10.3390/proceedings2020056040 - 20 Jan 2021
Viewed by 1408
Abstract
Plasmonic heating finds multiple applications in cell manipulation and stimulation, where heat generated by metal nanoparticles can be used to modify cell adhesion, control membrane currents, and suppress neuronal action potentials among others. Metal nanoparticles can also be easily integrated in artificial extracellular [...] Read more.
Plasmonic heating finds multiple applications in cell manipulation and stimulation, where heat generated by metal nanoparticles can be used to modify cell adhesion, control membrane currents, and suppress neuronal action potentials among others. Metal nanoparticles can also be easily integrated in artificial extracellular matrices to provide tunable, thermal cueing functionalities with nanometer spatial resolution. In this contribution, we present a platform enabling the combination of plasmonic heating with localized temperature sensing using quantum dots (QDs). Specifically, a functional nanocomposite material was designed with gold nanorods (AuNRs) and QDs incorporated in a cell-permissive hydrogel (e.g., collagen) as well as an optical set-up combining optical heating and temperature imaging, respectively. Specific area stimulation/readout can be realized through structured illumination using digital micromirror device (DMD) projection. Full article
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3 pages, 362 KiB  
Proceeding Paper
CO Detection Investigation at High Temperature by SiC MISFET Metal/Oxide Gas Sensors
by Lida Khajavizadeh, Anita Lloyd Spetz and Mike Andersson
Proceedings 2020, 56(1), 41; https://doi.org/10.3390/proceedings2020056041 - 21 Jan 2021
Viewed by 1359
Abstract
In order to investigate the necessary device improvements for high-temperature CO sensing with SiC metal insulator semiconductor field effect transistor (MISFET)-based chemical gas sensors, devices employing, as the gas-sensitive gate contact, a film of co-deposited Pt/Al2O3 instead of the commonly [...] Read more.
In order to investigate the necessary device improvements for high-temperature CO sensing with SiC metal insulator semiconductor field effect transistor (MISFET)-based chemical gas sensors, devices employing, as the gas-sensitive gate contact, a film of co-deposited Pt/Al2O3 instead of the commonly used catalytic metal-based contacts were fabricated and characterized for CO detection at elevated temperatures and different CO and O2 levels. It can be concluded that the sensing mechanism at elevated temperatures correlates with oxygen removal from the sensor surface rather than the surface CO coverage as observed at lower temperatures. The long-term stability performance was also shown to be improved compared to that of previously studied devices. Full article
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3 pages, 156 KiB  
Proceeding Paper
Passive Visible Light Sensing of Retroreflective Foils on a Moving Object for Indoor Application
by Andreas Peter Weiss and Franz-Peter Wenzl
Proceedings 2020, 56(1), 42; https://doi.org/10.3390/proceedings2020056042 - 20 Jan 2021
Viewed by 1421
Abstract
We present a novel approach to perform passive visible light sensing of retroreflective foils mounted on a moving object by utilizing low-cost hardware combined with a self-developed, low complex software algorithm with minimal training effort for successful classification. Therewith, we show the feasibility [...] Read more.
We present a novel approach to perform passive visible light sensing of retroreflective foils mounted on a moving object by utilizing low-cost hardware combined with a self-developed, low complex software algorithm with minimal training effort for successful classification. Therewith, we show the feasibility of utilizing the visible light spectrum not only for illumination, but also to perform sensing tasks, which consequently will lead to less energy consumption, no need for active sensors on the moving object, and finally no necessity of wireless radio frequency communication between the object and the processing device. Full article
3 pages, 326 KiB  
Proceeding Paper
Optimization of SnO2-Based CMOS-Integrated Gas Sensors by Mono-, Bi- and Trimetallic Nanoparticles
by Robert Wimmer-Teubenbacher, Florentyna Sosada-Ludwikowska, Anton Köck, Stephan Steinhauer, Mukhles Sowwan and Vidyadhar Singh
Proceedings 2020, 56(1), 43; https://doi.org/10.3390/proceedings2020056043 - 20 Jan 2021
Cited by 1 | Viewed by 1835
Abstract
In this paper, we report on the optimization of SnO2-based thin film gas sensor devices by mono-, bi- and trimetallic nanoparticles. Ag, AgRu, and AgRuPd nanoparticles are sputter deposited on CMOS-integrated SnO2-thin film gas sensor devices. The CMOS device [...] Read more.
In this paper, we report on the optimization of SnO2-based thin film gas sensor devices by mono-, bi- and trimetallic nanoparticles. Ag, AgRu, and AgRuPd nanoparticles are sputter deposited on CMOS-integrated SnO2-thin film gas sensor devices. The CMOS device is a worldwide unique chip containing an array of eight microhotplates. The response towards the target gas CO was dramatically increased from 10% to more than 70% by using trimetallic AgRuPd nanoparticles. Full article
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8 pages, 1473 KiB  
Proceeding Paper
Porphycene Films Grown on Highly Oriented Pyrolytic Graphite: Unveiling Structure–Property Relationship through Combined Reflectance Anisotropy Spectroscopy and Atomic Force Microscopy Investigations
by Marta Penconi, Lorenzo Ferraro, Jacek Waluk, Lamberto Duò, Franco Ciccacci, Alberto Bossi, Marcello Campione and Gianlorenzo Bussetti
Proceedings 2020, 56(1), 44; https://doi.org/10.3390/proceedings2020056044 - 3 Mar 2021
Cited by 1 | Viewed by 1535
Abstract
Thin organic films are widely used in sensors, solar cells, and optical devices due to their intense absorption in the visible/near-infrared (IR) region. Shifting, quenching, or reshaping of some spectral features can be achieved by chemical functionalization of the molecules, whereas an anisotropic [...] Read more.
Thin organic films are widely used in sensors, solar cells, and optical devices due to their intense absorption in the visible/near-infrared (IR) region. Shifting, quenching, or reshaping of some spectral features can be achieved by chemical functionalization of the molecules, whereas an anisotropic fingerprint due to preferential molecular alignment can be induced via a proper design and/or preparation of the substrate. Recently, we investigated the optical response of thin films of porphycene to acidification. With respect to the well-known and closely related tetraphenyl porphyrin, porphycene has the clear advantage of being optically active in the full visible range, and this makes visible by naked eye the immediate change of the film from brilliant blue-turquoise to green when exposed to HCl vapors. In this work, by exploiting a homemade reflectance anisotropy spectroscopy (RAS) apparatus, we explore possible optical anisotropies in the visible spectral range of porphycene films and relate them to the film morphology analyzed by atomic force microscopy (AFM). Full article
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