Skip to Content

Inorganics, Volume 12, Issue 8

2024 August - 31 articles

Cover Story: Novel thionitrosyl complexes of rhenium and technetium with triphenylphosphine or chelating ligands such as (η5-cyclopentadienyl)tris(dimethyl phosphito-P)cobaltate(III), the Kläui ligand, or N,N-diethyl-N′-benzoyl thiourea were prepared by reactions of corresponding nitrido complexes with S2Cl2 or ligand exchange procedures starting from the prepared PPh3 complexes. The products contained the metals in their oxidation states “+2” or “+1”. They were studied by X-ray crystallography and spectroscopic methods including EPR and infrared spectroscopy as well as by mass spectrometry. The products are stable in air and represent structural analogs to the better characterized nitrosyl complexes of rhenium and technetium. View this paper
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (31)

  • Article
  • Open Access
6 Citations
2,049 Views
14 Pages

Luminescence Efficiency and Spectral Compatibility of Cerium Fluoride (CeF3) Inorganic Scintillator with Various Optical Sensors in the Diagnostic Radiology X-ray Energy Range

  • Vasileios Ntoupis,
  • Christos Michail,
  • Nektarios Kalyvas,
  • Athanasios Bakas,
  • Ioannis Kandarakis,
  • George Fountos and
  • Ioannis Valais

The aim of this study was to experimentally assess the luminescence efficiency of a cerium fluoride (CeF3) inorganic scintillator in crystal form as a possible alternative to high-luminescence but hygroscopic cerium bromide (CeBr3). The experiments w...

  • Article
  • Open Access
7 Citations
2,363 Views
18 Pages

FeCo2O4/MoS2 binary composite catalysts were prepared by the hydrothermal method and calcination method. In this paper, the morphology and structure of the materials were characterized by means of SEM, EDS, XRD, and XPS. It was found that MoS2 has hi...

  • Article
  • Open Access
2 Citations
2,070 Views
16 Pages

Infrared Light Annealing Effect on Pressure Sensor Fabrication Using Graphene/Polyvinylidene Fluoride Nanocomposite

  • Victor K. Samoei,
  • Katsuhiko Takeda,
  • Keiichiro Sano,
  • Angshuman Bharadwaz,
  • Ambalangodage C. Jayasuriya and
  • Ahalapitiya H. Jayatissa

This paper reports the designing and testing, as well as the processing and testing, of a flexible piezoresistive sensor for pressure-sensing applications, utilizing a composite film of graphene/polyvinylidene fluoride (Gr/PVDF). Graphene serves as t...

  • Article
  • Open Access
2 Citations
2,265 Views
15 Pages

Raman Spectroscopy and Microstructural Characterization of Hot-Rolled Copper/Graphene Composite Materials

  • Antoine Bident,
  • Jean-Luc Grosseau-Poussard,
  • Florence Delange,
  • Ahmed Addad,
  • Gang Ji,
  • Yongfeng Lu,
  • Jean-Louis Bobet,
  • Amélie Veillere and
  • Jean-François Silvain

Given the increase in current density in the constituent materials of electrical systems, improving the electrical conductivity of these materials, particularly copper (Cu), is crucial. This would also help to mitigate the heat generated by Joule hea...

  • Article
  • Open Access
3 Citations
1,408 Views
13 Pages

BiFeO3-related perovskite-type materials attract a lot of attention from the viewpoint of applications and fundamental science. In this work, we prepared two modifications of heavily Mn-doped BiFeO3 with the composition of BiFe0.6Mn0.4O3. A high-pres...

  • Article
  • Open Access
2 Citations
3,395 Views
18 Pages

This investigation explores the potential of enhancing aqueous zinc-ion batteries (AZIBs) through the introduction of a novel cathode material, NH4V4O10 (NVO), combined with reduced graphene oxide (rGO). Utilizing Density Functional Theory (DFT), it...

  • Review
  • Open Access
8 Citations
4,901 Views
19 Pages

The Story, Properties and Applications of Bioactive Glass “1d”: From Concept to Early Clinical Trials

  • Dilshat U. Tulyaganov,
  • Simeon Agathopoulos,
  • Konstantinos Dimitriadis,
  • Hugo R. Fernandes,
  • Roberta Gabrieli and
  • Francesco Baino

Bioactive glasses in the CaO–MgO–Na2O–P2O5–SiO2–CaF2 system are highly promising materials for bone and dental restorative applications. Furthermore, if thermally treated, they can crystallize into diopside–fluorap...

  • Article
  • Open Access
3 Citations
2,468 Views
24 Pages

Nanoparticles of iron and iron oxides, as well as their composites, are of great scientific and technological interest. However, their properties and sustainability strongly depend on the preparation methods. Here, we present an original approach to...

  • Review
  • Open Access
2 Citations
2,864 Views
19 Pages

Exploring the Frontiers of Cathode Catalysts in Lithium–Carbon Dioxide Batteries: A Mini Review

  • Jing Guo,
  • Xin Yan,
  • Xue Meng,
  • Pengwei Li,
  • Qin Wang,
  • Yahui Zhang,
  • Shenxue Yan and
  • Shaohua Luo

To mitigate the greenhouse effect and environmental pollution caused by the consumption of fossil fuels, recent research has focused on developing renewable energy sources and new high-efficiency, environmentally friendly energy storage technologies....

  • Review
  • Open Access
10 Citations
4,214 Views
33 Pages

C–H Activation via Group 8–10 Pincer Complexes: A Mechanistic Approach

  • Juan S. Serrano-García,
  • Andrés Amaya-Flórez,
  • Jordi R.-Galindo,
  • Lucero González-Sebastián,
  • Luis Humberto Delgado-Rangel and
  • David Morales-Morales

C–H bond activation is a crucial synthetic strategy widely utilized in both academic and industrial settings. Due to the strong and kinetically inert nature of the C–H bond, its functionalization typically requires metal-based catalysts....

  • Article
  • Open Access
1,536 Views
16 Pages

Tetrahydroxidohexaoxidopentaborate(1-) Salts of C6-Linked Substituted Diimidazolium and Dipyrrolidinium Cations: Synthesis, Characterization and XRD Studies

  • Ahmad R. Al-Dulayymi,
  • Michael A. Beckett,
  • Radek Braganca,
  • Simon J. Coles,
  • Peter N. Horton and
  • Thomas A. Rixon

Several tetrahydroxidohexaoxidopentaborate(1-) salts of N-substituted diimidazolium cations or N-substituted dipyrrolidinium cations linked through N-C6-N chains have been synthesized and characterized spectroscopically (NMR, IR) and by single-crysta...

  • Article
  • Open Access
1 Citations
2,698 Views
13 Pages

Characterization and Degradation of Perovskite Mini-Modules

  • R. Ebner,
  • A. Mittal,
  • G. Ujvari,
  • M. Hadjipanayi,
  • V. Paraskeva,
  • G. E. Georghiou,
  • A. Hadipour,
  • A. Aguirre and
  • T. Aernouts

Organic–inorganic hybrid metal halide perovskites are poised to revolutionize the next generation of photovoltaics with their exceptional optoelectronic properties and compatibility with low-cost and large-scale fabrication methods. Since perov...

  • Article
  • Open Access
1,987 Views
13 Pages

Lithium–sulfur batteries (LSBs) hold promise for use in next-generation high-energy-density energy storage systems. However, the commercial application of LSBs is hindered by the shuttle effect of polysulfides. In this study, we synthesized a c...

  • Article
  • Open Access
1 Citations
1,626 Views
17 Pages

Compositional and Fabrication Cycle Optimization of Ceria-Zirconia-Supported Mo-Based Catalysts for NH3-SCR NOx Reduction

  • Luca Spiridigliozzi,
  • Viviana Monfreda,
  • Serena Esposito,
  • Olimpia Tammaro,
  • Nicola Blangetti,
  • Fabio Alessandro Deorsola and
  • Gianfranco Dell’Agli

The reduction of nitrogen oxides (NOx), critical pollutants from stationary to mobile sources, mainly relies on the selective catalytic reduction (NH3-SCR) method, employing ammonia to reduce NOx into nitrogen and water. However, conventional catalys...

  • Article
  • Open Access
2 Citations
1,702 Views
16 Pages

Nickel Ions Activated PbO–GeO2 Glasses for the Application of Electrolytes and Photonic Devices

  • L. Vijayalakshmi,
  • Shaik Meera Saheb,
  • R. Vijay,
  • Kishor Palle,
  • P. Ramesh Babu,
  • Seong-Jin Kwon and
  • G. Naga Raju

In this study, PbO–GeO2 glasses were melt-quenched at different nickel oxide concentrations. XRD and DSC techniques were characterized whether the samples are glass or crystalline materials. IR, Raman, and optical absorption techniques are used...

  • Article
  • Open Access
1 Citations
2,251 Views
12 Pages

Perovskite solar cells (PSCs) have demonstrated remarkable progress in performance in recent years, which has placed perovskite materials as the leading promising materials for future renewable energy applications. The solvent additive technique in p...

  • Article
  • Open Access
1 Citations
2,198 Views
10 Pages

Polysilane–Barium Titanate Polymeric Composite Obtained through Ultrasonication

  • Răzvan Rotaru,
  • Maria Emiliana Fortună,
  • Elena Ungureanu and
  • Liviu Sacarescu

This work describes the synthesis of a polysilane (PSH)–barium titanate (BT) ferroelectric polymer composite that keeps stable in the presence of ultraviolet light (UV). To evaluate the stability in the presence of UV radiation and the mechanis...

  • Article
  • Open Access
2 Citations
2,251 Views
13 Pages

Graphitic carbon plays a pivotal role in numerous technological applications, including energy storage, energy conversion, and different fields of material science. The transformation of amorphous carbon into graphitic carbon, a process known as grap...

  • Article
  • Open Access
1 Citations
2,420 Views
11 Pages

The interfacial perpendicular magnetic anisotropy (PMA) observed at ferromagnet/oxide interfaces presents great promise for energy-efficient spintronic technologies. The epitaxial strain induced by the lattice mismatch between films and substrates se...

  • Article
  • Open Access
4 Citations
2,567 Views
17 Pages

Thionitrosyl Complexes of Rhenium and Technetium with PPh3 and Chelating Ligands—Synthesis and Reactivity

  • Domenik Nowak,
  • Adelheid Hagenbach,
  • Till Erik Sawallisch and
  • Ulrich Abram

In contrast to corresponding nitrosyl compounds, thionitrosyl complexes of rhenium and technetium are rare. Synthetic access to the thionitrosyl core is possible by two main approaches: (i) the treatment of corresponding nitrido complexes with S2Cl2...

  • Article
  • Open Access
1 Citations
1,637 Views
15 Pages

Chalcogenide glasses have broad applications in the mid-infrared optoelectronics field and as phase-change materials (PCMs) due to their unique properties. Chalcogenide glasses can have crystalline and amorphous phases, making them suitable as PCMs f...

  • Review
  • Open Access
1 Citations
2,011 Views
44 Pages

Towards Construction of the “Periodic Table” of 1-Methylbenzotriazole

  • Christina Stamou,
  • Zoi G. Lada,
  • Sophia Paschalidou,
  • Christos T. Chasapis and
  • Spyros P. Perlepes

Metal complexes of benzotriazole-type ligands continue to attract the intense interest of many inorganic chemistry groups around the world for a variety of reasons, including their aesthetically beautiful structures, physical properties and applicati...

  • Article
  • Open Access
1 Citations
2,728 Views
9 Pages

Developing cost-effective methods to synthesize large-size GaN films remains a challenge owing to the high dislocation density during heteroepitaxy. Herein, AlGaN/GaN HEMTs were grown on 6- and 8-inch Si(111) substrates using metal–organic chem...

  • Article
  • Open Access
3 Citations
2,178 Views
21 Pages

New Iron(III)-Containing Composite of Salinomycinic Acid with Antitumor Activity—Synthesis and Characterization

  • Juliana Ivanova,
  • Rositsa Kukeva,
  • Radostina Stoyanova,
  • Tanya Zhivkova,
  • Abedulkadir Abudalleh,
  • Lora Dyakova,
  • Radostina Alexandrova,
  • Irena Pashkunova-Martic,
  • Johannes Theiner and
  • Ivo Grabchev
  • + 4 authors

In this study we demonstrated for the first time synthetic procedures for composites of salinomycin (SalH) and two-line ferrihydrite. The products were characterized by various methods such as elemental analysis, attenuated total reflectance–Fo...

  • Article
  • Open Access
6 Citations
3,090 Views
17 Pages

Designing of High-Performance MnNiS@MXene Hybrid Electrode for Energy Storage and Photoelectrochemical Applications

  • Maqsood Ahmad,
  • Muhammad Imran,
  • Amir Muhammad Afzal,
  • Muhammad Ahsan ul Haq,
  • Areej S. Alqarni,
  • Muhammad Waqas Iqbal,
  • Shams A. M. Issa and
  • Hesham M. H. Zakaly

The overconsumption of fossil fuels is leading to worsening environmental damage, making the generation of clean, renewable energy an absolute necessity. Two common components of electrochemical energy storage (EES) devices are batteries and supercap...

  • Article
  • Open Access
4 Citations
1,912 Views
15 Pages

Octa-methylpyridiloxy-substituted Zn(II)- and Ga(III)-phthalocyanines (ZnPc1 and GaPc1) were studied on human pigmented melanoma (SH4) and keratinocyte (HaCaT) cell lines. The efficacy of ZnPc1 and GaPc1 against melanoma cells was compared to the res...

  • Article
  • Open Access
3 Citations
1,940 Views
19 Pages

This study explores the influence of solution concentration, specifically that of water and ethylene glycol mixtures, on the optical and supercapacitive properties of cobalt tungstate (CoWO4) nanoparticles. CoWO4 nanoparticles were synthesized using...

  • Article
  • Open Access
2,057 Views
15 Pages

Anti-Cancer Stem Cell Cobalt(III)-Polypyridyl Complexes Containing Salicylic Acid

  • Jiaxin Fang,
  • Kuldip Singh and
  • Kogularamanan Suntharalingam

Metal-containing compounds are an important class of chemotherapeutics used to treat various manifestations of cancer. Despite the widespread clinical use and success of metallopharmaceuticals, they are ineffective towards a sub-population of tumours...

  • Article
  • Open Access
1 Citations
2,071 Views
15 Pages

Mono- and binuclear Cu(I) complexes were isolated employing 2,1,3-benzoselenadiazole (BSeD) as the N-donor ligand, and triphenylphosphine or bis[(2-diphenylphosphino)phenyl] ether (DPEphos) as P-donors. Then, 77Se NMR was measured for the free ligand...

  • Article
  • Open Access
2 Citations
2,063 Views
13 Pages

Electrochemically Active Copper Complexes with Pyridine-Alkoxide Ligands

  • Christopher K. Webber,
  • Erica K. Richardson,
  • Diane A. Dickie and
  • T. Brent Gunnoe

Pyridine-alkoxide (pyalk) ligands that support transition metals have been studied for their use in electrocatalytic applications. Herein, we used the pyalk proligands diphenyl(pyridin-2-yl)methanol ([H]PhPyalk, L1), 1-(pyren-1-yl)-1-(pyridin-2-yl)et...

Get Alerted

Add your email address to receive forthcoming issues of this journal.

XFacebookLinkedIn
Inorganics - ISSN 2304-6740