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Inorganics, Volume 12, Issue 8

August 2024 - 31 articles

Cover Story: Novel thionitrosyl complexes of rhenium and technetium with triphenylphosphine or chelating ligands such as (η5-cyclopentadienyl)tris(dimethyl phosphito-P)cobaltate(III), the Kläui ligand, or N,N-diethyl-N′-benzoyl thiourea were prepared by reactions of corresponding nitrido complexes with S2Cl2 or ligand exchange procedures starting from the prepared PPh3 complexes. The products contained the metals in their oxidation states “+2” or “+1”. They were studied by X-ray crystallography and spectroscopic methods including EPR and infrared spectroscopy as well as by mass spectrometry. The products are stable in air and represent structural analogs to the better characterized nitrosyl complexes of rhenium and technetium. View this paper
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Articles (31)

  • Article
  • Open Access
4 Citations
1,753 Views
14 Pages

Luminescence Efficiency and Spectral Compatibility of Cerium Fluoride (CeF3) Inorganic Scintillator with Various Optical Sensors in the Diagnostic Radiology X-ray Energy Range

  • Vasileios Ntoupis,
  • Christos Michail,
  • Nektarios Kalyvas,
  • Athanasios Bakas,
  • Ioannis Kandarakis,
  • George Fountos and
  • Ioannis Valais

The aim of this study was to experimentally assess the luminescence efficiency of a cerium fluoride (CeF3) inorganic scintillator in crystal form as a possible alternative to high-luminescence but hygroscopic cerium bromide (CeBr3). The experiments w...

  • Article
  • Open Access
6 Citations
1,992 Views
18 Pages

FeCo2O4/MoS2 binary composite catalysts were prepared by the hydrothermal method and calcination method. In this paper, the morphology and structure of the materials were characterized by means of SEM, EDS, XRD, and XPS. It was found that MoS2 has hi...

  • Article
  • Open Access
2 Citations
1,866 Views
16 Pages

Infrared Light Annealing Effect on Pressure Sensor Fabrication Using Graphene/Polyvinylidene Fluoride Nanocomposite

  • Victor K. Samoei,
  • Katsuhiko Takeda,
  • Keiichiro Sano,
  • Angshuman Bharadwaz,
  • Ambalangodage C. Jayasuriya and
  • Ahalapitiya H. Jayatissa

This paper reports the designing and testing, as well as the processing and testing, of a flexible piezoresistive sensor for pressure-sensing applications, utilizing a composite film of graphene/polyvinylidene fluoride (Gr/PVDF). Graphene serves as t...

  • Article
  • Open Access
2 Citations
1,826 Views
15 Pages

Raman Spectroscopy and Microstructural Characterization of Hot-Rolled Copper/Graphene Composite Materials

  • Antoine Bident,
  • Jean-Luc Grosseau-Poussard,
  • Florence Delange,
  • Ahmed Addad,
  • Gang Ji,
  • Yongfeng Lu,
  • Jean-Louis Bobet,
  • Amélie Veillere and
  • Jean-François Silvain

Given the increase in current density in the constituent materials of electrical systems, improving the electrical conductivity of these materials, particularly copper (Cu), is crucial. This would also help to mitigate the heat generated by Joule hea...

  • Article
  • Open Access
3 Citations
1,175 Views
13 Pages

BiFeO3-related perovskite-type materials attract a lot of attention from the viewpoint of applications and fundamental science. In this work, we prepared two modifications of heavily Mn-doped BiFeO3 with the composition of BiFe0.6Mn0.4O3. A high-pres...

  • Article
  • Open Access
1 Citations
2,880 Views
18 Pages

This investigation explores the potential of enhancing aqueous zinc-ion batteries (AZIBs) through the introduction of a novel cathode material, NH4V4O10 (NVO), combined with reduced graphene oxide (rGO). Utilizing Density Functional Theory (DFT), it...

  • Review
  • Open Access
6 Citations
3,847 Views
19 Pages

The Story, Properties and Applications of Bioactive Glass “1d”: From Concept to Early Clinical Trials

  • Dilshat U. Tulyaganov,
  • Simeon Agathopoulos,
  • Konstantinos Dimitriadis,
  • Hugo R. Fernandes,
  • Roberta Gabrieli and
  • Francesco Baino

Bioactive glasses in the CaO–MgO–Na2O–P2O5–SiO2–CaF2 system are highly promising materials for bone and dental restorative applications. Furthermore, if thermally treated, they can crystallize into diopside–fluorap...

  • Article
  • Open Access
2 Citations
2,046 Views
24 Pages

Nanoparticles of iron and iron oxides, as well as their composites, are of great scientific and technological interest. However, their properties and sustainability strongly depend on the preparation methods. Here, we present an original approach to...

  • Review
  • Open Access
2 Citations
2,271 Views
19 Pages

Exploring the Frontiers of Cathode Catalysts in Lithium–Carbon Dioxide Batteries: A Mini Review

  • Jing Guo,
  • Xin Yan,
  • Xue Meng,
  • Pengwei Li,
  • Qin Wang,
  • Yahui Zhang,
  • Shenxue Yan and
  • Shaohua Luo

To mitigate the greenhouse effect and environmental pollution caused by the consumption of fossil fuels, recent research has focused on developing renewable energy sources and new high-efficiency, environmentally friendly energy storage technologies....

  • Review
  • Open Access
7 Citations
3,254 Views
33 Pages

C–H Activation via Group 8–10 Pincer Complexes: A Mechanistic Approach

  • Juan S. Serrano-García,
  • Andrés Amaya-Flórez,
  • Jordi R.-Galindo,
  • Lucero González-Sebastián,
  • Luis Humberto Delgado-Rangel and
  • David Morales-Morales

C–H bond activation is a crucial synthetic strategy widely utilized in both academic and industrial settings. Due to the strong and kinetically inert nature of the C–H bond, its functionalization typically requires metal-based catalysts....

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Inorganics - ISSN 2304-6740