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Separations, Volume 9, Issue 1

2022 January - 20 articles

Cover Story: Natural phenols and phenolic acids are widespread in the plant kingdom, and the dietary sources include fruits and beverages derived from them. These compounds have been widely investigated for their beneficial effects on human health, and several analytical methods have been developed for their determination in these matrices. The GC-MS method presented here involves the derivatization of aromatic carboxylic acids and phenols with ethyl chloroformate; it is particularly advantageous as it can be carried out in aqueous media at room temperature, allowing excellent separation of many different phenolic compounds. This method has been used for the analysis of commercial fruit juices particularly rich in phenolic compounds. Among them, the richest in free aromatic carboxylic acids and phenols are those containing cranberry. View this paper
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Articles (20)

  • Feature Paper
  • Article
  • Open Access
9 Citations
4,464 Views
21 Pages

Steam and Pressure Management for the Conversion of Steelworks Arising Gases to H2 with CO2 Capture by Stepwise Technology

  • Francesco Sebastiani,
  • Leonie Lucking,
  • Marija Sarić,
  • Jebin James and ,
  • Jurriaan Boon,
  • H. J. A. Eric van Dijk,
  • Paul Cobden and
  • Johannis A. Z. Pieterse
  • + 3 authors+ 0 author

Steel production is a main source of CO2 emissions globally. These emissions must be drastically reduced to meet climate change mitigation goals. STEPWISE is a Sorption Enhanced Reactive Process (SERP) technology that converts steel works arising gas...

  • Article
  • Open Access
17 Citations
4,606 Views
13 Pages

Distribution and Estrogenic Risk of Alkylphenolic Compounds, Hormones and Drugs Contained in Water and Natural Surface Sediments, Morelos, Mexico

  • José Gustavo Ronderos-Lara,
  • Hugo Saldarriaga-Noreña,
  • Mario Alfonso Murillo-Tovar,
  • Laura Alvarez and ,
  • Josefina Vergara-Sánchez,
  • Victor Barba and
  • Jorge Antonio Guerrero-Alvarez
  • + 2 authors+ 0 author

This study evaluated the distribution and potential estrogenic risk of the presence of bisphenol A (BPA), 4-nonylphenol (4NP), naproxen (NPX), ibuprofen (IBU), 17-β-estradiol (E2) and 17-α-ethinylestradiol (EE2) in water and sediments of t...

(This article belongs to the Section Environmental Separations)
  • Review
  • Open Access
44 Citations
9,884 Views
33 Pages

Novel Applications of Microextraction Techniques Focused on Biological and Forensic Analyses

  • Cristian D’Ovidio,
  • Martina Bonelli,
  • Enrica Rosato,
  • Angela Tartaglia and ,
  • Halil İbrahim Ulusoy,
  • Victoria Samanidou,
  • Kenneth G. Furton,
  • Abuzar Kabir,
  • Imran Ali and
  • Ugo de Grazia
  • + 7 authors+ 2 authors

In recent years, major attention has been focused on microextraction procedures that allow high recovery of target analytes, regardless of the complexity of the sample matrices. The most used techniques included liquid-liquid extraction (LLE), solid-...

(This article belongs to the Section Advanced Separation Science in Biomedical Research and Clinical Applications)
  • Review
  • Open Access
36 Citations
12,596 Views
21 Pages

Hypericum spp.—An Overview of the Extraction Methods and Analysis of Compounds

  • Valentin Ion,
  • Irina Ielciu,
  • Anca-Gabriela Cârje,
  • Daniela Lucia Muntean and ,
  • Gianina Crişan and
  • Ramona Păltinean
  • + 1 author+ 0 author

The Hypericum genus contains one of the few genera of flowering plants that contains a species with authorization for marketing as a traditional medicine, H. perforatum. Due to the fact that this is a large genus, comprising numerous species, a large...

(This article belongs to the Special Issue Early Career Stars in Separation Analysis of Natural Products and Pharmaceuticals)
  • Article
  • Open Access
4 Citations
5,184 Views
14 Pages

Targeted UHPLC-ESI-MS/MS Analysis of Selected Neurotransmitters, Tryptophan and Its Metabolite Kynurenine in Tau Transgenic Rat Brain Tissue: A Pivotal Study

  • Juraj Piestansky,
  • Andrea Forgacsova,
  • Dominika Olesova,
  • Jaroslav Galba and ,
  • Peter Mikus,
  • Petra Majerova and
  • Andrej Kovac
  • + 2 authors+ 0 author

Neurotransmitters (NT) are widely distributed in the central nervous system. These molecules are important for many physiological processes and the function of the immune system. Imbalance of NT are linked to numerous neurological disorders and disea...

(This article belongs to the Special Issue Chromatographic and Electrophoretic Methods in Current Biomedical Analysis)
  • Article
  • Open Access
2 Citations
3,262 Views
10 Pages

Sensitivity Increase in Headspace Analysis of Hydrocarbons in Water by Using Online Selective Elimination of Gas Extractant

  • Oleg V. Rodinkov,
  • Alexey Y. Pisarev,
  • Leonid N. Moskvin,
  • Aleksandra S. Bugaichenko and
  • Pavel N. Nesterenko

In this study, a novel approach in headspace gas chromatographic analysis using the selective absorption of the gas extractant during concentration of the analytes was developed. The carbon dioxide used as the gas extractant was removed from the samp...

(This article belongs to the Section Environmental Separations)
  • Review
  • Open Access
16 Citations
6,520 Views
23 Pages

State of the Art in Separation Processes for Alternative Working Fluids in Clean and Efficient Power Generation

  • Odi Fawwaz Alrebei,
  • Abdulkarem I. Amhamed,
  • Muftah H. El-Naas,
  • Mahmoud Hayajnh and ,
  • Yasmeen A. Orabi,
  • Ward Fawaz,
  • Ahmad S. Al-tawaha and
  • Agustin Valera Medina
  • + 3 authors+ 0 author

Gas turbines must now comply with much stricter emission control regulations. In fact, to combat the greenhouse effect, regulatory authorities have drastically reduced allowable emission levels. For example, in less than 12 years, the United States&r...

(This article belongs to the Collection State of the Art in Separation Science)
  • Article
  • Open Access
5 Citations
4,126 Views
15 Pages

Escherichia coli are common pathogens, whereas E. coli O157:H7 is the most notorious E. coli strain, owing to its high virulence that can cause serious adverse effects and death. E. coli contains abundant peroxidases. Thus, the presence of E. coli ca...

(This article belongs to the Section Materials in Separation Science)
  • Communication
  • Open Access
2 Citations
5,533 Views
11 Pages

The former St. Antony’s Lead Works site, now the central part of an urban recreational park (Walker Riverside Park) in the east end of Newcastle upon Tyne (England, UK), has been assessed based on the Pb concentration in topsoil according to re...

(This article belongs to the Section Environmental Separations)
  • Article
  • Open Access
3 Citations
4,042 Views
15 Pages

A Novel and Green Method for Turning Food Waste into Environmentally-Friendly Organic Deicing Salts: Enhanced VFA Production through AnMBR

  • Qiuhong Xiang,
  • Kunlun Yang,
  • Ziwen Chen,
  • Manman Li and ,
  • Yuanqi Zhang,
  • Xiaorui Wang,
  • Yingying Jiang,
  • Peng Gu and
  • Hengfeng Miao
  • + 4 authors+ 0 author

In order to improve the production efficiency of volatile fatty acids (VFAs) by anaerobic fermentation of food waste and reduce the cost for the production of organic deicing salt (ODS), ceramic microfiltration (MF) membrane separation was applied in...

(This article belongs to the Section Environmental Separations)
  • Article
  • Open Access
43 Citations
9,359 Views
15 Pages

Low-Cost and Eco-Friendly Hydroxyapatite Nanoparticles Derived from Eggshell Waste for Cephalexin Removal

  • Huda S. Alhasan,
  • Nadiyah Alahmadi,
  • Suhad A. Yasin,
  • Mohammed Y. Khalaf and
  • Gomaa A. M. Ali

This work describes the hydroxyapatite nanoparticle (HAP) preparation from eggshell waste and their application as an adsorbent for Cephalexin (Ceph) antibiotic removal from aqueous solutions. Chemical precipitation with phosphoric acid was used to e...

  • Article
  • Open Access
7 Citations
5,149 Views
11 Pages

Natural phenol and phenolic acids are widely distributed in the plant kingdom and the major dietary sources include fruits and beverages derived therefrom. Over the past decades, these compounds have been widely investigated for their beneficial effe...

(This article belongs to the Special Issue Food Quality and Safety: Advances in Analytical Methods and Applications)
  • Article
  • Open Access
13 Citations
12,074 Views
9 Pages

Ecdysterone is a naturally occurring steroid hormone of the ecdysteroid class. This group is widely marketed to athletes in dietary supplements as a “natural anabolic agent”, advertised to increase strength and muscle mass during resistance training,...

(This article belongs to the Topic Application of Analytical Chemistry in Exercise Physiology and Pharmacology)
  • Article
  • Open Access
9 Citations
3,259 Views
17 Pages

Enantiomeric Separation and Molecular Modelling of Bioactive 4-Aryl-3,4-dihydropyrimidin-2(1H)-one Ester Derivatives on Teicoplanin-Based Chiral Stationary Phase

  • Isabella Bolognino,
  • Antonio Carrieri,
  • Rosa Purgatorio,
  • Marco Catto and ,
  • Rocco Caliandro,
  • Benedetta Carrozzini,
  • Benny Danilo Belviso,
  • Maria Majellaro,
  • Eddy Sotelo and
  • Cosimo Damiano Altomare
  • + 6 authors+ 1 author

The enantiomeric separation of 15 racemic 4-aryl-3,4-dihydropyrimidin-2(1H)-one (DHP) alkoxycarbonyl esters, some of which proved to be highly active as A2B adenosine receptor antagonists, was carried out by HPLC on ChirobioticTM TAG, a chiral statio...

(This article belongs to the Special Issue Separation, Extraction and Purification of Natural Products from Plants)
  • Article
  • Open Access
6 Citations
3,856 Views
17 Pages

Effect of Cone-Plate Clarifier Structure Parameters on Flocculation Efficiency

  • Yulong Zhang,
  • Peikun Liu,
  • Linjing Xiao,
  • Long Chang and ,
  • Fangping Yan and
  • Lanyue Jiang
  • + 1 author+ 0 author

In this study, a coal mine water flocculation system was established. A series of flocculation tests were carried out at different structural parameters (cylinder height, cone-plate insertion depth and cone-plate spacing) to better investigate the ef...

(This article belongs to the Special Issue Research on Separation Performance of Separator)
  • Article
  • Open Access
11 Citations
5,024 Views
14 Pages

A specific and sensitive approach using magnetic nanoparticle solid-phase extraction combined with gas chromatography-mass spectrometry (GC-MS) was carried out and applied in the simultaneous determination of 16 kinds of synthetic cathinones in human...

(This article belongs to the Section Forensic Science and Toxicology)
  • Editorial
  • Open Access
1 Citations
4,793 Views
4 Pages

The Pivotal Role of Chemistry in Research and Development

  • Victoria Samanidou,
  • George Zachariadis,
  • Michael A. Terzidis and
  • Adamantini Paraskevopoulou

Undoubtedly, all pivotal advances in a great number of scientific fields rely on advances in chemistry. [...]

(This article belongs to the Special Issue Research as Development Perspective 2019)
  • Article
  • Open Access
8 Citations
5,890 Views
17 Pages

In this study, a simple and environmentally friendly method was developed for the extraction of seven active coumarins from Angelica dahurica (Hoffm.) Benth. & Hook.f. ex Franch. & Sav.(A. dahurica) based on deep eutectic solvents (DESs)...

(This article belongs to the Special Issue Extraction and Analysis of Plant Active Ingredients)
  • Article
  • Open Access
14 Citations
5,866 Views
16 Pages

Cross-Linking Combined with Surfactant Bilayer Assembly Enhances the Hydrophilic and Antifouling Properties of PTFE Microfiltration Membranes

  • Shijie Xu,
  • Wenzhong Ma,
  • Haicun Yang,
  • Zheng Cao and ,
  • Fanghong Gong and
  • Chunlin Liu
  • + 1 author+ 0 author

The inherent strong hydrophobicity of Polytetrafluoroetylene (PTFE) microfiltration membranes results in low separation efficiency and easy contamination. In order to enhance its hydrophilic and antifouling properties, we first modified the PTFE micr...

(This article belongs to the Section Materials in Separation Science)
  • Review
  • Open Access
170 Citations
22,637 Views
44 Pages

This review investigates antifouling agents used in the process of membrane separation (MS), in reverse osmosis (RO), ultrafiltration (UF), nanofiltration (NF), microfiltration (MF), membrane distillation (MD), and membrane bioreactors (MBR), and cla...

(This article belongs to the Special Issue Advances in Novel Polymeric Membranes and Membrane Process)
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Separations - ISSN 2297-8739