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Metals, Volume 15, Issue 2

2025 February - 126 articles

Cover Story: Understanding texture formation in melt pools allows for the modification of the surface-layer microstructure and corresponding material properties, providing an opportunity to integrate laser surface re-melting into metal additive manufacturing. Assisted by recently developed real-time temperature monitoring techniques, namely laser surface re-melting and EBSD, this study investigates the fundamental relationship between cooling rate and crystallographic texture formation in single melting tracks on the Inconel 718 plate. The results imply that laser surface re-melting could modify the surface structure from a random grain orientation to a crystallographically layered structure. View this paper
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Articles (126)

  • Article
  • Open Access
1 Citations
1,331 Views
20 Pages

19 February 2025

The KR desulfurization process in steel plants faces challenges, such as excessive temperature drop and low lime utilization. This study employs numerical simulations to analyze the effects of cross-shaped impeller dimensions on the flow field, veloc...

  • Article
  • Open Access
2 Citations
2,016 Views
16 Pages

18 February 2025

The oxidation behaviour of Ti alloys is a crucial aspect for structural components operating at high service temperature. The aim of this study is to identify the oxidation kinetics and mechanism of binary Ti-Cu alloys with a progressively higher amo...

  • Article
  • Open Access
1 Citations
2,605 Views
39 Pages

18 February 2025

In the context of the deep geological disposal of high-level and intermediate-level long-lived radioactive waste in France, the Callovian–Oxfordian (Cox) clay formation has been selected as a natural barrier. Thus, understanding the corrosion p...

  • Article
  • Open Access
2 Citations
2,207 Views
24 Pages

Compression Behaviour of L-PBF-Manufactured Ti6Al4V BCC Lattices

  • John Daniel Arputharaj,
  • Shahrooz Nafisi and
  • Reza Ghomashchi

18 February 2025

Laser powder bed fusion (L-PBF) is a widely used additive manufacturing technique that enables the creation of complex lattice structures with applications in biomedical implants and aerospace components. This study investigates the impact of relativ...

  • Article
  • Open Access
2 Citations
952 Views
22 Pages

An Inverse Piecewise Flow Curve Determination Method for Torsion Tests at Elevated Temperature

  • Aditya Vuppala,
  • Holger Brüggemann,
  • David Bailly and
  • Emad Scharifi

18 February 2025

This paper presents an extended method for determining flow curves under shear loading using torsion tests, a technique often used to characterize plastic behavior in metal forming. Torsion tests are advantageous due to their ability to achieve flow...

  • Article
  • Open Access
2 Citations
1,609 Views
17 Pages

Analysis of the Influence of Process Parameters on Transverse Flux Induction Heating of Endless-Rolling Strip

  • Lin Gao,
  • Fang-Zhou Shi,
  • Meng Yan,
  • Yi-Ping He,
  • Jian Xiang,
  • Xiao-Hu Qi and
  • Hua-Gui Huang

18 February 2025

This study focuses on the effect of an induction heating device on the entry of a thin strip continuous casting and rolling line. A finite element model for the electromagnetic–thermal coupling of transverse magnetic flux induction heating was...

  • Article
  • Open Access
3 Citations
3,255 Views
13 Pages

18 February 2025

In order to improve the magnetic properties of non-oriented silicon steel, the effects of different normalizing temperatures on the microstructure, texture, and magnetic properties of 3.0%Si 0.8%Al non-oriented silicon steel were studied by OM, EBSD,...

  • Article
  • Open Access
2,199 Views
23 Pages

The Treatment of Iron-Containing Foundry Dusts with the Aim of Their Recycling and Their Effect on the Properties of Cast Iron

  • Patrik Fedorko,
  • Alena Pribulova,
  • Peter Futas,
  • Marcela Pokusova,
  • Jozef Petrik,
  • Peter Blasko,
  • Marcin Brzeziński and
  • Mariusz Łucarz

18 February 2025

The foundry industry is an industry with a large production of waste. One such type of waste is fine-grained to dust-like waste, depending on the stage of the foundry process in which it is generated. As part of this research, dust samples were colle...

  • Review
  • Open Access
5 Citations
2,583 Views
31 Pages

A Review on the Magnetovolume Effect of the Full Heusler Alloys Ni2MnZ (Z = In, Sn, Sb)

  • Takeshi Kanomata,
  • Xiao Xu,
  • Takuo Sakon,
  • Yuki Nagata,
  • Shin Imada,
  • Toshihiro Omori,
  • Ryosuke Kainuma,
  • Tetsujiro Eto,
  • Yoshiya Adachi and
  • Yoshiya Uwatoko
  • + 3 authors

18 February 2025

The full Heusler alloys Ni2MnZ (Z = In, Sn, Sb) exhibit ferromagnetic properties with a Curie temperature (TC) above room temperature. The magnetic properties of Ni2MnZ (Z = In, Sn, Sb) were studied through a combination of experiments and band calcu...

  • Article
  • Open Access
1 Citations
1,188 Views
11 Pages

18 February 2025

Copper alloys are widely used in many branches of industry due to their excellent corrosion resistance and high level of both electrical conductivity and strength. Among others, there are copper alloys with magnesium, which are known and commonly use...

  • Article
  • Open Access
1,290 Views
13 Pages

Effect of Ag and Ti Addition on the Deformation and Tribological Behavior of Zr-Co-Al Bulk Metallic Glass

  • Siva Shankar Alla,
  • Mohammad Eskandari,
  • Shristy Jha,
  • Ziyu Pei,
  • S. Vincent,
  • Wook Ha Ryu,
  • Eun Soo Park and
  • Sundeep Mukherjee

18 February 2025

The effects of a small addition of Ag and Ti on the thermal stability, mechanical properties, and tribological behavior of Zr-Co-Al bulk metallic glass (BMG) were investigated. A 5 at.% addition of Ag and Ti to the Zr-Co-Al base alloy improved the th...

  • Article
  • Open Access
2 Citations
1,729 Views
11 Pages

Extraction of Rhenium with Trialkylbenzylammonium Chloride

  • I. A. Kalina,
  • E. V. Zlobina,
  • Zh. Zh. Bekishev,
  • A. G. Ismailova,
  • Kh. S. Tassibekov,
  • Z. A. Iskakov,
  • B. Zh. Toksanbayev,
  • A. T. Kumarbekova and
  • A. S. Fomenko

18 February 2025

This study investigates the extraction of rhenium using trialkylbenzyl ammonium chloride (TABAC) as an alternative to trialkylamine (TAA) for recovering rhenium from highly diluted solutions. Rhenium, present as ReO4 over a wide acidity range,...

  • Article
  • Open Access
2 Citations
2,126 Views
14 Pages

17 February 2025

The notorious corrosion resistance of carbon steel significantly limits its scope of application. In this study, a strategy involving electrodeposited nickel followed by annealing was proposed to improve the corrosion resistance of materials. The eff...

  • Article
  • Open Access
3 Citations
1,515 Views
16 Pages

Effect of Porosity on the Corrosion Behavior of FeCoNiMnCrx Porous High-Entropy Alloy in 3.5 Wt.% NaCl Solution

  • Ying Wang,
  • Shuobin Chen,
  • Yuhua Peng,
  • Xijie Zheng,
  • Dong Li,
  • Cheng Nie,
  • Pan Gong,
  • Zhigang Hu and
  • Ming Ma

17 February 2025

The effects of different Cr contents on the corrosion resistance of FeCoNiMnCrx (x = 0.5;1;1.5) porous high-entropy alloys (HEAs) in 3.5 wt.% NaCl solution on corrosion resistance was investigated. With the increase in Cr content, the total porosity...

  • Article
  • Open Access
3 Citations
1,536 Views
19 Pages

17 February 2025

This study explores a new microdestructive on-site metallographic inspection technique for analyzing metal artifacts. In the current archeometrical work, the metallographic analysis of metal artifacts requires mechanical sampling, which not only dama...

  • Article
  • Open Access
1 Citations
1,242 Views
21 Pages

High-Efficiency Extraction of Lithium and Aluminum from Coal Fly Ash Using Activation-Sintering Technology

  • Chenliang Zhang,
  • Yanheng Li,
  • Qiaojing Zhao,
  • Mingjing Xu,
  • Bin Yao,
  • Pengpeng Zhang,
  • Xuan Ji and
  • Jiawei Fan

17 February 2025

The objective of this study was to investigate the potential for extracting lithium and aluminum from coal fly ash in depth. The activation-sintering method was used to study how factors like activators, sintering agents, sintering time, leaching con...

  • Article
  • Open Access
3 Citations
1,433 Views
14 Pages

Microstructure and Performance of Body-Centered Cubic-Based Dual-Phase Composite Eutectic High-Entropy Alloys Prepared by Si Doping

  • Saike Liu,
  • Aoxiang Li,
  • Kaiwen Kang,
  • Jinshan Zhang,
  • Di Huang,
  • Chunning Che,
  • Yiteng Jiang,
  • Mingkun Xu,
  • Borui Zhang and
  • Gong Li
  • + 1 author

16 February 2025

AlCrFeNi-based high-entropy alloys (HEAs) have emerged as a prominent research system, attracting significant interest due to their compositional diversity and the tunability of their phase structures. However, in practical applications, single-phase...

  • Article
  • Open Access
1,602 Views
15 Pages

15 February 2025

In this study, slow strain rate tensile tests (SSRT) were performed on T91 in lead-bismuth eutectic (LBE) with saturated oxygen to investigate the effects of temperature (350 °C, 450 °C, and 550 °C), strain rate (1 × 10−5/s an...

  • Article
  • Open Access
1 Citations
1,663 Views
11 Pages

15 February 2025

Copper alloys are widely used in faucet production due to their formability, enabling the casting of complex shapes, as well as to their antibacterial properties and good corrosion resistance. This study examined a faucet produced by the low-pressure...

  • Article
  • Open Access
2 Citations
7,299 Views
20 Pages

Gold Leaching from an Auriferous Ore by Alkaline Thiosulfate–Glycine–Copper Solution

  • Alex S. Redrovan,
  • Ernesto de la Torre and
  • Carlos F. Aragón-Tobar

14 February 2025

The thiosulfate–glycine–copper system has emerged as a promising alternative for gold recovery, offering significant advantages over cyanidation and ammoniacal thiosulfate leaching. Recognizing the limitations of thiosulfate degradation i...

  • Article
  • Open Access
3 Citations
1,381 Views
14 Pages

Effect of Multi-Phase Composite Structure on the Mechanical Properties of AlxFe1.5CoNiC0.12 High Entropy Alloys

  • Yiteng Jiang,
  • Aoxiang Li,
  • Kaiwen Kang,
  • Jinshan Zhang,
  • Di Huang,
  • Chunning Che,
  • Saike Liu,
  • Mingkun Xu,
  • Yaqing Li and
  • Gong Li
  • + 1 author

14 February 2025

Single-phase high entropy alloys (HEAs) exhibit limited mechanical properties while dual-phase and multi-phase HEAs offer better strength, toughness, and stability. In this paper, the as-cast AlxFe1.5CoNiC0.12 HEAs with triple-phase dendritic composi...

  • Article
  • Open Access
1,745 Views
15 Pages

An Investigation on Li-Ion Battery Recycling via In Situ Alloying: Influence of Slag Composition on Li and F Evaporation

  • Safoura Babanejad,
  • Hesham Ahmed,
  • Charlotte Andersson,
  • Olga Rodríguez-Largo,
  • Anton Andersson,
  • Lorena Alcaraz and
  • Félix A. López

14 February 2025

The amount of waste Li-Ion Batteries (LIBs) is significantly growing. Therefore, scholars and industries are exploring efficient ways to recover their valuable elements. Meanwhile, steel production generates Fe-rich slag, which is often sold for cons...

  • Article
  • Open Access
2 Citations
2,252 Views
11 Pages

14 February 2025

In this study, a series of quaternary TiFe-based alloys, Ti1.05Fe0.85Cr0.1−xMox (x = 0, 0.03, 0.05, 0.07, 0.1), were designed to investigate the activation and hydrogen ab-/desorption properties of TiFe hydrogen storage alloys through the subst...

  • Article
  • Open Access
1 Citations
2,047 Views
14 Pages

Preparation of Ultrafine Spherical Al-Mg Alloy and Its Energy Release Characteristics in Explosives

  • Junhui Liu,
  • Jie Yao,
  • Zichao Wang,
  • Wei Liu,
  • Jianxin Nie and
  • Shi Yan

14 February 2025

The substitution of aluminum powder with highly reactive ultrafine aluminum-based metal fuels has a significant impact on the energy release of aluminum-containing energetic materials because of their excellent energy density and combustion performan...

  • Article
  • Open Access
1 Citations
1,199 Views
14 Pages

14 February 2025

Grains of commercially pure titanium (CP-Ti) can be refined via rotary-die equal-channel angular pressing (RD-ECAP) to meet higher application requirements. However, the grain refinement mechanism of CP-Ti during RD-ECAP has not been fully studied. H...

  • Article
  • Open Access
1,264 Views
14 Pages

13 February 2025

This investigation aimed at evaluating the weldability of a 2.1 GPa-grade hot stamping steel (HSS) containing 0.40 wt.% carbon using laser butt welding. It is shown that the subject HSS can be properly joined by laser welding without welding defects,...

  • Feature Paper
  • Review
  • Open Access
8 Citations
4,796 Views
40 Pages

A Review on the Additive Manufacturing of W-Cu Composites

  • Muhammad Hussain,
  • Bosheng Dong,
  • Zhijun Qiu,
  • Ulf Garbe,
  • Zengxi Pan and
  • Huijun Li

13 February 2025

In recent years, W-Cu composite systems have become very interesting subjects due to good electrical and thermal conductivity, high-temperature strength, certain plasticity, and excellent radiation resistance. W-Cu composites are a very important cla...

  • Article
  • Open Access
1,351 Views
12 Pages

Unveiling Irreversible β-Relaxations in Metallic Glasses via Electrical Resistivity

  • Jianyu Chen,
  • Shuai Ren,
  • Zhe Chen,
  • Jie Dong,
  • Lixing Zhu,
  • Yangguang Zhan,
  • Wenxue Wang,
  • Shenghao Zeng,
  • Jing Xiao and
  • Jiang Ma
  • + 1 author

13 February 2025

Dynamic relaxations play an important role in understanding the nature of glass. The conventional methods to explore dynamic relaxations rely on the measurement of mechanical and thermic properties, while new methods that may provide a new perspectiv...

  • Article
  • Open Access
1,862 Views
19 Pages

Effect of the Use of Some Rare Earth Compounds as Corrosion Inhibitors for API 5L X70 Steel in Saline Medium

  • Salvador Hernández García,
  • Araceli Espinoza Vázquez,
  • Laura Nadxieli Palacios-Grijalva,
  • Anatolio Martínez Jiménez,
  • Francisco Javier Rodríguez Gómez,
  • Óscar Armando Gómez Vargas,
  • Alan Miralrio,
  • Miguel Castro and
  • Ricardo Orozco Cruz

13 February 2025

This work presents a comparative study of five rare earth compounds—Erbium nitrate pentahydrate lll (Er), Neodymium nitrate pentahydrate (Nd), Samarium III Nitrate Hexahydrate (Sm), Yterbium III Chloride Hexahydrate (Yb) and Praseodymium nitrat...

  • Article
  • Open Access
1 Citations
1,244 Views
28 Pages

12 February 2025

X-ray diffractograms of high-speed steels are analyzed using machine learning algorithms to accurately classify various heat treatments. These differently heat-treated steel samples are also investigated by dilatometric analysis and by metallographic...

  • Article
  • Open Access
1,588 Views
27 Pages

12 February 2025

Friction stir welding (FSW) is a solid-state welding method. The effects of tool structure, tool rotational speed, and welding speed in friction stir welding on the temperature, microstructure, and mechanical properties during the welding of 3 mm thi...

  • Review
  • Open Access
9 Citations
4,704 Views
25 Pages

12 February 2025

As advanced structural materials, titanium alloys have found extensive applications in aerospace, medical devices, and precision electronics industries, serving as critical components for achieving lightweight designs in high-end equipment. In aerosp...

  • Article
  • Open Access
2 Citations
1,577 Views
20 Pages

Consideration of Statistical Approaches Within the Accelerated Assessment of Fatigue Properties of Metallic Materials

  • Fabian Weber,
  • Aline Wagner,
  • Janina Koziol,
  • Felix Weber,
  • Christoph Broeckmann and
  • Peter Starke

12 February 2025

Understanding the fatigue behaviour of metallic materials is highly important when it comes to a reliable assessment of material degradation as a result of dynamic loading. Because the provision of such data is associated with great testing effort le...

  • Article
  • Open Access
1 Citations
1,329 Views
16 Pages

Influence of Augmentation Compositions and Confinement Layers on Flyer Velocity in Laser Impact Welding

  • Mohammed Abdelmaola,
  • Brian Thurston,
  • Boyd Panton,
  • Anupam Vivek and
  • Glenn Daehn

12 February 2025

Small-scale impact welding may have several advantages over rivets: the strength can be higher, it can be applied right at the edges in lap joints, and it can be lighter and more easily installed if simple systems can be developed. Laser Impact Weldi...

  • Article
  • Open Access
1,944 Views
14 Pages

Dynamic and Static Strength Analysis of 5056 Aluminum Alloy Fabricated by Wire-Arc Additive Manufacturing

  • Alexey Evstifeev,
  • Aydar Mavlyutov,
  • Darya Volosevich,
  • Marina Gushchina,
  • Olga Klimova-Korsmik,
  • Konstantin Nasonovskiy and
  • Sofya Shabunina

12 February 2025

This article presents the results of experimental studies on the dynamic and static strength of commercial aluminum alloy 5056 manufactured by wire-arc additive manufacturing (WAAM). The main objective is to evaluate the utilization potential of this...

  • Article
  • Open Access
1 Citations
1,099 Views
19 Pages

12 February 2025

High-strength steel (HSS) plates are widely used due to their superior performance. However, residual stresses generated during welding can exacerbate the initiation of fatigue cracks, and the accurate prediction of residual stresses is crucial. Ther...

  • Article
  • Open Access
4 Citations
2,459 Views
14 Pages

Intelligent System for Reducing Waste and Enhancing Efficiency in Copper Production Using Machine Learning

  • Bagdaulet Kenzhaliyev,
  • Timur Imankulov,
  • Aksultan Mukhanbet,
  • Sergey Kvyatkovskiy,
  • Maral Dyussebekova and
  • Nurdaulet Tasmurzayev

12 February 2025

The growing environmental impact of copper production necessitates innovative approaches for optimizing metallurgical processes and minimizing waste. This study addresses this challenge by leveraging advanced machine learning (ML) techniques to enhan...

  • Review
  • Open Access
5 Citations
4,812 Views
20 Pages

12 February 2025

CSAM is a solid-state process for depositing metal or metal-based composite materials in which the fine particles of metal or composite material are accelerated to supersonic velocity, making successful bonding feasible due to the high-impact velocit...

  • Article
  • Open Access
3 Citations
2,165 Views
17 Pages

Design and Performance Evaluation of Sn58Bi/SAC305 Layered Composite Solder for Low-Temperature Applications

  • Zhongxu Zhang,
  • Dan Zhang,
  • Chenyu Li,
  • Wenlong Yang,
  • Haitao Ma,
  • Haoran Ma and
  • Yunpeng Wang

12 February 2025

This study proposes a Sn58Bi/SAC305 layered composite solder designed for low-temperature applications. By alternating high-melting SAC305 and low-melting Sn58Bi layers, the composite achieves a liquidus temperature of ~180 °C, comparable to trad...

  • Article
  • Open Access
2 Citations
1,328 Views
16 Pages

11 February 2025

Mechanical properties and corrosion resistance of La2O3/A356 composites with different contents of La2O3 were investigated by optical microscopy, X-ray diffractometry, scanning electron microscopy, electrochemical tests, and immersion corrosion tests...

  • Article
  • Open Access
1 Citations
1,826 Views
20 Pages

11 February 2025

As the third generation of thin slab continuous casting and rolling technology, endless strip production (ESP) has been widely used in the steelmaking industry. The key equipment in this process, the funnel-type mold, is prone to accidents such as sl...

  • Article
  • Open Access
1,581 Views
18 Pages

Fracture Mechanism of H13 Steel During Tensile Testing Based on In Situ EBSD

  • Yunling Li,
  • Dangshen Ma,
  • Hongxiao Chi,
  • Shulan Zhang,
  • Jian Zhou and
  • Jin Cai

11 February 2025

This paper employs in situ Electron Backscatter Diffraction (EBSD) tensile technology to thoroughly consider the evolution of microstructure, grain size, grain boundary characteristics, orientation differences, and dislocation density of H13 steel du...

  • Article
  • Open Access
2 Citations
1,941 Views
29 Pages

Assessing the Impact of Top-Up Powder Reuse Strategy on MS1 Powder Characteristics and L-PBF Printed Part Properties

  • Tingting Huang,
  • Kaung Sitt Thu,
  • Zilu Zhang,
  • Luming Che,
  • Peilun Xu,
  • Jerry Ying Hsi Fuh and
  • Heow Pueh Lee

11 February 2025

In additive manufacturing, particularly with Laser–Powder-Bed Fusion (L-PBF), augmenting recycled powder with virgin powder is common to extend lifespan. This practice complicates tracking recycling cycles, as parts consist of layers from both...

  • Communication
  • Open Access
2 Citations
1,466 Views
9 Pages

Interfacial Cracking Failure Mechanism of Chromium-Coated Zircaloy Cladding for ATF Materials

  • Xinfeng Li,
  • Yang Liu,
  • Yan Cui,
  • Jun Hui,
  • Jianxun Fu and
  • Jin Zhang

11 February 2025

In this study, the interfacial cracking mechanism of Cr-coated Zircaloy cladding tubes was investigated through a combination of tensile testing, advanced microstructural characterization, and first-principle calculations. The results demonstrate the...

  • Article
  • Open Access
2 Citations
1,716 Views
32 Pages

Defining and Optimising High-Fidelity Models for Accurate Inherent Strain Calculation in Laser Powder Bed Fusion

  • Iñaki Setien,
  • Michele Chiumenti,
  • Maria San Sebastian,
  • Manuel A. Caicedo and
  • Carlos A. Moreira

11 February 2025

Powder Bed Fusion–Laser Beam (PBF-LB) is a leading technique in metal additive manufacturing, yet it continues to face challenges related to residual stresses and distortions. The inherent strain method has emerged as a valuable predictive tool...

  • Article
  • Open Access
2 Citations
1,195 Views
18 Pages

Effect of Aging Temperature on the Impact Wear Properties and Wear Mechanism of Lightweight Wear-Resistant Steel

  • Liwen Liang,
  • Jianchang Sun,
  • Ben Cheng,
  • Suotao Wang,
  • Mintao Chen and
  • Qingfeng Wang

10 February 2025

In this study, the microstructure, mechanical properties, wear resistance, and wear-hardening mechanism of Fe-28Mn-8.5Al-1.0C lightweight wear-resistant steel after heat treatment at different aging temperatures were examined. The results show that t...

  • Article
  • Open Access
3 Citations
4,076 Views
24 Pages

Mechanical and Corrosion Properties of AA2024 Aluminum Alloy with Multimodal Gradient Structures

  • Zhenwei Xie,
  • Liexing Zhou,
  • Jun Li,
  • Yonghua Duan,
  • Mingjun Peng,
  • Hongbo Xiao,
  • Xiong Du,
  • Yuanjie Zhao and
  • Mengnie Li

10 February 2025

Enhancing the strength and toughness of aluminum alloys using microstructure optimization remains a key challenge. In this study, an AA2024 aluminum alloy with a double-layer multi-gradient structure was fabricated using 50% constrained deformation a...

  • Article
  • Open Access
1 Citations
1,332 Views
15 Pages

Deformation Behavior and Microstructure Evolution of High-Strength and -Toughness Ti55531 Titanium Alloy

  • Yucheng Yang,
  • Tongsheng Deng,
  • Zhi Liu,
  • Hai Liu,
  • Yupeng Yuan and
  • Wei Chen

10 February 2025

In this paper, constant strain rate compression was carried out by means of an MMS-100 thermal/force simulation tester in a temperature range of 790~940 °C, with a strain rate of 0.01–1 s−1 and a compression volume of 60%. A linear re...

  • Article
  • Open Access
1 Citations
1,229 Views
13 Pages

10 February 2025

The microstructure, mechanical properties, corrosion behavior, cytocompatibility, and antibacterial properties of biodegradable Zn-3Cu-xMg (x = 0, 0.5, 1 wt.%) alloys with or without pulsed magnetic field treatment during casting were systematically...

  • Article
  • Open Access
2 Citations
1,591 Views
24 Pages

9 February 2025

Advanced high-strength steels are considered the first choice when manufacturing lighter vehicles. Quench-partitioning (QP) steels are good candidates that fulfill manufacturing and performance requirements with their outstanding strength and formabi...

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Metals - ISSN 2075-4701