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Crystals, Volume 15, Issue 2

2025 February - 100 articles

Cover Story: This study investigates the self-assembly of KTOF4 sphere–rod amphiphilic molecules in mixed water–dioxane solvents. TEM uncovers self-assembled spherical structures of KTOF4 in dilute solutions. These spheres are filled with smectic-like layers of KTOF4 which are separated by layers of the solution. There are two types of layer packings: (i) concentric spheres and (ii) flat layers. The layered structures resemble thermotropic smectic A liquid crystals and their lyotropic analogs. The layered packings reveal edge and screw dislocations. The evaporation of the solvent produces a bulk birefringent liquid crystal phase with textures resembling that of uniaxial nematic liquid crystals. These findings demonstrate that sphere–rod molecules produce a variety of self-assembled structures that are controlled by the solvent properties. View this paper
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Articles (100)

  • Article
  • Open Access
1 Citations
1,461 Views
15 Pages

19 February 2025

Ilmenite concentrate has emerged as the key titanium raw material for exploitation and utilization, playing a crucial role in the preparation of metallic titanium and titanium dioxide. However, the presence of impurities such as Fe, Ca, and Mg in ilm...

  • Article
  • Open Access
1,030 Views
13 Pages

Interactions Between Sc2O3 Ceramics and Calcium–Magnesium–Alumina–Silicate (CMAS) at Elevated Temperature

  • Zupeng Mo,
  • Zijian Mo,
  • Zhiyun Yu,
  • Yifan Cheng,
  • Yiling Miao and
  • Tianquan Liang

19 February 2025

The thermochemical interactions of Sc2O3 ceramics with CMAS at 1250 °C and 1300 °C were investigated in this paper. A continuously dense reaction layer (DRL) forms on the surface of the ceramic at the beginning of the reaction within 15 min,...

  • Article
  • Open Access
1 Citations
1,905 Views
20 Pages

19 February 2025

Silicon carbide is a covalently bonded engineering material and structural ceramic with excellent mechanical properties, high resistance to oxidation, corrosion, and wear, and tunable thermal conductivity. The exceptional thermal conductivity of sili...

  • Article
  • Open Access
1,004 Views
17 Pages

18 February 2025

In this study, the authors employed first-principles calculations to investigate the adsorption and decomposition processes involved in non-catalytic growth of vapor-growth carbon fiber (VGCF) using a non-catalytic growth method. The adsorption and d...

  • Article
  • Open Access
1,580 Views
18 Pages

Structural Properties of PE-Based Wood–Plastic Composites Depending on the Share of Lignocellulosic Particles

  • Izabela Betlej,
  • Marek Barlak,
  • Sławomir Borysiak,
  • Aneta Bombalska,
  • Barbara Nasiłowska,
  • Ján Sedliačik and
  • Piotr Borysiuk

18 February 2025

Wood–plastic composites (WPCs) are an excellent example of materials that, thanks to the possibility of using recycled raw materials, directly fit into the circular economy. The properties and quality of composites depend largely on the appropr...

  • Article
  • Open Access
1 Citations
912 Views
15 Pages

Kinetics of Reduction of Iron Ore Powder by Industrial Lignin from Pulping and Papermaking Waste Biomass Energy

  • Wendi Zhou,
  • Dongwen Xiang,
  • Qiang Zhang,
  • Guoqing Wu,
  • Yajie Wang,
  • Dong Li,
  • Qinghua Zhang and
  • Huaxin Hu

17 February 2025

To explore the application of industrial lignin, a waste biomass resource, in the field of metallurgy, the kinetic behavior of iron ore powder reduction by Shenmu bituminous coal, Lu’an anthracite, and industrial lignin under different carbon&n...

  • Review
  • Open Access
7 Citations
5,908 Views
57 Pages

17 February 2025

With recent electronic devices relying on sub-nanometer features, the understanding of device performance requires a direct probe of the atomic arrangement. As an ideal tool for crystallographic analysis at the nanoscale, aberration-corrected transmi...

  • Review
  • Open Access
3 Citations
2,732 Views
24 Pages

Innovation in Metal Casting Processes: A Review of Metal Matrix Nanocomposites in Metal and Bimetal Castings

  • Tayyab Subhani,
  • Mohamed Ramadan,
  • Naglaa Fathy,
  • Abdel Khaliq and
  • K. S. Abdel Halim

17 February 2025

The arrival of nanotechnology in the field of metal castings is considered a promising approach to significantly improve the quality, performance and lifetime of castings. A better understanding of the implementation of nanotechnology in the metal ca...

  • Article
  • Open Access
1 Citations
1,660 Views
14 Pages

17 February 2025

Impurities significantly constrain the production of high-purity magnesium sulfate crystals, essential for advanced magnesium-based materials. Sodium–magnesium co-precipitation affects the crystals’ purity and surface smoothness, with NaC...

  • Article
  • Open Access
2 Citations
988 Views
15 Pages

The Effect of Carbon on the Crystallization and Electrochemical Behavior of Portland Cement

  • Jeunghyeuon Cho,
  • Byung-Hyun Shin,
  • Miyoung You,
  • Seongjun Kim,
  • Jinyong Park,
  • Jung-Woo Ok,
  • Jonggi Hong,
  • Taekyu Lee,
  • Jong-Seong Bae and
  • Jang-Hee Yoon
  • + 1 author

17 February 2025

Cement is one of the most widely used structural materials and serves as the primary component of concrete. Among the various types, Portland cement is the most commonly utilized due to its excellent strength and corrosion resistance. Recently, effor...

  • Article
  • Open Access
2 Citations
1,267 Views
20 Pages

16 February 2025

Crystallography, a cornerstone of materials science, provides critical insights into material structures through techniques such as X-ray diffraction (XRD). Among the metrics derived from XRD, intensity serves as a key parameter, reflecting the elect...

  • Article
  • Open Access
1,068 Views
17 Pages

16 February 2025

The nano-architecture of titanium oxide is a key element of a wide range of applications, mainly optical and catalytic activities. Therefore, the current study focuses on engineering and designing three interesting nanostructures of titanium oxides:...

  • Article
  • Open Access
1 Citations
1,036 Views
24 Pages

15 February 2025

Semiconductors characterized by ultrawide bandgaps (UWBGs), exceeding the SiC bandgap of 3.2 eV and the GaN bandgap of 3.4 eV, are currently under focus for applications in high-power and radio-frequency (RF) electronics, as well as in deep-ultraviol...

  • Article
  • Open Access
2 Citations
920 Views
15 Pages

15 February 2025

Serial crystallography (SX) enables the determination of biologically relevant structures at room temperature while minimizing radiation damage. During SX experiments, the beam center on diffraction images can shift due to X-ray beam movements or det...

  • Article
  • Open Access
2 Citations
1,218 Views
22 Pages

14 February 2025

CuMn1−xMgxO2 (x = 0–0.06) polycrystalline samples were prepared using the hydrothermal method at T = 100 °C for 24 h in Teflon-line stainless steel autoclaves. The samples were crystallized, forming crednerite structures (C2/m space g...

  • Article
  • Open Access
1 Citations
1,462 Views
20 Pages

14 February 2025

As part of crystal growth experiments on transition metal oxidotellurates using chemical vapor transport reactions or hydrothermal conditions, single crystals of NiIITeVIO4 and CuIITeIV2O5 were obtained for the first time in the form of new modificat...

  • Review
  • Open Access
3 Citations
3,260 Views
24 Pages

13 February 2025

This review summarizes the application of two-dimensional metal–organic framework (2D MOF) nanostructures and their composites in the detoxification of chemical warfare agents (CWAs). Two-dimensional MOFs, characterized by their high specific s...

  • Article
  • Open Access
2 Citations
1,442 Views
24 Pages

13 February 2025

The double-arrow hollow cylinder (DAHC) has excellent mechanical properties under axial compression loads due to its negative Poisson ratio structure. To improve finite element simulation efficiency for parameter optimization analysis, an automatic m...

  • Article
  • Open Access
2 Citations
1,182 Views
16 Pages

Low-Cost Foamed Ceramics with Enhanced Mechanical Performance and Uniform Pore Size Structure

  • Junchi Weng,
  • Xiulin Shen,
  • Yixian Yang,
  • Xuejia Zhang,
  • Mengke Fan,
  • Ge Gao,
  • Zeming Guo,
  • Zhenfei Lv and
  • Xiujuan Feng

13 February 2025

Due to the lack of effective utilization, fly ash and red mud accumulate in large quantities and cause serious harm to the environment. In this experiment, a low-cost preparation of foamed ceramics was realized by applying the foaming agent addition...

  • Article
  • Open Access
1 Citations
1,085 Views
14 Pages

13 February 2025

Micrometeorites (MMs), which are cosmic dust grains ranging from 10 microns to 2 mm in size, can reach the Earth’s surface through collisions with asteroids or by fragmentation of comets in space. When MMs enter the atmosphere, they are heated...

  • Article
  • Open Access
1 Citations
796 Views
9 Pages

13 February 2025

An evaluation method was proposed to calculate the deformation strain of a high-temperature mushy zone (HTMZ) related to twin-roll strip casting (TSC) with regard to typical 6.5 wt.% Si electrical steel (6.5 Si steel) on the basis of the crystal&mdas...

  • Article
  • Open Access
2 Citations
1,649 Views
15 Pages

Liquid Crystalline Structures Formed by Sphere–Rod Amphiphilic Molecules in Solvents

  • Nilanthi P. Haputhanthrige,
  • Yifan Zhou,
  • Jingfan Wei,
  • Min Gao,
  • Tianbo Liu and
  • Oleg D. Lavrentovich

13 February 2025

Self-assembly of amphiphilic molecules is an important phenomenon attracting a broad range of research. In this work, we study the self-assembly of KTOF4 sphere–rod amphiphilic molecules in mixed water–dioxane solvents. The molecules are...

  • Article
  • Open Access
2,483 Views
16 Pages

Stabilizing Perovskite Solar Cells by Methyltriphenylphosphonium Iodide Studied with Maximum Power Point Tracking

  • Niklas Manikowsky,
  • Zekarias Teklu Gebremichael,
  • Chikezie Williams Ugokwe,
  • Bashudev Bhandari,
  • Steffi Stumpf,
  • Ulrich S. Schubert and
  • Harald Hoppe

13 February 2025

The use of organic halide salts to passivate metal halide perovskite (MHP) surface defects has been studied extensively. Passivating the surface defects of the MHP is of critical importance for realizing highly efficient and stable perovskite solar c...

  • Article
  • Open Access
1,201 Views
15 Pages

12 February 2025

Ultrasonic imaging methods show significant advantages in detecting internal defects of composite crystalline materials. For polymer-bonded explosives (PBXs) with highly filled crystalline particles, the strong acoustic attenuation caused by their he...

  • Article
  • Open Access
1,438 Views
13 Pages

Influence of the Annealing Temperature on the Properties of {ZnO/CdO}30 Superlattices Deposited on c-Plane Al2O3 Substrate by MBE

  • Anastasiia Lysak,
  • Aleksandra Wierzbicka,
  • Piotr Dłużewski,
  • Marcin Stachowicz,
  • Jacek Sajkowski and
  • Ewa Przezdziecka

10 February 2025

{CdO/ZnO}m superlattices (SLs) have been grown on c-plane sapphire substrates by plasma-assisted molecular beam epitaxy (PA-MBE). The observation of satellite peaks in the XRD studies of the as-grown and annealed samples confirms the presence of a pe...

  • Article
  • Open Access
1 Citations
1,207 Views
14 Pages

A Study of the Sorption Properties and Changes in the Structure and State of the Ti-25Al-25Nb (at.%) Alloy System Under Thermocyclic Loading

  • Yernat Kozhakhmetov,
  • Yerkezhan Tabiyeva,
  • Nurya Mukhamedova,
  • Azamat Urkunbay,
  • Madina Aidarova,
  • Aibar Kizatov and
  • Elfira Sagymbekova

10 February 2025

This study is focused on the sorption properties and the changes in the structure and state of Ti-25Al-25Nb (at.%) system alloys under thermal cyclic loading. These samples were produced by combining high-energy processing methods through mechanizati...

  • Article
  • Open Access
10 Citations
2,016 Views
12 Pages

Simulation of Lead-Free Perovskite Solar Cells with Improved Performance

  • Saood Ali,
  • Praveen Kumar,
  • Khursheed Ahmad and
  • Rais Ahmad Khan

10 February 2025

At present, lead halide PVSKSCs are promising photovoltaic cells but have some limitations, including their low stability in ambient conditions and the toxicity of lead. Thus, it will be of great significance to explore lead-free perovskite materials...

  • Article
  • Open Access
1 Citations
1,140 Views
14 Pages

Effects of Y Additions on the Microstructure and Mechanical Properties of CoCr1.7Ni Medium-Entropy Alloys

  • Shaoshuai Zhou,
  • Xiaoyong Shu,
  • Linli Hu,
  • Xunyu Yuan,
  • Panpan Qiu and
  • Xiwen Xu

10 February 2025

In order to improve the room temperature yield strength of X and enhance its engineering applicability, a series of CoCr1.7NiYx (x = 0, 0.01, 0.02, 0.03, 0.04, and 0.1 at.%) medium-entropy alloys were synthesized to investigate the effect of Y additi...

  • Article
  • Open Access
4 Citations
1,306 Views
17 Pages

10 February 2025

Materials utilized in extreme environments, such as those necessitating protection and impact resistance at cryogenic temperatures, must exhibit high strength, ductility, and structural stability. However, most alloys fail to maintain adequate toughn...

  • Article
  • Open Access
1 Citations
2,911 Views
22 Pages

Procedures for X-Ray Diffraction Phase Analysis: The Case of Fine Sediments from Peña Blanca, Chihuahua, Mexico

  • Carmen del Rocio Caraveo-Castro,
  • Yair Rodríguez-Guerra,
  • Luis Fuentes-Montero,
  • Andrés Isaak González-Jacquez,
  • Luis E. Fuentes-Cobas and
  • María Elena Montero-Cabrera

10 February 2025

In a broad project designed to examine uranium transport by surface water from Sierra Peña Blanca to Laguna del Cuervo in the Chihuahuan Desert, sediments from intermittent streams and the lagoon have been extracted and studied. Two samples we...

  • Article
  • Open Access
9 Citations
3,689 Views
18 Pages

Effect of Nickel Content and Cooling Rate on the Microstructure of as Cast 316 Stainless Steels

  • Lei Chen,
  • Yang Wang,
  • Yafeng Li,
  • Zhengrui Zhang,
  • Zhixuan Xue,
  • Xinyu Ban,
  • Chaohui Hu,
  • Haixiao Li,
  • Jun Tian and
  • Chao Chen
  • + 2 authors

10 February 2025

To meet the requirement of low magnetic permeability, which, in turn, lowers the ferrite content of castings, of special interest is 316 stainless steel, whose low ferrite content renders it suitable also for nuclear power applications. Therefore, th...

  • Article
  • Open Access
6 Citations
2,397 Views
16 Pages

Photodegradation of Amoxicillin Under UV Irradiation Using Hydrogen Peroxide

  • Isam Y. Qudsieh,
  • Mohammad Ashraf Ali and
  • Ibrahim M. Maafa

9 February 2025

This experiment investigated the degradation of amoxicillin in water using hydrogen peroxide (H2O2) and UV Irradiation. The parameters analyzed included the initial concentration of amoxicillin, the pH of the solution, and the quantity of H2O2 used....

  • Review
  • Open Access
1,969 Views
25 Pages

Progress in Plastic Work–Heat Conversion of Metallic Crystals

  • Peng-Fei Yue,
  • Shao-Dan Yang,
  • Yan Gao,
  • Rong-Hao Shi,
  • Guo-Shang Zhang,
  • Zhi-Yuan Zhu,
  • Dong Han and
  • Ke-Xing Song

8 February 2025

The Taylor–Quinney coefficient (TQC) is a critical parameter quantifying the thermal conversion of plastic work during deformation in metallic crystals. This review provides a comprehensive summary of recent advances in TQC research, spanning e...

  • Article
  • Open Access
1,026 Views
21 Pages

8 February 2025

Traditional magnesium structural materials are used widely due to their light weight; however, their corrosion resistance is poor. In order to address this problem and improve the strength simultaneously, SiCp-, SiCnp-, and SiCnw-reinforced Mg-2Zn-0....

  • Article
  • Open Access
1 Citations
793 Views
12 Pages

Study on Pitting Behavior of Welding Joint of Bimetal Composite Pipes in Suspended Sulfur Solution

  • Yuwei Sun,
  • Sirong Yu,
  • Bingying Wang,
  • Lin Liu,
  • Enyang Liu and
  • Tao Feng

8 February 2025

Due to the severe corrosion environment, corrosion problems caused by sulfur deposition are one important reason for the failure of composite pipes in the long-term service process when Incoloy825/X65 bimetallic composite pipes are used in high-sulfu...

  • Review
  • Open Access
1 Citations
3,484 Views
15 Pages

8 February 2025

The chemical transport method is a process that occurs naturally; however, it is also very useful in the chemical laboratory environment for the synthesis of inorganic crystals. It was successfully used for the syntheses of simple and complex inorgan...

  • Article
  • Open Access
922 Views
15 Pages

8 February 2025

In response to the growing demand for fuel economy and the imperative to reduce greenhouse gas emissions, the automotive industry has embraced structural lightweighting through multi-material solutions. This poses challenges in joining dissimilar lig...

  • Article
  • Open Access
1 Citations
1,547 Views
15 Pages

One-Pot Strategies for Lithium Recovery from Beta-Spodumene and LTA-Type Zeolite Synthesis

  • Leonardo Leandro dos Santos,
  • Rubens Maribondo do Nascimento and
  • Sibele Berenice Castellã Pergher

8 February 2025

This study presents a groundbreaking method for extracting lithium from beta-spodumene while simultaneously achieving the sustainable synthesis of LTA-type zeolite, designated as LPM-15, without relying on organic solvents or calcination. Lithium ext...

  • Article
  • Open Access
1,428 Views
19 Pages

First-Principles Study of Mechanical Properties of Pb(ZrxTi1−x)O3 in the Cubic and Tetragonal Phase

  • Xudong Ran,
  • Shaolan Zhou,
  • Shaowen Zhou,
  • Wei Lei,
  • Lin Xiang,
  • Yang Wu,
  • Bingfei Hu,
  • Jianquan Tao and
  • Qiang Chen

5 February 2025

In this study, we employed the first-principles method based on density functional theory to calculate the elastic constants, bulk modulus, shear modulus, Young’s modulus, Poisson’s ratio, and density of states for both cubic and tetragon...

  • Article
  • Open Access
1 Citations
3,445 Views
10 Pages

Aerosol Deposited Polycrystalline PbZr0.53Ti0.47O3 Thick Films with a Large Transverse Piezoelectric Coefficient

  • Long Teng,
  • Juan Yang,
  • Yongguang Xiao,
  • Hongbo Cheng,
  • Shibo Gong,
  • Gao Luo,
  • Jinlin Yang,
  • Wenjia Zhang,
  • Zhenwei Shen and
  • Jun Ouyang

5 February 2025

The aerosol deposition (AD) method utilizes high kinetic-energy submicron powders to impact and form a film on a substrate. It is a highly efficient deposition method, capable of producing films or coatings with a strong interfacial bonding and a den...

  • Article
  • Open Access
3,365 Views
13 Pages

4 February 2025

Urbanization in hot and humid regions such as southern China has increased the demand for comfortable indoor environments. In order to design a material for efficient passive indoor humidity regulation, this study investigates a composite material th...

  • Article
  • Open Access
1,647 Views
33 Pages

Unraveling the Determinant Mechanisms in Flow-Mediated Crystal Growth and Phase Behaviors

  • L. Connor Willis,
  • Tesia D. Janicki,
  • Rekha R. Rao and
  • Z. Leonardo Liu

4 February 2025

To uncover the critical mechanisms responsible for mesoscopic level development during flow-mediated crystal growth, we develop a semi-two-way hydrodynamic coupled structural phase-field crystal formalism (HXPFC-s2). The new formalism, inspired by pr...

  • Article
  • Open Access
2 Citations
1,805 Views
15 Pages

Estimation of Hardness of Single-Phase Metallic Alloys

  • Ottó K. Temesi,
  • Nguyen Q. Chinh,
  • Levente Vitos and
  • Lajos K. Varga

2 February 2025

First, we discuss a common feature of single-phase pure metals and amorphous and high-entropy alloys: the maximum value of hardness corresponding to a valence electron count (VEC) value of around 6.5–7. This correlation is explained by the coin...

  • Article
  • Open Access
1,313 Views
22 Pages

2 February 2025

Multi-robot coordinated wire-arc directed energy deposition (MRC-WA-DED) has proliferated in recent decades, employing asynchronous independent heating sources to deposit material simultaneously. Beyond enhancing efficiency, MRC-WA-DED introduces a s...

  • Article
  • Open Access
1,034 Views
18 Pages

The Effect of Different Laser Powers on the Properties of Ni65A Cladding Reinforced by WC

  • Mengqiong Huang,
  • Jincheng Yu,
  • Jinyi Wang,
  • Guilin Xu and
  • Xin Jin

2 February 2025

In this paper, the effects of different laser powers on the microstructure, microhardness, and wear resistance of Ni65A/WC composite coatings were investigated by using laser cladding technology. The morphology, phase structure, elemental distributio...

  • Article
  • Open Access
2 Citations
1,184 Views
20 Pages

Copper-Substituted Calcium Orthophosphate (CaxCu1-x)HPO4.nH2O for Humidity Detection

  • Yurii Milovanov,
  • Mehran Dadkhah,
  • Ahmed Sabry Afify and
  • Jean-Marc Tulliani

1 February 2025

Calcium orthophosphate material (Ca1-xCux)HPO4.nH2O (0.4 ≤ x ≤ 1) with the gradual replacement of Ca2+ with Cu2+ ions were synthesized by a chemical precipitation technique. Samples were characterized by X-ray diffraction (XRD), scanning electr...

  • Article
  • Open Access
2 Citations
2,268 Views
15 Pages

1 February 2025

Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, yet their stability under environmental stressors remains a critical challenge. This study examines the substrate-dependent degradation mechanisms of perovskite films...

  • Article
  • Open Access
1,534 Views
14 Pages

1 February 2025

Recently, a variety of nephrite containing localized pink mineral aggregates has emerged on the market, which is sometimes referred to as “peach blossom jade” by some merchants. Currently, there is limited research on this type of nephrit...

  • Article
  • Open Access
922 Views
13 Pages

Nonlinear Optical Bistability in a Bragg Reflector Multilayered Structure with MoS2

  • Songqing Tang,
  • Xilei Dong,
  • Leyong Jiang,
  • Haishao Chen,
  • Zhuoya Sun,
  • Fuping Zhang,
  • Yangbin Zhu and
  • Yunyang Ye

31 January 2025

The special band structure of bilayer MoS2 makes it show strong nonlinear optical characteristics in the visible band, which provides a new way to develop visible nonlinear devices. In this paper, we present a theoretical analysis of the optical bist...

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Crystals - ISSN 2073-4352