Materials, Volume 18, Issue 15
2025 August-1 - 297 articles
Cover Story: The use of small-molecule active materials in AORFBs is significantly limited by the issue of stability and crossover. To address these challenges, we designed a polymer cathode material, P-T-S, with high water solubility, which features a polyvinylimidazole backbone functionalized with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and sulfonate groups. P-T-S exhibits a solubility of 34 Ah L−1 in water and 31 Ah L−1 in 1.0 M NaCl aqueous solution (NaClaq). When paired with methyl viologen to assemble a pH-neutral AORFB with a theoretical capacity of 15 Ah L−1, the system exhibits a material utilization rate of 92.0%, an average capacity retention rate of 99.74% per cycle (99.74% per hour), and an average Coulombic efficiency of 98.69% over 300 consecutive cycles at 30 mA cm−2. This work provides a new design strategy for polymer materials for high-performance AORFBs. View this paper - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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