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Materials, Volume 11, Issue 2

2018 February - 157 articles

Cover Story: Metal–elastomer interfacial systems—often encountered in stretchable electronics—demonstrate remarkably high interface fracture toughness values. This paper unravels the underlying dissipative mechanisms through a systematic numerical/experimental multi-scale approach. In particular, the experimental studies conclusively reveal the essential role of fibrillation mechanisms at the micro-meter scale during the metal–elastomer delamination process. Micro-scale numerical analyses on single and multiple fibrils show that the dynamic release of the stored elastic energy by multiple fibril fracture—including the interaction with the adjacent deforming bulk elastomer and its highly nonlinear behaviour—provide a mechanistic understanding of the high work-of-separation. View this paper
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Articles (157)

  • Feature Paper
  • Article
  • Open Access
13 Citations
6,241 Views
10 Pages

TopUp SERS Substrates with Integrated Internal Standard

  • Sophie Patze,
  • Uwe Huebner,
  • Karina Weber,
  • Dana Cialla-May and
  • Juergen Popp

24 February 2018

Surface-enhanced Raman spectroscopy (SERS) is known as a molecular-specific and highly sensitive method. In order to enable the routine application of SERS, powerful SERS substrates are of great importance. Within this manuscript, a TopUp SERS substr...

  • Review
  • Open Access
208 Citations
10,776 Views
11 Pages

24 February 2018

Bone defects caused by trauma or pathological events are major clinical and socioeconomic burdens. Thus, the efforts of regenerative medicine have been focused on the development of non-biodegradable materials resembling bone features. Consequently,...

  • Article
  • Open Access
5 Citations
4,047 Views
11 Pages

24 February 2018

A meso-mechanical damage model is developed to predict the tensile damage behaviors of bulk metallic glass composites (BMGCs) toughened by ductile particles. In this model, the deformation behaviors of the BMG matrix and particles are described by th...

  • Article
  • Open Access
51 Citations
7,144 Views
10 Pages

24 February 2018

The microstructure with homogeneously distributed grains and less prior particle boundary (PPB) precipitates is always desired for powder metallurgy superalloys after hot isostatic pressing (HIPping). In this work, we studied the effects of HIPping p...

  • Feature Paper
  • Article
  • Open Access
8 Citations
4,686 Views
12 Pages

24 February 2018

Magnesium alloys offer a favored alternative to steels and aluminum alloys due to their low density and relatively high specific strength. Their application potentials are, however, impeded by poor formability at room temperature. In the current work...

  • Article
  • Open Access
31 Citations
7,388 Views
14 Pages

24 February 2018

Modifying bio-based degradable polymers such as polylactide (PLA) and poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) with non-degradable agents will compromise the 100% degradability of their resultant composites. This work developed a facile and so...

  • Letter
  • Open Access
40 Citations
8,889 Views
7 Pages

Bottom–Up Electrodeposition of Large-Scale Nanotwinned Copper within 3D Through Silicon Via

  • Fu-Long Sun,
  • Zhi-Quan Liu,
  • Cai-Fu Li,
  • Qing-Sheng Zhu,
  • Hao Zhang and
  • Katsuaki Suganuma

23 February 2018

This paper is the first to report a large-scale directcurrent electrodeposition of columnar nanotwinned copper within through silicon via (TSV) with a high aspect ratio (~4). With this newly developed technique, void-free nanotwinned copper array cou...

  • Article
  • Open Access
78 Citations
8,394 Views
18 Pages

23 February 2018

High-entropy alloys (HEAs) are promising structural materials due to their excellent comprehensive performances. The use of mechanically alloyed powders to deposit HEA coatings through atmospheric plasma spraying (APS) is an effective approach that c...

  • Article
  • Open Access
6 Citations
5,067 Views
12 Pages

23 February 2018

In this work, a three dimensional (3D) graphene-nitrogen doped carbon nanotubes (G-NCNTs) network was successfully fabricated on the surface of a glassy carbon (GC) electrode using the pulse potential method (PPM) in a graphene oxide-nitrogen doped c...

  • Feature Paper
  • Review
  • Open Access
45 Citations
8,270 Views
33 Pages

23 February 2018

In a recent report, the World Health Organisation (WHO) classified antibiotic resistance as one of the greatest threats to global health, food security, and development. Methicillin-resistant Staphylococcus aureus (MRSA) remains at the core of this t...

  • Article
  • Open Access
16 Citations
4,950 Views
17 Pages

23 February 2018

Graphene oxide (GO) was employed for the preparation of GO-zinc oxide (ZnO). The hydroxyl group on the surface was exploited to trigger the l-lactide ring-opening polymerization. A composite material with poly(l-lactide) (PLLA) chains grafted to the...

  • Review
  • Open Access
264 Citations
15,584 Views
29 Pages

23 February 2018

Fe3O4 nanoparticles (NPs), the most traditional magnetic nanoparticles, have received a great deal of attention in the biomedical field, especially for targeted drug/gene delivery systems, due to their outstanding magnetism, biocompatibility, lower t...

  • Article
  • Open Access
11 Citations
5,032 Views
9 Pages

22 February 2018

The location and nature of the doped elements strongly affect the structural, electronic and optical properties of TiO2. To tailor the band structure and modify the photoelectrochemical properties of TiO2, a pair of dopants is selected. Fe and N atom...

  • Article
  • Open Access
28 Citations
5,894 Views
11 Pages

Gentamicin-Releasing Mesoporous ZnO Structures

  • Marco Laurenti and
  • Valentina Cauda

22 February 2018

Among metal oxides, zinc oxide (ZnO) is one of the most attractive materials thanks to its biocompatible and biodegradable properties along with the existence of various morphologies featuring piezoelectric, semiconducting and photocatalytic activiti...

  • Article
  • Open Access
9 Citations
4,767 Views
12 Pages

Electrical/Mechanical Monitoring of Shape Memory Alloy Reinforcing Fibers Obtained by Pullout Tests in SMA/Cement Composite Materials

  • Eui-Hyun Kim,
  • Hyunbae Lee,
  • Jae-Hwan Kim,
  • Seung-Muk Bae,
  • Heesu Hwang,
  • Heesun Yang,
  • Eunsoo Choi and
  • Jin-Ha Hwang

22 February 2018

Self-healing is an essential property of smart concrete structures. In contrast to other structural metals, shape memory alloys (SMAs) offer two unique effects: shape memory effects, and superelastic effects. Composites composed of SMA wires and conv...

  • Article
  • Open Access
9 Citations
5,829 Views
17 Pages

Carbon-Fibre-Reinforced SiC Composite (C/SiSiC) as an Alternative Material for Endoprosthesis: Fabrication, Mechanical and In-Vitro Biological Properties

  • Aline Reichert,
  • Michael Seidenstuecker,
  • Rainer Gadow,
  • Hermann O. Mayr,
  • Norbert P. Suedkamp,
  • Sergio H. Latorre,
  • Partick Weichand and
  • Anke Bernstein

22 February 2018

Particle-induced periprosthetic osteolysis and subsequent aseptic implant loosening are a major cause of compromising the long-term results of total joint replacements. To date, no implant has been able to mirror radically the tribological factors (f...

  • Article
  • Open Access
5 Citations
5,486 Views
14 Pages

Ultrarapid Multimode Microwave Synthesis of Nano/Submicron β-SiC

  • Min Zhao,
  • Michael Johnson,
  • Wenzhi He,
  • Guangming Li,
  • Chen Zhao,
  • Luling Yu,
  • Juwen Huang and
  • Haochen Zhu

22 February 2018

This paper presents the design, development and realization of a fast and novel process for the synthesis of 3C silicon carbide (β-SiC) nanorods and submicron powder. Using SiO2 (or Si) and activated carbon (AC), this process allows β-SiC to be synth...

  • Article
  • Open Access
20 Citations
6,000 Views
18 Pages

Effect of Silver-Emitting Filler on Antimicrobial and Mechanical Properties of Soft Denture Lining Material

  • Ewa Jabłońska-Stencel,
  • Wojciech Pakieła,
  • Anna Mertas,
  • Elżbieta Bobela,
  • Jacek Kasperski and
  • Grzegorz Chladek

22 February 2018

Colonization of silicone-based soft lining materials by pathogenic yeast-type fungi is a common problem associated with the use of dentures. In this study, silver sodium hydrogen zirconium phosphate (SSHZP) was introduced into polydimethylsiloxane-ba...

  • Article
  • Open Access
21 Citations
4,239 Views
12 Pages

Research on the Transmission Characteristics of Air-Coupled Ultrasound in Double-Layered Bonded Structures

  • Xing-Guo Wang,
  • Wen-Lin Wu,
  • Zhi-Cheng Huang,
  • Jun-Jie Chang and
  • Nan-Xing Wu

21 February 2018

The ultrasonic transmission spectrum in a double-layered bonded structure is related closely to its interfacial stiffness. Consequently, researching the regularity of the transmission spectrum is of significant interest in evaluating the integrity of...

  • Feature Paper
  • Article
  • Open Access
52 Citations
9,601 Views
10 Pages

Comparison of SF6 and CF4 Plasma Treatment for Surface Hydrophobization of PET Polymer

  • Matic Resnik,
  • Rok Zaplotnik,
  • Miran Mozetic and
  • Alenka Vesel

21 February 2018

The fluorination of the polymer polyethylene terephthalate in plasma created from SF6 or CF4 gas at various pressures was investigated. The surface was analysed by X-ray photoelectron spectroscopy and water contact angle measurements, whereas the pla...

  • Article
  • Open Access
57 Citations
5,218 Views
8 Pages

Further Theoretical Insight into the Mechanical Properties of Polycaprolactone Loaded with Organic–Inorganic Hybrid Fillers

  • Saverio Maietta,
  • Teresa Russo,
  • Roberto De Santis,
  • Dante Ronca,
  • Filomena Riccardi,
  • Michelina Catauro,
  • Massimo Martorelli and
  • Antonio Gloria

21 February 2018

Experimental/theoretical analyses have already been performed on poly(ε-caprolactone) (PCL) loaded with organic–inorganic fillers (PCL/TiO2 and PCL/ZrO2) to find a correlation between the results from the small punch test and Young’s modulus of the m...

  • Article
  • Open Access
38 Citations
6,615 Views
12 Pages

20 February 2018

Owing to its controllable tolerance, simple operation and no need for welding at construction site, the composite system involving grouted cement material, steel material and ductile iron material is widely used as grouted splice sleeve (GSS) connect...

  • Article
  • Open Access
11 Citations
5,063 Views
7 Pages

20 February 2018

In this work, plastic deformation was locally introduced at room temperature by nanoindentation on a γ-TiAl-based alloy. Comprehensive analyses of microstructures were performed before and after deformation. In particular, the Burgers vectors, the li...

  • Feature Paper
  • Article
  • Open Access
15 Citations
6,330 Views
18 Pages

TiO2@PEI-Grafted-MWCNTs Hybrids Nanocomposites Catalysts for CO2 Photoreduction

  • Caterina Fusco,
  • Michele Casiello,
  • Lucia Catucci,
  • Roberto Comparelli,
  • Pietro Cotugno,
  • Aurelia Falcicchio,
  • Francesco Fracassi,
  • Valerio Margiotta,
  • Anna Moliterni and
  • Angelo Nacci
  • + 2 authors

20 February 2018

Anatase (TiO2) and multiwalled carbon nanotubes bearing polyethylenimine (PEI) anchored on their surface were hybridized in different proportions according to a sol-gel method. The resulting nanocomposites (TiO2@PEI-MWCNTs), characterized by BET, XRD...

  • Article
  • Open Access
3 Citations
4,833 Views
12 Pages

Layup Configuration Effect on Notch Residual Strength in Composite Laminates

  • Venkateswaran Santhanakrishnan Balakrishnan,
  • Holger Seidlitz and
  • Sabine Weiß

20 February 2018

The current trend shows an increasing demand for composites due to their high stiffness to weight ratio and the recent progress in manufacturing and cost reduction of composites. To combine high strength and stiffness in a cost-effective way, composi...

  • Article
  • Open Access
20 Citations
5,816 Views
26 Pages

20 February 2018

The corrosion of reinforced steel, and subsequent reinforced concrete degradation, is a major concern for infrastructure durability. New materials with specific, tailor-made properties or the establishment of optimum construction regimes are among th...

  • Article
  • Open Access
44 Citations
6,742 Views
16 Pages

Tunable Bandgap and Optical Properties of Black Phosphorene Nanotubes

  • Chunmei Li,
  • Zhongjing Xie,
  • Zhiqian Chen,
  • Nanpu Cheng,
  • Jinghui Wang and
  • Guoan Zhu

19 February 2018

Black phosphorus (BP), a new two-dimensional material, has been the focus of scientists’ attention. BP nanotubes have potential in the field of optoelectronics due to their low-dimensional effects. In this work, the bending strain energy, electronic...

  • Article
  • Open Access
5 Citations
4,177 Views
23 Pages

18 February 2018

A novel photocatalyst ZnBiErO4 was firstly synthesized by solid-state reaction method and its structural and photocatalytic properties were analyzed by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and UV-Vis diffu...

  • Feature Paper
  • Review
  • Open Access
68 Citations
8,624 Views
15 Pages

16 February 2018

Nanogels are hydrogels formed by connecting nanoscopic micelles dispersed in an aqueous medium, which give an opportunity for incorporating hydrophilic payloads to the exterior of the micellar networks and hydrophobic payloads in the core of the mice...

  • Article
  • Open Access
16 Citations
7,145 Views
21 Pages

15 February 2018

A Boundary Element Method (BEM) approach was developed for the analysis of pile groups. The proposed method includes: the non-linear behavior of the soil by a hyperbolic modulus reduction curve; the non-linear response of reinforced concrete pile sec...

  • Article
  • Open Access
36 Citations
6,470 Views
18 Pages

Highly Efficient Intracellular Protein Delivery by Cationic Polyethyleneimine-Modified Gelatin Nanoparticles

  • Ming-Ju Chou,
  • Hsing-Yi Yu,
  • Jui-Ching Hsia,
  • Ying-Hou Chen,
  • Tzu-Ting Hung,
  • Hsiao-Mei Chao,
  • Edward Chern and
  • Yi-You Huang

15 February 2018

Intracellular protein delivery may provide a safe and non-genome integrated strategy for targeting abnormal or specific cells for applications in cell reprogramming therapy. Thus, highly efficient intracellular functional protein delivery would be be...

  • Article
  • Open Access
21 Citations
6,209 Views
18 Pages

The Preparation and Optical Properties of Novel LiLa(MoO4)2:Sm3+,Eu3+ Red Phosphor

  • Jiaxi Wang,
  • Li Luo,
  • Baoyu Huang,
  • Jingqi He,
  • Wei Zhang,
  • Weiren Zhao and
  • Jianqing Wang

14 February 2018

Novel LiLa1−xy(MoO4)2:xSm3+,yEu3+ (in short: LL1−xyM:xSm3+,yEu3+) double molybdate red phosphors were synthesized by a solid-state reaction at as low temperature as 610 °C. The optimal doping concentration of Sm3+ in LiLa1−x(MoO4)2:xSm3+ (LL1−xM:xS...

  • Article
  • Open Access
98 Citations
9,290 Views
18 Pages

Influence of Scanning Strategies on Processing of Aluminum Alloy EN AW 2618 Using Selective Laser Melting

  • Daniel Koutny,
  • David Palousek,
  • Libor Pantelejev,
  • Christian Hoeller,
  • Rudolf Pichler,
  • Lukas Tesicky and
  • Jozef Kaiser

14 February 2018

This paper deals with various selective laser melting (SLM) processing strategies for aluminum 2618 powder in order to get material densities and properties close to conventionally-produced, high-strength 2618 alloy. To evaluate the influence of lase...

  • Article
  • Open Access
72 Citations
6,114 Views
12 Pages

14 February 2018

Biochar is an excellent absorbent for most heavy metal ions and organic pollutants with high specific surface area, strong aperture structure, high stability, higher cation exchange capacity and rich surface functional groups. To improve the selectiv...

  • Article
  • Open Access
22 Citations
6,668 Views
10 Pages

Printing Smart Designs of Light Emitting Devices with Maintained Textile Properties

  • Inge Verboven,
  • Jeroen Stryckers,
  • Viktorija Mecnika,
  • Glen Vandevenne,
  • Manoj Jose and
  • Wim Deferme

13 February 2018

To maintain typical textile properties, smart designs of light emitting devices are printed directly onto textile substrates. A first approach shows improved designs for alternating current powder electroluminescence (ACPEL) devices. A configuration...

  • Article
  • Open Access
12 Citations
6,301 Views
15 Pages

HDPE/Chitosan Blends Modified with Organobentonite Synthesized with Quaternary Ammonium Salt Impregnated Chitosan

  • Maria José G. De Araújo,
  • Rossemberg C. Barbosa,
  • Marcus Vinícius L. Fook,
  • Eduardo L. Canedo,
  • Suédina M. L. Silva,
  • Eliton S. Medeiros and
  • Itamara F. Leite

13 February 2018

In this study, blends based on a high density polyethylene (HDPE) and chitosan (CS) were successfully prepared by melt processing, in a laboratory internal mixer. The CS biopolymer content effect (up to maximum of 40%), and, the addition of bentonite...

  • Article
  • Open Access
23 Citations
5,147 Views
19 Pages

13 February 2018

Epoxy coatings incorporating different content of sulfosalicylic acid doped polyaniline (PANI-SSA) have been investigated for corrosion protection of 5083 aluminum alloy in 3.5% NaCl solution. The performance of the coatings is studied using a combin...

  • Review
  • Open Access
37 Citations
6,391 Views
16 Pages

13 February 2018

Stress in laser cladding coating is an important factor affecting the safe operation of remanufacturing components. Ultrasonic testing has become a popular approach in the nondestructive evaluation of stress, because it has the advantages of safety,...

  • Article
  • Open Access
50 Citations
4,796 Views
12 Pages

13 February 2018

This paper presents a study of new two-dimensional composite structures with respect to their thermomechanical properties. The investigated structures are based on very well-known auxetic geometries—i.e., the anti-tetrachiral and re-entrant honeycomb...

  • Review
  • Open Access
350 Citations
19,652 Views
24 Pages

Carbon-Based Nanomaterials/Allotropes: A Glimpse of Their Synthesis, Properties and Some Applications

  • Salisu Nasir,
  • Mohd Zobir Hussein,
  • Zulkarnain Zainal and
  • Nor Azah Yusof

13 February 2018

Carbon in its single entity and various forms has been used in technology and human life for many centuries. Since prehistoric times, carbon-based materials such as graphite, charcoal and carbon black have been used as writing and drawing materials....

  • Article
  • Open Access
13 Citations
5,693 Views
13 Pages

Encapsulation of Multiple Microalgal Cells via a Combination of Biomimetic Mineralization and LbL Coating

  • Minjeong Kim,
  • Myoung Gil Choi,
  • Ho Won Ra,
  • Seung Bin Park,
  • Yong-Joo Kim and
  • Kyubock Lee

13 February 2018

The encapsulation of living cells is appealing for its various applications to cell-based sensors, bioreactors, biocatalysts, and bioenergy. In this work, we introduce the encapsulation of multiple microalgal cells in hollow polymer shells of rhomboh...

  • Article
  • Open Access
60 Citations
5,892 Views
8 Pages

Fatigue Behavior of Porous Ti-6Al-4V Made by Laser-Engineered Net Shaping

  • Nima Razavi,
  • Giancarlo G. Bordonaro,
  • Paolo Ferro,
  • Jan Torgersen and
  • Filippo Berto

12 February 2018

The fatigue behavior and fracture mechanisms of additively manufactured Ti-6Al-4V specimens are investigated in this study. Three sets of testing samples were fabricated for the assessment of fatigue life. The first batch of samples was built by usin...

  • Article
  • Open Access
87 Citations
10,720 Views
14 Pages

Comparison of Ultem 9085 Used in Fused Deposition Modelling (FDM) with Polytherimide Blends

  • Gianluca Cicala,
  • Giulia Ognibene,
  • Salvatore Portuesi,
  • Ignazio Blanco,
  • Mario Rapisarda,
  • Eugenio Pergolizzi and
  • Giuseppe Recca

12 February 2018

Polyetherimide (PEI) blends modified by either polycarbonate (PC) or polyethylene terephthalate glycol-modified (PETG) were prepared. The latter modifier (PETG) was an industrial grade widely used for fused deposition modelling (FDM) printing. PEI bl...

  • Article
  • Open Access
9 Citations
4,599 Views
10 Pages

12 February 2018

The magnetic, electrical transport and thermal expansion properties of Mn3Zn1−xCoxN (x = 0.2, 0.4, 0.5, 0.7, 0.9) have been systematically investigated. Co-doping in Mn3ZnN complicates the magnetic interactions, leading to a competition between antif...

  • Review
  • Open Access
232 Citations
11,096 Views
38 Pages

Chemical Sensing Applications of ZnO Nanomaterials

  • Savita Chaudhary,
  • Ahmad Umar,
  • K. K. Bhasin and
  • Sotirios Baskoutas

12 February 2018

Recent advancement in nanoscience and nanotechnology has witnessed numerous triumphs of zinc oxide (ZnO) nanomaterials due to their various exotic and multifunctional properties and wide applications. As a remarkable and functional material, ZnO has...

  • Article
  • Open Access
80 Citations
8,058 Views
11 Pages

12 February 2018

Poly-ether-ether-ketone (PEEK) fabricated by fused deposition modeling for medical applications was evaluated in terms of mechanical strength and in vitro cytotoxicity in this study. Orthogonal experiments were firstly designed to investigate the sig...

  • Feature Paper
  • Article
  • Open Access
42 Citations
6,040 Views
16 Pages

Magnetic Characterization of Direct-Write Free-Form Building Blocks for Artificial Magnetic 3D Lattices

  • Mohanad K. I. Al Mamoori,
  • Lukas Keller,
  • Jonathan Pieper,
  • Sven Barth,
  • Robert Winkler,
  • Harald Plank,
  • Jens Müller and
  • Michael Huth

12 February 2018

Three-dimensional (3D) nanomagnetism, where spin configurations extend into the vertical direction of a substrate plane allow for more complex, hierarchical systems and the design of novel magnetic effects. As an important step towards this goal, we...

  • Communication
  • Open Access
12 Citations
4,692 Views
7 Pages

Synthesis of α-Fe2O3 and Fe-Mn Oxide Foams with Highly Tunable Magnetic Properties by the Replication Method from Polyurethane Templates

  • Yuping Feng,
  • Jordina Fornell,
  • Huiyan Zhang,
  • Pau Solsona,
  • Maria Dolors Barό,
  • Santiago Suriñach,
  • Eva Pellicer and
  • Jordi Sort

11 February 2018

Open cell foams consisting of Fe and Fe-Mn oxides are prepared from metallic Fe and Mn powder precursors by the replication method using porous polyurethane (PU) templates. First, reticulated PU templates are coated by slurry impregnation. The templa...

  • Article
  • Open Access
11 Citations
4,173 Views
15 Pages

Carrier-Free Microspheres of an Anti-Cancer Drug Synthesized via a Sodium Catalyst for Controlled-Release Drug Delivery

  • Yong Xie,
  • Xinxin Ma,
  • Xujie Liu,
  • Qingming Long,
  • Yu Wang,
  • Youwei Yao and
  • Qiang Cai

11 February 2018

There are several challenges involved in the development of effective anti-cancer drugs, including accurate drug delivery without toxic side effects. Possible systemic toxicity and the rapid biodegradation of drug carriers are potential risks in the...

  • Article
  • Open Access
19 Citations
4,299 Views
11 Pages

Investigation of Surface Morphology of 6H-SiC Irradiated with He+ and H2+ Ions

  • Qiang Shen,
  • Guang Ran,
  • Wei Zhou,
  • Chao Ye,
  • Qijie Feng and
  • Ning Li

11 February 2018

Light ion implantation is one of the important procedures of smart cut for SiC-based semiconductor fabrication. This work investigated the surface morphologies and microstructures of single crystal 6H-SiC irradiated by one or both of H2+ and He+ ions...

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Materials - ISSN 1996-1944