Safety

Professional football players face considerable occupational hazards, with injuries posing serious challenges to player safety, club performance, and regulatory oversight. This descriptive study examines the multifaceted implications of Portugal’s Laws No. 48/2023, which formally recognises professional football as a high-risk occupation and strengthens the mandatory insurance regime through a major regulatory update. Adopting a qualitative approach, the analysis focuses on Portugal, where the professional football business model heavily relies on player commercialisation, and compares regulatory frameworks in Spain, Germany, England, Italy, France, and Brazil. Findings indicate that Portugal’s legal framework enhances player safety by ensuring comprehensive coverage and improved disability protections, yet also introduces financial pressures on clubs, particularly those with lower economic capacity. These pressures are exacerbated by limited market competition and high insurance concentration, increasing premium costs. Cross-country comparisons reveal persistent disparities in legal standards, insurance scope, and institutional coordination, which complicate risk allocation in an increasingly globalised football market. Notably, Portugal’s high-risk insurance model most closely aligns with France’s hybrid approach, in contrast to fully public schemes seen in countries like Germany and Italy. While complete harmonisation remains challenging, the study identifies key principles to guide policy reform and international cooperation. Overall, the findings advance understanding of occupational risk regulation in sport and offer practical insights for designing effective, equitable, and safety-oriented protection systems for professional athletes.

Whilst subtractive manufacturing has been de-risked significantly over recent decades, the emergence of new unfamiliar materials is proving to be a significant challenge for social sustainability. Given this rapidly evolving landscape, this review serves to outline the current available data on the occupational health implications of various existing and emerging material species, ranging from radioactive metals to composite materials. A structured search of sources up to January 2025 was conducted using databases such as Google Scholar, PubMed and Web of Science in addition to various authoritative occupational health reports, prioritising the literature directly pertaining or analogous to machining-related hazards. Evidence highlights the complexity of the machining environment, with occupational hazards ranging from toxicological factors to fire risks (i.e., due to swarf pyrophoricity). Case studies outline both relatively benign pathologies (e.g., dermatitis and sensitisation) and much more severe health complications (e.g., carcinogenicity, systemic organ damage and death), underscoring the need for continuous assessment and updating of exposure controls, even for materials traditionally regarded as safe.

This comprehensive review examines the transformative role of metal–organic frameworks (MOFs) in advancing battery separator technology to address critical safety challenges in rechargeable lithium metal batteries. MOF-based separators leverage their highly specific surface area, tunable pore structures, and functionalized organic ligands to enable precise ion-sieving effects, uniform lithium-ion flux regulation, and dendrite suppression—significantly mitigating risks of internal short circuits and thermal runaway. We systematically analyze the mechanisms by which classical MOF families (e.g., ZIF, UiO, MIL series) enhance separator performance through physicochemical properties such as electrolyte wettability, thermal stability (>400 °C), and mechanical robustness. Furthermore, we highlight innovative composite strategies integrating MOFs with polymer matrices (e.g., PVDF, PAN) or traditional separators, which synergistically improve ionic conductivity while inhibiting polysulfide shuttling in lithium–sulfur batteries and side reactions in aqueous zinc-ion systems. Case studies demonstrate that functionalized MOF separators achieve exceptional electrochemical outcomes: Li–S batteries maintain >99% Coulombic efficiency over 500 cycles, while solid-state batteries exhibit 2400 h dendrite-free operation. Despite promising results, scalability challenges related to MOF synthesis costs and long-term stability under operational conditions require further research. This review underscores MOFs’ potential as multifunctional separator materials to enable safer, high-energy-density batteries and provides strategic insights for future material design.