Studies on Electrochemical Corrosion and Protection in Metals and Alloys

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Corrosion and Protection".

Deadline for manuscript submissions: 31 August 2025 | Viewed by 810

Special Issue Editors


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Guest Editor
Technical Faculty in Bor, University of Belgrade, 19210 Bor, Serbia
Interests: corrosion science; electrochemistry; electrodes; material characterization; green corrosion inhibitors; electrochemical methods
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Technical Faculty in Bor, University of Belgrade, 19210 Bor, Serbia
Interests: electrochemical analysis; corrosion; environmentally friendly corrosion inhibitors; material characterization; biomaterials
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Technical Faculty in Bor, University of Belgrade, 19210 Bor, Serbia
Interests: electrochemical analysis; corrosion; corrosion inhibition; electrochemical techniques
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Technical Faculty in Bor, University of Belgrade, 19210 Bor, Serbia
Interests: corrosion; corrosion inhibition; material characterization; electrochemical techniques; impedance analysis; biomaterials
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

In everyday life, metals are used extensively in infrastructure, transportation, household appliances, and electronic devices. However, these metals and alloys are often exposed to moisture, salt, and pollutants, which can accelerate corrosion. The understanding of electrochemical processes and the implementation of protective measures are essential for extending the service life of metals and alloys in various environments. Electrochemical methods play a crucial role in helping us to understand, monitor, and control corrosion processes. Based on this, scientists can predict corrosion rates, identify areas at risk, and develop effective protection strategies. Techniques such as electrochemical impedance spectroscopy, potentiodynamic polarization, and open-circuit potential measurements are often used to investigate corrosion mechanisms and evaluate protective coatings or inhibitors. Therefore, this Special Issue focuses on scientific papers on the electrochemical corrosion of metals and alloys in different environments, electrochemical methods for monitoring the corrosion rate of metallic materials, and the application of different methods for corrosion protection in aggressive environments.

Dr. Žaklina Z. Tasić
Dr. Marija B. Petrović Mihajlović
Dr. Ana Simonovic
Prof. Dr. Milan B. Radovanović
Guest Editors

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Keywords

  • electrochemical corrosion
  • metals and alloys
  • corrosion protection
  • electrochemical methods
  • corrosive environments
  • inhibitors
  • protective coatings

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Published Papers (2 papers)

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Research

17 pages, 9177 KiB  
Article
Electrodeposition and Corrosion Behavior of Cu-Sn Alloys in 3.5 wt.% NaCl and 0.1 M HNO3 Solutions
by Xiye Jiao, Zhou Yang, Jie Yan, Jin Zhang, Xiaolin Chen and Renguo Guan
Metals 2025, 15(4), 426; https://doi.org/10.3390/met15040426 - 10 Apr 2025
Viewed by 247
Abstract
In this study, Cu-Sn alloys with varying compositions were synthesized using nickel sulfate as a structure-directing agent during electrodeposition. The crystalline structure of the alloys and the influence of nickel sulfate on the morphology were systematically investigated. The corrosion behavior of these alloys [...] Read more.
In this study, Cu-Sn alloys with varying compositions were synthesized using nickel sulfate as a structure-directing agent during electrodeposition. The crystalline structure of the alloys and the influence of nickel sulfate on the morphology were systematically investigated. The corrosion behavior of these alloys was examined in 3.5 wt.% NaCl and 0.1 M HNO3 solutions using kinetic potential polarization and electrochemical impedance spectroscopy (EIS) techniques. X-ray diffractometry (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) were employed to analyze the corrosion products of the alloys. The result revealed that the absolute value of corrosion potential of Cu43Sn57 alloy prepared by adding nickel sulfate in 3.5 wt. % NaCl solution decreased from 0.259 V to 0.186 V, and the corrosion current density decreased from 9.456 × 10−6 mA cm−2 to 1.248 × 10−6 mA cm−2. In 0.1 M HNO3 solution, the absolute values of corrosion potential of Cu43Sn57 alloy prepared by adding nickel sulfate decreased from 0.065 V to 0.028 V, and the corrosion current density decreased from 5.384 × 10−5 mA cm−2 to 2.63 × 10−5 mA cm−2. This research contributes to the understanding of how structural modification affects the electrochemical performance of Cu-Sn alloys. Full article
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15 pages, 4283 KiB  
Article
Investigation into the Effects of Citric Acid on the Corrosion Behavior of AM 350 Stainless Steel Using Electrochemical Impedance Spectroscopy
by Citlalli Gaona-Tiburcio, Miguel Villegas-Tovar, Erick Maldonado-Bandala, María Lara-Banda, Miguel Angel Baltazar-Zamora, Ce Tochtli Méndez-Ramírez, Demetrio Nieves-Mendoza, Verónica Almaguer-Cantu, Jesus Manuel Jaquez-Muñoz, Aldo Landa-Gómez and Facundo Almeraya-Calderón
Metals 2025, 15(4), 420; https://doi.org/10.3390/met15040420 - 8 Apr 2025
Viewed by 358
Abstract
Stainless steels are used in the aeronautical industry for their corrosion resistance and good mechanical performance. The chemical treatment used to improve corrosion resistance is passivation, forming a compact, continuous, adherent chromium oxide film. This research aimed to investigate the effect of citric [...] Read more.
Stainless steels are used in the aeronautical industry for their corrosion resistance and good mechanical performance. The chemical treatment used to improve corrosion resistance is passivation, forming a compact, continuous, adherent chromium oxide film. This research aimed to investigate the effect of citric acid at different concentrations (citric acid; citric acid + oxalic acid, citric acid + hydrogen peroxide, and citric acid + hydrogen peroxide + ethanol) on AM 350 stainless steel passivated for 90 and 120 min at 25 and 50 °C and immersed in 5% by weight sodium chloride (NaCl) solutions. The electrochemical technique used was electrochemical impedance spectroscopy (EIS) based on ASTM-G106. The EIS (equivalent circuit) results indicate that there are one and two constant phase elements (CPE), which indicate the presence of various factors on the stainless steel surface, such as roughness and the formation of porous and passive layers, respectively. A double-layer system was employed for some samples. However, when the ethanol was added to the passivation bath, the behavior changed to a one-time constant system. The AM 350 passivated in citric and oxalic acid presented the higher corrosion resistance with values of 6 × 105 Ω·cm2. Full article
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