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Electrochem, Volume 2, Issue 1

March 2021 - 12 articles

Cover Story: The nanocrystalline Ni-Co alloys are electrodeposited with a sulfamate bath. The addition of NiBr2 and a surface brightener (NSF-E) into the bath leads to an increase in the Co content (up to 65 at.%) in the alloy as well as the grain refinement effect (roughly 14 nm). The Ni-Co alloys show higher microhardness than pure Ni and Co deposits prepared under the same condition, which reveals the solid solution strengthening effect. With a decrease in the grain size, the microhardness of the alloy further increases, and this trend follows the Hall–Petch relationship well, which indicates the grain boundary strengthening effect. Moreover, the dependency of microhardness is confirmed to be higher on the grain size than on the Co content. View this paper.
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Articles (12)

  • Review
  • Open Access
96 Citations
9,751 Views
36 Pages

Designing of Nanomaterials-Based Enzymatic Biosensors: Synthesis, Properties, and Applications

  • Francisco T. T. Cavalcante,
  • Italo R. de A. Falcão,
  • José E. da S. Souza,
  • Thales G. Rocha,
  • Isamayra G. de Sousa,
  • Antônio L. G. Cavalcante,
  • André L. B. de Oliveira,
  • Maria C. M. de Sousa and
  • José C. S. dos Santos

12 March 2021

Among the many biological entities employed in the development of biosensors, enzymes have attracted the most attention. Nanotechnology has been fostering excellent prospects in the development of enzymatic biosensors, since enzyme immobilization ont...

  • Article
  • Open Access
12 Citations
5,138 Views
14 Pages

Investigation of the Applicability of Helium-Based Cooling System for Li-Ion Batteries

  • Mohammad Alipour,
  • Aliakbar Hassanpouryouzband and
  • Riza Kizilel

This paper proposes a novel He-based cooling system for the Li-ion batteries (LIBs) used in electric vehicles (EVs) and hybrid electric vehicles (HEVs). The proposed system offers a novel alternative battery thermal management system with promising p...

  • Review
  • Open Access
7 Citations
5,387 Views
17 Pages

28 February 2021

Wearable self-powered sensors represent a theme of interest in the literature due to the progress in the Internet of Things and implantable devices. The integration of different materials to harvest energy from body movement or the environment to pow...

  • Article
  • Open Access
2 Citations
3,202 Views
12 Pages

20 February 2021

A double layer capacitance (DLC) has mainly been brought about in the Helmholtz layer rather than in the diffuse layer, as was demonstrated with the invariance of DLC to salt concentration, c, less than 0.5 M (M = mol dm−3). The DLC measured here inc...

  • Article
  • Open Access
12 Citations
4,124 Views
12 Pages

Effect of Spin Coating Parameters on the Electrochemical Properties of Ruthenium Oxide Thin Films

  • Elisabetta Petrucci,
  • Monica Orsini,
  • Francesco Porcelli,
  • Serena De Santis and
  • Giovanni Sotgiu

20 February 2021

Ruthenium oxide (RuOx) thin films were spin coated by thermal decomposition of alcoholic solutions of RuCl3 on titanium foils and subsequently annealed at 400 °C. The effect of spin coating parameters, such as spinning speed, volume, and molar concen...

  • Article
  • Open Access
9 Citations
7,081 Views
23 Pages

Structural and Electrochemical Properties of the High Ni Content Spinel LiNiMnO4

  • Tianyi Li,
  • Kai Chang,
  • Ahmed M. Hashem,
  • Ashraf E. Abdel-Ghany,
  • Rasha S. El-Tawil,
  • Hua Wang,
  • Hazim El-Mounayri,
  • Andres Tovar,
  • Likun Zhu and
  • Christian M. Julien

20 February 2021

This work presents a contribution to the study of a new Ni-rich spinel cathode material, LiNiMnO4, for Li-ion batteries operating in the 5-V region. The LiNiMnO4 compound was synthesized by a sol-gel method assisted by ethylene diamine tetra-acetic a...

  • Communication
  • Open Access
18 Citations
7,369 Views
7 Pages

Direct Electrochemical Reduction of Bicarbonate to Formate Using Tin Catalyst

  • Andreu Bonet Navarro,
  • Adrianna Nogalska and
  • Ricard Garcia-Valls

10 February 2021

Nowadays, the self-accelerating increase in global temperatures strengthens the idea that the cutting of CO2 emissions will not be enough to avoid climate change, thus CO2 from the atmosphere must be removed. This gas can be easily trapped by convert...

  • Article
  • Open Access
4 Citations
3,588 Views
14 Pages

23 January 2021

This investigation’s primary purpose was to illustrate the cooling mechanism within a lithium titanate oxide lithium-ion battery pack through the experimental measurement of heat generation inside lithium titanate oxide batteries. Dielectric water/gl...

  • Article
  • Open Access
27 Citations
4,963 Views
9 Pages

Electrochemical Detection of Bisphenol A by Tyrosinase Immobilized on Electrospun Nanofibers Decorated with Gold Nanoparticles

  • Luiza A. Mercante,
  • Leonardo E. O. Iwaki,
  • Vanessa P. Scagion,
  • Osvaldo N. Oliveira,
  • Luiz H. C. Mattoso and
  • Daniel S. Correa

22 January 2021

Bisphenol A (BPA) is an endocrine-disrupting chemical (EDC) employed in industrial processes that causes adverse effects on the environment and human health. Sensitive and inexpensive methods to detect BPA are therefore needed. In this paper, we desc...

  • Article
  • Open Access
12 Citations
4,290 Views
12 Pages

Effect of KOH on the Energy Storage Performance of Molasses-Based Phosphorus and Nitrogen Co-Doped Carbon

  • Iris Denmark,
  • Samantha Macchi,
  • Fumiya Watanabe,
  • Tito Viswanathan and
  • Noureen Siraj

21 January 2021

In this study, we have evaluated the effect of potassium hydroxide (KOH) on the energy storage performance of metal-free carbon-based materials prepared from molasses. Molasses are a renewable-resource biomass and economical by-product of sugar refin...

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Electrochem - ISSN 2673-3293