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Surfaces, Volume 2, Issue 1

March 2019 - 16 articles

Cover Story: Energy transfer between excited electrons and adsorbate vibrational modes is behind surface dynamics such as diffusion, desorption, and reaction. Here, we tune this energy transfer by decoupling CO from the Cu(110) surface with a metalloporphyrin. An ultrafast green pump pulse excites electrons into the CO 2π if CO binds directly to Cu(110), and infrared–visible sum frequency generation detects CO bond weakening as a frequency redshift. For CO coordinated to the metalloporphyrin, the 2π state is too high in energy and the observed frequency blueshift is caused by electron-mediated vibrational mode coupling. This is depicted below using the example of a PhD celebratory chocolate cake. View Paper here.
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Articles (16)

  • Article
  • Open Access
16 Citations
6,436 Views
11 Pages

Cyclic Voltammetry Characterization of Au, Pd, and AuPd Nanoparticles Supported on Different Carbon Nanofibers

  • Anna Testolin,
  • Stefano Cattaneo,
  • Wu Wang,
  • Di Wang,
  • Valentina Pifferi,
  • Laura Prati,
  • Luigi Falciola and
  • Alberto Villa

19 March 2019

Three types of carbon nanofibers (pyrolytically stripped carbon nanofibers (PS), low-temperature heat treated carbon nanofibers (LHT), and high-temperature heat treated carbon nanofibers (HHT)) with different graphitization degrees and surface chemis...

  • Article
  • Open Access
17 Citations
6,497 Views
12 Pages

“Click” Chemistry on Gold Electrodes Modified with Reduced Graphene Oxide by Electrophoretic Deposition

  • Vladyslav Mishyn,
  • Patrik Aspermair,
  • Yann Leroux,
  • Henri Happy,
  • Wolfgang Knoll,
  • Rabah Boukherroub and
  • Sabine Szunerits

18 March 2019

The coating of electrical interfaces with reduced graphene oxide (rGO) films and their subsequent chemical modification are essential steps in the fabrication of graphene-based sensing platforms. In this work, electrophoretic deposition (EPD) of grap...

  • Article
  • Open Access
21 Citations
4,283 Views
16 Pages

Effects of the Interfacial Structure on the Methanol Oxidation on Platinum Single Crystal Electrodes

  • Mohammad Ali Kamyabi,
  • Ricardo Martínez-Hincapié,
  • Juan M. Feliu and
  • Enrique Herrero

12 March 2019

Methanol oxidation has been studied on low index platinum single crystal electrodes using methanol solutions with different pH (1–5) in the absence of specific adsorption. The goal is to determine the role of the interfacial structure in the re...

  • Article
  • Open Access
26 Citations
5,312 Views
18 Pages

Strategies to Hierarchical Porosity in Carbon Nanofiber Webs for Electrochemical Applications

  • Svitlana Yarova,
  • Deborah Jones,
  • Frédéric Jaouen and
  • Sara Cavaliere

5 March 2019

Morphology and porosity are crucial aspects for designing electrodes with facile transport of electrons, ions and matter, which is a key parameter for electrochemical energy storage and conversion. Carbon nanofibers (CNFs) prepared by electrospinning...

  • Article
  • Open Access
16 Citations
5,361 Views
14 Pages

Potential Dependent Structure and Stability of Cu(111) in Neutral Phosphate Electrolyte

  • Yvonne Grunder,
  • Jack Beane,
  • Adam Kolodziej,
  • Christopher A. Lucas and
  • Paramaconi Rodriguez

24 February 2019

Copper and copper oxide electrode surfaces are suitable for the electrochemical reduction of CO2 and produce a range of products, with the product selectivity being strongly influenced by the surface structure of the copper electrode. In this paper,...

  • Article
  • Open Access
14 Citations
5,964 Views
14 Pages

Fe2O3 Blocking Layer Produced by Cyclic Voltammetry Leads to Improved Photoelectrochemical Performance of Hematite Nanorods

  • Mahshid Poornajar,
  • Nhat Truong Nguyen,
  • Hyo-Jin Ahn,
  • Markus Büchler,
  • Ning Liu,
  • Stepan Kment,
  • Radek Zboril,
  • Jeong Eun Yoo and
  • Patrik Schmuki

19 February 2019

Hematite is a low band gap, earth abundant semiconductor and it is considered to be a promising choice for photoelectrochemical water splitting. However, as a bulk material its efficiency is low because of excessive bulk, surface, and interface recom...

  • Article
  • Open Access
6 Citations
4,363 Views
14 Pages

7 February 2019

We have studied CO coordinated to ruthenium tetraphenylporphyrin (RuTPP)/Cu(110) and directly adsorbed to Cu(110), using femtosecond pump-sum frequency probe spectroscopy, to alter the degree of electron-vibration coupling between the metal substrate...

  • Article
  • Open Access
4 Citations
5,333 Views
17 Pages

Characterization and Neutral Atom Beam Surface Modification of a Clear Castable Polyurethane for Biomicrofluidic Applications

  • Atul Dhall,
  • Tim Masiello,
  • Suhasini Gattu,
  • Matt Strohmayer,
  • Logan Butt,
  • Lewdeni Pathirannehelage Madhubhani Hemachandra,
  • Sandra Schujman,
  • Natalya Tokranova,
  • Joseph Khoury and
  • Satyavolu Papa Rao
  • + 3 authors

1 February 2019

Polyurethanes (PU) are a broad class of polymers that offer good solvent compatibility and a wide range of properties that can be used to generate microfluidic layers. Here, we report the first characterization of a commercially available Shore 80D p...

  • Article
  • Open Access
54 Citations
10,100 Views
22 Pages

Interface Science Using Ambient Pressure Hard X-ray Photoelectron Spectroscopy

  • Marco Favaro,
  • Fatwa Firdaus Abdi,
  • Ethan Jon Crumlin,
  • Zhi Liu,
  • Roel van de Krol and
  • David Edward Starr

28 January 2019

The development of novel in situ/operando spectroscopic tools has provided the opportunity for a molecular level understanding of solid/liquid interfaces. Ambient pressure photoelectron spectroscopy using hard X-rays is an excellent interface charact...

  • Article
  • Open Access
3 Citations
3,937 Views
8 Pages

24 January 2019

There have been several reports concerning the performance improving properties of additives, such as polyvinylidene difluoride (PVDF), to the membrane or electrocatalyst layer of proton exchange membrane fuel cells (PEMFC). However, it is not clear...

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Surfaces - ISSN 2571-9637