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Ceramics, Volume 1, Issue 2

2018 December - 13 articles

Cover Story: Without doubt, nanosized ceramic powders can have remarkable properties. However, transferring such structures into dense, bulk ceramic materials compatible with e.g. use in fuel cells is highly challenging. The problem, from a practical point of view, is that the subsequent annealing and sintering steps would destroy these nanostructures. Here we use a novel approach to overcome this obstacle. By using well-defined nanosized particles with a core–shell structure, the desired nanoscale microstructure is already defined in the reactant. In combination with spark plasma sintering, which enables very short sintering times at temperatures lower than in conventional sintering methods, it is possible to partly preserve the core–shell architecture of the primary powders after densification. View this paper.
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Articles (13)

  • Article
  • Open Access
9 Citations
6,348 Views
18 Pages

Calcium Phosphate Powder Synthesized from Calcium Acetate and Ammonium Hydrophosphate for Bioceramics Application

  • Tatiana Safronova,
  • Valery Putlayev,
  • Yaroslav Filippov,
  • Tatiana Shatalova,
  • Evgeny Karpushkin,
  • Dmitrii Larionov,
  • Gilyana Kazakova and
  • Yury Shakhtarin

15 December 2018

Calcium phosphate powder was synthesized at room temperature from aqueous solutions of ammonium hydrophosphate and calcium acetate without pH adjusting at constant Ca/P molar ratio 1.5. Phase composition of the as-synthesized powder depended on the p...

  • Article
  • Open Access
9 Citations
4,022 Views
11 Pages

11 December 2018

Improving optical fiber amplifiers requires the elaboration and use of new materials and new compositions. In this sense, we prepared erbium-doped optical fiber samples that were co-doped with magnesium or lanthanum by gradual-time solution doping. D...

  • Article
  • Open Access
16 Citations
4,944 Views
11 Pages

Fabricating MOF/Polymer Composites via Freeze Casting for Water Remediation

  • Coral Rogers,
  • Daniel Pun,
  • Qingshan Fu and
  • Haifei Zhang

28 November 2018

Various porous materials have been used as adsorbents for water remediation. Among them, metal-organic framework (MOF) particles have been explored intensively, due to their size-controlled micropores and high surface areas. MOF nanoparticles are oft...

  • Article
  • Open Access
2 Citations
4,470 Views
10 Pages

Equimolar Yttria-Stabilized Zirconia and Samaria-Doped Ceria Solid Solutions

  • Reginaldo Muccillo,
  • Daniel Z. De Florio and
  • Eliana N. S. Muccillo

22 November 2018

Compositions of (ZrO2)0.92(Y2O3)0.08 (zirconia: 8 mol % yttria—8YSZ) and (CeO2)0.8(Sm2O3)0.2 (ceria: 20 mol % samaria—SDC20) ceramic powders were prepared by attrition milling to form an equimolar powder mixture, followed by uniaxial and...

  • Article
  • Open Access
18 Citations
6,734 Views
14 Pages

6 November 2018

Shaped porous ceramics have proven to be the most adapted materials for several industrial applications, both at low and high temperatures. Recent research has been focused on developing shaping techniques, allowing for a better control over the tota...

  • Article
  • Open Access
5 Citations
3,843 Views
10 Pages

28 October 2018

Macroporous composite foams consisting of β-tricalcium phosphate (β-TCP) and titanium nitride (TiN) have been prepared by a facile emulsion route involving sintering at elevated temperatures after shaping. Commercially available hydroxyapat...

  • Article
  • Open Access
8 Citations
4,078 Views
15 Pages

Mechanochemically-Assisted Synthesis of Lead-Free Piezoelectric CaZrO3-Modified (K,Na,Li)(Nb,Ta)O3-Solid Solution

  • Kristian Radan,
  • Brigita Kmet,
  • Silvo Drnovšek,
  • Uroš Prah,
  • Tadej Rojac and
  • Barbara Malič

17 October 2018

Lead-free piezoelectric 0.95(Na0.49K0.49Li0.02)(Nb0.8Ta0.2)O3–0.05CaZrO3 with 2 wt % MnO2 addition was prepared using mechanochemically-assisted solid-state synthesis. Upon mechanochemical activation of the mixture of reagents partial amorphization o...

  • Article
  • Open Access
9 Citations
4,280 Views
17 Pages

Influence of Aging on Mechanical Properties of Yttria-Doped Zirconia

  • Yuta Kimura,
  • Takuto Kushi,
  • Atsushi Unemoto,
  • Koji Amezawa and
  • Tatsuya Kawada

12 October 2018

We evaluated the influence of aging on mechanical properties of 8% yttria-doped zirconia (8YSZ) from room temperature to 1200 K. The temperature dependence of the dynamic Young’s and shear moduli of 8YSZ with and without the aging treatment was inves...

  • Article
  • Open Access
9 Citations
4,174 Views
13 Pages

Devitrification Behavior of Sol-Gel Derived ZrO2-SiO2 Rare-Earth Doped Glasses: Correlation between Structural and Optical Properties

  • Masato Isogai,
  • Alexander Veber,
  • Maria Rita Cicconi,
  • Tomokatsu Hayakawa and
  • Dominique De Ligny

7 October 2018

Optical and structural properties of glasses and glass-ceramics (GC) obtained by different heat-treatment of Tb and Tb-Yb doped sol-gel derived 30ZrO2-70SiO2 materials were investigated. A glass was formed after treatment at 700 °C whereas devitrific...

  • Article
  • Open Access
3 Citations
5,195 Views
15 Pages

Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceria

  • Yu Xu,
  • Philipp Zielke,
  • Ngo Van Nong,
  • Stéven Pirou,
  • Raquel Reolon,
  • Xiaoqing Si,
  • Søren Bredmose Simonsen,
  • Poul Norby,
  • Henning Lühmann and
  • Ragnar Kiebach
  • + 1 author

2 October 2018

In this work, nanostructured (La0.6Sr0.4)0.99CoO3 (LSC)-Ce0.8Gd0.2O1.9 (CGO) core-shell particles were prepared by precipitating CGO nanoparticles on the surface of LSC particles under hydrothermal conditions. The as-prepared core-shell particles wer...

  • Article
  • Open Access
2 Citations
4,203 Views
13 Pages

Evolution of Copper Electrodes Fabricated by Electroless Plating on BaZr0.7Ce0.2Y0.1O3-δ Proton-Conducting Ceramic Membrane: From Deposition to Testing in Methane

  • Steven P. Harvey,
  • Sandrine Ricote,
  • David R. Diercks,
  • Chun-Sheng Jiang,
  • Neil S. Patki,
  • Anthony Manerbino,
  • Brian Gorman and
  • Mowafak Al-Jassim

2 October 2018

We investigated copper electrodes deposited onto a BaZr0.7Ce0.2Y0.1O3-δ (BZCY72) proton-conducting membrane via a novel electroless plating method, which resulted in significantly improved performance when compared to a traditional painted copp...

  • Article
  • Open Access
5 Citations
4,792 Views
17 Pages

Exploring the Processing of Tubular Chromite- and Zirconia-Based Oxygen Transport Membranes

  • Astri Bjørnetun Haugen,
  • Lev Martinez Aguilera,
  • Kawai Kwok,
  • Tesfaye Molla,
  • Kjeld Bøhm Andersen,
  • Stéven Pirou,
  • Andreas Kaiser,
  • Peter Vang Hendriksen and
  • Ragnar Kiebach

29 September 2018

Tubular oxygen transport membranes (OTMs) that can be directly integrated in high temperature processes have a large potential to reduce CO2 emissions. However, the challenging processing of these multilayered tubes, combined with strict material sta...

  • Article
  • Open Access
6 Citations
5,143 Views
18 Pages

27 September 2018

The evaluation of the piezoelectric properties of ferroelectric ceramics generally has a high level of uncertainty, due to incomplete poling, porosity, domain wall clamping and other effects. In addition, the poling process is often difficult and dan...

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Ceramics - ISSN 2571-6131