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Magnetochemistry, Volume 7, Issue 6

2021 June - 16 articles

Cover Story: Crystal-to-crystal transformation is a path to obtain crystals with different crystal structures and physical properties. Orange crystal K2[Co(C2O4)2(H2O)2]·4H2O (1) is obtained from K2C2O4·2H2O and CoCl2·6H2O in H2O with a yield of 60%. It quantitatively transfers to pink crystal K2[Co(μ-C2O4)(C2O4)] (2) by dehydration. Co2+ is coordinated by two bisbendentate oxalate anions and one bidentated oxalate anion in a trigonal prism. View this paper
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Articles (16)

  • Article
  • Open Access
5 Citations
3,393 Views
16 Pages

Chiral Radical Cation Salts of Me-EDT-TTF and DM-EDT-TTF with Octahedral, Linear and Tetrahedral Monoanions

  • Nabil Mroweh,
  • Alexandra Bogdan,
  • Flavia Pop,
  • Pascale Auban-Senzier,
  • Nicolas Vanthuyne,
  • Elsa B. Lopes,
  • Manuel Almeida and
  • Narcis Avarvari

Methyl-ethylenedithio-tetrathiafulvalene (Me-EDT-TTF (1) and dimethyl-ethylenedithio-tetrathiafulvalene (DM-EDT-TTF (2) are valuable precursors for chiral molecular conductors, which are generally obtained by electrocrystallization in the presence of...

  • Feature Paper
  • Article
  • Open Access
3,036 Views
15 Pages

Simulation and Theory of Classical Spin Hopping on a Lattice

  • Hope D. Gerst,
  • Rodrigo Becerra Silva and
  • Nicholas J. Harmon

The behavior of spin for incoherently hopping carriers is critical to understand in a variety of systems such as organic semiconductors, amorphous semiconductors, and muon-implanted materials. This work specifically examined the spin relaxation of ho...

  • Review
  • Open Access
45 Citations
20,004 Views
22 Pages

Magnetotactic Bacteria and Magnetosomes: Basic Properties and Applications

  • Kamil G. Gareev,
  • Denis S. Grouzdev,
  • Petr V. Kharitonskii,
  • Andrei Kosterov,
  • Veronika V. Koziaeva,
  • Elena S. Sergienko and
  • Maxim A. Shevtsov

Magnetotactic bacteria (MTB) belong to several phyla. This class of microorganisms exhibits the ability of magneto-aerotaxis. MTB synthesize biominerals in organelle-like structures called magnetosomes, which contain single-domain crystals of magneti...

  • Article
  • Open Access
2 Citations
3,265 Views
8 Pages

The sentinel lymph node is the first lymph-node-draining cancer metastasis. The identification of the sentinel lymph node using magnetic particles and a magnetic sensor has attracted attention in recent years, as this method is less invasive than the...

  • Feature Paper
  • Review
  • Open Access
8 Citations
6,248 Views
11 Pages

The implementation of artificial intelligence into the research and development of (currently) the most economically relevant classes of engineering hard and soft magnetic materials is addressed. Machine learning is nowadays the key approach utilized...

  • Feature Paper
  • Article
  • Open Access
5 Citations
3,031 Views
15 Pages

New organic (super)conductors of the β″-(BEDT-TTF)4A+[M3+(C2O4)3]G family, where BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene; M is Fe; A is the monovalent cation NH4+; G is 2-fluoropyridine (2-FPy) (1); 2,3-difluoropyridine (2,3-DFPy) (2); 2-ch...

  • Article
  • Open Access
27 Citations
5,593 Views
13 Pages

The Effect of pH and Viscosity on Magnetophoretic Separation of Iron Oxide Nanoparticles

  • Leonie Wittmann,
  • Chiara Turrina and
  • Sebastian P. Schwaminger

Magnetic nanoparticles (MNPs) are used for magnetophoresis-based separation processes in various biomedical and engineering applications. Essential requirements are the colloidal stability of the MNPs and the ability to be separated even in low magne...

  • Article
  • Open Access
1 Citations
2,923 Views
8 Pages

Engineered Magnetization Dynamics of Magnonic Nanograting Filters

  • Rawana Yagan,
  • Ferhat Katmis and
  • Mehmet C. Onbaşlı

Magnonic crystals and gratings could enable tunable spin-wave filters, logic, and frequency multiplier devices. Using micromagnetic models, we investigate the effect of nanowire damping, excitation frequency and geometry on the spin wave modes, spati...

  • Feature Paper
  • Article
  • Open Access
7 Citations
3,301 Views
17 Pages

Effect of the Alkaline Metal Ion on the Crystal Structure and Magnetic Properties of Heterometallic GdIII-VIV Complexes Based on Cyclobutane-1,1-Dicarboxylate Anions

  • Evgeniya S. Bazhina,
  • Alexander A. Korlyukov,
  • Julia K. Voronina,
  • Konstantin A. Babeshkin,
  • Elena A. Ugolkova,
  • Nikolay N. Efimov,
  • Matvey V. Fedin,
  • Mikhail A. Kiskin and
  • Igor L. Eremenko

A series of heterometallic GdIII-VIV compounds were synthesized by the reaction of VOSO4·3H2O with cyclobutane-1,1-dicarboxylic acid salts M2(cbdc) (M = Na, Rb, Cs). The new compounds were formed by [Gd(VO)2(cbdc)4(H2O)8] trinuclear anionic units th...

  • Feature Paper
  • Article
  • Open Access
10 Citations
4,096 Views
20 Pages

Near-Infrared Emissive Cyanido-Bridged {YbFe2} Molecular Nanomagnets Sensitive to the Nitrile Solvents of Crystallization

  • Michal Liberka,
  • Kseniia Boidachenko,
  • Jakub J. Zakrzewski,
  • Mikolaj Zychowicz,
  • Junhao Wang,
  • Shin-ichi Ohkoshi and
  • Szymon Chorazy

One of the pathways toward luminescent single-molecule magnets (SMMs) is realized by the self-assembly of lanthanide(3+) ions with cyanido transition metal complexes. We report a novel family of emissive SMMs, {YbIII(4-pyridone)4[FeII(phen)2(CN)2]2}(...

  • Article
  • Open Access
6 Citations
5,627 Views
20 Pages

A Ti/Pt/Co Multilayer Stack for Transfer Function Based Magnetic Force Microscopy Calibrations

  • Baha Sakar,
  • Sibylle Sievers,
  • Alexander Fernández Scarioni,
  • Felipe Garcia-Sanchez,
  • İlker Öztoprak,
  • Hans Werner Schumacher and
  • Osman Öztürk

Magnetic force microscopy (MFM) is a widespread technique for imaging magnetic structures with a resolution of some 10 nanometers. MFM can be calibrated to obtain quantitative (qMFM) spatially resolved magnetization data in units of A/m by determinin...

  • Feature Paper
  • Article
  • Open Access
4 Citations
5,155 Views
6 Pages

Crystal-to-Crystal Transformation from K2[Co(C2O4)2(H2O)2]·4H2O to K2[Co(μ-C2O4)(C2O4)]

  • Bin Zhang,
  • Yan Zhang,
  • Guangcai Chang,
  • Zheming Wang and
  • Daoben Zhu

Crystal-to-crystal transformation is a path to obtain crystals with different crystal structures and physical properties. K2[Co(C2O4)2(H2O)2]·4H2O (1) is obtained from K2C2O4·2H2O, CoCl2·6H2O in H2O with a yield of 60%. It is crystallized in the tric...

  • Feature Paper
  • Article
  • Open Access
23 Citations
3,568 Views
31 Pages

A series of mononuclear Co(II) complexes showing slow magnetic relaxation is assessed from the point of view of relaxation mechanisms. In certain cases, the reciprocating thermal behavior is detected: On cooling, the slow relaxation time is prolonged...

  • Feature Paper
  • Article
  • Open Access
4 Citations
3,171 Views
14 Pages

Solvent-Induced Hysteresis Loop in Anionic Spin Crossover (SCO) Isomorph Complexes

  • Emmelyne Cuza,
  • Samia Benmansour,
  • Nathalie Cosquer,
  • Françoise Conan,
  • Carlos J. Gómez-García and
  • Smail Triki

Reaction of Fe(II) with the tris-(pyridin-2-yl)ethoxymethane (py3C-OEt) tripodal ligand in the presence of the pseudohalide ancillary NCSe (E = S, Se, BH3) ligand leads to the mononuclear complex [Fe(py3C-OEt)2][Fe(py3C-OEt)(NCSe)3]2·2CH3CN (3), whi...

  • Feature Paper
  • Article
  • Open Access
2 Citations
3,127 Views
18 Pages

Neutron Studies of a High Spin Fe19 Molecular Nanodisc

  • Francis L. Pratt,
  • Tatiana Guidi,
  • Pascal Manuel,
  • Christopher E. Anson,
  • Jinkui Tang,
  • Stephen J. Blundell and
  • Annie K. Powell

The molecular cluster system [Fe19(metheidi)10(OH)14O6(H2O)12]NO3·24H2O, abbreviated as Fe19, contains nineteen Fe(III) ions arranged in a disc-like structure with the total spin S = 35/2. For the first order, it behaves magnetically as a single mole...

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Magnetochemistry - ISSN 2312-7481