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ChemEngineering, Volume 2, Issue 4

2018 December - 17 articles

Cover Story: Mechanism identification and determination of the kinetic parameters are key points in the development of effective catalytic systems in the dry reforming reaction. In order to find the more appropriate rate law, which adequately describes the reaction with a selected catalyst, model discrimination can be applied to identify the existing model that best fits the experimental data. This discrimination, applied to literature data with Eley–Rideal and Langmuir–Hinshelwood Kinetic Models, was easily accomplished with the proposed ANEMONA.XLT tool. View Paper here.
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Articles (17)

  • Article
  • Open Access
16 Citations
7,056 Views
13 Pages

Experimental Demonstration and Validation of Hydrogen Production Based on Gasification of Lignocellulosic Feedstock

  • Jürgen Loipersböck,
  • Markus Luisser,
  • Stefan Müller,
  • Hermann Hofbauer and
  • Reinhard Rauch

The worldwide production of hydrogen in 2010 was estimated to be approximately 50 Mt/a, mostly based on fossil fuels. By using lignocellulosic feedstock, an environmentally friendly hydrogen production route can be established. A flow sheet simulatio...

  • Article
  • Open Access
32 Citations
5,322 Views
10 Pages

Micronization for Enhancement of Curcumin Dissolution via Electrospraying Technique

  • Kimthet Chhouk,
  • Wahyu Diono,
  • Hideki Kanda and
  • Motonobu Goto

Curcumin is a hydrophobic polyphenol compound exhibiting a wide range of biological activities such as anti-inflammatory, anti-bacterial, anti-fungal, anti-carcinogenic, anti-HIV, and anti-microbial activity. Recently, electrospraying has been succes...

  • Article
  • Open Access
23 Citations
4,691 Views
13 Pages

Magnesium Incorporation in n-CdTe to Produce Wide Bandgap p-Type CdTe:Mg Window Layers

  • Ashfaque E. Alam,
  • Ayotunde A. Ojo,
  • Jacek B. Jasinski and
  • Imyhamy M. Dharmadasa

In order to develop wide bandgap p-type window materials to use in graded bandgap devices, the effects of magnesium (Mg) in n-CdTe layers were explored. In this work, magnesium-incorporated cadmium telluride (CdTe:Mg) layers were electroplated using...

  • Article
  • Open Access
6 Citations
4,668 Views
11 Pages

Transfer of Graphene with Protective Oxide Layers

  • Haim Grebel,
  • Liliana Stan,
  • Anirudha V. Sumant,
  • Yuzi Liu,
  • David Gosztola,
  • Leonidas Ocola and
  • Brandon Fisher

Transfer of graphene, grown by chemical vapor deposition (CVD), to a substrate of choice, typically involves the deposition of a polymeric layer (for example, poly(methyl methacrylate) (PMMA), or polydimethylsiloxane, PDMS). These polymers are quite...

  • Article
  • Open Access
14 Citations
5,307 Views
9 Pages

Light from red (661 nm) and blue (417 nm) LEDs were applied for 12, 24, and 48 h on freshly harvested blueberry leaves of different cultivars mixed together. The extracts obtained through microwave extraction of these leaves were analysed in terms of...

  • Communication
  • Open Access
5 Citations
8,194 Views
10 Pages

A Useful Excel-Based Program for Kinetic Model Discrimination

  • Lidia Pino,
  • Vincenzo Recupero and
  • Agustín Hernández

In the present study, the ANEMONA.XLT tool, an Excel template that was designed for calculation of enzyme kinetic parameters, has been successful adapted to some proposed models for dry reforming reaction, such as Eley-Rideal or Langmuir-Hinshelwood...

  • Article
  • Open Access
6 Citations
5,825 Views
26 Pages

Experimental Investigation of the Gas/Liquid Phase Separation Using a Membrane-Based Micro Contactor

  • Kay Marcel Dyrda,
  • Vincent Wilke,
  • Katja Haas-Santo and
  • Roland Dittmeyer

The gas/liquid phase separation of CO2 from a water-methanol solution at the anode side of a µDirect-Methanol-Fuel-Cell (µDMFC) plays a key role in the overall performance of fuel cells. This point is of particular importance if the &micr...

  • Article
  • Open Access
7 Citations
4,611 Views
16 Pages

As a result of their high tuneability and low volatility, room temperature ionic liquids have been proposed as replacement solvents in a wide range of industrial applications. They are particularly well-suited for use as an entrainer (or solvent) in...

  • Article
  • Open Access
5 Citations
4,221 Views
17 Pages

The goal of this work is to assess the application of ultrasonic power to the reactive dissolution of limestone particles in an acidic environment; this would represent a novel method for improving wet Flue Gas Desulfurization industrial systems. In...

  • Article
  • Open Access
4 Citations
3,360 Views
11 Pages

Demonstration of the Use of 3D X-ray Tomography to Compare the Uniformity of Catalyst Coatings in Open-Cell Foams

  • Marie-Line Zanota,
  • Stéphanie Pallier,
  • Anaïs Dousse,
  • Joël Lachambre and
  • Valérie Meille

Coating open-cell foams by a catalytic layer is a necessary step to obtain structured catalytic foam reactors. The dip-coating method, consisting of immersing the foam in a suspension or in a sol-gel, is generally used to obtain the coating. The exce...

  • Article
  • Open Access
12 Citations
5,064 Views
19 Pages

Coupled CFD-Response Surface Method (RSM) Methodology for Optimizing Jettability Operating Conditions

  • Nuno Couto,
  • Valter Silva,
  • João Cardoso,
  • Leo M. González-Gutiérrez and
  • Antonio Souto-Iglesias

A volume-of-fluid (VOF) finite volume model under the ANSYS® Fluent framework was coupled with the response surface method (RSM) to find the best operating conditions within a jettability window for two selected responses in a drop-on-demand inkj...

  • Article
  • Open Access
2 Citations
5,723 Views
12 Pages

Dry Reforming in a Milli-Scale Reactor Driven by Simulated Sunlight

  • Yige Wang,
  • Fuqiong Lei,
  • Lucas Freiberg,
  • Elham Bagherisereshki,
  • Piyanut Inbamrung,
  • Saowaluk Intarasiri,
  • Goran Jovanovic,
  • Alexandre F. T. Yokochi,
  • Líney Árnadóttir and
  • Nick AuYeung

In this study, a directly irradiated, milli-scale chemical reactor with a simple nickel catalyst was designed for dry reforming of methane for syngas. A milli-scale reactor was used to facilitate rapid heating, which is conducive to combating thermal...

  • Article
  • Open Access
1 Citations
3,822 Views
15 Pages

Modeling of Copper Adsorption on Mesoporous Carbon CMK-3: Response Surface Design

  • Zeinab Ezzeddine,
  • Isabelle Batonneau-Gener and
  • Yannick Pouilloux

CMK-3 mesoporous carbon was nanocast from SBA-15 silica. The obtained carbon was characterized by nitrogen sorption isotherms, X-ray diffraction and transmission electron microscopy (TEM). The batch adsorption tests were done at constant pH taking in...

  • Article
  • Open Access
20 Citations
6,643 Views
17 Pages

Dry Reforming of Methane in a Pd-Ag Membrane Reactor: Thermodynamic and Experimental Analysis

  • Alessio Caravella,
  • Adele Brunetti,
  • Monia Grandinetti and
  • Giuseppe Barbieri

The present work is a study of CO2 Reforming of Methane (DRM) carried out in a catalytic Pd-based membrane reactor. A detailed thermodynamic analysis is carried out, calculating the chemical equilibrium parameters in two different cases: (a) DRM alon...

  • Article
  • Open Access
6 Citations
4,102 Views
8 Pages

Effective Concentration of Ionic Liquids for Enhanced Saccharification of Cellulose

  • Kazuhiko Tanimura,
  • Yoshiko Ooe,
  • Keishi Suga and
  • Hiroshi Umakoshi

In an aqueous enzymatic saccharification using cellulase, the dissolution of crystalline cellulose is one of the rate-limiting steps. Insoluble cellulose powder was preliminarily heat-treated with ionic liquids (ILs), such as [Bmim][Cl] (1-butyl-3-me...

  • Article
  • Open Access
5 Citations
3,769 Views
14 Pages

Empirical Kinetic Modelling of the Effect of l-Ascorbic Acid on the Cu(II)-Induced Oxidation of Quercetin

  • Nikoletta Bobolaki,
  • Angelos Photiades,
  • Spyros Grigorakis and
  • Dimitris P. Makris

This study aimed at investigating the effect of l-ascorbic acid on the Cu2+-induced oxidation of quercetin, within a pH range from 6.7 to 8.3 and temperatures varying from 53 to 87 °C. Initial examinations showed that quercetin degradation obeyed...

  • Article
  • Open Access
13 Citations
7,015 Views
14 Pages

UV-Vis Spectroscopy and Chemometrics for the Monitoring of Organosolv Pretreatments

  • Stefan Beisl,
  • Mathias Binder,
  • Kurt Varmuza,
  • Angela Miltner and
  • Anton Friedl

Lignocellulosic agricultural side products like wheat straw are widely seen as an important contribution to a sustainable future economy. However, the optimization of biorefinery processes, especially the pretreatment step, is crucial for an economic...

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ChemEngineering - ISSN 2305-7084