Inorganics, Volume 7, Issue 11

[2 + 2 + 2] cycloaddition of a 1,2-bis(propiolyl)benzene derivative with terminal and internal alkynes takes place in the presence of [Ir(cod)Cl]₂ (cod = 1,5-cyclooctadiene) combined with bis(diphenylphosphino)ethane (DPPE) to give anthraquinones in...

A new [Zn₂L₂] metallocycle bearing two metal centers that can coordinate ancillary ligands and a pocket suitable to host guest molecules is reported. These two features are exploited by reacting the metallocycle with a pyridine ligand to self-assembl...

A high-pressure/high-temperature experiment at 7.5 GPa and 1673 K led to the formation of the new compound β-Y₂B₄O₉. In contrast to the already known polymorph α-Y₂B₄O₉, which crystallizes in the space group C2/c, the reported structure co...

Taking advantage of the radiation properties of ^99mTc and ^186/188Re and the photophysical characteristics of the {M(CO)₃}⁺ moiety (M = Re), we developed a multifunctional silica platform with the theranostic pair ^99mTc/Re with high potential for (nan...

The Mo/Cu-dependent CO dehydrogenase from O. carboxidovorans is an enzyme that is able to catalyse CO oxidation to CO ${}_2$ ; moreover, it also expresses hydrogenase activity, as it is able to oxidize H ${}_2$ . Here, we have studied the dihydro...

With the aim of developing ^99mTc-labeled fatty acids intended for myocardial metabolism imaging we report herein the synthesis and characterization of two novel derivatives of undecanonoic and hexadecanonoic acid that have been functionalized at the...

The novel phosphanylalumanes, Al–P single-bond species, fully bearing carbon protecting groups on aluminum and phosphorus atoms, are synthesized by the reactions of aluminum monohalides [(t-Bu)₂AlBr and (C₆F₅)₂AlCl·0.5(toluene)] with Mes...

Following the discovery of the first specific and essential role of nickel in biology in 1975 (the dinuclear active site of the enzyme urease) [...]

The authors express their sincere apologies to all readers of abovementioned article as mistakes were found upon discussion of the article with colleagues [...]

The reaction of the bulky Eind-based dialumane, (Eind)HAl(μ-H)₂AlH(Eind) (1) (Eind = 1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl), with pyridines is described. When 1 was treated with pyridine (Py) in toluene, the Py adduct of aryldihydroalumane,...

Technetium-99m has a rich coordination chemistry that offers many possibilities in terms of oxidation states and donor atom sets. Modifications in the structure of the technetium complexes could be very useful for fine tuning the physicochemical and...