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Inorganics, Volume 14, Issue 5

2026 May - 24 articles

Cover Story: All-solid-state lithium batteries are promising next-generation energy storage systems because they can improve both safety and energy density. Among available solid electrolytes, Li-argyrodite sulfides (Li6PS5X, X = Cl, Br, I) are especially attractive due to their high room-temperature ionic conductivity, good mechanical deformability, and cost advantages. This review summarizes recent advances in their crystal structures, Li+ conduction mechanisms, synthesis strategies, compositional regulation, air stability, and electrode interfacial compatibility. It also discusses the remaining challenges and future directions for translating Li-argyrodite electrolytes from fundamental materials research into practical all-solid-state lithium batteries. View this paper
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Articles (24)

  • Communication
  • Open Access
658 Views
14 Pages

Structural Aspects of Cu(I)(κ2-X1,X2)(Y3) and Cu(I)(η2-X1,X2)(Y3) Complexes

  • Milan Melník,
  • Natalia Miklášová,
  • Veronika Mikušová and
  • Peter Mikuš

Structural parameters for over seventy complexes of the composition Cu(η2-X1×2)(Y3) or Cu(κ2-X1X2)(Y3) were analyzed in this work, being the third of a series of structural studies on three coordinated copper(I) complexes. Bidentate (...

(This article belongs to the Section Coordination Chemistry)
  • Article
  • Open Access
1,071 Views
19 Pages

Turning Colombian Banana Waste into a Lignocellulosic Carbocatalyst: A Green Photocatalytic Route for Mercury Remediation

  • Hasleidy Úsuga-Guerra,
  • Milton Rojas,
  • John Rojas,
  • Lis Manrique-Losada and ,
  • Daniel Ávila-Torres,
  • Ricardo A. Torres-Palma and
  • Yenny P. Ávila-Torres
  • + 2 authors+ 0 author

Mercury pollution from artisanal and small-scale gold mining remains one of the most persistent environmental threats due to the high toxicity, mobility, and bioaccumulation of Hg(II). In this work, Colombian banana pseudostem waste is valorized into...

(This article belongs to the Special Issue Inorganic Photocatalysts for Environmental Applications)
  • Article
  • Open Access
1,285 Views
12 Pages

Toward Photoactivatable Copper(I) Anticancer Agents: Heteroleptic Cu(I) Complexes with Functionalized Dipyridylamine Ligands

  • Alondra Villegas-Menares,
  • María Herrera-Maldonado,
  • Iván Brito,
  • Michelle Palacios and ,
  • Sebastián Muñoz-Farias,
  • Mario A. Faundez and
  • Alan R. Cabrera
  • + 2 authors+ 0 author

In this study, we report the synthesis and characterization of three Cu(I) complexes bearing functionalized dipyridylamine ligands and DPEphos. Structural analysis confirms a distorted tetrahedral coordination environment around the metal center. Pho...

(This article belongs to the Special Issue Synthesis, Structural Analysis and Biological Activity of Metal Complexes)
  • Article
  • Open Access
979 Views
14 Pages

Low-Temperature Synthesis of TaxHf1−xC Solid Solutions via Pectin Gelation: Phase and Morphological Evolution

  • Aimé L. Acosta-Soto,
  • Laura G. Ceballos-Mendívil,
  • Jonathan C. Luque-Ceballos,
  • Rody Soto-Rojo and ,
  • Francisco Baldenebro-López,
  • Adriana Cruz-Enríquez,
  • José J. Campos-Gaxiola,
  • Carlos A. Pérez-Rábago and
  • Jesús Baldenebro-López
  • + 4 authors+ 0 author

Ultra-high-temperature ceramics (UHTCs) in the Ta–Hf–C ternary system are of significant interest for extreme aerospace and energy applications due to their melting points near 4000 °C. However, their synthesis typically requires extr...

(This article belongs to the Special Issue Novel Ceramics and Refractory Composites)
  • Review
  • Open Access
1,887 Views
33 Pages

Material Design Strategies for Suppressing Thermal Runaway in Lithium-Ion Batteries

  • Xing Hu,
  • Qinming Liu,
  • Chenglin Ding,
  • Kuo Yang and
  • Bingqi Tian

Thermal runaway (TR) remains a critical bottleneck for the safe application of lithium-ion battery (LIB) in large-scale energy storage systems, arising from the instability of battery materials under high temperatures. This review systematically summ...

(This article belongs to the Special Issue Novel Research on Electrochemical Energy Storage Materials, 2nd Edition)
  • Article
  • Open Access
1 Citations
726 Views
13 Pages

Simulation Study on the Instability of Microscopic Columnar Structures in TiN Coatings Prepared by Magnetron Sputtering

  • Youqing Wang,
  • Tiantian Yang,
  • Minghui Liu,
  • Xilin Xu and ,
  • Furong Hou,
  • Renqianzhuoma,
  • Linjuan Yang,
  • Xiangyi Guan,
  • Huixia Liao and
  • Ying Xiang
  • + 5 authors+ 0 author

To clarify the instability behavior of the columnar microstructure in RF magnetron sputtered TiN coatings under compressive loading, experimental characterization and finite element simulation were combined to investigate the microstructural features...

(This article belongs to the Special Issue Novel Inorganic Coatings and Thin Films)
  • Article
  • Open Access
745 Views
16 Pages

With the rapid development of the photovoltaic industry, the issue of high-value conversion and utilization of end-of-life photovoltaic modules emerges. This study proposes using them in silicon-air batteries and designs a one-step pretreatment proce...

(This article belongs to the Special Issue Novel Research on Electrochemical Energy Storage Materials, 2nd Edition)
  • Article
  • Open Access
1,142 Views
28 Pages

CO2 adsorption on subnanometric metal clusters is highly sensitive to the computational protocol used to describe the potential energy surface, particularly when several low-lying geometries and spin states are accessible. In this work, CO2 adsorptio...

  • Retraction
  • Open Access
1,265 Views
34 Pages

The journal retracts the article entitled “A Comprehensive Review of Recent Advances in Perovskite Materials: Electrical, Dielectric, and Magnetic Properties” [...]

  • Article
  • Open Access
1,060 Views
14 Pages

Mechanochemical Synthesis and Luminescent Properties of Pure and Dy-Doped SrMoO4 Crystalline Phases

  • Maria Gancheva,
  • Reni Iordanova,
  • Iovka Koseva,
  • Georgi Avdeev and
  • Petar Ivanov

The pure and xDy3+-doped SrMoO4 series (x = 0.5, 1.0, 1.5 and 2.0 at.%) were synthesized using a direct mechanochemical route. We found that a milling speed of 850 rpm and a milling time of 30 min result in a complete chemical reaction at different c...

(This article belongs to the Special Issue Current Trends in Inorganic Materials Synthesis)
  • Article
  • Open Access
1,026 Views
17 Pages

Novel Method of Synthesizing MoO3@MgSiO3 Nanohybrids for Decontaminating Water from Pharmaceutical Pollutants

  • Mutaz Salih,
  • Soad S. Alzahrani,
  • Tarig G. Ibrahim,
  • Mohamed R. Elamin and ,
  • Naif Alarifi,
  • Ahmed A. Alhadi and
  • Babiker Y. Abdulkhair
  • + 2 authors+ 0 author

This work focused on synthesizing MgSiO3 (0%Mo@MgSi), 2.5%MoO3@MgSiO3 (2.5%Mo@MgSi), 5%MoO3@MgSiO3 (5%Mo@MgSi), and 10%MoO3@MgSiO3 (10%Mo@MgSi) by a single-step process utilizing butylated hydroxytoluene (BYHT) as a novel capping agent. The X-ray dif...

  • Review
  • Open Access
3 Citations
1,191 Views
21 Pages

Cyclic pollutants such as dyes, antibiotics, phenols and VOCs in water and atmosphere feature stable structures and are difficult to mineralize, which constitutes the core problem in current environmental governance. Semiconductor photocatalysis prov...

(This article belongs to the Special Issue Inorganic Nanomaterials for Catalysis and Energy Storage)
  • Article
  • Open Access
13 Citations
1,571 Views
19 Pages

Wide-Bandgap A2TiSiO6 (A = Ca, Sr, Ba) Double Perovskites for Optoelectronic Applications

  • Łukasz Szeleszczuk,
  • Katarzyna Mądra-Gackowska and
  • Marcin Gackowski

The structural, mechanical, electronic, and optical properties of cubic double perovskite oxides A2TiSiO6 (A = Ca, Sr, Ba) were systematically investigated using first-principles density functional theory calculations. Structural optimization within...

(This article belongs to the Special Issue Recent Progress in Perovskites)
  • Article
  • Open Access
1,319 Views
13 Pages

High-entropy oxide (HEO) thin films hold significant potential for applications in spintronics and catalysis; however, their widespread utilization is hindered by weak room-temperature ferromagnetism (RTFM). Herein, we demonstrate a facile vacuum ann...

(This article belongs to the Special Issue High-Entropy Alloys and High-Entropy Ceramics)
  • Article
  • Open Access
1 Citations
1,675 Views
12 Pages

Ti-Ce Nanocatalysts for Evaluation in the Photodegradation of Naproxen and Acetaminophen

  • Adriana Marizcal-Barba,
  • Gerardo Vallejo-Espinosa,
  • Yéssica V. Contreras-Pacheco,
  • Carlos A. Soto-Robles and ,
  • Karina Nava-Andrade,
  • María del Camen Leal-Moya,
  • Suresh Ghotekar,
  • Mamoun Fellah,
  • Claudia M. Gomez and
  • Alejandro Pérez-Larios
  • + 6 authors+ 1 author

The pharmaceutical industry is a major source of pollution in wastewater effluents, characterized by chemical residues that are complex and difficult to degrade. Naproxen, a commonly detected drug in sewage effluents, exceeds safe concentrations for...

(This article belongs to the Section Inorganic Materials)
  • Review
  • Open Access
1,467 Views
29 Pages

Advances in Air-Stable Silicon-Based Anodes and Their Application in Li–Air Batteries

  • Zixuan Liu,
  • Huafeng Zhou,
  • Haiyong He,
  • Deyu Wang and ,
  • Zhoupeng Li and
  • Zhengfei Chen
  • + 1 author+ 0 author

In recent years, silicon-based anodes have become a model of commercial success among various high-capacity electrode materials. They also offer a promising substitute for the lithium metal anode (LMA) in lithium–air batteries (LABs), which hav...

(This article belongs to the Special Issue Novel Research on Electrochemical Energy Storage Materials, 2nd Edition)
  • Article
  • Open Access
1,487 Views
19 Pages

Since the synthesis of ferrocene in 1951, metallocenes have attracted attention, making the accurate prediction of their electronic structure and ionization energy crucial for understanding their photophysical and electrochemical behavior in material...

(This article belongs to the Special Issue Advances in Metal Ion Research and Applications)
  • Review
  • Open Access
2,510 Views
39 Pages

Covalent organic frameworks (COFs) have emerged as promising materials for the capture and photoluminescent detection of pharmaceutical contaminants in aquatic environments due to their tunable porosity, high surface area, and structural versatility....

(This article belongs to the Section Inorganic Solid-State Chemistry)
  • Review
  • Open Access
1 Citations
3,030 Views
34 Pages

All-solid-state lithium batteries (ASSLBs) are widely regarded as a promising next-generation energy-storage technology because they offer the potential to simultaneously improve the safety and energy density of conventional lithium battery systems....

(This article belongs to the Special Issue Novel Research on Electrochemical Energy Storage Materials, 2nd Edition)
  • Article
  • Open Access
1,883 Views
15 Pages

In Situ Sulfidation-Induced Construction of Ni9S8/NiMoO4 Heterojunction and Its Synergistically Enhanced Hydrogen Evolution Performance

  • Yanhong Ding,
  • Yong Cao,
  • Zhichao Gao,
  • Zijing Zeng and ,
  • Chenyu Xu,
  • Teng Fu,
  • Jintao Yang and
  • Yirong Zhu
  • + 3 authors+ 0 author

This study reports a straightforward and controllable two-step hydrothermal synthesis of novel Ni9S8@NiMoO4/NF nanospherical catalysts supported on nickel foam (NF), accompanied by a systematic evaluation of their performance in the electrochemical h...

(This article belongs to the Special Issue Advanced Inorganic Nanomaterials for Energy Conversion and Catalysis Applications, 2nd Edition)
  • Article
  • Open Access
1,548 Views
16 Pages

CuIn5Se8 is reported as a remarkable copper-deficient layer that contains ordered vacancy compounds (OVCs) for high-efficiency chalcopyrite-based solar cells; however, the understanding of its carrier characteristics has remained limited. OVCs could...

(This article belongs to the Special Issue Feature Papers in Inorganic Solid-State Chemistry 2026)
  • Article
  • Open Access
2,525 Views
17 Pages

In Vitro Antitumor Activity of Metal Complexes of Salinomycin with Cobalt (Co(II)), Copper (Cu(II)) and Zinc (Zn(II)) Ions Against Human Cervical Cancer (HeLa) and Melanoma (A375, SH-4) Cells

  • Tanya Zhivkova,
  • Hristo Hristov,
  • Radostina Alexandrova,
  • Abedulkadir Abudalleh and ,
  • Lora Dyakova,
  • Peter Dorkov and
  • Juliana Ivanova
  • + 2 authors+ 0 author

In this study, we present new data about the cytotoxic activity of metal complexes of salinomycin with Co(II), Cu(II) and Zn(II) against human cervical cancer (HeLa) and melanoma (A375, SH-4) cell lines. The effect of the compounds on cell viability...

(This article belongs to the Special Issue Metal-Based Compounds: Relevance for the Biomedical Field, 2nd Edition)
  • Review
  • Open Access
4 Citations
2,444 Views
19 Pages

Water pollution caused by harmful organic pollutants discharged from various industries, such as textiles, pharmaceuticals, papermaking, and printing, is resulting in serious health complications and adversely impacting aquatic life. Numerous strateg...

(This article belongs to the Special Issue Inorganic Photocatalysts for Environmental Applications)
  • Communication
  • Open Access
1,878 Views
12 Pages

Microstructural Refinement of Electroless Ni-P Amorphous Composite Coatings on Carbon Fibers Induced by Al2O3 Nanoparticles Dispersed with a PEG/NNO Additive

  • Yongjie Zhao,
  • Weixin Ge,
  • Tiebao Wang,
  • Pan Gong and ,
  • Wei Yang,
  • Lichen Zhao and
  • Xin Wang
  • + 2 authors+ 0 author

Controlling the microstructure of electroless nickel coatings is crucial for optimizing the interfacial properties of carbon fibers. However, a systematic understanding of how dispersants can effectively leverage the refining effect of nanoparticles...

(This article belongs to the Special Issue Recent Research and Application of Amorphous Materials, 2nd Edition)
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Inorganics - ISSN 2304-6740