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Separations, Volume 5, Issue 1 (March 2018)
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Cover Story (view full-size image) This paper describes a poly(octadecyl acrylate) (pODA)-based organic phase grafted on porous [...] Read more. This paper describes a poly(octadecyl acrylate) (pODA)-based organic phase grafted on porous silica, which is assisted by 2-vinyl-4,6-diamino-1,3,5-triazine (AT), for a chromatography stationary phase. The copolymer-grafted stationary phase exhibited higher phase transition temperature and molecular shape selectivity than the corresponding ODA homopolymer-grafted phase, because the AT moiety promoted the side-chain ordering of the pODA moiety, bringing about the selectivity enhancement for polycyclic aromatic hydrocarbons (PAHs) in HPLC through multiple carbonyl-interactions. View the paper