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Polymers, Volume 16, Issue 24

2024 December-2 - 165 articles

Cover Story: Bioplastics have emerged as eco-friendly solutions for the waste management of plastics. An industrial-scale composting experiment was conducted over 12 weeks using 37.5 tons of manure/wood and 50 tons of processed biopolymer bags composed of 20% starch, 10% additives, and 70% polybutylene adipate terephthalate (PBAT). Bioplastic disintegration tests revealed that 95% of the bags disintegrated by the 12th week, although ecotoxicity tests indicated varying germination inhibition rates. The result of the biodegradation assessment using gas chromatography coupled with mass spectrometry indicated that the PBAT biopolymer was not fully decomposed even in 1-year matured compost and identified three major final metabolites. View this paper
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Articles (165)

  • Article
  • Open Access
8 Citations
2,022 Views
21 Pages

3D-Printed Acrylated Soybean Oil Scaffolds with Vitrimeric Properties Reinforced by Tellurium-Doped Bioactive Glass

  • Matteo Bergoglio,
  • Matthias Kriehuber,
  • Bernhard Sölle,
  • Elisabeth Rossegger,
  • Sandra Schlögl,
  • Ziba Najmi,
  • Andrea Cochis,
  • Federica Ferla,
  • Marta Miola and
  • Marco Sangermano
  • + 1 author

23 December 2024

In this study, we present novel, vitrimeric and biobased scaffolds that are designed for hard tissue applications, composed of acrylated, epoxidized soybean oil (AESO) and reinforced with bioactive glass that is Tellurium doped (BG-Te) and BG-Te sila...

  • Article
  • Open Access
5 Citations
1,526 Views
20 Pages

23 December 2024

This study introduces a novel method to enhance the antibacterial functionality of electrospun nanofibrous textiles by integrating silver nanoparticles (AgNPs) into poly (lactic acid) (PLA) fabrics through pre- and post-electrospinning techniques. Ag...

  • Review
  • Open Access
4 Citations
1,316 Views
18 Pages

23 December 2024

As a category of polymeric materials, soft dielectrics, such as most elastomers and rubber-like materials, have shown great potential for extensive applications in various fields. Owing to their intriguing electromechanical coupling behaviors, the mo...

  • Review
  • Open Access
1 Citations
1,871 Views
22 Pages

23 December 2024

The sensitivity of positron annihilation characteristics to changes in the molecular packing in network-forming polymers has been demonstrated since the early 1980s. Positron annihilation lifetime spectroscopy (PALS) is a unique technique that can pr...

  • Article
  • Open Access
1 Citations
1,467 Views
13 Pages

A Novel Polytetrahydrofuran-Based Shape Memory Polyurethane Enhanced by Polyglycolide-Block-Polytetrahydrofuran-Block-Polyglycolide Copolymer

  • Xin Li,
  • Lingchen Mao,
  • Weiqian Li,
  • Han Wu,
  • Suyang Dai,
  • Rui Xiao,
  • Jiayi Huang,
  • Guodong Liu,
  • Keda Yang and
  • Zhenbo Ning
  • + 3 authors

23 December 2024

A series of polyurethanes (PU-GT) were prepared using polyglycolide-block-polytetrahydrofuran-block-polyglycolide (PGA-PTHF-PGA), polytetrahydrofuran homopolymer (PTHF), glycerol, and hexamethylene diisocyanate (HDI) by a one-pot synthesis method. Th...

  • Article
  • Open Access
5 Citations
1,660 Views
22 Pages

Alkali-Polymer Flooding in an Austrian Brownfield: From Laboratory to Field—Insights

  • Muhammad Tahir,
  • Rafael Hincapie,
  • Torsten Clemens,
  • Dominik Steineder,
  • Amir Farzaneh and
  • Silvan Mikulic

23 December 2024

We focus on optimizing oil displacement in brownfields using alkali polymers (AP) flooding. The goal is to enhance rock–fluid and fluid–fluid interactions to improve oil recovery. The evaluation includes detailed screening of AP mixtures...

  • Article
  • Open Access
7 Citations
2,617 Views
14 Pages

23 December 2024

This work investigates the sustainable reuse of expanded polystyrene (EPS) waste through a multi-cycle physical recycling process involving dissolution in acetone and subsequent manufacturing via Direct Ink Write (DIW) 3D printing and casting. Morpho...

  • Article
  • Open Access
9 Citations
2,103 Views
17 Pages

In Situ Preparation of Silver Nanoparticles/Organophilic-Clay/Polyethylene Glycol Nanocomposites for the Reduction of Organic Pollutants

  • Amina Sardi,
  • Bouhadjar Boukoussa,
  • Aouicha Benmaati,
  • Kheira Chinoune,
  • Adel Mokhtar,
  • Mohammed Hachemaoui,
  • Soumia Abdelkrim,
  • Issam Ismail,
  • Jibran Iqbal and
  • Mohamed Abboud
  • + 2 authors

23 December 2024

This work focuses on the preparation and application of silver nanoparticles/organophilic clay/polyethylene glycol for the catalytic reduction of the contaminants methylene blue (MB) and 4-nitrophenol (4-NP) in a simple and binary system. Algerian cl...

  • Article
  • Open Access
7 Citations
2,857 Views
22 Pages

Poly(3-hydroxybutyrate) Modified with Thermoplastic Polyurethane and Microfibrillated Cellulose: Hydrolytic Degradation and Thermal and Mechanical Properties

  • Adriana Nicoleta Frone,
  • Denis Mihaela Panaitescu,
  • Augusta Raluca Gabor,
  • Cristian-Andi Nicolae,
  • Marius Ghiurea and
  • Corina Bradu

23 December 2024

Blending poly(3-hydroxybutyrate) (PHB) with other polymers could be a rapid and accessible solution to overcome some of its drawbacks. In this work, PHB was modified with microfibrillated cellulose (MC) and a thermoplastic polyurethane containing bio...

  • Article
  • Open Access
2 Citations
1,813 Views
20 Pages

High Speed Sintering of Polyamide 12: From Powder to Part Properties

  • Jan Kemnitzer,
  • Marco Wimmer,
  • Anna Tarasova and
  • Frank Döpper

23 December 2024

High Speed Sintering (HSS) is an additive manufacturing process with great potential to produce complex, high-quality polymer parts on an industrial scale. However, little information is currently available on the characteristics of the powder materi...

  • Review
  • Open Access
13 Citations
4,972 Views
38 Pages

Extraction of Natural-Based Raw Materials Towards the Production of Sustainable Man-Made Organic Fibres

  • Ana Catarina Vale,
  • Liliana Leite,
  • Vânia Pais,
  • João Bessa,
  • Fernando Cunha and
  • Raul Fangueiro

23 December 2024

Bioresources have been gaining popularity due to their abundance, renewability, and recyclability. Nevertheless, given their diverse composition and complex hierarchical structures, these bio-based sources must be carefully processed to effectively e...

  • Article
  • Open Access
9 Citations
3,500 Views
24 Pages

Development of a Modular Sandwich Panel with a Composite Core of Recycled Material for Application in Sustainable Building

  • Juan José Valenzuela Expósito,
  • Elena Picazo Camilo and
  • Francisco Antonio Corpas Iglesias

23 December 2024

In recent years, the construction industry has faced challenges related to rising material costs, labor shortages and environmental sustainability, resulting in an increased interest in modular construction cores composed of recycled materials, such...

  • Review
  • Open Access
17 Citations
4,669 Views
30 Pages

Participation of Polymer Materials in the Structure of Piezoelectric Composites

  • Cosmin Ionuț Pîrvu,
  • Alexandru Sover and
  • Mărioara Abrudeanu

23 December 2024

This review explores the integration of polymer materials into piezoelectric composite structures, focusing on their application in sensor technologies, and wearable electronics. Piezoelectric composites combining ceramic phases like BaTiO3, KNN, or...

  • Article
  • Open Access
7 Citations
2,777 Views
16 Pages

23 December 2024

The coagulation of fresh latex is one of the critical processes that impacts rubber quality during natural rubber processing. Constitutive relationships are the basis for the study of the mechanical properties of rubber materials and serve as a prere...

  • Article
  • Open Access
5 Citations
1,255 Views
17 Pages

23 December 2024

Antioxidants are contained in fruits and vegetables and are commonly obtained through food. However, it is frequently necessary to supplement the diet with substances that are often poorly soluble in water and sensitive to light and oxygen. For this...

  • Article
  • Open Access
3 Citations
1,910 Views
18 Pages

23 December 2024

In this work, twin-screw extruder and compression moulding techniques were utilized to fabricate polymer blends: polypropylene (PP), polybutadiene (PB), and composites using glass fibre (GF) and flax fibre (FF). During fabrication, the polymer ratios...

  • Article
  • Open Access
1 Citations
1,586 Views
14 Pages

Highlighting Free-Recovery and Work-Generating Shape Memory Effects at 80r-PET Thermoformed Cups

  • Ștefan-Dumitru Sava,
  • Bogdan Pricop,
  • Mihai Popa,
  • Nicoleta-Monica Lohan,
  • Elena Matcovschi,
  • Nicanor Cimpoeșu,
  • Radu-Ioachim Comăneci and
  • Leandru-Gheorghe Bujoreanu

23 December 2024

The paper starts by describing the manufacturing process of cups thermoformed from extruded foils of 80% recycled PET (80r-PET), which comprises heating, hot deep drawing and cooling. The 80r-PET foils were heated up to 120 °C, at heating rates o...

  • Article
  • Open Access
1,813 Views
15 Pages

23 December 2024

The curing distortion is a critical determinant of the quality of integrally manufactured composite structures, playing a pivotal role in the design and fabrication of composite. This paper presents two simplified methods in predicting the curing dis...

  • Retraction
  • Open Access
1 Citations
1,755 Views
1 Page

RETRACTED: Ahmed et al. Thermal Analysis of a Metal–Organic Framework ZnxCo1-X-ZIF-8 for Recent Applications. Polymers 2021, 13, 4051

  • Moustafa Ahmed,
  • Yas M. Al-Hadeethi,
  • Ahmed Alshahrie,
  • Arwa T Kutbee,
  • Essam R. Shaaban and
  • Ahmed F. Al-Hossainy

23 December 2024

The journal retracts the article “Thermal Analysis of a Metal–Organic Framework ZnxCo1-X-ZIF-8 for Recent Applications” [...]

  • Article
  • Open Access
4 Citations
1,798 Views
17 Pages

22 December 2024

Currently, few studies have been conducted on the use of fluorocarbon resin (FEVE) and polytetrafluoroethylene (PTFE) as adhesive substrates and lubricating and anti-corrosion fillers, respectively, for the fabrication of PTFE-reinforced fluorocarbon...

  • Article
  • Open Access
8 Citations
5,114 Views
22 Pages

22 December 2024

The chemical mechanical polishing/planarization (CMP) is essential for achieving the desired surface quality and planarity required for subsequent layers and processing steps. However, the aggregation of slurry particles caused by abrasive materials...

  • Article
  • Open Access
6 Citations
1,477 Views
12 Pages

Clarification of Bio-Degumming Enzymes Based on a Visual Analysis of the Hemp Roving Structure

  • Tianyi Yu,
  • Pandeng Li,
  • Tong Shu,
  • Tingting Liu,
  • Chunhua Fu and
  • Longjiang Yu

22 December 2024

Hemp fibers, recognized for their breathability, specific strength, and ultraviolet resistance, are widely utilized in textile manufacturing and composite materials. Bio-degumming is a promising alternative technology to traditional chemical degummin...

  • Article
  • Open Access
15 Citations
3,955 Views
20 Pages

22 December 2024

The effect of dispersing multiwalled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) in the matrix on the low-velocity impact resistance and post-impact residual tensile strength of the carbon fiber reinforced epoxy composite laminates ha...

  • Article
  • Open Access
6 Citations
3,125 Views
16 Pages

22 December 2024

Among 3D printing technologies, fused filament fabrication (FFF) is a fast, simple, and low-cost technology that is being explored in a variety of industries. FFF produces composites using thermoplastic filaments, limiting the applicability of weldin...

  • Article
  • Open Access
4 Citations
1,960 Views
11 Pages

Detecting Early Degradation of Wood Ultrastructure with Nonlinear Optical Imaging and Fluorescence Lifetime Analysis

  • Alice Dal Fovo,
  • Riccardo Cicchi,
  • Claudia Gagliardi,
  • Enrico Baria,
  • Marco Fioravanti and
  • Raffaella Fontana

22 December 2024

Understanding the deterioration processes in wooden artefacts is essential for accurately assessing their conservation status and developing effective preservation strategies. Advanced imaging techniques are currently being explored to study the impa...

  • Article
  • Open Access
5 Citations
2,569 Views
13 Pages

Optimisation of Clutch Disc Friction Material Using a Multi-Layer Perceptron Artificial Neural Network

  • George Bălășoiu,
  • Cristian Munteniță,
  • Valentin Tiberiu Amortila and
  • Larisa Titire

22 December 2024

This paper presents an analysis of four clutch disc friction materials (from different manufacturers) used in manual transmissions. Scanning electron microscopy and energy-dispersive X-ray spectroscopy were employed for the microstructural and chemic...

  • Article
  • Open Access
8 Citations
2,162 Views
22 Pages

Layered Composites for High Tan Delta Plateau over Wide Temperature Range

  • Taoxi Wang,
  • Hongmei Chen,
  • Wei Jun Liang,
  • Boon Siang Lucas Ng,
  • Runzhi Lu,
  • Ji Qi,
  • Huaquan Wang,
  • Junhua Zhang,
  • Hui Xie and
  • Wei Min Huang
  • + 1 author

22 December 2024

Tan Delta reflects the viscoelastic behavior of materials, particularly polymers. In most cases, a high Tan Delta value is associated with transitions (such as glass transition or melting), enabling effective damping properties near these temperature...

  • Article
  • Open Access
5 Citations
2,066 Views
19 Pages

Synthesis of a Bimetallic-Doped Phytate-Melamine Composite as an Efficient Additive for Epoxy Resins with High Fire Safety

  • Shunxiang Wang,
  • Jianfeng Huang,
  • An Wei,
  • Yulian Chen,
  • Xulan Lu,
  • Yongjin Zou,
  • Fen Xu,
  • Lixian Sun,
  • Yunhao Lu and
  • Cuili Xiang

21 December 2024

The issue of hazardous smoke and toxic gases released from epoxy resins (EP), which often causes casualties in real fires, has limited its application. Therefore, we have developed a novel flame retardant based on a bimetallic-doped phytate-melamine...

  • Article
  • Open Access
7 Citations
1,607 Views
16 Pages

21 December 2024

The effective use of polymer carbon dots (PCD) in various fields of science and technology requires a more detailed understanding of the mechanisms of their photoluminescence formation and change as a result of their interaction with the environment....

  • Article
  • Open Access
1,622 Views
18 Pages

Synthesis and Characterization of Photocurable Difunctional Monomers for Medical Applications

  • Gokhan Demirci,
  • Agata Goszczyńska,
  • Martyna Sokołowska,
  • Marek Żwir,
  • Krzysztof Gorący and
  • Miroslawa El Fray

21 December 2024

Photocurable materials offer a rapid transition from a liquid to a solid state, and have recently received great interest in the medical field. However, while dental resins are very popular, only a few materials have been developed for soft tissue re...

  • Article
  • Open Access
3 Citations
3,057 Views
22 Pages

The Catalytic Degradation of Waste PU and the Preparation of Recycled Materials

  • Xiaohua Gu,
  • Jiahao Xu,
  • Shangwen Zhu,
  • Qinglong Zhao,
  • Shaochun Sun,
  • Yanxun Zhang,
  • Qingyong Su and
  • Canyan Long

21 December 2024

In this paper, we investigated the efficient metal-free phosphorus–nitrogen (PN) catalyst and used the PN catalyst to degrade waste PU with two-component binary mixed alcohols as the alcohol solvent. We examined the effects of reaction temperat...

  • Article
  • Open Access
2 Citations
1,228 Views
19 Pages

Temperature Areas of Local Inelasticity in Polyoxymethylene

  • Viktor A. Lomovskoy,
  • Svetlana A. Shatokhina,
  • Raisa A. Alekhina and
  • Nadezhda Yu. Lomovskaya

21 December 2024

The spectra of internal friction and temperature dependencies of the frequency of a free-damped oscillation process excited in the specimens of an amorphous–crystalline copolymer of polyoxymethylene with the co-monomer trioxane (POM-C) with a d...

  • Article
  • Open Access
1 Citations
1,538 Views
15 Pages

New Composite Packaging Material from Edible Oil By-Product Coated with Paraffin Wax for Dry Apricot Slice Packing Under a Modified Atmosphere

  • Nevena Hromiš,
  • Sanja Ostojić,
  • Lato Pezo,
  • Senka Popović,
  • Zdravko Šumić,
  • Anita Milić,
  • Sunčica Kocić-Tanackov and
  • Danijela Šuput

21 December 2024

Composite biopolymer hydrogel as food packaging material, apart from being environmentally favorable, faces high standards set upon food packaging materials. The feature that favors biopolymer film application is their low gas permeability under room...

  • Article
  • Open Access
3 Citations
1,332 Views
15 Pages

Ultrasonic Effect on the Growth of Crystals from Aqueous Electrolyte Solutions on Polymer Substrates: The Role of Isotopic Composition of Liquid

  • Nikolai F. Bunkin,
  • Polina N. Bolotskova,
  • Sergey V. Gudkov,
  • Valery V. Voronov,
  • Vladimir I. Pustovoy,
  • Valery N. Sorokovikov,
  • Oleg T. Kamenev and
  • Yulia V. Novakovskaya

21 December 2024

The peculiarities of the crystal formation from supersaturated aqueous solutions of CuSO4 on polymer substrates were studied using X-ray diffractometry. During the crystal formation, the test solutions were irradiated with one or two counter-propagat...

  • Article
  • Open Access
2 Citations
1,683 Views
14 Pages

Elucidating Extracellular Vesicle Isolation Kinetics via an Integrated Off-Stoichiometry Thiol-Ene and Cyclic Olefin Copolymer Microfluidic Device

  • Janis Cipa,
  • Edgars Endzelins,
  • Arturs Abols,
  • Nadezda Romanchikova,
  • Aija Line,
  • Guido W. Jenster,
  • Gatis Mozolevskis and
  • Roberts Rimsa

21 December 2024

Extracellular vesicles (EVs) are promising biomarkers for diagnosing complex diseases such as cancer and neurodegenerative disorders. Yet, their clinical application is hindered by challenges in isolating cancer-derived EVs efficiently due to their b...

  • Article
  • Open Access
3 Citations
1,616 Views
12 Pages

Valorization of Xylose-Rich Medium from Cynara cardunculus Stalks for Lactic Acid Production via Microbial Fermentation

  • Gianfrancesco Russo,
  • Mattia Gelosia,
  • Giacomo Fabbrizi,
  • Mariarosaria Angrisano,
  • Grazia Policastro and
  • Gianluca Cavalaglio

21 December 2024

Lactic acid (LA) is a versatile, optically active compound with applications across the food, cosmetics, pharmaceutical, and chemical industries, largely driven by its role in producing biodegradable polylactic acid (PLA). Due to its abundance, ligno...

  • Article
  • Open Access
4 Citations
1,508 Views
15 Pages

21 December 2024

The main purpose of this study is to prepare a melamine aniline formaldehyde foam, an MAF copolymer, with lower water sensitivity and non-flammability properties obtained by the condensation reaction of melamine, aniline, and formaldehyde. In additio...

  • Article
  • Open Access
25 Citations
7,851 Views
20 Pages

Design, Analysis, and Testing of a Type V Composite Pressure Vessel for Hydrogen Storage

  • Maria Mikroni,
  • Grigorios Koutsoukis,
  • Dimitrios Vlachos,
  • Vassilis Kostopoulos,
  • Antonios Vavouliotis,
  • George Trakakis,
  • Dimitrios Athinaios,
  • Chrysavgi Nikolakea and
  • Dimitrios Zacharakis

21 December 2024

Hydrogen, as a zero-emission fuel, produces only water when used in fuel cells, making it a vital contributor to reducing greenhouse gas emissions across industries like transportation, energy, and manufacturing. Efficient hydrogen storage requires l...

  • Article
  • Open Access
5 Citations
2,331 Views
12 Pages

21 December 2024

Smart fibers with tunable luminescence properties, as a new form of visual output, present the potential to revolutionize personal living habits in the future and are receiving more and more attention. However, a huge challenge of smart fibers as wea...

  • Article
  • Open Access
1,602 Views
10 Pages

21 December 2024

Polyurethane materials, widely used in indoor environments, occasionally exhibit unpleasant odors. An important source of polyurethane odorants is polyether polyols. Previous studies identified odorous 2-ethyldimethyl-1,3,6-trioxocanes in polyurethan...

  • Article
  • Open Access
1 Citations
1,910 Views
21 Pages

21 December 2024

Rubber is widely used in situations involving cyclic loads, and the influence of temperature on rubber properties is particularly pronounced under cyclic loading. In this study, mechanical property tests and crack propagation tests of carbon black-fi...

  • Article
  • Open Access
3 Citations
1,822 Views
11 Pages

21 December 2024

The effects of different doses (10–100 kGy) of electron beams on the molecular structure, microstructure, and thermoelectric properties of polypyrrole (PPy) under high-energy electron beam irradiation (10 MeV) were studied. The results showed t...

  • Article
  • Open Access
2 Citations
2,250 Views
17 Pages

20 December 2024

A fully bio-based polyester polyol based on isosorbide (ISB) and dimer fatty acid (DA) was synthesized through esterification. An ISB-based polyester polyol (DIS) was developed to synthesize a bio-based polyurethane elastomer (PUE) with enhanced mech...

  • Review
  • Open Access
3 Citations
2,714 Views
26 Pages

Fats and Oils as a Sustainable Source of Photopolymerizable Monomers

  • Alberto Spessa,
  • Franca Castiglione,
  • Alessandra Vitale,
  • Roberta Bongiovanni and
  • Sara Dalle Vacche

20 December 2024

Bio-derived monomers and biobased building blocks obtained from natural sources, e.g., fats and oils, are attracting increasing attention mainly due to sustainability concerns. Due to their features, renewable feedstocks are an excellent alternative...

  • Review
  • Open Access
22 Citations
5,337 Views
35 Pages

20 December 2024

Natural plant fibers (NPFs) have emerged as a sustainable alternative in the manufacture of composites due to their renewability and low environmental impact. This has led to a significant increase in the use of natural plant fiber-reinforced polymer...

  • Article
  • Open Access
16 Citations
4,629 Views
14 Pages

20 December 2024

Additive manufacturing is an attractive technology due to its versatility in producing parts with diverse properties from a single material. However, the process often generates plastic waste, particularly from failed prints, making sustainability a...

  • Article
  • Open Access
8 Citations
4,366 Views
11 Pages

20 December 2024

The development of dynamic covalent materials with repairability, reprocessability, and recyclability is crucial for sustainable development. In this work, we report a new strategy to adjust the thermomechanical properties of boronic ester cross-link...

  • Article
  • Open Access
9 Citations
2,588 Views
9 Pages

Towards Green Dentistry: Evaluating the Potential of 4D Printing for Sustainable Orthodontic Aligners with a Reduced Carbon Footprint

  • Elena Palmieri,
  • Luca Montaina,
  • Denise Bellisario,
  • Ivano Lucarini,
  • Francesco Maita,
  • Martina Ielmini,
  • Maria Elena Cataldi,
  • Loredana Cerroni,
  • Roberta Condò and
  • Luca Maiolo

20 December 2024

Clear aligners have transformed orthodontic care by providing an aesthetic, removable alternative to traditional braces. However, their significant environmental footprint, contributing to approximately 15,000 tons of plastic waste annually, poses a...

  • Article
  • Open Access
1,926 Views
11 Pages

20 December 2024

Polybenzimidazole (PBI) is a high-performance polymer known for its excellent thermal stability, mechanical strength, and chemical resistance, attributes that are derived from its unique structure comprising repeated benzene and imidazole rings. Howe...

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Polymers - ISSN 2073-4360