polymers-logo

Journal Browser

Journal Browser

Mechanic Properties of Polymer Materials

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Physics and Theory".

Deadline for manuscript submissions: 31 August 2025 | Viewed by 5244

Special Issue Editor


E-Mail Website
Guest Editor
State Key Laboratory of Intelligent Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Interests: nanocomposite; multi-scale modelling; nanomechanics; structural dynamics; computational mechanics

Special Issue Information

Dear Colleagues,

Polymer materials are widely used because of their light weight and excellent mechanical properties, either alone or as the matrix of composites. To rational design polymer materials based on needs, the relationship between the polymer microstructure and the effective macroscopic properties is currently a focus of research and requires continued exploration. We are pleased to invite you to share research results and exchange ideas on the fabrication, testing, and modelling of high-performance polymers.

This Special Issue aims to provide a comprehensive overview of current knowledge. In this Special Issue, original research articles and reviews are welcome. Research areas may include the elasticity, viscoelasticity, yield, and fracture of polymer materials, the design and fabrication of polymer composites, and the accurate and fast testing methods for the mechanical properties of polymers.

We look forward to receiving your contributions.

Prof. Dr. Li Li
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • elasticity
  • viscoelasticity
  • plasticity
  • fracture
  • polymer testing
  • modelling
  • fabrication
  • polymer composites

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.

Further information on MDPI's Special Issue policies can be found here.

Published Papers (7 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

Jump to: Review

18 pages, 8784 KiB  
Article
Experimental and Numerical Research of 3D DLP-Printed Solid and Voronoi PLA Resin Specimens Under Tensile and Bending Loads
by Zorana Golubović, Jovan Tanasković, Aleksa Milovanović and Božica Bojović
Polymers 2025, 17(9), 1180; https://doi.org/10.3390/polym17091180 - 26 Apr 2025
Viewed by 208
Abstract
Additive manufacturing (AM), especially vat photopolymerization processes such as digital light processing (DLP), enables the production of highly detailed and complex geometries with precise material structure control. In this study, the influence of internal structure on the mechanical properties of PLA resin specimens [...] Read more.
Additive manufacturing (AM), especially vat photopolymerization processes such as digital light processing (DLP), enables the production of highly detailed and complex geometries with precise material structure control. In this study, the influence of internal structure on the mechanical properties of PLA resin specimens produced using a DLP 3D printer is investigated. Two designs were analyzed: a fully solid structure and a shell with a Voronoi pattern. Tensile and bending tests revealed that solid specimens exhibited higher strength, while Voronoi structures performed better under bending loading despite lower load-bearing capacity due to their porosity ratio. The developed numerical model, analyzed through different numerical simulations using the Ansys 2025R01 Software package and validated by experimental results, showed a strong correlation between experimental and numerical results that confirmed the reliability of the developed models for preliminary design verification. These models hold significant potential for the design of mechanical and biomedical components, including orthopedic immobilization devices. Microscopic analysis revealed brittle fracture in solid specimens with striations and bubble-shaped irregularities, while Voronoi specimens exhibited fragmented surfaces with clean, brittle failure along structural voids. Based on the results obtained, this research demonstrates how additive manufacturing enables the optimization of mechanical properties and material efficiency through precise control of internal structures. In the future, validated numerical models can be used to check the preliminary designs of different components, which will significantly reduce development costs. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

29 pages, 3593 KiB  
Article
A Surface-Enabled Computational Homogenization Method for Variable-Density Polymer Lattice Metastructures
by Aofei Zhang, Shuo Li, Ling Ling and Li Li
Polymers 2025, 17(6), 769; https://doi.org/10.3390/polym17060769 - 14 Mar 2025
Viewed by 350
Abstract
The current limitations in predicting mechanical properties arise from an incomplete understanding of surface-induced size effects in variable-density polymer lattice metastructures. Through large-scale, high-fidelity finite element simulations, we identify a novel variable-density surface law governing the surface intrinsic length at the macroscopic scale. [...] Read more.
The current limitations in predicting mechanical properties arise from an incomplete understanding of surface-induced size effects in variable-density polymer lattice metastructures. Through large-scale, high-fidelity finite element simulations, we identify a novel variable-density surface law governing the surface intrinsic length at the macroscopic scale. Capitalizing on this surface law discovery, we propose a surface-enhanced computational homogenization framework. By incorporating the surface intrinsic length parameters with the variable-density surface law and an offline database constructed through high-throughput numerical simulations, we develop an efficient predictive model capable of online analysis for the mechanical behavior of variable-density polymeric lattice metastructures. This innovative approach preserves critical configuration-dependent surface effects while achieving both efficiency and precision in predicting the macro-scale mechanical performance of such metastructures. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

22 pages, 12070 KiB  
Article
Nonlinear Viscoelasticity of and Structural Modulation in Guar Gum-Enhanced Triple-Network Hydrogels
by Yi Luo, Werner Pauer and Gerrit A. Luinstra
Polymers 2025, 17(5), 597; https://doi.org/10.3390/polym17050597 - 24 Feb 2025
Viewed by 591
Abstract
The effect of the presence of guar gum (0–0.75 wt%) in a thermo-responsive triple-network (TN) PVA/TA/PVA-MA-g-PNIPAAm hydrogel (PVA: polyvinyl alcohol; MA: methacrylate, PNIPAAm: poly-N-isopropyl acryl amide; TA: tannic acid) with respect to the structural, mechanical, and viscoelastic properties was mapped. A comprehensive analysis, [...] Read more.
The effect of the presence of guar gum (0–0.75 wt%) in a thermo-responsive triple-network (TN) PVA/TA/PVA-MA-g-PNIPAAm hydrogel (PVA: polyvinyl alcohol; MA: methacrylate, PNIPAAm: poly-N-isopropyl acryl amide; TA: tannic acid) with respect to the structural, mechanical, and viscoelastic properties was mapped. A comprehensive analysis, using large-amplitude oscillatory shear (LAOS), SEM imaging, XRD, and mechanical analysis revealed that guar enhances hydrogel crystallinity (up to 30% at 0.75 wt%), which goes along with a strain hardening. The hydrogel achieved superior mechanical performance at a gum concentration of 0.5 wt% with a 40% increase in shear-thickening, an enhanced strain tolerance in nonlinear regimes, and a good mechanical robustness (maximum elongation to break of 500% and stress of 620 kPa). The hydrogel with 0.5 wt% guar exhibited also a good thermal response (equilibrium swelling ratio changed from 8.4 at 5 °C to 2.5 at 50 °C) and an excellent thermal cycling dimensional stability. Higher guar concentrations reduce structural resilience, leading to brittle hydrogels with lower extensibility and viscoelastic stability. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

17 pages, 6929 KiB  
Article
Exploring the Weathering and Accelerated Environmental Aging of Wave-Transparent Reinforced Composites
by Imran Haider, Muhammad Ali Khan, Shahid Aziz, Syed Husain Imran Jaffery, Muhammad Iftikhar Faraz, Iftikhar Hussain Gul, Dong-Won Jung, Taoufik Saidani and Walid M. Shewakh
Polymers 2025, 17(3), 357; https://doi.org/10.3390/polym17030357 - 28 Jan 2025
Viewed by 814
Abstract
Approaches to retain or improve wave-transparent composite properties received ongoing attention. Silica glass fiber composites are being utilized in wave transparency applications owing to their excellent dielectric properties. During operational service life, they are exposed to ambient and harsh environments, which degrade their [...] Read more.
Approaches to retain or improve wave-transparent composite properties received ongoing attention. Silica glass fiber composites are being utilized in wave transparency applications owing to their excellent dielectric properties. During operational service life, they are exposed to ambient and harsh environments, which degrade their performance and properties. The objective is to evaluate the progressive degradation of silica fiber wave-transparent composite material’s properties and overall performance. Silica fiber/epoxy wave-transparent composites (SFWCs) were fabricated by stacking high-silica glass cloth (HSG) plies via multi-layer compression and curing at 150 °C (14 hrs) and were investigated upon one-year real-time weathering and 20-year accelerated aging (Hallberg peck model). The morphology of one-year-aged SFWC composite was found to be better than that of 20-year-aged SFWC, where relatively weakened interfacial bonding and composite structure were observed. One year weathering the dielectric constant (εr) was increased to 4.34%, and dielectric loss (δ) was found to be 5.6%, whereas upon accelerated conditions (equivalent to 20 yrs of ambient conditions), εr was significantly raised 30.63% from its original value (3.2), and δ was increased 22.8% (0.035). In the 20-year aged SFWC composite, the maximum absorbed moisture was 3.1%. Tensile strength dropped from 147.8 MPa to 136.48 MPa, and compressive strength from 388.54 MPa to 374.41 MPa. Upon aging (from 1 year of weathering to 20 years of accelerated aging), SFWC composite properties and functional performance were lowered but remained reasonable. SFWC properties, as revealed by microscale characterization, can contribute to the determination of the impact of deterioration and useful service life in respective microelectronics wave transparency applications. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

28 pages, 6105 KiB  
Article
Exploring the Effect of Annealing on PLA/Carbon Nanotube Nanocomposites: In Search of Efficient PLA/MWCNT Nanocomposites for Electromagnetic Shielding
by Flávio Urbano da Silva, Carlos Bruno Barreto Luna, Fabiano Santana da Silva, José Vinícius Melo Barreto, Debora Pereira Schmitz, Bluma Guenther Soares, Renate Maria Ramos Wellen and Edcleide Maria Araújo
Polymers 2025, 17(2), 246; https://doi.org/10.3390/polym17020246 - 20 Jan 2025
Viewed by 1170
Abstract
In this research, poly(lactic acid) (PLA) nanocomposites with multi-walled carbon nanotubes (MWCNT) were produced by extrusion, injection, and compression molding, focusing on electromagnetic shielding. Various amounts of carbon nanotubes (MWCNTs) were tested in PLA matrix, specifically ranging from 1 to 4 parts per [...] Read more.
In this research, poly(lactic acid) (PLA) nanocomposites with multi-walled carbon nanotubes (MWCNT) were produced by extrusion, injection, and compression molding, focusing on electromagnetic shielding. Various amounts of carbon nanotubes (MWCNTs) were tested in PLA matrix, specifically ranging from 1 to 4 parts per hundred resin (phr). The resulting nanocomposites were analyzed before and after undergoing annealing heat treatment. It was observed that as the MWCNT content increased, the melt flow index of PLA decreased. This reduction indicates that the nanotubes were effectively accommodated into the PLA chain. The PLA/MWCNT (2 phr) formulation presented the greatest balance of properties, with potential for electromagnetic shielding application. Scanning electron microscopy (SEM) demonstrated that incorporating 2 phr of carbon nanotubes in PLA promoted good distribution, favoring high electrical conductivity and electromagnetic shielding between 20–22 dB (8.2–18 GHz), corresponding to approximately 99% attenuation. Furthermore, its properties, such as elastic modulus (3156 MPa), tensile strength (65.1 MPa), hardness (77.8 Shore D), and heat deflection temperature (55.3 °C), increased compared to pure PLA. After annealing, the PLA/MWCNT (2 phr) nanocomposite underwent a molecular reordering, resulting in an increased crystalline fraction, as confirmed by X-ray diffraction (XRD). However, the electrical conductivity maintained the same order of magnitude, while the electromagnetic shielding varied from 19.7 to 20 dB. The results indicate that these nanocomposites are promising for electromagnetic shielding applications and can be manufactured in the molten state. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

17 pages, 9758 KiB  
Article
The Influence of Matrix Resin Toughening on the Compressive Properties of Carbon Fiber Composites
by Xinfeng Ouyang, Xiao Wang, Qiufei Chen, Guojie Ge, Dong Liu, Kang Lin, Yunpeng Liu, Yangyang Zong, Shuo Duan and Kangmin Niu
Polymers 2024, 16(23), 3328; https://doi.org/10.3390/polym16233328 - 27 Nov 2024
Viewed by 835
Abstract
The study investigated the effects of a toughening agent and micron-sized toughening particles (TP) on the resin and carbon fiber-reinforced polymer (CFRP) composites, with a particular focus on compressive strength. The results showed that the addition of the toughening agent improved the overall [...] Read more.
The study investigated the effects of a toughening agent and micron-sized toughening particles (TP) on the resin and carbon fiber-reinforced polymer (CFRP) composites, with a particular focus on compressive strength. The results showed that the addition of the toughening agent improved the overall mechanical properties of both the resin and CFRP but had a minor effect on the residual compressive strength (CAI) of CFRP after impact. Compared to the pure toughening agent, the addition of TP increased the CAI, GIC, and GIIC of CFRP by 74%, 35%, and 68%, respectively. The SEM, ultrasonic C-scan, and metallographic microscopy were used to analyze the failure morphology and TP distribution. Compared to pure toughening agent modification, the introduction of TP led to the formation of continuous toughening particle layers, which reduced the compression damage area by 61%, significantly balancing and absorbing the load. This modification also resulted in typical kink band damage. This study found that resin toughening significantly improved the compressive strength of CFRP, while micron-sized toughening particles, in the form of toughening layers, notably improved the CAI. These findings provide valuable insights for enhancing the compression and impact resistance of CFRP. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

Review

Jump to: Research

18 pages, 3446 KiB  
Review
Mechanics of Surface Instabilities in Soft Dielectrics Subject to Electromechanical Loading
by Jiangfei Li, Zehua Wang and Jianyou Zhou
Polymers 2024, 16(24), 3612; https://doi.org/10.3390/polym16243612 - 23 Dec 2024
Viewed by 600
Abstract
As a category of polymeric materials, soft dielectrics, such as most elastomers and rubber-like materials, have shown great potential for extensive applications in various fields. Owing to their intriguing electromechanical coupling behaviors, the morphological instabilities in soft dielectrics have been an active research [...] Read more.
As a category of polymeric materials, soft dielectrics, such as most elastomers and rubber-like materials, have shown great potential for extensive applications in various fields. Owing to their intriguing electromechanical coupling behaviors, the morphological instabilities in soft dielectrics have been an active research field in recent years. In this work, the recent progress in experimental and theoretical research on their electromechanical morphological instabilities is reviewed, especially regarding the theoretical aspect. First, we revisit the theoretical framework for the electroelasticity of soft dielectrics. Then, the typical configurations of soft dielectric membranes used to generate two typical types of surface instabilities, namely wrinkles and creases, are introduced. Three commonly used modeling approaches (i.e., the stress balance method, the incremental method, and the energy method) for surface instabilities are reviewed with specific examples. Moreover, discussions on the difference between these methods and the corresponding critical loading conditions are presented. Furthermore, this review also covers the relation and transition between wrinkling and creasing phenomena. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

Back to TopTop