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Crystals, Volume 10, Issue 9

2020 September - 134 articles

Cover Story: Nanoclusters of amorphous calcium phosphate sequestered by a shell of phosphopeptides have helped us to understand how soft and hard tissues can co-exist in the same organism with relative ease, even when permeated by the same supersaturated biofluid. They may be metastable intermediates in the formation of more crystalline forms of calcium phosphate, contributing to hard tissue mineralization, or constituents of thermodynamically stable biofluids in contact with soft tissues. The latter type of biofluid can contain high concentrations of calcium and phosphate, as in the milk of many species. Lenton et al. comprehensively review the structural biology of calcium phosphate nanocluster complexes formed with phosphopeptides from caseins and osteopontin and model studies with recombinant phosphopeptides. View this paper
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Articles (134)

  • Review
  • Open Access
29 Citations
4,870 Views
19 Pages

22 September 2020

We review here new advances in the synthesis and investigation of iron(II) coordination compounds with tris(pyrazol-1-yl)methane and its derivatives as ligands. The complexes demonstrate thermally induced spin crossover accompanied by thermochromism....

  • Article
  • Open Access
7 Citations
3,550 Views
9 Pages

Proton, UV, and X-ray Induced Luminescence in Tb3+ Doped LuGd2Ga2Al3O12 Phosphors

  • U. Fawad,
  • H. J. Kim,
  • Ibrahim Gul,
  • Matiullah Khan,
  • Sajjad Tahir,
  • Tauseef Jamal and
  • Wazir Muhammad

22 September 2020

The well-known solid-state reaction method is used for the synthesis of Tb doped LuGd2Ga2Al3O12 phosphor. XRD and SEM techniques are used for the phase and structural morphology of the synthesized phosphor. UV, X-ray and proton induced spectroscopy i...

  • Article
  • Open Access
16 Citations
7,215 Views
16 Pages

Depth Profile Analysis of Deep Level Defects in 4H-SiC Introduced by Radiation

  • Tomislav Brodar,
  • Luka Bakrač,
  • Ivana Capan,
  • Takeshi Ohshima,
  • Luka Snoj,
  • Vladimir Radulović and
  • Željko Pastuović

22 September 2020

Deep level defects created by implantation of light-helium and medium heavy carbon ions in the single ion regime and neutron irradiation in n-type 4H-SiC are characterized by the DLTS technique. Two deep levels with energies 0.4 eV (EH1) and 0.7 eV (...

  • Article
  • Open Access
14 Citations
7,273 Views
12 Pages

Characterization of Accumulated B-Integral of Regenerative Amplifier Based CPA Systems

  • Stefan Bock,
  • Franziska Marie Herrmann,
  • Thomas Püschel,
  • Uwe Helbig,
  • René Gebhardt,
  • Jakob Johannes Lötfering,
  • Richard Pausch,
  • Karl Zeil,
  • Tim Ziegler and
  • Ulrich Schramm
  • + 7 authors

22 September 2020

We report on a new approach to measure the accumulated B-integral in the regenerative and multipass amplifier stages of ultrashort-pulse high-power laser systems by B-integral-induced coupling between delayed test post-pulses and the main pulse. A nu...

  • Article
  • Open Access
7 Citations
4,828 Views
7 Pages

Effects of GaN Buffer Resistance on the Device Performances of AlGaN/GaN HEMTs

  • Ki-Sik Im,
  • Jae-Hoon Lee,
  • Yeo Jin Choi and
  • Sung Jin An

22 September 2020

We investigated the effects of GaN buffer resistance of AlGaN/GaN high-electron-mobility transistors (HEMTs) on direct current (DC), low-frequency noise (LFN), and pulsed I-V characterization performances. The devices with the highest GaN buffer resi...

  • Article
  • Open Access
8 Citations
4,637 Views
8 Pages

22 September 2020

In this paper we provide a design for a vertical grating coupler for a silicon thin film on lithium niobate. The parameters-such as the cladding layer thickness of lithium niobate, fiber position, fiber angle, grating period, and duty cycle are analy...

  • Article
  • Open Access
20 Citations
7,438 Views
12 Pages

A Multifaceted Kinetic Model for the Thermal Decomposition of Calcium Carbonate

  • Jingxue Zheng,
  • Junchen Huang,
  • Lin Tao,
  • Zhi Li and
  • Qi Wang

22 September 2020

The existing kinetic models often consider the influence of a single factor alone on the chemical reaction and this is insufficient to completely describe the decomposition reaction of solids. Therefore, the existing kinetic models were improved usin...

  • Article
  • Open Access
3 Citations
2,913 Views
11 Pages

Si Quantum Dots Assist Synthesized Microflower-Like Si/MoS2 Composites for Supercapacitors

  • Jiahong Zheng,
  • Kangkang Cheng,
  • Runmei Zhang,
  • Yamei Yang,
  • Yuntao Wu and
  • Pengfei Yu

22 September 2020

The microflower-like Si/MoS2 composites were fabricated using Si quantum dots (QDs) to assist a facile hydrothermal method. The electrochemical performance of Si/MoS2 composite in symmetric and asymmetric systems was studied. Electrochemical characte...

  • Article
  • Open Access
3,394 Views
10 Pages

Single Source Precursor for PAD-LaMnO3 Thin Films

  • Ramona Bianca Sonher,
  • Richard Attila Varga,
  • Mircea Nasui,
  • Traian Petrisor Jr,
  • Mihai Sebastian Gabor,
  • Marin Senila,
  • Alessandro Rufoloni,
  • Traian Petrisor and
  • Lelia Ciontea

22 September 2020

A new lanthanum and manganese ethylenediaminetetraacetate (EDTA) coordination polymer (EDTA4− = [(CH2N)2(CH2-COOH)(CH2COO)4]) was synthesized from La(NO3)3 and Mn(NO3)2 reagents, ethylenediaminetetraacetic acid, and water at room temperature. T...

  • Article
  • Open Access
11 Citations
6,128 Views
13 Pages

Development of Catalytic-CVD SiNx Passivation Process for AlGaN/GaN-on-Si HEMTs

  • Myoung-Jin Kang,
  • Hyun-Seop Kim,
  • Ho-Young Cha and
  • Kwang-Seok Seo

21 September 2020

We optimized a silicon nitride (SiNx) passivation process using a catalytic-chemical vapor deposition (Cat-CVD) system to suppress the current collapse phenomenon of AlGaN/GaN-on-Si high electron mobility transistors (HEMTs). The optimized Cat-CVD Si...

  • Article
  • Open Access
7 Citations
5,682 Views
10 Pages

High-Intensity Laser-Driven Oxygen Source from CW Laser-Heated Titanium Tape Targets

  • Kotaro Kondo,
  • Mamiko Nishiuchi,
  • Hironao Sakaki,
  • Nicholas P. Dover,
  • Hazel F. Lowe,
  • Takumi Miyahara,
  • Yukinobu Watanabe,
  • Tim Ziegler,
  • Karl Zeil and
  • Kiminori Kondo
  • + 7 authors

19 September 2020

The interaction of high-intensity laser pulses with solid targets can be used as a highly charged, energetic heavy ion source. Normally, intrinsic contaminants on the target surface suppress the performance of heavy ion acceleration from a high-inten...

  • Article
  • Open Access
8 Citations
4,101 Views
10 Pages

19 September 2020

Anosovite crystalline is an ideal mineral for flotation from the Ti-bearing blast furnace (TBBF) slag. Ti3O5 crystal and Al2TiO5 crystal are two kinds of anosovites, and the Al element significantly affects the electronic structure and flotation perf...

  • Article
  • Open Access
10 Citations
5,471 Views
32 Pages

A Nature’s Curiosity: The Argonaut “Shell” and Its Organic Content

  • Morgane Oudot,
  • Ira Ben Shir,
  • Asher Schmidt,
  • Laurent Plasseraud,
  • Cédric Broussard,
  • Pascal Neige and
  • Frédéric Marin

19 September 2020

Molluscs are known for their ability to produce a calcified shell resulting from a genetically controlled and matrix-mediated process, performed extracellularly. The occluded organic matrix consists of a complex mixture of proteins, glycoproteins and...

  • Article
  • Open Access
25 Citations
4,894 Views
17 Pages

19 September 2020

Photo-alignment is a versatile tool to pattern the alignment at the confining substrates in a liquid crystal (LC) cell. Arbitrary alignment patterns can be created by using projection with a spatial light modulator (SLM) for the illumination. We demo...

  • Article
  • Open Access
5 Citations
3,591 Views
9 Pages

Gas-Dependent Reversible Structural and Magnetic Transformation between Two Ladder Compounds

  • Jun Manabe,
  • Kazuki Nishida,
  • Xiao Zhang,
  • Yuki Nakano,
  • Masaru Fujibayashi,
  • Goulven Cosquer,
  • Katsuya Inoue,
  • Seiya Shimono,
  • Hiroki Ishibashi and
  • Sadafumi Nishihara
  • + 4 authors

19 September 2020

We report reversible structural transformation that occurs in two ladder compounds: Cu2CO3(ClO4)2(NH3)6 (1) and Cu2CO3(ClO4)2(NH3)5(H2O) (2), when they are exposed to gaseous vapors. The ladder structures of both 1 and 2 consist of two Cu2+ ions and...

  • Article
  • Open Access
22 Citations
5,685 Views
13 Pages

18 September 2020

The depletion of fossil fuel resources has prompted the scientific community to find renewable alternatives for the production of energy and chemicals. The products of the aldol condensation between bio-based furfural and acetone have been individuat...

  • Article
  • Open Access
15 Citations
4,627 Views
21 Pages

Dual-Energy X-ray Medical Imaging with Inverse Compton Sources: A Simulation Study

  • Gianfranco Paternò,
  • Paolo Cardarelli,
  • Mauro Gambaccini and
  • Angelo Taibi

18 September 2020

It has been long recognized that dual-energy imaging could help to enhance the detectability of lesions in diagnostic radiology, by removing the contrast of surrounding tissues. Furthermore, X-ray attenuation is material specific and information abou...

  • Article
  • Open Access
21 Citations
3,711 Views
14 Pages

Engineering Aspheric Liquid Crystal Lenses by Using the Transmission Electrode Technique

  • José Francisco Algorri,
  • Dimitrios C. Zografopoulos,
  • Luis Rodríguez-Cobo,
  • José Manuel Sánchez-Pena and
  • José Miguel López-Higuera

18 September 2020

The transmission electrode technique has been recently proposed as a versatile method to obtain various types of liquid-crystal (LC) lenses. In this work, an equivalent electric circuit and new analytical expressions based on this technique are devel...

  • Article
  • Open Access
9 Citations
3,376 Views
17 Pages

18 September 2020

The effect of N content on the characteristics and formation of inclusions in the Fe-5Mn-3Al steels was investigated in this study. Two synthetic steel melts were produced by two different methods—N2 gas purging and injecting—to introduce...

  • Article
  • Open Access
8 Citations
3,828 Views
14 Pages

17 September 2020

The addition of transition element oxides to tungsten heavy alloys (WHAs) fabricated by powder metallurgy technique provides new materials with higher density and electrical conductivity, which may be adequate in some applications such as kinetic ene...

  • Article
  • Open Access
10 Citations
4,628 Views
12 Pages

Thermal Stability of PS-PVD YSZ Coatings with Typical Dense Layered and Columnar Structures

  • Zefei Cheng,
  • Jiasheng Yang,
  • Fang Shao,
  • Xinghua Zhong,
  • Huayu Zhao,
  • Yin Zhuang,
  • Jing Sheng,
  • Jinxing Ni and
  • Shunyan Tao

17 September 2020

Yttria-stabilized zirconia (YSZ) coatings with typical pyramid columnar and dense layered structure were prepared by plasma spray-physical vapor deposition (PS-PVD). The evolution behavior of microstructure and crystallography of the coatings before...

  • Article
  • Open Access
6 Citations
3,675 Views
13 Pages

Crystal Growth by the Floating Zone Method of Ce-Substituted Crystals of the Topological Kondo Insulator SmB6

  • Monica Ciomaga Hatnean,
  • Talha Ahmad,
  • Marc Walker,
  • Martin R. Lees and
  • Geetha Balakrishnan

17 September 2020

SmB6 is a mixed valence topological Kondo insulator. To investigate the effect of substituting Sm with magnetic Ce ions on the physical properties of samarium hexaboride, Ce-substituted SmB6 crystals were grown by the floating zone method for the fir...

  • Article
  • Open Access
3 Citations
5,139 Views
15 Pages

Guided Crystallization of Zeolite Beads Composed of ZSM-12 Nanosponges

  • Kassem Moukahhal,
  • Ludovic Josien,
  • Habiba Nouali,
  • Joumana Toufaily,
  • Tayssir Hamieh,
  • T. Jean Daou and
  • Bénédicte Lebeau

17 September 2020

The direct route using a bifunctional amphiphilic structuring agent for the synthesis of hierarchical nanozeolites coupled with pseudomorphic transformation was used for the crystallization of hierarchized zeolite beads/hollow spheres composed of ZSM...

  • Article
  • Open Access
14 Citations
4,125 Views
7 Pages

Low-Frequency Noise Behavior of AlGaN/GaN HEMTs with Different Al Compositions

  • Yeo Jin Choi,
  • Jae-Hoon Lee,
  • Sung Jin An and
  • Ki-Sik Im

17 September 2020

AlxGa1−xN/GaN heterostructures with two kinds of Al composition were grown by metal organic chemical vapor deposition (MOCVD) on sapphire substrates. The Al compositions in the AlGaN barrier layer were confirmed to be 13% and 28% using high res...

  • Article
  • Open Access
2 Citations
4,634 Views
9 Pages

High-Thermal-Conductivity SiC Ceramic Mirror for High-Average-Power Laser System

  • Yasuhiro Miyasaka,
  • Kotaro Kondo and
  • Hiromitsu Kiriyama

17 September 2020

The importance of heat-resistant optics is increasing together with the average power of high-intensity lasers. A silicon carbide (SiC) ceramic with high thermal conductivity is proposed as an optics substrate to suppress thermal effects. The tempera...

  • Editorial
  • Open Access
9 Citations
3,181 Views
4 Pages

17 September 2020

This Special Issue on “Cement-Based Composites: Advancements in Development and Characterization” presents the latest research and advances in the field of cement-based composites. This special issue covers a variety of experimental studi...

  • Article
  • Open Access
49 Citations
6,518 Views
13 Pages

Effect of CeO2-ZnO Nanocomposite for Photocatalytic and Antibacterial Activities

  • Asad Syed,
  • Lakshmi Sagar Reddy Yadav,
  • Ali H. Bahkali,
  • Abdallah M. Elgorban,
  • Deshmukh Abdul Hakeem and
  • Nagaraju Ganganagappa

16 September 2020

The impact of a CeO2-ZnO nanocomposite on the photocatalytic and antibacterial properties compared to bare ZnO was investigated. A CeO2-ZnO nanocomposite was synthesized using Acacia nilotica fruit extract as a novel fuel by a simple solution combust...

  • Review
  • Open Access
6 Citations
3,494 Views
11 Pages

16 September 2020

Post-translational modifications are one way that biomineral-associated cells control the function and fate of proteins. Of the ten different types of post-translational modifications, one of the most interesting and complex is glycosylation, or the...

  • Article
  • Open Access
10 Citations
5,968 Views
20 Pages

16 September 2020

Crystal plasticity models attempt to reproduce the complex deformation processes of polycrystalline metals based on a virtual representation of the real microstructure. When choosing this representation, a compromise must be made between level of det...

  • Article
  • Open Access
3 Citations
2,780 Views
10 Pages

Relation between Fish Habitat and the Periodicity of Incremental Lines in the Fossil Otoliths

  • Hiroyuki Mishima,
  • Yasuo Kondo,
  • Fumio Ohe,
  • Yasuo Miake and
  • Tohru Hayakawa

16 September 2020

There are few research reports on the relationship between fish habitats and the periodicity of the fishes’ incremental lines of otolith fossils. The present study examines this relationship through histological and analytical studies on otolit...

  • Article
  • Open Access
14 Citations
4,713 Views
14 Pages

Enhancing Protein Crystallization under a Magnetic Field

  • Sun Young Ryu,
  • In Hwan Oh,
  • Sang Jin Cho,
  • Shin Ae Kim and
  • Hyun Kyu Song

16 September 2020

High-quality crystals are essential to ensure high-resolution structural information. Protein crystals are controlled by many factors, such as pH, temperature, and the ion concentration of crystalline solutions. We previously reported the development...

  • Article
  • Open Access
17 Citations
5,152 Views
18 Pages

16 September 2020

Grain boundary sliding is an important deformation mechanism, and therefore its description is essential for modeling different technological processes of thermomechanical treatment, in particular the superplasticity forming of metallic materials. Fo...

  • Review
  • Open Access
45 Citations
9,032 Views
19 Pages

Polymer-Derived Si-Based Ceramics: Recent Developments and Perspectives

  • Aidong Xia,
  • Jie Yin,
  • Xiao Chen,
  • Xuejian Liu and
  • Zhengren Huang

16 September 2020

Polymer derived ceramics (PDCs) are promising candidates for usages as the functionalization of inorganic Si-based materials. Compared with traditional ceramics preparation methods, it is easier to prepare and functionalize ceramics with complex shap...

  • Article
  • Open Access
14 Citations
6,578 Views
10 Pages

16 September 2020

We report optical and mechanical properties of hard aluminum magnesium boride films magnetron sputtered from a stoichiometric AlMgB14 ceramic target onto Corning® 1737 Glass and Si (100) wafers. High target sputtering rf-power and sufficiently sh...

  • Article
  • Open Access
19 Citations
3,260 Views
18 Pages

Convective Transport of Fluid–Solid Interaction: A Study between Non-Newtonian Casson Model with Dust Particles

  • Abdul Rahman Mohd Kasim,
  • Nur Syamilah Arifin,
  • Syazwani Mohd Zokri,
  • Mohd Zuki Salleh,
  • Nurul Farahain Mohammad,
  • Dennis Ling Chuan Ching,
  • Sharidan Shafie and
  • Noor Amalina Nisa Ariffin

15 September 2020

The Casson model is a fascinating model, which is genuinely recommended for use with fluids of a non-Newtonian type. The conventional model is not capable to represent the Casson model with the suspension of foreign bodies (dust particles). Due to th...

  • Communication
  • Open Access
2 Citations
3,387 Views
9 Pages

Designer Synthesis of Ultra-Fine Fe-LTL Zeolite Nanocrystals

  • Fen Zhang,
  • Yunhong Luo,
  • Lei Chen,
  • Wei Chen,
  • Yin Hu,
  • Guihua Chen,
  • Shengyong You and
  • Weiguo Song

15 September 2020

Nanosized zeolites with larger external surface area and decreased diffusion pathway provide many potential opportunities in adsorption, diffusion, and catalytic applications. Herein, we report a designer synthesis of ultra-fine Fe-LTL zeolite nanocr...

  • Article
  • Open Access
53 Citations
5,762 Views
17 Pages

15 September 2020

In order to improve the early age strength of ordinary Portland cement-based materials, many early strength agents were applied in different conditions. Different from previous research, the nano calcium silicate hydrate (C-S-H) particles used in thi...

  • Review
  • Open Access
105 Citations
12,128 Views
30 Pages

Viable Materials with a Giant Magnetocaloric Effect

  • Nikolai A. Zarkevich and
  • Vladimir I. Zverev

15 September 2020

This review of the current state of magnetocalorics is focused on materials exhibiting a giant magnetocaloric response near room temperature. To be economically viable for industrial applications and mass production, materials should have desired use...

  • Article
  • Open Access
13 Citations
5,495 Views
10 Pages

Small-Polaron Hopping and Low-Temperature (45–225 K) Photo-Induced Transient Absorption in Magnesium-Doped Lithium Niobate

  • Simon Messerschmidt,
  • Andreas Krampf,
  • Laura Vittadello,
  • Mirco Imlau,
  • Tobias Nörenberg,
  • Lukas M. Eng and
  • David Emin

14 September 2020

A strongly temperature-dependent photo-induced transient absorption is measured in 6.5 mol% magnesium-doped lithium niobate at temperatures ranging from 45 K to 225 K. This phenomenon is interpreted as resulting from the generation and subsequent rec...

  • Article
  • Open Access
1 Citations
3,396 Views
11 Pages

Effects of CF4 Plasma Treatment on Indium Gallium Oxide and Ti-doped Indium Gallium Oxide Sensing Membranes in Electrolyte–Insulator–Semiconductors

  • Chyuan-Haur Kao,
  • Yen-Lin Su,
  • Wei-Jen Liao,
  • Ming-Hsien Li,
  • Wei-Lun Chan,
  • Shang-Che Tsai and
  • Hsiang Chen

14 September 2020

Electrolyte–insulator–semiconductor (EIS) sensors, used in applications such as pH sensing and sodium ion sensing, are the most basic type of ion-sensitive field-effect transistor (ISFET) membranes. Currently, some of the most popular tec...

  • Article
  • Open Access
47 Citations
4,547 Views
22 Pages

14 September 2020

Recently, the use of fiber-reinforced polymers (FRP)-confinement has increased due to its various favorable effects on concrete structures, such as an increase in strength and ductility. Therefore, researchers have been attracted to exploring the beh...

  • Article
  • Open Access
4 Citations
3,550 Views
9 Pages

Synthesis, Crystal Structures and Characterization of Two Nonmetal Cation Tetrafluoroborates

  • Noura Othman Alzamil,
  • Ghareeba Mussad Al-Enzi,
  • Aishah Hassan Alamri,
  • Insaf Abdi and
  • Amor BenAli

14 September 2020

Two new nonmetal cation tetrafluoroborate phases [H3tren](BF4)3 (I) and [H3tren](BF4)3 HF (II) were synthesized by microwave-assisted solvothermal and characterized by single crystal X-ray diffraction, IR spectroscopy and thermal analysis DTA-TGA. [H...

  • Article
  • Open Access
21 Citations
14,746 Views
16 Pages

13 September 2020

Cohesion is defined as the shear strength of material when compressive stress is zero. This article presents a new method for the experimental determination of cohesion at pre-set angles of shear deformation. Specially designed moulds are created to...

  • Article
  • Open Access
33 Citations
6,219 Views
14 Pages

Large Angle Forward Diffraction by Chiral Liquid Crystal Gratings with Inclined Helical Axis

  • Migle Stebryte,
  • Inge Nys,
  • Yera Ye. Ussembayev,
  • Jeroen Beeckman and
  • Kristiaan Neyts

12 September 2020

A layer of chiral liquid crystal (CLC) with a photonic bandgap in the visible range has excellent reflective properties. Recently, two director configurations have been proposed in the literature for CLC between two substrates with periodic photo-ali...

  • Article
  • Open Access
32 Citations
4,870 Views
11 Pages

Tunable Non-Volatile Memory by Conductive Ferroelectric Domain Walls in Lithium Niobate Thin Films

  • Thomas Kämpfe,
  • Bo Wang,
  • Alexander Haußmann,
  • Long-Qing Chen and
  • Lukas M. Eng

11 September 2020

Ferroelectric domain wall conductance is a rapidly growing field. Thin-film lithium niobate, as in lithium niobate on insulators (LNOI), appears to be an ideal template, which is tuned by the inclination of the domain wall. Thus, the precise tuning o...

  • Article
  • Open Access
43 Citations
5,436 Views
16 Pages

Characterization and Luminescence of Eu3+- and Gd3+-Doped Hydroxyapatite Ca10(PO4)6(OH)2

  • Veronica Paterlini,
  • Marco Bettinelli,
  • Rosanna Rizzi,
  • Asmaa El Khouri,
  • Manuela Rossi,
  • Giancarlo Della Ventura and
  • Francesco Capitelli

11 September 2020

Luminescence properties of europium-doped Ca10-xEux(PO4)6(OH)2 (xEu = 0, 0.01, 0.02, 0.10 and 0.20) and gadolinium-doped hydroxyapatite Ca9.80Gd0.20(PO4)6(OH)2 (HA), synthesized via solid-state reaction at T = 1300 °C, were investigated using sca...

  • Article
  • Open Access
14 Citations
2,997 Views
13 Pages

10 September 2020

New symmetrical 1:2 supramolecular H-bonded liquid crystals (SMHBLCs) interactions, A/2Bn, were formed between adipic acid and 4-(4′–pyridylazophenyl) 4″-alkoxybenzoates. Optical and mesomorphic behaviors of the prepared SMHBLC comp...

  • Article
  • Open Access
1 Citations
2,291 Views
11 Pages

10 September 2020

The instantaneous response of liquid crystal (LC) molecules near the dye-adsorbed layer of azo dye-doped LCs (ADDLCs) in early-stage photoexcitation was observed through the pumped-attenuated total reflection (PATR) method. As the sensing depth of th...

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Crystals - ISSN 2073-4352