Materials, Volume 17, Issue 24
2024 December-2 - 281 articles
Cover Story: The phase evolution of Li-rich Li-Mn-Ni-(Al)-O cathode materials upon heat treatments was studied by X-ray and neutron powder diffraction. For two-phase mixtures containing a monoclinic Li2MnO3 type phase M and a rhombohedral LiMn0.5Ni0.5O2 type phase R, the structures, compositions, and phase fractions change with heat treatment time, realized by the substitution mechanism 3Ni2+ ↔ 2Li+ + 1Mn4+. Sample peak broadening is dominated by strain broadening. The X-ray domain sizes of M and R increase with heat treatment time and are larger than the sizes observed by electron microscopy. The domain size is smaller for R than for M and decreases with increasing Al doping. View this paper - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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