This work summarizes the results of a new approach to the synthesis of previously undescribed, hard-to-obtain five-membered cyclic organophosphorus compounds: 3-alkyl(aryl)-substituted phospholanes, α,ω-bisphospholanes, polycyclic phospho...
Five-membered saturated metallacarbocycles represent a large family of organometallic compounds, which are frequently postulated as reactive intermediates in catalysis or as precursors for the synthesis of a wide range of functionally substituted com...
A method for the synthesis of 3R-substituted and norbornane-annelated 1H-phospholan oxides has been developed. The method is based on the in situ substitution of the Al atom by the P atom in five-membered cyclic alumolanes using phosphorus trichlorid...
The aim of the research is the development of a one-pot method for the synthesis of lignans, natural compounds that show a wide spectrum of biological activities. For this purpose, the ansa-zirconocenes of various structures were tested as catalysts...