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Article

5 Citations

3,036 Views

25 Pages

Controlling of Photophysical Behavior of Rhenium(I) Complexes with 2,6-Di(thiazol-2-yl)pyridine-Based Ligands by Pendant π-Conjugated Aryl Groups

Anna M. Maroń,
Joanna Palion-Gazda,
Agata Szłapa-Kula,
Ewa Schab-Balcerzak and ,
Mariola Siwy,
Karolina Sulowska,
Sebastian Maćkowski and
Barbara Machura
+ 3 authors+ 0 author

Int. J. Mol. Sci.2022, 23(19), 11019;https://doi.org/10.3390/ijms231911019

20 September 2022

The structure–property correlations and control of electronic excited states in transition metal complexes (TMCs) are of high significance for TMC-based functional material development. Within these studies, a series of Re(I) carbonyl complexes...

(This article belongs to the Section Molecular Biophysics)

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Communication

3,699 Views

6 Pages

Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with 2-(Phenylsulfonyl)acetonitrile

Konstantinos Plakas,
Andreas S. Kalogirou,
Andreas Kourtellaris and
Panayiotis A. Koutentis

Molbank2022, 2022(1), M1322;https://doi.org/10.3390/M1322

24 January 2022

The reaction of 4,5-dichloro-1,2,3-dithiazolium chloride with 2-(phenylsulfonyl)acetonitrile (1 equiv) in the presence of pyridine (2 equiv) gave S-(3-chloro-5-cyanoisothiazol-4-yl)benzenesulfonothioate and (Z)-2-(4-chloro-5H-1,2,3-dithiazol-5-yliden...

(This article belongs to the Section Organic Synthesis and Biosynthesis)

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Article

3 Citations

2,523 Views

15 Pages

Thiazole Functionalization of Thiosemicarbazone for Cu(II) Complexation: Moving toward Highly Efficient Anticancer Drugs with Promising Oral Bioavailability

Song-Yu Luo,
Chun-Mei Zeng,
Ping Xu,
Ye Ning and ,
Meng-Lin Dong,
Wen-Hua Zhang and
Guangliang Yu
+ 2 authors+ 0 author

Molecules2024, 29(16), 3832;https://doi.org/10.3390/molecules29163832

13 August 2024

In this work, we report the synthesis of a new thiosemicarbazone-based drug of N′-(di(pyridin-2-yl)methylene)-4-(thiazol-2-yl)piperazine-1-carbothiohydrazide (HL) featuring a thiazole spectator for efficient coordination with Cu(II) to give [Cu...

(This article belongs to the Special Issue Design, Synthesis and Biological Activity of Novel Antitumor Drugs)

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Article

1,070 Views

17 Pages

The Synthesis, Metal Exchange, and Hyaluronate Functionalization of a Cationic Gallium-Based Thiosemicarbazone Anticancer Drug

Ye Ning,
Meng-Lin Dong,
Wen-Hua Zhang and
David J. Young

Molecules2026, 31(3), 577;https://doi.org/10.3390/molecules31030577

6 February 2026

We herein demonstrate that the thiosemicarbazone (TSC) ligand N′-(di(pyridin-2-yl)methylene)-4-(thiazol-2-yl)piperazine-1-carbothiohydrazide (HL) can coordinate with Ga³⁺ to give cationic complex [Ga(L)₂]NO₃ featuring an octahedral Ga(III) cent...

(This article belongs to the Special Issue Transition Metal Complexes with Bioactive Ligands)

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