molecules-logo

Journal Browser

Journal Browser

Preparation, Characterization and Applications of Polymer Composites

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (20 August 2022) | Viewed by 36428

Special Issue Editors


E-Mail Website
Guest Editor
School of Mechanical and Design Engineering, University of Portsmouth, Anglesea Building, Anglesea Road, Portsmouth PO1 3DJ, Hampshire, UK
Interests: design; development; testing and characterization of sustainable lightweight composites; nanocomposites; natural fiber composites and biocomposites; including their mechanical (tensile, flexural, low-velocity impact, and fracture toughness); thermal and environmental properties (dimensional stability under various environmental conditions)
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Polymer composites are nowadays well-established systems in everyone’s life. Peculiarities such as lightness and high mechanical properties, among others, make them very appealing for different structural and/or functional applications. In addition, the wide possibility of selecting polymer matrices and reinforcements make them suitable for up-to-date uses that could have never been foreseen in the past. Though the research on polymer composites is still growing, as witnessed by the huge number of articles published also in journals specifically devoted to this topic, there is still a high interest in the design and development of more performing systems, even suitable in harsh environments.    

This Special Issue aims to cover recent progress and trends in the preparation, characterization, and applications of polymer composites. Submissions are welcome but not limited to the topics listed below. Types of contributions welcome in this Special Issue are full research articles, short communications, and reviews.

Prof. Dr. Giulio Malucelli
Prof. Dr. Hom Nath Dhakal
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Polymer nano-, micro- and macro-composites
  • Bio-based composites
  • Interfaces in polymer composites
  • Characterization of polymer composites
  • Modelling of polymer composite systems
  • Mechanical behavior
  • Thermal behavior
  • Durability
  • Fire behavior
  • Advanced applications of polymer composites

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.

Further information on MDPI's Special Issue polices can be found here.

Published Papers (13 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

19 pages, 6456 KiB  
Article
Preparation, Characterization and Molecular Dynamics Simulation of Rutin–Cyclodextrin Inclusion Complexes
by Chaokang Chang, Meng Song, Mingxing Ma, Jihong Song, Fengyi Cao and Qi Qin
Molecules 2023, 28(3), 955; https://doi.org/10.3390/molecules28030955 - 18 Jan 2023
Cited by 12 | Viewed by 2201
Abstract
Rutin is a natural flavonoid that carries out a variety of biological activities, but its application in medicine and food is limited by its water solubility. One of the classical methods used to enhance drug solubility is encapsulation with cyclodextrins. In this paper, [...] Read more.
Rutin is a natural flavonoid that carries out a variety of biological activities, but its application in medicine and food is limited by its water solubility. One of the classical methods used to enhance drug solubility is encapsulation with cyclodextrins. In this paper, the encapsulation of different cyclodextrins with rutin was investigated using a combination of experimental and simulation methods. Three inclusions of rutin/beta-cyclodextrin (β-CD), rutin/2-hydroxypropyl beta-cyclodextrin (HP-β-CD) and rutin/2,6-dimethyl beta-cyclodextrin (DM-β-CD) were prepared by the freeze-drying method, and the inclusions were analyzed using Fourier infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), differential scanning calorimetry (DSC) and ultraviolet–visible spectroscopy (UV) to characterize and demonstrate the formation of the inclusion complexes. Phase solubility studies showed that rutin formed a 1:1 stoichiometric inclusion complex and significantly increased its solubility. β-CD, HP-β-CD, DM-β-CD, rutin and the three inclusion complexes were modeled by using MS2018 and AutoDock 4.0, and molecular dynamics simulations were performed to calculate the solubility parameters, binding energies, mean square displacement (MSD), hydrogen bonding and radial distribution functions (RDF) after the equilibration of the systems. The results of simulation and experiment showed that rutin/DM-β-CD had the best encapsulation effect among the three cyclodextrin inclusion complexes. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

14 pages, 4482 KiB  
Article
Polypyrrole/Schiff Base Composite as Electromagnetic Absorbing Material with High and Tunable Absorption Performance
by Ji Huang, Huiling Gu, Na Li, Hua Yang, Gang Chen, Lizhu Zhang, Chengjun Dong and Hongtao Guan
Molecules 2022, 27(19), 6160; https://doi.org/10.3390/molecules27196160 - 20 Sep 2022
Cited by 3 | Viewed by 1534
Abstract
In recent years, Schiff base-related conjugated systems have received extensive attention, but little research has been done in the field of electromagnetic materials. In this work, an organic conjugated system based on polypyrrole/hydrazone Schiff base (PPy/HSB) composites was constructed via a Schiff base [...] Read more.
In recent years, Schiff base-related conjugated systems have received extensive attention, but little research has been done in the field of electromagnetic materials. In this work, an organic conjugated system based on polypyrrole/hydrazone Schiff base (PPy/HSB) composites was constructed via a Schiff base synthetic route and their electromagnetic behavior was investigated. The electromagnetic response of PPy/HSB complexes demonstrates fine electromagnetic absorption performance. When the filler loading is 30 wt% in a paraffin matrix, an absorption peak of −43.1 dB was achieved and its effective absorption bandwidth (EAB) was located in the range of 10.88−18.0 GHz. The electromagnetic response behavior of PPy/HSB complexes is explained by models involving electronic structure, multi-polarization and conductive network. The mechanisms of PPy/HSB complexes formation and HSB crystallization are also discussed through the compatibility of PPy/HSB and the structure of HSB. Moreover, the morphology transformation of HSB in the PPy/HSB systems has been studied. This study opens the exploration of organic–dielectric conjugated systems in the field of electromagnetic materials, and significantly broadens the application range of organic–dielectric–dielectric composites. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

17 pages, 2815 KiB  
Article
Dimethylaminoethyl Methacrylate/Diethylene Glycol Dimethacrylate Grafted onto Folate-Esterified Bagasse Xylan/Andrographolide Composite Nanoderivative: Synthesis, Molecular Docking and Biological Activity
by Yue Su, Shufen Zhang, Heping Li, Bin Zhao, Kexin Tian and Zhiming Zou
Molecules 2022, 27(18), 5970; https://doi.org/10.3390/molecules27185970 - 14 Sep 2022
Cited by 4 | Viewed by 1747
Abstract
As a biocompatible biomaterial, bagasse xylan (BX) has been widely used in the biomedical field. The low biological activity of andrographolide (AD) restricts its development, so AD with certain anticancer activity is introduced. We use chemical modification methods such as grafting and esterification [...] Read more.
As a biocompatible biomaterial, bagasse xylan (BX) has been widely used in the biomedical field. The low biological activity of andrographolide (AD) restricts its development, so AD with certain anticancer activity is introduced. We use chemical modification methods such as grafting and esterification to improve the biological activity and make a novel anticancer nanomaterial. On the basis of the esterification of a mixture of BX and AD with folic acid (FA), a novel anticancer nanoderivative of bagasse xylan/andrographolide folate-g-dimethylaminoethyl methacrylate (DMAEMA)/diethylene glycol dimethacrylate (DEGDMA) nanoparticles (FA-BX/AD-g-DMAEMA/DEGDMA NPs) was synthesized by introducing DMAEMA and DEGDMA monomers through a graft copolymerization and nanoprecipitation method. The effects of reaction temperature, reaction time, the initiator concentration and the mass ratio of FA-BX/AD to mixed monomers on the grafting rate (GR) were investigated. The structure of the obtained product was characterized by FTIR, SEM, XRD and DTG. Further, molecular docking and MTT assays were performed to understand the possible docking sites with the target proteins and the anticancer activity of the product. The results showed that the GR of the obtained product was 79% under the conditions of the initiator concentration 55 mmol/L, m (FA-BX/AD):m (mixed monomer) = 1:2, reaction temperature 50 °C and reaction time 5 h. The inhibition rate of FA-BX/AD-g-DMAEMA/DEGDMA NPs on human lung cancer cells (NCI-H460) can reach 39.77 ± 5.62%, which is about 7.6 times higher than that of BX. Therefore, this material may have potential applications in the development of anticancer drug or carriers and functional materials. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

17 pages, 4893 KiB  
Article
Moisture Absorption Effects on the Mechanical Properties of Sandwich Biocomposites with Cork Core and Flax/PLA Face Sheets
by Hom Nath Dhakal, Chulin Jiang, Moumita Sit, Zhongyi Zhang, Moussa Khalfallah and Erwan Grossmann
Molecules 2021, 26(23), 7295; https://doi.org/10.3390/molecules26237295 - 1 Dec 2021
Cited by 5 | Viewed by 2645
Abstract
The aim of this study was to evaluate the moisture absorption behaviour and its influence on the mechanical properties of newly developed sandwich biocomposites with flax fibre-reinforced poly-lactic acid (PLA) face sheets and soft cork as the core material. Three different types of [...] Read more.
The aim of this study was to evaluate the moisture absorption behaviour and its influence on the mechanical properties of newly developed sandwich biocomposites with flax fibre-reinforced poly-lactic acid (PLA) face sheets and soft cork as the core material. Three different types of sandwich biocomposite laminates comprised of different layup configurations, namely, non-woven flax/PLA (Sample A), non-woven flax/PLA and cork as core (Sample B) and non-woven flax/paper backing/PLA, cork as core (Sample C), were fabricated. In order to evaluate the influence of moisture ingress on the mechanical properties, the biocomposites were immersed in seawater for a period of 1200 h. The biocomposites (both dry and water immersed) were then subjected to tensile, flexural and low-velocity falling weight impact tests. It was observed from the experimental results that the moisture uptake significantly influenced the mechanical properties of the biocomposites. The presence of the cork and paper in sample C made it more susceptible to water absorption, reaching a value of 34.33%. The presence of cork in the core also has a considerable effect on the mechanical, as well as energy dissipation, behaviours. The results of sample A exhibited improved mechanical performance in both dry and wet conditions compared to samples B and C. Sample A exhibits 32.6% more tensile strength and 81.4% more flexural strength in dry conditions than that in sample C. The scanning electron microscopy (SEM) and X-ray micro-CT images revealed that the failure modes observed are a combination of matrix cracking, core crushing and face core debonding. The results from this study suggest that flax/PLA sandwich biocomposites can be used in various lightweight applications with improved environmental benefits. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

15 pages, 14061 KiB  
Article
Effect of Hostile Solutions on the Residual Fatigue Life of Kevlar/Epoxy Composites after Impact Loading
by Paulo N. B. Reis, Marco P. Silva, Paulo Santos, João Parente and Sara Valvez
Molecules 2021, 26(18), 5520; https://doi.org/10.3390/molecules26185520 - 11 Sep 2021
Cited by 5 | Viewed by 1779
Abstract
Due to the enormous benefits inherent to composite materials, they have been widely used in the most diverse fields of engineering. Therefore, it is not surprising that in many of these applications they can be exposed to hostile environments, which can affect the [...] Read more.
Due to the enormous benefits inherent to composite materials, they have been widely used in the most diverse fields of engineering. Therefore, it is not surprising that in many of these applications they can be exposed to hostile environments, which can affect the mechanical performance of such materials. Therefore, the main goal of this work was to study the effect of immersion into different hostile solutions on the impact strength and, subsequently, to evaluate the residual fatigue life. For this purpose, the specimens were initially immersed into solutions of hydrochloric acid (HCl), sodium hydroxide (NaOH), sulphuric acid (H2SO4), diesel, distilled water, and seawater. Subsequently, the specimens were subjected to impact loads with an energy of 12 J and, finally, subjected to fatigue loads to assess the residual fatigue life. Seawater and NaOH solution provided the lowest impact strength. This was confirmed by the lower energy restored and impact bending stiffness (IBS), a parameter that allows evaluating the damage resistance of a composite. In terms of restored energy, for example, the seawater promoted a decrease around 30.4% in relation to the value obtained with non-immersed samples, while this value was 27.6% for the alkaline solution (NaOH). In terms of IBS, the lowest values were also obtained with these solutions (437.4 and 444.9 N/mm, respectively). Finally, the lowest residual fatigue life was also observed for these two solutions, and it was noticed that there was a direct relationship between the IBS and the residual fatigue life. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

16 pages, 2406 KiB  
Article
PLA Electrospun Fibers Reinforced with Organic and Inorganic Nanoparticles: A Comparative Study
by Adrián Leonés, Valentina Salaris, Alicia Mujica-Garcia, Marina P. Arrieta, Daniel Lopez, Marcela Lieblich, José Maria Kenny and Laura Peponi
Molecules 2021, 26(16), 4925; https://doi.org/10.3390/molecules26164925 - 14 Aug 2021
Cited by 19 | Viewed by 3337
Abstract
In this work, different poly (lactic acid) (PLA)-based nanocomposite electrospun fibers, reinforced with both organic and inorganic nanoparticles, were obtained. As organic fibers, cellulose nanocrystals, CNC, both neat and functionalized by “grafting from” reaction, chitosan and graphene were used; meanwhile, hydroxyapatite [...] Read more.
In this work, different poly (lactic acid) (PLA)-based nanocomposite electrospun fibers, reinforced with both organic and inorganic nanoparticles, were obtained. As organic fibers, cellulose nanocrystals, CNC, both neat and functionalized by “grafting from” reaction, chitosan and graphene were used; meanwhile, hydroxyapatite and silver nanoparticles were used as inorganic fibers. All of the nanoparticles were added at 1 wt% with respect to the PLA matrix in order to be able to compare their effect. The main aim of this work was to study the morphological, thermal and mechanical properties of the different systems, looking for differences between the effects of the addition of organic or inorganic nanoparticles. No differences were found in either the glass transition temperature or the melting temperature between the different electrospun systems. However, systems reinforced with both neat and functionalized CNC exhibited an enhanced degree of crystallinity of the electrospun fibers, by up to 12.3%. From a mechanical point of view, both organic and inorganic nanoparticles exhibited a decreased elastic modulus and tensile strength in comparison to neat electrospun PLA fibers, improving their elongation at break. Furthermore, all of the organic and inorganic reinforced systems disintegrated under composting conditions after 35 days. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

24 pages, 5359 KiB  
Article
Effects of Water and Chemical Solutions Ageing on the Physical, Mechanical, Thermal and Flammability Properties of Natural Fibre-Reinforced Thermoplastic Composites
by Baljinder K. Kandola, S. Ilker Mistik, Wiwat Pornwannachai and A. Richard Horrocks
Molecules 2021, 26(15), 4581; https://doi.org/10.3390/molecules26154581 - 29 Jul 2021
Cited by 10 | Viewed by 2560
Abstract
Biocomposites comprising a combination of natural fibres and bio-based polymers are good alternatives to those produced from synthetic components in terms of sustainability and environmental issues. However, it is well known that water or aqueous chemical solutions affect natural polymers/fibres more than the [...] Read more.
Biocomposites comprising a combination of natural fibres and bio-based polymers are good alternatives to those produced from synthetic components in terms of sustainability and environmental issues. However, it is well known that water or aqueous chemical solutions affect natural polymers/fibres more than the respective synthetic components. In this study the effects of water, salt water, acidic and alkali solutions ageing on water uptake, mechanical properties and flammability of natural fibre-reinforced polypropylene (PP) and poly(lactic acid) (PLA) composites were compared. Jute, sisal and wool fibre- reinforced PP and PLA composites were prepared using a novel, patented nonwoven technology followed by the hot press method. The prepared composites were aged in water and chemical solutions for up to 3 week periods. Water absorption, flexural properties and the thermal and flammability performances of the composites were investigated before and after ageing each process. The effect of post-ageing drying on the retention of mechanical and flammability properties has also been studied. A linear relationship between irreversible flexural modulus reduction and water adsorption/desorption was observed. The aqueous chemical solutions caused further but minor effects in terms of moisture sorption and flexural modulus changes. PLA composites were affected more than the respective PP composites, because of their hydrolytic sensitivity. From thermal analytical results, these changes in PP composites could be attributed to ageing effects on fibres, whereas in PLA composite changes related to both those of fibres present and of the polymer. Ageing however, had no adverse effect on the flammability of the composites. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

12 pages, 3617 KiB  
Article
Statistical Analysis of Polymer Nanocomposites for Mechanical Properties
by Shankar A. Hallad, N. R. Banapurmath, T. M. Yunus Khan, M. A. Umarfarooq, Manzoore Elahi M. Soudagar, Anand M. Hunashyal, Sandeep V. Gujjar, Jayachandra S. Yaradoddi, Sharanabasava V. Ganachari, Ashraf Elfasakhany, Md Irfanul Haque Siddiqui and Masood Ashraf Ali
Molecules 2021, 26(14), 4135; https://doi.org/10.3390/molecules26144135 - 7 Jul 2021
Cited by 14 | Viewed by 2866
Abstract
Epoxy resins, due to their high stiffness, ease of processing, good heat, and chemical resistance obtained from cross-linked structures, have found applications in electronics, adhesives coatings, industrial tooling, and aeronautic and automotive industries. These resins are inherently brittle, which has limited their further [...] Read more.
Epoxy resins, due to their high stiffness, ease of processing, good heat, and chemical resistance obtained from cross-linked structures, have found applications in electronics, adhesives coatings, industrial tooling, and aeronautic and automotive industries. These resins are inherently brittle, which has limited their further application. The emphasis of this study is to improve the properties of the epoxy resin with a low-concentration (up to 0.4% by weight) addition of Multi-Walled Carbon Nanotubes (MWCNTs). Mechanical characterization of the modified composites was conducted to study the effect of MWCNTs infusion in the epoxy resin. Nanocomposites samples showed significantly higher tensile strength and fracture toughness compared to pure epoxy samples. The morphological studies of the modified composites were studied using Scanning Electron Microscopy (SEM). Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

16 pages, 4203 KiB  
Article
Development of Novel Polyamide-Imide/DES Composites and Their Application for Pervaporation and Gas Separation
by Alexandra Pulyalina, Valeriia Rostovtseva, Ilya Faykov, Maksim Tataurov, Roman Dubovenko and Sergey Shugurov
Molecules 2021, 26(4), 990; https://doi.org/10.3390/molecules26040990 - 13 Feb 2021
Cited by 8 | Viewed by 3617
Abstract
Novel polymer composites based on polyamide–imide Torlon and deep eutectic solvent (DES) were fabricated and adapted for separation processes. DES composed of zinc chloride and acetamide in a ratio of 1:3 M was first chosen as a Torlon-modifier due to the possibility of [...] Read more.
Novel polymer composites based on polyamide–imide Torlon and deep eutectic solvent (DES) were fabricated and adapted for separation processes. DES composed of zinc chloride and acetamide in a ratio of 1:3 M was first chosen as a Torlon-modifier due to the possibility of creating composites with a uniform filling of the DES through the formation of hydrogen bonds. The structure of the membranes was investigated by scanning electron microscopy and X-ray diffraction analysis; thermal stability was determined by thermogravimetric analysis and mass spectrometry. The surface of the composites was studied by determining the contact angles and calculating the surface tension. The transport properties were investigated by such membrane methods as pervaporation and gas separation. It was found that the inclusion of DES in the polymer matrix leads to a significant change in the structure and surface character of composites. It was also shown that DES plays the role of a plasticizer and increases the separation performance in the separation of liquids and gases. Torlon/DES composites with a small amount of modifier were effective in alcohol dehydration, and were permeable predominantly to water impurities in isopropanol. Torlon/DES-5 demonstrates high selectivity in the gas separation of O2/N2 mixture. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

11 pages, 2184 KiB  
Article
Mechanical and Morphological Properties of Bio-Phenolic/Epoxy Polymer Blends
by Ahmad Safwan Ismail, Mohammad Jawaid, Norul Hisham Hamid, Ridwan Yahaya and Azman Hassan
Molecules 2021, 26(4), 773; https://doi.org/10.3390/molecules26040773 - 3 Feb 2021
Cited by 9 | Viewed by 2744
Abstract
Polymer blends is a well-established and suitable method to produced new polymeric materials as compared to synthesis of a new polymer. The combination of two different types of polymers will produce a new and unique material, which has the attribute of both polymers. [...] Read more.
Polymer blends is a well-established and suitable method to produced new polymeric materials as compared to synthesis of a new polymer. The combination of two different types of polymers will produce a new and unique material, which has the attribute of both polymers. The aim of this work is to analyze mechanical and morphological properties of bio-phenolic/epoxy polymer blends to find the best formulation for future study. Bio-phenolic/epoxy polymer blends were fabricated using the hand lay-up method at different loading of bio-phenolic (5 wt%, 10 wt%, 15 wt%, 20 wt%, and 25 wt%) in the epoxy matrix whereas neat bio-phenolic and epoxy samples were also fabricated for comparison. Results indicated that mechanical properties were improved for bio-phenolic/epoxy polymer blends compared to neat epoxy and phenolic. In addition, there is no sign of phase separation in polymer blends. The highest tensile, flexural, and impact strength was shown by P-20(biophenolic-20 wt% and Epoxy-80 wt%) whereas P-25 (biophenolic-25 wt% and Epoxy-75 wt%) has the highest tensile and flexural modulus. Based on the finding, it is concluded that P-20 shows better overall mechanical properties among the polymer blends. Based on this finding, the bio-phenolic/epoxy blend with 20 wt% will be used for further study on flax-reinforced bio-phenolic/epoxy polymer blends. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

10 pages, 1929 KiB  
Article
Effect of Polymer Removal on the Morphology and Phase of the Nanoparticles in All-Inorganic Heterostructures Synthesized via Two-Step Polymer Infiltration
by Diana Berman, Yuchen Sha and Elena V. Shevchenko
Molecules 2021, 26(3), 679; https://doi.org/10.3390/molecules26030679 - 28 Jan 2021
Cited by 3 | Viewed by 2877
Abstract
Polymer templates play an essential role in the robust infiltration-based synthesis of functional multicomponent heterostructures with controlled structure, porosity, and composition. Such heterostructures are be used as hybrid organic–inorganic composites or as all-inorganic systems once the polymer templates are removed. Using iron oxide/alumina [...] Read more.
Polymer templates play an essential role in the robust infiltration-based synthesis of functional multicomponent heterostructures with controlled structure, porosity, and composition. Such heterostructures are be used as hybrid organic–inorganic composites or as all-inorganic systems once the polymer templates are removed. Using iron oxide/alumina heterostructures formed by two-step infiltration of polystyrene-block-polyvinyl pyridine block copolymer with iron and aluminum precursors from the solution and vapor-phases, respectively, we show that the phase and morphology of iron oxide nanoparticles dramatically depend on the approach used to remove the polymer. We demonstrate that thermal and plasma oxidative treatments result in iron oxide nanoparticles with either solid or hollow morphologies, respectively, that lead to different magnetic properties of the resulting materials. Our study extends the boundaries of structure manipulations in multicomponent heterostructures synthesized using polymer infiltration synthesis, and hence their properties. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

14 pages, 15690 KiB  
Article
Ballistic Impact Behaviour of Glass/Epoxy Composite Laminates Embedded with Shape Memory Alloy (SMA) Wires
by Luv Verma, Jefferson Andrew, Srinivasan M. Sivakumar, Gurusamy Balaganesan, Srikanth Vedantam and Hom N. Dhakal
Molecules 2021, 26(1), 138; https://doi.org/10.3390/molecules26010138 - 30 Dec 2020
Cited by 10 | Viewed by 2713
Abstract
This paper aims to estimate the enhancement in the energy absorption characteristics of the glass fiber reinforced composites (GFRP) by embedding prestrained pseudo-elastic shape memory alloy (SMA) that was used as a secondary reinforcement. The pseudo-elastic SMA (PE-SMA) embedded were in the form [...] Read more.
This paper aims to estimate the enhancement in the energy absorption characteristics of the glass fiber reinforced composites (GFRP) by embedding prestrained pseudo-elastic shape memory alloy (SMA) that was used as a secondary reinforcement. The pseudo-elastic SMA (PE-SMA) embedded were in the form of wires and have an equiatomic composition (i.e., 50%–50%) of nickel (Ni) and titanium (Ti). These specimens are fabricated using a vacuum-assisted resin infusion process. The estimation is done for the GFRP and SMA/GFRP specimens at four different impact velocities (65, 75, 85, and 103 m/s) using a gas-gun impact set-up. At all different impact velocities, the failure modes change as we switch from GFRP to SMA/GFRP specimen. In the SMA/GFRP specimen, the failure mode changed from delamination in the primary region to SMA-pull out and SMA deformation. This leads to an increase in the ballistic limit. It is observed that energy absorbed by SMA/GFRP specimens is higher than the GFRP specimens subjected to the same levels of impact energy. To understand the damping capabilities of SMA embedment, vibration signals are captured, and the damping ratio is calculated. SMA dampens the vibrations imparted by the projectile to the specimen. The damping ratio of the SMA/GFRP specimens is higher than the GFRP specimens. The damping effect is more prominent below the ballistic limit when the projectile got rebounded (65 m/s). Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Graphical abstract

18 pages, 6027 KiB  
Article
Cyclic Olefin Copolymer Interleaves for Thermally Mendable Carbon/Epoxy Laminates
by Riccardo Costan Zovi, Haroon Mahmood, Andrea Dorigato, Giulia Fredi and Alessandro Pegoretti
Molecules 2020, 25(22), 5347; https://doi.org/10.3390/molecules25225347 - 16 Nov 2020
Cited by 11 | Viewed by 3262
Abstract
Thin cyclic olefin copolymer (COC) foils were used as intrinsic thermoplastic healing agents in carbon fiber (CF)-reinforced epoxy laminates. COC films were produced by hot pressing and were interleaved in the interlaminar regions between each EP/CF lamina, during the hand layup fabrication of [...] Read more.
Thin cyclic olefin copolymer (COC) foils were used as intrinsic thermoplastic healing agents in carbon fiber (CF)-reinforced epoxy laminates. COC films were produced by hot pressing and were interleaved in the interlaminar regions between each EP/CF lamina, during the hand layup fabrication of the laminates. Three samples were produced, i.e., the neat EP/CF laminate without COC, and two laminates containing COC layers with a thickness of 44 μm and 77 μm, respectively. It was observed that the fiber volume fraction decreased, and the porosity increased with the introduction of COC layers, and this effect was more evident when thick films were used. These two effects, combined with the sub-optimal adhesion between COC and EP, caused a decrease in the mechanical properties (i.e., the elastic modulus, flexural strength, interlaminar shear strength and interlaminar fracture toughness) of the laminates. Specimens subjected to mode I interlaminar fracture toughness test were then thermally mended under pressure by resistive heating, through the Joule effect of conductive CFs. A temperature of approximately 190 °C was reached during the healing treatment. The healing efficiency was evaluated as the ratio of critical strain energy release rate (GIC) of the healed and virgin specimens. Healed specimens containing COC layers of 44 μm and 77 μm exhibited a healing efficiency of 164% and 100%, respectively. As expected, the healing treatment was not beneficial for the neat EP/CF laminate without COC, which experienced a healing efficiency of only 2%. This result proved the efficacy of COC layers as a healing agent for EP/CF laminates, and the effectiveness of resistive heating as a way to activate the intrinsic healing mechanism. Full article
(This article belongs to the Special Issue Preparation, Characterization and Applications of Polymer Composites)
Show Figures

Figure 1

Back to TopTop