Recent Advances in Metal Ion Separation

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Extractive Metallurgy".

Deadline for manuscript submissions: 30 June 2025 | Viewed by 1181

Special Issue Editor


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Guest Editor
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade, Serbia
Interests: sustainable engineering; waste(water) treatment; energy neutrality; bio-sourced (waste) revalorization; green solution

Special Issue Information

Dear Colleagues,

The rapid technological development that we have witnessed in recent years has caused an increase in demand for metals, either in their extraction or recovery approach. An essential step in the production of metals is their separation from aqueous solutions obtained from leaching ore or recycling waste. The adsorption is considered an effective technique for the recovery or removal of metals from aqueous media. It offers excellent workability in process operation and design, and the sorbent can be reused after proper regeneration (multicycling application). Many traditional sorbents, including inorganic clays/zeolites, activated carbon, and polymeric resins, have been used for metal ion separation. Recently, advanced sorbents, such as modified natural inorganic/organic materials, modified carbons/biochar, agricultural waste (biosorbent), metal–organic frameworks, synthesized polymers, magnetic sorbents, hydrogels, and nanosorbents, were successfully applied in the separation of metal ions.

For this Special Issue in Metals, we welcome reviews and articles in the areas of separation of metal ions, including new and modified sorbent preparation, characterization and applications, mechanism elucidation, and theoretical calculations.

This Special Issue will be focused on, but not limited to, advances in the following areas:

  • Various separation techniques for metal ion removal;
  • Synthesis and characterization of advanced separation materials;
  • Physical and chemical modifications and functionalization of sorbents;
  • Theoretical considerations of interactions between dissolved metals and solid surfaces;
  • Adsorption mechanism of metal cations, metal oxyanions, and metal complexes;
  • Process design in static and flow systems;
  • Automatization of the adsorption processes;
  • Miniaturization of adsorption and solid-phase extraction of metals;
  • Novel applications of sorbents for metal ion separation.

This open access Special Issue aims to outline the current state of the art in the area of separation of metal ion.

Dr. Maja Branko Đolić
Guest Editor

Manuscript Submission Information

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Keywords

  • adsorption
  • cations
  • oxyanions
  • removal
  • heavy metals
  • extraction
  • leaching
  • hydrometallurgy

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Published Papers (1 paper)

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Research

20 pages, 1547 KiB  
Article
Dispersive Liquid–Liquid Chelate Microextraction of Rare Earth Elements: Optimization and Greenness Evaluation
by Milica Delić, Mirjana Ristić, Maja Đolić, Aleksandra Perić-Grujić and Antonije Onjia
Metals 2025, 15(1), 52; https://doi.org/10.3390/met15010052 - 8 Jan 2025
Viewed by 907
Abstract
An ultrasound-assisted dispersive liquid–liquid microextraction (DLLME) method was developed to concentrate and quantify rare earth elements (REEs) (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) in acidic aqueous solutions. Tetrachloroethylene (PCE) was used as [...] Read more.
An ultrasound-assisted dispersive liquid–liquid microextraction (DLLME) method was developed to concentrate and quantify rare earth elements (REEs) (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) in acidic aqueous solutions. Tetrachloroethylene (PCE) was used as the diluent, di-(2-ethyl hexyl) phosphoric acid (D2EHPA) as the extracting agent, and acetone as the dispersant solvent. The method was optimized at pH = 2.3, T = 25 °C, and VS = 400 µL of a PCE ÷ D2EHPA mixture (10 ÷ 1) using the response surface methodology (RSM) with a Box–Behnken design. Under optimal conditions, the method proved efficient for the DLLME of most REEs (Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu), where the achieved recoveries were in the range of 61–109%, while relative standard deviations were in the range 11–28%. The proposed method was applied to recover REEs from real coal ash leachate samples. A greenness evaluation using the Green Analytical Procedure Index (GAPI), Analytical GREEnness (AGREE), and Analytical Eco-Scale (AES) methodologies revealed acceptable metric scores of 74, 0.61, and 26.6–79.8, respectively. Full article
(This article belongs to the Special Issue Recent Advances in Metal Ion Separation)
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