Journal Description
Materials
Materials
is an international peer-reviewed, open access journal on materials science and engineering published semimonthly online by MDPI. The Portuguese Materials Society (SPM), Spanish Materials Society (SOCIEMAT) and Manufacturing Engineering Society (MES) are affiliated with Materials and their members receive discounts on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
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- Journal Rank: JCR - Q2 (Metallurgy & Metallurgical Engineering) / CiteScore - Q2 (Condensed Matter Physics)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 13.9 days after submission; acceptance to publication is undertaken in 2.7 days (median values for papers published in this journal in the second half of 2023).
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- Companion journals for Materials include: Electronic Materials and Construction Materials.
Impact Factor:
3.4 (2022);
5-Year Impact Factor:
3.8 (2022)
Latest Articles
The Quest for High-Temperature Superconductivity in Nickelates under Ambient Pressure
Materials 2024, 17(11), 2546; https://doi.org/10.3390/ma17112546 (registering DOI) - 25 May 2024
Abstract
Recently, superconductivity with Tc ≈ 80 K was discovered in La3Ni2O7 under extreme hydrostatic pressure (>14 GPa). For practical applications, we needed to stabilize this state at ambient pressure. It was proposed that this could be accomplished
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Recently, superconductivity with Tc ≈ 80 K was discovered in La3Ni2O7 under extreme hydrostatic pressure (>14 GPa). For practical applications, we needed to stabilize this state at ambient pressure. It was proposed that this could be accomplished by substituting La with Ba. To put this hypothesis to the test, we used the state-of-the-art atomic-layer-by-layer molecular beam epitaxy (ALL-MBE) technique to synthesize (La1−xBax)3Ni2O7 films, varying x and the distribution of La (lanthanum) and Ba (barium). Regrettably, none of the compositions we explored could be stabilized epitaxially; the targeted compounds decomposed immediately into a mixture of other phases. So, this path to high-temperature superconductivity in nickelates at ambient pressure does not seem promising.
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(This article belongs to the Special Issue Novel Superconducting Materials and Applications of Superconductivity)
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New Advances in Strengthening of Structural Timber
by
Paweł Grzegorz Kossakowski
Materials 2024, 17(11), 2545; https://doi.org/10.3390/ma17112545 - 24 May 2024
Abstract
As one of the oldest building materials, wood is still widely used today [...]
Full article
(This article belongs to the Special Issue New Advances in Strengthening of Structural Timber)
Open AccessArticle
High Temperature Oxidation Behavior of Additive Manufactured Ti6Al4V Alloy with the Addition of Yttrium Oxide Nanoparticles
by
Qiang Wang, Pu Song, Wenjuan Niu, Nan Li and Ning Hu
Materials 2024, 17(11), 2544; https://doi.org/10.3390/ma17112544 - 24 May 2024
Abstract
Titanium alloys face challenges of high temperature oxidation during the service period when used as aircraft engine components. In this paper, the effect of Y2O3 addition on the oxidation behavior and the microstructural change of the Ti6Al4V alloy fabricated by
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Titanium alloys face challenges of high temperature oxidation during the service period when used as aircraft engine components. In this paper, the effect of Y2O3 addition on the oxidation behavior and the microstructural change of the Ti6Al4V alloy fabricated by selective laser melting (SLM) was comprehensively studied. The results show that the surface of the Ti6Al4V alloy is a dense oxide layer composed of TiO2 and Al2O3 compounds. The thickness of the oxide layer of the Ti6Al4V increased from 59.55 μm to 139.15 μm. In contrast, with the addition of Y2O3, the thickness of the oxide layer increased from 35.73 μm to 80.34 μm. This indicates that the thickness of the oxide layer formation was a diffusion-controlled process and, therefore, the thickness of the oxide layer increased with an increase in temperature. The Ti6Al4V-1.0 wt.% Y2O3 alloy exhibits excellent oxidation resistance, and the thickness is significantly lower than that of the Ti6Al4V alloy. The oxidation kinetics of the Ti6Al4V and Ti6Al4V-1.0 wt.% Y2O3 alloys at 600 °C and 800 °C follows a parabolic rule, whereas the oxidation of the Ti6Al4V and Ti6Al4V-1.0 wt.% Y2O3 alloys at 1000 °C follows the linear law. The average microhardness values of Ti6Al4V samples after oxidation increased to 818.9 ± 20 HV0.5 with increasing temperature, and the average microhardness values of the Ti6Al4V-1.0 wt.% Y2O3 alloy increases until 800 °C and then decreases at 1000 °C. The addition of Y2O3 shows a significant improvement in the microhardness during the different temperatures after oxidation.
Full article
(This article belongs to the Special Issue Advances in Titanium and Titanium Alloys: Processing, Properties and Additive Manufacturing)
Open AccessArticle
Core–Double-Shell TiO2@Fe3O4@C Microspheres with Enhanced Cycling Performance as Anode Materials for Lithium-Ion Batteries
by
Yuan Chen, Jiatong Yang, Aoxiong He, Jian Li, Weiliang Ma, Marie-Christine Record, Pascal Boulet, Juan Wang and Jan-Michael Albina
Materials 2024, 17(11), 2543; https://doi.org/10.3390/ma17112543 - 24 May 2024
Abstract
Due to the volume expansion effect during charge and discharge processes, the application of transition metal oxide anode materials in lithium-ion batteries is limited. Composite materials and carbon coating are often considered feasible improvement methods. In this study, three types of TiO2
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Due to the volume expansion effect during charge and discharge processes, the application of transition metal oxide anode materials in lithium-ion batteries is limited. Composite materials and carbon coating are often considered feasible improvement methods. In this study, three types of TiO2@Fe3O4@C microspheres with a core–double-shell structure, namely TFCS (TiO2@Fe3O4@C with 0.0119 g PVP), TFCM (TiO2@Fe3O4@C with 0.0238 g PVP), and TFCL (TiO2@Fe3O4@C with 0.0476 g PVP), were prepared using PVP (polyvinylpyrrolidone) as the carbon source through homogeneous precipitation and high-temperature carbonization methods. After 500 cycles at a current density of 2 C, the specific capacities of these three microspheres are all higher than that of TiO2@Fe2O3 with significantly improved cycling stability. Among them, TFCM exhibits the highest specific capacity of 328.3 mAh·g−1, which was attributed to the amorphous carbon layer effectively mitigating the capacity decay caused by the volume expansion of iron oxide during charge and discharge processes. Additionally, the carbon coating layer enhances the electrical conductivity of the TiO2@Fe3O4@C materials, thereby improving their rate performance. Within the range of 100 to 1600 mA·g−1, the capacity retention rates for TiO2@Fe2O3, TFCS, TFCM, and TFCL are 27.2%, 35.2%, 35.9%, and 36.9%, respectively. This study provides insights into the development of new lithium-ion battery anode materials based on Ti and Fe oxides with the abundance and environmental friendliness of iron, titanium, and carbon resources in TiO2@Fe3O4@C microsphere anode materials, making this strategy potentially applicable.
Full article
(This article belongs to the Special Issue New Materials for Lithium-Based Battery Alternatives)
Open AccessArticle
Durability and Mechanical Properties of Nano-SiO2 and Polyvinyl Alcohol Fiber-Reinforced Cementitious Composites Subjected to Saline Freeze–Thaw Cycles
by
Lijun Wan, Yongqi Zhao, Maopei Yu, Ye Tian and Yipeng Wang
Materials 2024, 17(11), 2542; https://doi.org/10.3390/ma17112542 - 24 May 2024
Abstract
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To investigate the effects of nano-SiO2 (NS) and polyvinyl alcohol (PVA) fibers on the durability and mechanical properties of cementitious composites subjected to saline freeze–thaw cycling, a series of PVA fiber-reinforced cementitious composite (PFRCC) specimens were prepared using various fiber contents, and
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To investigate the effects of nano-SiO2 (NS) and polyvinyl alcohol (PVA) fibers on the durability and mechanical properties of cementitious composites subjected to saline freeze–thaw cycling, a series of PVA fiber-reinforced cementitious composite (PFRCC) specimens were prepared using various fiber contents, and a series of NS and PVA fiber-reinforced cementitious composite (NPFRCC) specimens were prepared using various combinations of NS and fiber contents. Durability and fracture toughness tests were subsequently conducted on the specimens after different numbers of saline freeze–thaw cycles. The results indicate that the degradation of material properties can be divided into slow and accelerated damage stages before/after 50 freeze–thaw cycles. The durability and fracture toughness of the specimen series tended to increase, then decrease with increasing NS and PVA contents, suggesting optimum levels. When the PVA fiber content was 0.5%, PFRCC specimens had the best durability after saline freeze–thaw cycles; when the NS and PVA fiber contents were 1.0% and 0.5%, respectively, NPFRCC specimens had the best durability and fracture properties, and the initiation toughness, destabilization toughness, and fracture energy after 100 saline freeze–thaw cycles were 120.69%, 160.02%, and 451.31%, respectively. The results of this study may guide future exploration of the durability and mechanical properties of concrete subjected to freeze–thaw action.
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Open AccessArticle
Influence of Cold Wave Diversities on Thermal Stress and Thermal Fatigue Life of Asphalt Mixture
by
Haimei, Lili Li, Qinglin Guo, Wenli He and Aosen Xu
Materials 2024, 17(11), 2541; https://doi.org/10.3390/ma17112541 - 24 May 2024
Abstract
Apart from low-temperature cracking, asphalt pavement may also suffer from thermal fatigue cracking. To clarify the impact of cold waves on the thermal fatigue performance of asphalt mixtures, the typical atmospheric temperature characteristics of different regions in China from 2012 to 2019 were
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Apart from low-temperature cracking, asphalt pavement may also suffer from thermal fatigue cracking. To clarify the impact of cold waves on the thermal fatigue performance of asphalt mixtures, the typical atmospheric temperature characteristics of different regions in China from 2012 to 2019 were analyzed, and the frequency of cold waves in these regions was determined. The viscoelastic parameters of an asphalt mixture are determined through an indirect tensile relaxation test. The thermal stress of the asphalt mixture is simulated and analyzed by using the finite element method. The effect of cold waves on the thermal fatigue life of the asphalt mixture was evaluated. The results show that the frequency of cold waves is different from region to region in China, and the cold waves mainly occurred from October of one year to February of the next year. Northeast China has the most frequency and the largest temperature drop amplitude, followed by North China. The maximum thermal stress increases with the decrease in temperature drop and initial temperature and is unrelated to the duration of cold waves. The thermal stress calculated based on the atmospheric thermal boundary is higher than the value using the road surface temperature. The thermal fatigue lives of asphalt mixtures in North China and Northeast China are very short, while the thermal fatigue life of the mixture in Central China is the longest. To meet the requirement of thermal fatigue damage caused by cold waves during the designed service stage, the recommended threshold for thermal stress is 0.39–0.77 MPa.
Full article
(This article belongs to the Special Issue Characterization, Applications and New Technologies of Civil Engineering Materials and Structures, 2nd Edition)
Open AccessArticle
Changes in Current Transport and Regulation of the Microstructure of Graphene/Polyimide Films under Joule Heating Treatment
by
Jianshu Yu, Hui Ding, Bin Chen, Xuejiao Sun, Ying Zhang and Zhongfu Zhou
Materials 2024, 17(11), 2540; https://doi.org/10.3390/ma17112540 - 24 May 2024
Abstract
The excellent electrical properties of graphene have received widespread attention. However, the difficulty of electron transfer between layers still restricts the application of graphene composite materials to a large extent. Therefore, in this study, graphene/polyimide films were subjected to a Joule heating treatment
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The excellent electrical properties of graphene have received widespread attention. However, the difficulty of electron transfer between layers still restricts the application of graphene composite materials to a large extent. Therefore, in this study, graphene/polyimide films were subjected to a Joule heating treatment to improve the electrical conductivity of the film by ~76.85%. After multiple Joule thermal cycle treatments, the conductivity of the graphene/polyimide film still gradually increased, but the increase in amplitude tended to slow down. Finally, after eight Joule heat treatments, the conductivity of the graphene/polyimide film was improved by ~93.94%. The Joule heating treatment caused the polyimide to undergo atomic rearrangement near the interface bonded to the graphene, forming a new crystalline phase favourable for electron transport with graphene as a template. Accordingly, a model of the bilayer capacitive microstructure of graphene/polyimide was proposed. The experiment suggests that the Joule heating treatment can effectively reduce the distance between graphene electrode plates in the bilayer capacitive micro-nanostructures of graphene/polyimide and greatly increases the number of charge carriers on the electrode plates. The TEM and WAXS characterisation results imply atomic structure changes at the graphene/polyimide bonding interface.
Full article
Open AccessArticle
Investigation on the Preparation and Performances of Epoxy-Modified Asphalt Binder and Its Mixtures
by
Xiaodong Liu, Zhiheng Wu, Zhaohui Min and Lei Zhang
Materials 2024, 17(11), 2539; https://doi.org/10.3390/ma17112539 - 24 May 2024
Abstract
Epoxy-modified asphalt binder has been widely used in steel deck pavement due to its excellent properties and it is a potential candidate for long life pavements. However, its short reserve time limits its widespread application in pavement engineering. Therefore, this work developed a
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Epoxy-modified asphalt binder has been widely used in steel deck pavement due to its excellent properties and it is a potential candidate for long life pavements. However, its short reserve time limits its widespread application in pavement engineering. Therefore, this work developed a novel epoxy-modified asphalt binder composed of a laboratory-made curing agent as a solution. Firstly, optimization of preparation temperature of this new material was studied to balance the requirements of enough construction time and the material strength and elongation. The epoxy-modified asphalt binder, prepared at the optimal temperature of 140 °C, had a reserve time exceeding 120 min, whereas the tensile strength and the elongation at failure were 2.22 MPa and 216%, respectively, which satisfied the standard requirements of paving epoxy material well. Secondly, the asphalt mixture property tests demonstrate excellent high-temperature rutting resistance, water stability and low-temperature anti-cracking ability. Additionally, the compatibility and colloidal stability of this epoxy-modified asphalt binder were analyzed in terms of microphase structure. The uniform microphase distribution of this binder showed by the laser confocal microscope observation in both short-term aging case and long-term aging case, indicates the great compatibility between asphalt and epoxy resin during paving process and service life. Furthermore, fatigue tests were conducted to evaluate the long-term durability. The fatigue life of epoxy-modified asphalt mixtures increased by 435%, 427%, 342%, and 276% under the stress ratios of 0.3, 0.4, 0.5, and 0.6, respectively, compared to those of SBS-modified asphalt mixtures. All these results indicate that the new epoxy-modified asphalt material is promising for applications in pavement engineering, especially suitable for long-life road pavement.
Full article
(This article belongs to the Special Issue Production, Application and Properties of Bitumen (2nd Edition))
Open AccessArticle
Hydrophobization of Reduced Graphene Oxide Aerogel Using Soy Wax to Improve Sorption Properties
by
Sergey A. Baskakov, Yulia V. Baskakova, Eugene N. Kabachkov, Mikhail V. Zhidkov, Anastasia V. Alperovich, Svetlana S. Krasnikova, Dmitrii A. Chernyaev, Yury M. Shulga and Gennady L. Gutsev
Materials 2024, 17(11), 2538; https://doi.org/10.3390/ma17112538 - 24 May 2024
Abstract
A special technique has been developed for producing a composite aerogel which consists of graphene oxide and soy wax (GO/wax). The reduction of graphene oxide was carried out by the stepwise heating of this aerogel to 250 °C. The aerogel obtained in the
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A special technique has been developed for producing a composite aerogel which consists of graphene oxide and soy wax (GO/wax). The reduction of graphene oxide was carried out by the stepwise heating of this aerogel to 250 °C. The aerogel obtained in the process of the stepwise thermal treatment of rGO/wax was studied by IR and Raman spectroscopy, scanning electron microscopy, and thermogravimetry. The heat treatment led to an increase in the wax fraction accompanied by an increase in the contact angle of the rGO/wax aerogel surface from 136.2 °C to 142.4 °C. The SEM analysis has shown that the spatial structure of the aerogel was formed by sheets of graphene oxide, while the wax formed rather large (200–1000 nm) clumps in the folds of graphene oxide sheets and small (several nm) deposits on the flat surface of the sheets. The sorption properties of the rGO/wax aerogel were studied with respect to eight solvent, oil, and petroleum products, and it was found that dichlorobenzene (85.8 g/g) and hexane (41.9 g/g) had the maximum and minimum sorption capacities, respectively. In the case of oil and petroleum products, the indicators were in the range of 52–63 g/g. The rGO/wax aerogel was found to be highly resistant to sorption–desorption cycles. The cyclic tests also revealed a swelling effect that occurred differently for different parts of the aerogel.
Full article
(This article belongs to the Special Issue Preparation and Characterization of Functional Composite Materials)
Open AccessArticle
Studies on the Evolution of Fatigue Strength of Aluminium Wires for Overhead Line Conductors
by
Bartosz Jurkiewicz and Beata Smyrak
Materials 2024, 17(11), 2537; https://doi.org/10.3390/ma17112537 - 24 May 2024
Abstract
Traditional ACSR overhead wires, which consist of a high-strength steel core and several layers of aluminium wires, are currently the most popular overhead line conductor (OHL) design globally. Operating conditions, particularly operating under varying stresses from Karman vortices, lead to the fatigue cracking
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Traditional ACSR overhead wires, which consist of a high-strength steel core and several layers of aluminium wires, are currently the most popular overhead line conductor (OHL) design globally. Operating conditions, particularly operating under varying stresses from Karman vortices, lead to the fatigue cracking of wires of the outer layer, followed by wires of the inner layers. Karman vortices are formed by the detachment of a laminar wind stream flowing around the conductor, which causes vibrations in the conductor called wind or aeolian oscillations. Aluminium wires are manufactured using standard batch material drawing technology. Although the fatigue strength of such wires is not standardised, there are various criteria for evaluating this characteristic, as well as established limits on the number of cycles needed to break the first wires of the outer layer. Fatigue strength also strongly depends on the geometric structure of the wire and its operating conditions. The article analyses the influence of the mechanical condition of aluminium wires used in ACSR cables on their fatigue strength. We then present results from aluminium wire fatigue tests conducted on a specially constructed test rig. In addition, fatigue cracks were interpreted using scanning microscopy.
Full article
(This article belongs to the Special Issue Study on Cyclic Mechanical Behaviors of Materials – 2nd Edition)
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Open AccessArticle
Quasi-Static Penetration Properties of 3D-Printed Composite Plates
by
Axel Baruscotti, Yuri Borgianni and Franco Concli
Materials 2024, 17(11), 2536; https://doi.org/10.3390/ma17112536 - 24 May 2024
Abstract
This work investigated the impact and piercing load resistance (energy absorption capabilities) of 3D-printed composites plates manufactured by means of the Fused-Filament-Fabrication (FFF) technique. Two sets of reinforced composite plates were produced. The first set of plates was printed with short-carbon-fiber-reinforced polyamide-12, while
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This work investigated the impact and piercing load resistance (energy absorption capabilities) of 3D-printed composites plates manufactured by means of the Fused-Filament-Fabrication (FFF) technique. Two sets of reinforced composite plates were produced. The first set of plates was printed with short-carbon-fiber-reinforced polyamide-12, while the second set was reinforced with continuous fibers. The plates were tested with quasi-static indentation tests at various Span-to-Punch ratios and with three different indenter nose shapes (blunt, hemispherical, and conical). The quasi-static measurements were subsequently elaborated to estimate the energy absorption capability of the plates during a ballistic impact. The addition of continuous fibers increased the quasi-static energy absorption capability by 20–185% with respect to the short-fiber-reinforced plates. The quasi-static results showed that by including the continuous reinforcement in the plates, the normalized energy absorbed increased by an order of magnitude. Finally, a comparison with data from the literature concerning continuous-reinforced composite plates manufactured by means of traditional techniques was carried out. The comparison revealed that FFF-printed composite plates can compete with traditional composite ones in terms of both ballistic and quasi-static penetrating load conditions, even if limited by the lower fiber volume fraction. Thus, these findings confirm that this novel Additive Manufacturing technique is promising and worth investigating further.
Full article
(This article belongs to the Special Issue Additive Manufacturing of Alloys and Composites (2nd Edition))
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Open AccessArticle
Fabrication of Ceramic Microchannels with Periodic Corrugated Microstructures as Catalyst Support for Hydrogen Production via Diamond Wire Sawing
by
Xinying Li, Chao Gao, Ding Yuan, Yuanbao Qin, Dongbi Fu, Xiyang Jiang and Wei Zhou
Materials 2024, 17(11), 2535; https://doi.org/10.3390/ma17112535 - 24 May 2024
Abstract
Hydrogen energy is the clean energy with the most potential in the 21st century. The microchannel reactor for methanol steam reforming (MSR) is one of the effective ways to obtain hydrogen. Ceramic materials have the advantages of high temperature resistance, corrosion resistance, and
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Hydrogen energy is the clean energy with the most potential in the 21st century. The microchannel reactor for methanol steam reforming (MSR) is one of the effective ways to obtain hydrogen. Ceramic materials have the advantages of high temperature resistance, corrosion resistance, and high mechanical strength, and are ideal materials for preparing the catalyst support in microchannel reactors. However, the structure of ceramic materials is hard and brittle, and the feature size of microchannel is generally not more than 1 mm, which is difficult to process using traditional processing methods. Diamond wire saw processing technology is mainly used in the slicing of hard and brittle materials such as sapphire and silicon. In this paper, a microchannel with a periodic corrugated microstructure was fabricated on a ceramic plate using diamond wire sawing, and then as a catalyst support when used in a microreactor for MSR hydrogen production. The effects of wire speed and feed speed on the amplitude and period size of the periodic corrugated microstructure were studied using a single-factor experiment. The microchannel surface morphology was observed via SEM and a 3D confocal laser microscope under different processing parameters. The microchannel samples obtained under different processing parameters were supported by a multiple impregnation method. The loading strength of the catalyst was tested via a strong wind purge experiment. The experimental results show that the periodic corrugated microstructure can significantly enhance the load strength of the catalyst. The microchannel catalyst support with the periodic corrugated microstructure was put into the microreactor for a hydrogen production experiment, and a good hydrogen production effect was obtained. The experimental results have a positive guiding effect on promoting ceramic materials as the microchannel catalyst support for the development of hydrogen energy.
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(This article belongs to the Special Issue Advanced Abrasive Processing Technology and Applications)
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Corrosion Behavior of Nacre-Inspired (TiBw-TiB2)/Al Composites Fabricated by Freeze Casting
by
Jidong Zhang, Mingfang Qian, Ruiqing Yang, Feng Yu, Xuexi Zhang, Zhenggang Jia, Aibin Li, Guisong Wang and Lin Geng
Materials 2024, 17(11), 2534; https://doi.org/10.3390/ma17112534 - 24 May 2024
Abstract
Nacre-inspired metal matrix composites have received much attention due to their excellent deformation coordination ability, which can achieve the synergy of strength and ductility. The preparation of nacre-like Al matrix composites by freeze casting has been a promising application, but the continuous ceramic-rich
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Nacre-inspired metal matrix composites have received much attention due to their excellent deformation coordination ability, which can achieve the synergy of strength and ductility. The preparation of nacre-like Al matrix composites by freeze casting has been a promising application, but the continuous ceramic-rich layer affects the corrosion resistance of the composites, facing complex corrosion problems during service. In this work, the microstructure and corrosion behavior of the nacre-inspired (TiBw-TiB2)/Al composites fabricated by freeze casting and squeeze casting were systematically studied. The results indicated that the Al layers and ceramic-rich layers had little change, about 35 μm and 31 μm, respectively, with an increasing ratio of the Ti/TiB2. Meanwhile, a high Ti/TiB2 ratio resulted in an increase in the Fe-Ti intermetallic phases, which was detrimental to the corrosion performance of the composites and was prone to pitting. The electrochemical test results showed that the 3Ti7TiB2 composite had the lowest corrosion current density (15.9 μA) and intergranular corrosion depth (231 μm), indicating that it had the best corrosion resistance, which can be attributable to its stable and dense passivation film. Two different corrosion phenomena during the intergranular corrosion test existed in the present nacre-inspired (TiBw-TiB2)/Al composites: intergranular corrosion in the Al matrix layer and pitting corrosion in the ceramic-rich layer. Among all the composites, the corrosion depth of the 3Ti7TiB2 composite was the smallest and significantly less than that of the 2024Al alloy. In addition, the continuous ceramic-rich layer acted as a corrosion channel during corrosion, significantly degrading the corrosion resistance of the nacre-like Al composites.
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(This article belongs to the Special Issue Corrosion Mechanism and Protection Technology of Metallic Materials)
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Open AccessArticle
TPMS Microarchitectures for Vertical Bone Augmentation and Osteoconduction: An In Vivo Study
by
Ekaterina Maevskaia, Chafik Ghayor, Indranil Bhattacharya, Julien Guerrero and Franz E. Weber
Materials 2024, 17(11), 2533; https://doi.org/10.3390/ma17112533 - 24 May 2024
Abstract
Triply periodic minimal surface microarchitectures (TPMS) were developed by mathematicians and evolved in all kingdoms of living organisms. Renowned for their lightweight yet robust attributes, TPMS structures find application in diverse fields, such as the construction of satellites, aircrafts, and electric vehicles. Moreover,
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Triply periodic minimal surface microarchitectures (TPMS) were developed by mathematicians and evolved in all kingdoms of living organisms. Renowned for their lightweight yet robust attributes, TPMS structures find application in diverse fields, such as the construction of satellites, aircrafts, and electric vehicles. Moreover, these microarchitectures, despite their intricate geometric patterns, demonstrate potential for application as bone substitutes, despite the inherent gothic style of natural bone microarchitecture. Here, we produced three TPMS microarchitectures, D-diamond, G-gyroid, and P-primitive, by 3D printing from hydroxyapatite. We explored their mechanical characterization and, further, implanted them to study their bone augmentation and osteoconduction potential. In terms of strength, the D-diamond and G-gyroid performed significantly better than the P-primitive. In a calvarial defect model and a calvarial bone augmentation model, where osteoconduction is determined as the extent of bony bridging of the defect and bone augmentation as the maximal vertical bone ingrowth, the G-gyroid performed significantly better than the P-primitive. No significant difference in performance was observed between the G-gyroid and D-diamond. Since, in real life, the treatment of bone deficiencies in patients comprises elements of defect bridging and bone augmentation, ceramic scaffolds with D-diamond and G-gyroid microarchitectures appear as the best choice for a TPMS-based scaffold in bone tissue engineering.
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(This article belongs to the Collection 3D Printing in Medicine and Biomedical Engineering)
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Research on Macroscopic Mechanical Behavior of Recycled Aggregate Concrete Based on Mesoscale
by
Anyu Yang, Qizhi Shang, Yanan Zhang and Junlong Zhu
Materials 2024, 17(11), 2532; https://doi.org/10.3390/ma17112532 - 24 May 2024
Abstract
Recycled concrete is a heterogeneous composite material, and the composition and volume fraction of each phase affect its macroscopic properties. In this paper, ANSYS APDL was used to construct a two-dimensional numerical model of recycled aggregate concrete with different replacement rates of recycled
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Recycled concrete is a heterogeneous composite material, and the composition and volume fraction of each phase affect its macroscopic properties. In this paper, ANSYS APDL was used to construct a two-dimensional numerical model of recycled aggregate concrete with different replacement rates of recycled aggregate (0%, 25%, 50%, 75% and 100%), and a uniaxial compression test was carried out to explore the relationship between recycled aggregate content and its macroscopic mechanical behavior. On this basis, the numerical simulation of different strain rates (0.1 s−1, 0.05 s−1, 0.01 s−1, 0.005 s−1 and 0.001 s−1) was carried out. It was found that with the increase in the recycled aggregate replacement rate, the peak stress decreases first and then increases, and the peak strain increases continuously. When the replacement rate of recycled aggregate exceeds 50%, the overall damage area of the material increases rapidly. The strain rate will change the path of the micro-crack initiation and expansion of recycled concrete, as well as the process of damage accumulation and evolution. As a result, the unit area and shape of recycled concrete are different at different strain rates, and the damage degree of each phase material is also different.
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(This article belongs to the Special Issue Sustainable and Advanced Cementitious Materials)
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Hot Deformation Behavior and Microstructure Evolution Mechanisms of Ti6Al4V Alloy under Hot Stamping Conditions
by
Mingjia Qu, Zhengwei Gu, Xin Li, Lingling Yi, Yi Li, Ge Yu and Yafu Zhao
Materials 2024, 17(11), 2531; https://doi.org/10.3390/ma17112531 - 24 May 2024
Abstract
Through the study of the thermal rheological behavior of Ti6Al4V alloy at different temperatures (500 °C, 600 °C, 700 °C, and 800 °C) and different strain rates (0.1 s−1, 0.05 s−1, 0.01 s−1, and 0.005 s−1
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Through the study of the thermal rheological behavior of Ti6Al4V alloy at different temperatures (500 °C, 600 °C, 700 °C, and 800 °C) and different strain rates (0.1 s−1, 0.05 s−1, 0.01 s−1, and 0.005 s−1), a constitutive model was developed for Ti6Al4V alloy across a wide temperature range in the hot stamping process. The model’s correlation coefficient reached 0.9847, indicating its high predictive accuracy. Hot processing maps suitable for the hot stamping process of Ti6Al4V alloy were developed, demonstrating the significant impact of the strain rate on the hot formability of Ti6Al4V alloy. At higher strain rates (>0.05 s−1), the hot processing of Ti6Al4V alloy is less prone to instability. Combining hot processing maps with hot stamping experiments, it was found that the forming quality and thickness uniformity of parts improved significantly with the increase in stamping speed. The phase composition and microstructures of the forming parts under different heating temperature conditions have been investigated using SEM, EBSD, XRD, and TEM, and the maximum heating temperature of hot stamping forming was determined to be 875 °C. The recrystallization mechanism in hot stamping of Ti6Al4V alloys was proposed based on EBSD tests on different sections of a hot stamping formed box-shaped component. With increasing deformation, the effect of dynamic recrystallization (DRX) was enhanced. When the thinning rate reached 15%, DRX surpassed dynamic recovery (DRV) as the dominant softening mechanism. DRX grains at different thinning rates were formed through both discontinuous dynamic recrystallization (DDRX) and continuous dynamic recrystallization (CDRX), with CDRX always being the dominant mechanism.
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(This article belongs to the Special Issue Mechanical Behavior of Advanced Engineering Materials)
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Spectrally Tunable Lead-Free Perovskite Rb2ZrCl6:Te for Information Encryption and X-ray Imaging
by
Guoxue Pan, Mingqing Li, Xiaotong Yu, Yuanhao Zhou, Minghui Xu, Xinxin Yang, Zhan Xu, Qianli Li and He Feng
Materials 2024, 17(11), 2530; https://doi.org/10.3390/ma17112530 - 24 May 2024
Abstract
A series of lead-free Rb2ZrCl6:xTe4+ (x = 0%, 0.1%, 0.5%, 1.0%, 2.0%, 3.0%, 5.0%, 10.0%) perovskite materials were synthesized through a hydrothermal method in this work. The substitution of Te4+ for Zr in Rb
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A series of lead-free Rb2ZrCl6:xTe4+ (x = 0%, 0.1%, 0.5%, 1.0%, 2.0%, 3.0%, 5.0%, 10.0%) perovskite materials were synthesized through a hydrothermal method in this work. The substitution of Te4+ for Zr in Rb2ZrCl6 was investigated to examine the effect of Te4+ doping on the spectral properties of Rb2ZrCl6 and its potential applications. The incorporation of Te4+ induced yellow emission of triplet self-trapped emission (STE). Different luminescence wavelengths were regulated by Te4+ concentration and excitation wavelength, and under a low concentration of Te4+ doping (x ≤ 0.1%), different types of host STE emission and Te4+ triplet state emission could be achieved through various excitation energies. These luminescent properties made it suitable for applications in information encryption. When Te4+ was doped at high concentrations (x ≥ 1%), yellow triplet state emission of Te4+ predominated, resulting in intense yellow emission, which stemmed from strong exciton binding energy and intense electron-phonon coupling. In addition, a Rb2ZrCl6:2%Te4+@RTV scintillating film was fabricated and a spatial resolution of 3.7 lp/mm was achieved, demonstrating the potential applications of Rb2ZrCl6:xTe4+ in nondestructive detection and bioimaging.
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(This article belongs to the Special Issue Computed Tomography and X-ray Imaging in Material Science)
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Open AccessArticle
Enhanced Photocatalytic Activity of V2C MXene-Coupled ZnO Porous Nanosheets with Increased Surface Area and Effective Charge Transfer
by
Weibing Zhou, Lilong Sun, Kang Li and Shouqin Tian
Materials 2024, 17(11), 2529; https://doi.org/10.3390/ma17112529 - 24 May 2024
Abstract
Photocatalysis performs excellently when degrading organic pollutants, but the photocatalytic degradation rate is not high for most photocatalysts due to their narrow sunlight adsorption range and high recombination rate of electron hole pairs. Herein, we use V2C-MXene with a wide sunlight
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Photocatalysis performs excellently when degrading organic pollutants, but the photocatalytic degradation rate is not high for most photocatalysts due to their narrow sunlight adsorption range and high recombination rate of electron hole pairs. Herein, we use V2C-MXene with a wide sunlight adsorption range to couple ZnO porous nanosheets and form ZnO/MXene hybrids using a facile electrostatic self-assembly method. The ZnO/MXene hybrids acquired demonstrated improved photochemical efficiency in breaking down methylene blue (MB) when contrasted with porous ZnO nanosheets. The degradation rate of MB reached 99.8% under UV irradiation for 120 min after the ZnO/MXene hybrid formation, while 38.6% was attained by the ZnO porous nanosheets. Moreover, photodegradation rate constants (k) were calculated as 3.05 × 10−3 and 5.42 × 10−2 min−1 for ZnO porous nanosheets and ZnO/MXene hybrids, respectively, indicating that the photodegradation performance was enhanced by 17.8 times after the modification of V2C. This was probably because the modification of V2C can increase the specific surface area to provide more sites for MB adsorption, widen the sunlight adsorption range to produce good photothermal effect, and facilitate the transfer of photogenerated carriers in ZnO to promote the reaction of more photogenerated carriers with MB. Hence, this work offers a simple approach to creating effective photocatalysts for breaking down organic contaminants.
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(This article belongs to the Special Issue Advances in Photocatalyst Materials and Green Chemistry)
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Open AccessArticle
Ultrasonic Non-Destructive Detection Method for Residual Stress in Rotary Forging Aluminum Alloy Plates
by
Hongyu Chen, Xiaokai Wang, Xinghui Han, Fangyan Zheng and Wenlong Yan
Materials 2024, 17(11), 2528; https://doi.org/10.3390/ma17112528 - 24 May 2024
Abstract
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Aluminum alloy plates are widely used to manufacture large-scale integral structure parts in the field of aerospace. During the forming and processing of aluminum alloy plates, different degrees of residual stress are inevitably produced. Fast and accurate detection of residual stress is very
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Aluminum alloy plates are widely used to manufacture large-scale integral structure parts in the field of aerospace. During the forming and processing of aluminum alloy plates, different degrees of residual stress are inevitably produced. Fast and accurate detection of residual stress is very essential to ensuring the quality of these plates. In this work, the longitudinal critically refracted (LCR) wave detection method based on a one-transmitter and double-receiver (OTDR) transducer and the finite element simulation were employed to obtain the residual stress. Aluminum alloy plates with different deformation amounts were fabricated by rotary forging to obtain different residual stress states. Results reveal that the plate formed by rotary forging is in a stress state of central tension and edge compression. As the deformation increases from 20% to 60%, the peak residual tensile stress increases from 156 MPa to 262 MPa, and there is no significant difference in the peak compressive stress. When the deformation reaches 60%, the difference in the residual stresses at different depths is less than 13%, which indicates that the plastic deformation zone basically penetrates the entire longitudinal cross-section of the plate. The maximum deviation between measurement and FE is 61 MPa, which means the experimental data are in good agreement with the FE results.
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Open AccessArticle
A Macroscopic Interpretation of the Correlation between Electrical Percolation and Mechanical Properties of Poly-(Ethylene Vinyl Acetate)/Zn Composites
by
Jerónimo Agrisuelas, Rafael Balart, José J. García-Jareño, Juan López-Martínez and Francisco Vicente
Materials 2024, 17(11), 2527; https://doi.org/10.3390/ma17112527 - 24 May 2024
Abstract
Elastic composites were prepared using a procedure involving hot plates and zinc powder that was directly dispersed into an EVA matrix. The correlation between the zinc content and the conductive properties of the material was studied via impedance spectroscopy, the thermal properties of
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Elastic composites were prepared using a procedure involving hot plates and zinc powder that was directly dispersed into an EVA matrix. The correlation between the zinc content and the conductive properties of the material was studied via impedance spectroscopy, the thermal properties of the material were studied via differential calorimetry and the mechanical properties of the composites were studied via tensile strength curves, representing an important advancement in the characterization of this type of composite material. The composites’ tensile strength and elongation at break decrease with the addition of filler since zinc particles act as stress-concentrating centres, while the composites’ hardness and Young’s modulus increase because of an increase in the stiffness of the material. The AC perturbation across the EVA/Zn composites was characterized using an RC parallel equivalent circuit that allowed us to easily measure their resistivity ( ) and permittivity ( ). The dependence of these electrical magnitudes on the zinc content is correlated with their mechanical properties across the characteristic time constant = of this equivalent circuit. The dependence of the mechanical and electrical magnitudes on the zinc content is consistent with the formation of percolation clusters. The addition of graphite particles increases their potential performance. Three possible mechanisms for the electrical transport of the ac-perturbation across the EVA/Zn composites have been identified. Chemical corrosion in acid media causes the loss of zinc surface particles, but their bulk physical properties practically remain constant.
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(This article belongs to the Section Advanced Composites)
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