Special Issue "Advancements in Catalytic Conversion of Biomass into Biofuels and Chemicals"

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "Bio-Energy".

Deadline for manuscript submissions: 31 January 2020.

Special Issue Editors

Prof. Dr. Tae Hyun Kim
E-Mail Website1 Website2
Guest Editor
Hanyang University, Seoul, South Korea
Interests: biofuel; bio-based product; biochemical; pretreatment; bioconversion process integration; biorefinery; bioprocessing
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Dr. Chang Geun Yoo
E-Mail Website
Guest Editor
Department of Paper and Bioprocess Engineering, State University of New York College of Environmental Science and Forestry, Syracuse, NY 13210, USA
Interests: biological/thermochemical conversion of biomass to fuels and chemicals; bio-based material application; elucidation of biomass and bio-product properties; development of lignocellulosic biorefinery
Special Issues and Collections in MDPI journals

Special Issue Information

Dear Colleagues,

Numerous efforts have been devoted to using biomass as a feedstock for the production of bio-based materials, biochemicals, and biofuels that reduce greenhouse gas emissions and dependence on conventional fossil resources.

Conversion strategies for the production of platform chemicals, building blocks, fine chemicals, and biofuels, include a wide range of processes, for example, chemical and mechanical pretreatment for improved carbohydrates production, fractionation of biomass into carbohydrates and lignin and their further conversions, microbial and enzymatic conversion of biomass into valuable products, direct catalytic conversion of biomass or its components into chemicals and fuels.

The goal of this Special Issue is to publish both recent innovative research results as well as review papers in the area of bioenergy and value-added chemicals from various feedstock through chemical and/or biological catalytic processes. Review and research papers on advances in the applications of carbohydrates and lignin components derived from biomass are also of interest.

If you would like to contribute a review paper, please contact one of the editors to discuss the relevance of the topic before submitting the manuscript.

Prof. Dr. Tae Hyun Kim
Prof. Dr. Chang Geun Yoo
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All papers will be peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Energies is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 1800 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • bioenergy
  • bio-based product
  • carbohydrates
  • lignin
  • catalytic conversion

Published Papers (3 papers)

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Research

Open AccessArticle
Extraction Behaviors of Lignin and Hemicellulose-Derived Sugars During Organosolv Fractionation of Agricultural Residues Using a Bench-Scale Ball Milling Reactor
Energies 2020, 13(2), 352; https://doi.org/10.3390/en13020352 - 10 Jan 2020
Abstract
Ethanol organosolv fractionation combined with ball milling was conducted on three major agricultural residues: Rice husk (RH), rice straw (RS), and barley straw (BS). The highest lignin extraction yields of RH, RS, and BS were 55.2%, 53.1%, and 59.4% and the purity of [...] Read more.
Ethanol organosolv fractionation combined with ball milling was conducted on three major agricultural residues: Rice husk (RH), rice straw (RS), and barley straw (BS). The highest lignin extraction yields of RH, RS, and BS were 55.2%, 53.1%, and 59.4% and the purity of lignin recovered was 99.5% for RH and RS, and 96.8% for BS, with similar chemical characteristics, i.e., low molecular weight distributions (1453–1817 g/mol) and poly dispersity index (1.15–1.28). However, considering the simultaneous production of hemicellulose-derived sugars, distinctive fractionation behaviors were shown for the three agricultural residues. The highest hemicellulose-derived sugar yield was 73.8% when RH was fractionated at 170 °C for 30 min. Meanwhile, very low sugar yields of 31.9% and 35.7% were obtained from RS and BS, respectively. The highest glucan-to-glucose conversion yield from enzymatic hydrolysis of fractionated RH reached 85.2%. Meanwhile, the enzymatic digestibility of the fractionated RS and BS was 60.0% and 70.5%, respectively. Consequently, the fractionation efficiency for RH can be improved with fine refinement. For the case of RS, other fractionation process should be applied to achieve effective fractionation performance. Full article
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Open AccessArticle
Application of Sulfated Tin (IV) Oxide Solid Superacid Catalyst to Partial Coupling Reaction of α-Pinene to Produce Less Viscous High-Density Fuel
Energies 2019, 12(10), 1905; https://doi.org/10.3390/en12101905 - 18 May 2019
Abstract
Brønsted acid-catalyzed reactions of α-pinene have been studied because of their ability to produce various types of fragrance molecules. Beyond this application, dimeric hydrocarbon products produced from coupling reactions of α-pinene have been suggested as renewable high-density fuel molecules. In this context, this [...] Read more.
Brønsted acid-catalyzed reactions of α-pinene have been studied because of their ability to produce various types of fragrance molecules. Beyond this application, dimeric hydrocarbon products produced from coupling reactions of α-pinene have been suggested as renewable high-density fuel molecules. In this context, this paper presents the application of a sulfated tin(IV) oxide catalyst for the partial coupling reaction of α-pinene from turpentine. Brønsted acid sites inherent in this solid superacid catalyst calcined at 550 °C successfully catalyzed the reaction, giving the largest yield of dimeric products (49.6%) at 120 °C over a reaction time of 4 h. Given that the low-temperature viscosity of the mentioned dimeric products is too high for their use as a fuel in transportation engines, lowering the viscosity is an important avenue of study. Therefore, our partial coupling reaction of α-pinene provides a possible solution as a considerable amount of the isomers of α-pinene still remained after the reaction, which reduces the low-temperature viscosity. On the basis of a comparison of the reaction products, a plausible mechanism for the reaction involving coinstantaneous isomerization and coupling reaction of α-pinene was elucidated. Full article
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Open AccessFeature PaperArticle
Improvement of Organosolv Fractionation Performance for Rice Husk through a Low Acid-Catalyzation
Energies 2019, 12(9), 1800; https://doi.org/10.3390/en12091800 - 11 May 2019
Cited by 2
Abstract
For the effective utilization of rice husk, organosolv fractionation was investigated to separate three main components (glucan, xylose, and lignin) with low acid concentration. Reaction temperatures of 170–190 °C, ethanol concentrations of 50%–70% (v/v), and sulfuric acid concentrations of [...] Read more.
For the effective utilization of rice husk, organosolv fractionation was investigated to separate three main components (glucan, xylose, and lignin) with low acid concentration. Reaction temperatures of 170–190 °C, ethanol concentrations of 50%–70% (v/v), and sulfuric acid concentrations of 0%–0.7% (w/v) were investigated, with the reaction time and liquid-to-solid ratio kept constant at 60 min and 10, respectively. The fractionation conditions for the efficient separation into the three components of rice husk were determined to be 180 °C, 60% (v/v) of ethanol, and 0.25% (w/v) of sulfuric acid. Under these fractionation conditions, 86.8% of the xylan and 77.5% of the lignin were removed from the rice husk, and xylose and lignin were obtained from the liquid in 67.6% and 49.8% yields, respectively. The glucan digestibility of the fractionated rice husk was 85.2% with an enzyme loading of 15 FPU (filter paper unit) of cellulase per g-glucan. Full article
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