This study investigated the carbonaceous species [elemental carbon (EC), organic carbon (OC), water soluble organic carbon (WSOC)] along with the trace elements (Al, S, Ti, Mn, Fe, Cu, Zn, As, Br, Pb, Cr, F, Cl, Na, K, Mg, Ca, P) in PM
10
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This study investigated the carbonaceous species [elemental carbon (EC), organic carbon (OC), water soluble organic carbon (WSOC)] along with the trace elements (Al, S, Ti, Mn, Fe, Cu, Zn, As, Br, Pb, Cr, F, Cl, Na, K, Mg, Ca, P) in PM
10 over the megacity Delhi, India (collected from 2015–2019) to address certain significant scientific issues (i.e., what are the directionality or pathway of these emissions; what are the possible emission sources which are distressing the observation site; what are the periodical variations in these emissions; and whether the emissions are local, regional, or trans-boundary). Integration of these problems are addressed using various statistical approaches including potential source areas (PSA) [using hybrid modelling i.e., potential source contribution factor (PSCF)], the conditional bivariate probability function (CBPF), and principal component analysis (PCA). Furthermore, seasonal PSCF and CBPF indicate both local source (highly polluted residential areas, traffic congestions, and industrial emissions) and regional sources (Haryana, Punjab) dominancy during winter and post-monsoon seasons at the receptor site, whereas during summer and monsoon along with local source and the regional, trans-boundaries (Indo-Gangatic plane, Pakistan, Afghanistan, and Bay of Bengal) air parcel patterns also contribute to the aerosol loading at the sites. Moreover, the PCA approach framed four common sources [crustal/road dust (RD), industrial emission (IE), fossil fuel combustion + biomass burning (FCC+ BB), vehicular emission (VE)] with one mixed source over the sampling site of Delhi.
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