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Batteries, Volume 3, Issue 4

2017 December - 13 articles

Cover Story: It was shown, for the first time, that a thin film Al/nc–Si/Al structure with a porous top contact may spontaneously generate electromotive force (emf) up to 1V, upon interaction with water vapor in the surrounding atmosphere. The possibility of emf observation is denoted to the inequality of two aluminum electrodes. We investigated volt–ampere characteristics in different conditions and proposed a model of emf generation in the structures. View this paper
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Articles (13)

  • Article
  • Open Access
9 Citations
7,983 Views
15 Pages

Effects of Cs2CO3 Additive in KOH Electrolyte Used in Ni/MH Batteries

  • Shuli Yan,
  • Jean Nei,
  • Peifeng Li,
  • Kwo-Hsiung Young and
  • K. Y. Simon Ng

18 December 2017

The effects of Cs2CO3 addition in a KOH-based electrolyte were investigated for applications in nickel/metal hydride batteries. Both MgNi-based and Laves phase-related body-centered cubic solid solution metal hydride alloys were tested as the anode a...

  • Article
  • Open Access
5 Citations
7,202 Views
16 Pages

Electron Backscatter Diffraction Studies on the Formation of Superlattice Metal Hydride Alloys

  • Shuli Yan,
  • Kwo-Hsiung Young,
  • Xin Zhao,
  • Zhi Mei and
  • K. Y. Simon Ng

13 December 2017

Microstructures of a series of La-Mg-Ni-based superlattice metal hydride alloys produced by a novel method of interaction of a LaNi5 alloy and Mg vapor were studied using a combination of X-ray energy dispersive spectroscopy and electron backscatter...

  • Article
  • Open Access
9 Citations
14,491 Views
13 Pages

A Bilevel Equalizer for Large Lithium Ion Batteries

  • Ngalula Sandrine Mubenga,
  • Zachary Linkous and
  • Thomas Stuart

7 December 2017

Due to variations among the cells, large lithium ion batteries (LIB) such as those in battery energy storage stations (BESS) and electric vehicles (EVs) must have an equalizer (EQU) circuit to balance the cell voltages. In spite of their significant...

  • Article
  • Open Access
7 Citations
8,121 Views
13 Pages

A Ni/MH Pouch Cell with High-Capacity Ni(OH)2

  • Shuli Yan,
  • Tiejun Meng,
  • Kwo-Hsiung Young and
  • Jean Nei

4 December 2017

Electrochemical performances of a high-capacity and long life β-α core-shell structured Ni0.84Co0.12Al0.04(OH)2 as the positive electrode active material were tested in a pouch design and compared to those of a standard β-Ni0.91Co0.045Zn0.045(OH)2. T...

  • Article
  • Open Access
10 Citations
11,593 Views
14 Pages

15 November 2017

As a concept for electrode architecture in high power lithium ion batteries, self-supported nanoarrays enable ultra-high power densities as a result of their open pore geometry, which results in short and direct Li+-ion and electron pathways. Vertica...

  • Article
  • Open Access
11 Citations
6,974 Views
15 Pages

Effects of Boron-Incorporation in a V-Containing Zr-Based AB2 Metal Hydride Alloy

  • Shiuan Chang,
  • Kwo-Hsiung Young,
  • Taihei Ouchi,
  • Jean Nei and
  • Xin Wu

14 November 2017

In this study, boron, a metalloid element commonly used in semiconductor applications, was added in a V-containing Zr-based AB2 metal hydride alloy. In general, as the boron content in the alloy increased, the high-rate dischargeability, surface exch...

  • Article
  • Open Access
8 Citations
6,871 Views
12 Pages

Performance Comparison between AB5 and Superlattice Metal Hydride Alloys in Sealed Cells

  • John M. Koch,
  • Kwo-Hsiung Young,
  • Jean Nei,
  • Chaolan Hu and
  • Benjamin Reichman

6 November 2017

High-power cylindrical nickel metal/hydride batteries using a misch metal-based Al-free superlattice alloy with a composition of La11.3Pr1.7Nd5.1Mg4.5Ni63.6Co13.6Zr0.2 were fabricated and evaluated against those using a standard AB5 metal hydride all...

  • Article
  • Open Access
11 Citations
7,919 Views
20 Pages

Comparison among Constituent Phases in Superlattice Metal Hydride Alloys for Battery Applications

  • Kwo-Hsiung Young,
  • Taihei Ouchi,
  • Jean Nei,
  • John M. Koch and
  • Yu-Ling Lien

31 October 2017

The effects of seven constituent phases—CeNi3, NdNi3, Nd2Ni7, Pr2Ni7, Sm5Ni19, Nd5Co19, and CaCu5—on the gaseous phase and electrochemical characteristics of a superlattice metal hydride alloy made by induction melting with a composition of Sm14La5.7...

  • Article
  • Open Access
4 Citations
8,825 Views
12 Pages

23 October 2017

Rutile FeOF was used as a conversion-type cathode material for Li-ion batteries. In the present study, 0.6Li, 1.4Li, and 2.7Li per mole lithiation reactions were carried out by changing the electrochemical discharge reaction depth. The thermal charac...

  • Article
  • Open Access
21 Citations
11,778 Views
14 Pages

16 October 2017

Effective prognosis of lithium-ion batteries involves the inclusion of the influences of uncertainties that can be incorporated through random effect parameters in a nonlinear mixed effect degradation model framework. This study is geared towards the...

  • Article
  • Open Access
1 Citations
6,490 Views
10 Pages

Spontaneous Generation of Electromotive Force in Thin Film Al/Nanosilicon/Al Structures

  • Sergey G. Dorofeev,
  • Nikolay N. Kononov,
  • Sergei S. Bubenov,
  • Pavel A. Kotin,
  • Aleksandr N. Zolotykh and
  • Denis V. Grigoriev

10 October 2017

Contemporary pursuits in electronics include the miniaturization as well as flexibilization of devices. Although there are a large number of different thin and flexible electrochemical batteries, only a few can boast the possibility of working in hig...

  • Feature Paper
  • Article
  • Open Access
9 Citations
7,259 Views
13 Pages

Effects of Alkaline Pre-Etching to Metal Hydride Alloys

  • Tiejun Meng,
  • Kwo-Hsiung Young,
  • Chaolan Hu and
  • Benjamin Reichman

The responses of one AB5, two AB2, four A2B7, and one C14-related body-centered-cubic (BCC) metal hydrides to an alkaline-etch (45% KOH at 110 °C for 2 h) were studied by internal resistance, X-ray diffraction, scanning electron microscope, inductive...

  • Article
  • Open Access
19 Citations
7,359 Views
15 Pages

Cell Performance Comparison between C14- and C15-Predomiated AB2 Metal Hydride Alloys

  • Kwo-Hsiung Young,
  • John M. Koch,
  • Chubin Wan,
  • Roman V. Denys and
  • Volodymyr A. Yartys

25 September 2017

The performance of cylindrical cells made from negative electrode active materials of two selected AB2 metal hydride chemistries with different dominating Laves phases (C14 vs. C15) were compared. Cells made from Alloy C15 showed a higher high-rate p...

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Batteries - ISSN 2313-0105