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Magnetochemistry, Volume 6, Issue 3

September 2020 - 16 articles

Cover Story: The cornerstone of molecular magnetism is understanding the magneto-structural relationship. The ideal way of probing this is to combine high pressure single crystal X-ray crystallography with high pressure magnetometry, high pressure inelastic neutron scattering, high pressure EPR spectroscopy, and high pressure absorption/emission/Raman spectroscopy. This review highlights the extraordinary effects that can result from putting molecular magnets under pressure. View this paper.
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Articles (16)

  • Feature Paper
  • Article
  • Open Access
6 Citations
3,088 Views
12 Pages

The effects of mechanochemical synthesis and postsynthetic grinding on the spin crossover material [Fe(atrz)3](BF4)2 was examined in detail using a combination of X-ray diffraction, magnetometry, EXAFS and TEM. Mechanochemical synthesis yielded a dif...

  • Article
  • Open Access
12 Citations
2,529 Views
9 Pages

The magnetic field dependence of chiral surface formation was investigated in magnetoelectrodeposition (MED) and magnetoelectrochemical etching (MEE) of copper films. The MED and MEE was conducted in magnetic fields of up to 5 T, which were parallel...

  • Article
  • Open Access
6 Citations
3,071 Views
8 Pages

Hydrogen Peroxide-Assisted Hydrothermal Synthesis of BiFeO3 Microspheres and Their Dielectric Behavior

  • Asad Syed,
  • Ashoka Siddaramanna,
  • Abdallah M. Elgorban,
  • D. A. Hakeem and
  • G. Nagaraju

Despite considerable efforts undertaken in a rapidly developing area of multiferroic research, synthesis of phase pure BiFeO3 is still a matter of intensive research. In this work, we report the shape-controlled synthesis of pure BiFeO3 microspheres...

  • Feature Paper
  • Article
  • Open Access
6,183 Views
20 Pages

Saccharomyces cerevisiae and Candida albicans Yeast Cells Labeled with Fe(III) Complexes as MRI Probes

  • Akanksha Patel,
  • Didar Asik,
  • Eric M. Snyder,
  • Joseph A. Spernyak,
  • Paul J. Cullen and
  • Janet R. Morrow

The development of MRI probes is of interest for labeling antibiotic-resistant fungal infections based on yeast. Our work showed that yeast cells can be labeled with high-spin Fe(III) complexes to produce enhanced T2 water proton relaxation. These Fe...

  • Communication
  • Open Access
2 Citations
3,622 Views
5 Pages

A general equation describing the motion of domain walls in a magnetic thin film in the presence of an external magnetic field has been reported in this paper. The equation includes all the contributions from the effects of domain wall inertia, dampi...

  • Article
  • Open Access
5 Citations
3,080 Views
5 Pages

In this work, we are presenting magnetic field dependent electrochemical method to grow enantiopure monolayer. Thiol gold monolayer formation by redox reaction is studied on gold coated ferromagnetic surface. Infrared and photoemission spectroscopies...

  • Article
  • Open Access
4 Citations
2,921 Views
13 Pages

Water Diffusion Modulates the CEST Effect on Tb(III)-Mesoporous Silica Probes

  • Fabio Carniato,
  • Giuseppe Ferrauto,
  • Mónica Muñoz-Úbeda and
  • Lorenzo Tei

The anchoring of lanthanide(III) chelates on the surface of mesoporous silica nanoparticles (MSNs) allowed their investigation as magnetic resonance imaging (MRI) and chemical exchange saturation transfer (CEST) contrast agents. Since their efficienc...

  • Perspective
  • Open Access
15 Citations
4,236 Views
14 Pages

Designing Magnetic NanoMOFs for Biomedicine: Current Trends and Applications

  • Mariangela Oggianu,
  • Noemi Monni,
  • Valentina Mameli,
  • Carla Cannas,
  • Suchithra Ashoka Sahadevan and
  • Maria Laura Mercuri

Metal–organic frameworks (MOFs) have shown a great potential in biomedicine due to their promising applications in different fields, including drug delivery, thermometry, theranostics etc. In this context, the development of magnetic sub-microm...

  • Article
  • Open Access
8 Citations
3,805 Views
11 Pages

Can the Double Exchange Cause Antiferromagnetic Spin Alignment?

  • Andrew Palii,
  • Juan M. Clemente-Juan,
  • Sergey Aldoshin,
  • Denis Korchagin,
  • Evgenii Golosov,
  • Shmuel Zilberg and
  • Boris Tsukerblat

The effect of the double exchange in a square-planar mixed-valence dn+1−dn+1−dn−dn–type tetramers comprising two excess electrons delocalized over four spin cores is discussed. The detailed analysis of a relatively simple d2&m...

  • Review
  • Open Access
57 Citations
7,796 Views
26 Pages

The transfer of the inherent bistability of spin crossover compounds to surfaces has attracted considerable interest in recent years. The deposition of the complexes on surfaces allows investigating them individually and to further understand the mic...

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Magnetochemistry - ISSN 2312-7481