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C, Volume 6, Issue 2

2020 June - 27 articles

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Articles (27)

  • Article
  • Open Access
31 Citations
8,021 Views
20 Pages

Biochar and Energy Production: Valorizing Swine Manure through Coupling Co-Digestion and Pyrolysis

  • Rubén González,
  • Judith González,
  • José G. Rosas,
  • Richard Smith and
  • Xiomar Gómez

24 June 2020

Anaerobic digestion is an established technological option for the treatment of agricultural residues and livestock wastes beneficially producing renewable energy and digestate as biofertilizer. This technology also has significant potential for beco...

  • Article
  • Open Access
17 Citations
5,166 Views
18 Pages

A Comparative Study of the ZnO Growth on Graphene and Graphene Oxide: The Role of the Initial Oxidation State of Carbon

  • Miguel Angel Gomez-Alvarez,
  • Carlos Morales,
  • Javier Méndez,
  • Adolfo del Campo,
  • Fernando J. Urbanos,
  • Aarón Díaz,
  • Luis Reséndiz,
  • Jan Ingo Flege,
  • Daniel Granados and
  • Leonardo Soriano

20 June 2020

The role of the oxidation state of carbon on the early stages of growth of metal oxides was studied for the particular case of ZnO deposition on graphene and graphene oxide on SiO2 (G/SiO2 and GO/SiO2, respectively) substrates. The growth was carried...

  • Article
  • Open Access
9 Citations
7,165 Views
21 Pages

20 June 2020

New methods in lowering energy consumption costs for evaporation and concentration are needed in many commercial chemical processes. Pervaporation is an underutilized, low-energy processing method that has a potential capability in achieving lower en...

  • Article
  • Open Access
13 Citations
4,331 Views
17 Pages

Nitrogen-Doped Flower-Like Hybrid Structure Based on Three-Dimensional Graphene

  • Kinshuk Dasgupta,
  • Mahnoosh Khosravifar,
  • Shrilekha Sawant,
  • Paa Kwasi Adusei,
  • Sathya Narayan Kanakaraj,
  • Jacob Kasik and
  • Vesselin Shanov

19 June 2020

A new flower-like hybrid structure consisting of nitrogen-doped 3-dimensional (3D) graphene and vertically aligned graphene has been synthesized using a combination of low-pressure chemical vapor deposition (LPCVD) and plasma-enhanced chemical vapor...

  • Article
  • Open Access
19 Citations
7,471 Views
8 Pages

10 June 2020

This paper argues that electrification and gasification go hand in hand and are crucial on our pathway to a carbon-neutral energy transition. Hydrogen made from renewable electricity will be crucial on this path but is not sufficient, mainly due to i...

  • Article
  • Open Access
8 Citations
4,403 Views
11 Pages

In Situ Formation of Metal Hydrides Inside Carbon Aerogel Frameworks for Hydrogen Storage Applications

  • Mohammad Reza Ghaani,
  • Mahdi Alam,
  • Michele Catti and
  • Niall J. English

9 June 2020

Nano-confined chemical reactions bear great promise for a wide range of important applications in the near-to-medium term, e.g., within the emerging area of chemical storage of renewable energy. To explore this important trend, in the present work, r...

  • Article
  • Open Access
2 Citations
6,105 Views
9 Pages

Plasma Treatments and Light Extraction from Fluorinated CVD-Grown (400) Single Crystal Diamond Nanopillars

  • Mariusz Radtke,
  • Abdallah Slablab,
  • Sandra Van Vlierberghe,
  • Chao-Nan Lin,
  • Ying-Jie Lu and
  • Chong-Xin Shan

3 June 2020

We investigate the possibilities to realize light extraction from single crystal diamond (SCD) nanopillars. This was achieved by dedicated 519 nm laser-induced spin-state initiation of negatively charged nitrogen vacancies (NV). We focus on the natu...

  • Article
  • Open Access
14 Citations
6,370 Views
21 Pages

26 May 2020

There is currently quite a lot of scientific interest in carbon dioxide (CO2) capture and valorization with ionic liquids (ILs). In this manuscript, we analyze the influence of the potential applied, the nature of the cathode and the electrolyte usin...

  • Article
  • Open Access
3,274 Views
7 Pages

The Effect of Hydrogen on the Electrical Properties of the Graphene Nanomeshes

  • Pavel V. Barkov,
  • Michael M. Slepchenkov and
  • Olga E. Glukhova

26 May 2020

This paper is devoted to the in silico study of the electronic properties and electrical conductivity of hydrogenated graphene nanomesh (GNM). It is found that the conductivity of GNM can be controlled by varying the type of hydrogenation. Due to the...

  • Review
  • Open Access
24 Citations
9,215 Views
12 Pages

A Review of the Use of Immobilized Ionic Liquids in the Electrochemical Conversion of CO2

  • Jerry J. Kaczur,
  • Hongzhou Yang,
  • Zengcai Liu,
  • Syed D. Sajjad and
  • Richard I. Masel

24 May 2020

This paper is a review on the application of imidazolium-based ionic liquids tethered to polymer backbones in the electrochemical conversion of CO2 to carbon monoxide and formic acid. These tethered ionic liquids have been incorporated into novel ani...

  • Communication
  • Open Access
4 Citations
3,295 Views
11 Pages

19 May 2020

Porous carbon monoliths can be used as key components in a variety of applications, such as energy storage, adsorption and catalysis. The preparation of porous carbon monoliths suffers from several limitations, e.g., time-consuming synthesis steps, t...

  • Article
  • Open Access
9 Citations
3,698 Views
16 Pages

Graphene Nanoplatelets-Based Ni-Zeolite Composite Catalysts for Heptane Hydrocracking

  • Roba Saab,
  • Kyriaki Polychronopoulou,
  • Nikolaos Charisiou,
  • Maria A. Goula and
  • Andreas Schiffer

18 May 2020

This paper examines the effect of incorporating graphene nanoplatelets (GNPs) in an Ni-based/Zeolite-Y catalyst on the hydrocracking of heptane fuel at two temperatures, 350 and 400 °C. Specifically, reduced GNP/NiO-ZY and NiO-ZY catalysts, each...

  • Article
  • Open Access
5 Citations
4,093 Views
9 Pages

11 May 2020

It has been reported that even if single-walled carbon nanotubes (SWNTs) are coated with the same polymer, the redox characteristics change of each chirality may differ. Particularly, the addition of hydrogen peroxide (H2O2) minimally affects the nea...

  • Communication
  • Open Access
6 Citations
3,551 Views
10 Pages

9 May 2020

A semiconductor bonding technique that is mediated by graphene quantum dots is proposed and demonstrated. The mechanical stability, electrical conductivity, and optical activity in the bonded interfaces are experimentally verified. First, the bonding...

  • Review
  • Open Access
54 Citations
14,964 Views
20 Pages

Proton Exchange Membrane Electrolyzer Modeling for Power Electronics Control: A Short Review

  • Burin Yodwong,
  • Damien Guilbert,
  • Matheepot Phattanasak,
  • Wattana Kaewmanee,
  • Melika Hinaje and
  • Gianpaolo Vitale

9 May 2020

The main purpose of this article is to provide a short review of proton exchange membrane electrolyzer (PEMEL) modeling used for power electronics control. So far, three types of PEMEL modeling have been adopted in the literature: resistive load, sta...

  • Article
  • Open Access
14 Citations
5,617 Views
13 Pages

Expendable Graphite as an Efficient Flame-Retardant for Novel Partial Bio-Based Rigid Polyurethane Foams

  • Felipe M. de Souza,
  • Jonghyun Choi,
  • Sanket Bhoyate,
  • Pawan K. Kahol and
  • Ram K. Gupta

1 May 2020

The rigid polyurethane foam (PU) is a versatile material, used especially for construction and household applications. The current situation demands a facile, cost-efficient, and greener approach for developing the polyurethanes from bio-derived mate...

  • Article
  • Open Access
23 Citations
5,636 Views
15 Pages

Power Cycling and Reliability Testing of Epoxy-Based Graphene Thermal Interface Materials

  • Jacob S. Lewis,
  • Timothy Perrier,
  • Amirmahdi Mohammadzadeh,
  • Fariborz Kargar and
  • Alexander A. Balandin

25 April 2020

We report on the lifespan evolution of thermal diffusivity and thermal conductivity in curing epoxy-based thermal interface materials with graphene fillers. The performance and reliability of graphene composites have been investigated in up to 500 po...

  • Article
  • Open Access
2 Citations
3,193 Views
14 Pages

Silicon/Biogas-Derived Carbon Nanofibers Composites for Anodes of Lithium-Ion Batteries

  • Ignacio Cameán,
  • Nuria Cuesta,
  • Alberto Ramos and
  • Ana B. García

24 April 2020

The electrochemical performance of novel nano-silicon/biogas-derived carbon nanofibers composites (nSi/BCNFs) as anodes in lithium-ion batteries was investigated, focusing on composition and galvanostatic cycling conditions. The optimization of these...

  • Article
  • Open Access
10 Citations
6,444 Views
30 Pages

22 April 2020

Methane is the second most important greenhouse gas. Natural methane emissions represent 35–50% of the global emissions budget. They are identified, measured and categorized, but, in stark contrast to anthropogenic emissions, research on their...

  • Review
  • Open Access
16 Citations
5,195 Views
24 Pages

15 April 2020

The combined effects of geometrical structure and chemical composition on the diamond surface electronic structures have been investigated in the present study by using high-level theoretical calculations. The effects of diamond surface planes [(111)...

  • Review
  • Open Access
18 Citations
5,776 Views
16 Pages

14 April 2020

Thermo-catalytic decomposition is well-suited for the generation of hydrogen from natural gas. In a decarbonization process for fossil fuel—pre-combustion—solid carbon is produced, with potential commercial uses including energy storage....

  • Feature Paper
  • Review
  • Open Access
164 Citations
25,820 Views
25 Pages

Review on Activated Carbons by Chemical Activation with FeCl3

  • Jorge Bedia,
  • Manuel Peñas-Garzón,
  • Almudena Gómez-Avilés,
  • Juan J. Rodriguez and
  • Carolina Belver

10 April 2020

This study reviews the most relevant results on the synthesis, characterization, and applications of activated carbons obtained by novel chemical activation with FeCl3. The text includes a description of the activation mechanism, which compromises th...

  • Article
  • Open Access
3 Citations
3,699 Views
10 Pages

Adsorption of H2 on Penta-Octa-Penta Graphene: Grand Canonical Monte Carlo Study

  • Maxim N. Popov,
  • Thomas Dengg,
  • Dominik Gehringer and
  • David Holec

1 April 2020

In this paper, we report the results of hydrogen adsorption properties of a new 2D carbon-based material, consisting of pentagons and octagons (Penta-Octa-Penta-graphene or POP-graphene), based on the Grand-Canonical Monte Carlo simulations. The new...

  • Feature Paper
  • Article
  • Open Access
10 Citations
3,749 Views
10 Pages

Hydrogen Sorption and Reversibility of the LiBH4-KBH4 Eutectic System Confined in a CMK-3 Type Carbon via Melt Infiltration

  • Filippo Peru,
  • SeyedHosein Payandeh,
  • Georgia Charalambopoulou,
  • Torben R. Jensen and
  • Theodore Steriotis

31 March 2020

Metal borohydrides have very high hydrogen densities but their poor thermodynamic and kinetic properties hinder their use as solid hydrogen stores. An interesting approach to improve their functionality is nano-sizing by confinement in mesoporous mat...

  • Review
  • Open Access
18 Citations
5,532 Views
14 Pages

30 March 2020

The mechanism of bamboo-like growth behavior of carbon fibers is discussed. We propose that there is a requirement to have this type of growth: operation above the Tammann temperature of the catalyst (defined as half of the melting point). The metal...

  • Article
  • Open Access
25 Citations
4,997 Views
12 Pages

Supercapacitor Electrodes from Viscose-Based Activated Carbon Fibers: Significant Yield and Performance Improvement Using Diammonium Hydrogen Phosphate as Impregnating Agent

  • Stefan Breitenbach,
  • Alexander Lumetzberger,
  • Mathias Andreas Hobisch,
  • Christoph Unterweger,
  • Stefan Spirk,
  • David Stifter,
  • Christian Fürst and
  • Achim Walter Hassel

27 March 2020

Viscose fibers were impregnated with different concentrations of diammonium hydrogen phosphate (DAHP), carbonized, activated, and tested as high-performance electrode materials for supercapacitors. The yield of these activated carbon fibers (ACFs) co...

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C - ISSN 2311-5629