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ChemEngineering, Volume 3, Issue 4

2019 December - 15 articles

Cover Story: In this work, a new chlorine-free process for producing the monomers tetrafluorethene (TFE, C2F4) and hexafluorpropene (HFP, C3F6) in a plug flow microreactor will be presented, starting from partially fluorinated alkanes obtained from electrochemical fluorination (ECF). Depending on the feedstock of the ECF, up to 70% of partially fluorinated alkanes can be obtained in the product spectrum. No industrial process currently exists for utilizing these by-products besides incineration. Therefore, great attempts are made to achieve a material instead of thermal utilization. View this paper
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Articles (15)

  • Article
  • Open Access
28 Citations
6,296 Views
9 Pages

Chitin is an abundant organic resource but shows poor solubility, leading to difficulty in utilization as materials. We have already reported that an ionic liquid (IL), 1-allyl-3-methylimidazolium bromide, dissolves chitin at concentrations up to ca....

  • Article
  • Open Access
10 Citations
3,393 Views
12 Pages

Nonthermal pulsed filamentary microplasma treatment for drying is a nonthermal technology with promising perspectives to dehydrate plant agricultural materials. The modified set of Luikov’s equations for heat, mass and pressure transfer, has be...

  • Article
  • Open Access
14 Citations
3,728 Views
19 Pages

Nowadays, the contamination of groundwater and soils by chlorinated organic solvents is a severe and worldwide problem. Due to their swelling properties, Layered Double Hydroxides (LDHs) are potentially excellent compounds to retain chlorinated organ...

  • Article
  • Open Access
9 Citations
7,217 Views
16 Pages

Effect of Pyrolysis Temperature on the Electrical Property and Photosensitivity of a PAN-PMMA Derived Carbon Fiber

  • Tyler Xu,
  • Antonino Nguyen,
  • Noe Rosas,
  • Isidro Flores,
  • Cindy Chen,
  • Jeremy B. Gan,
  • Anan S. Hamdan and
  • Yong X. Gan

Fibers are promising materials being utilized in electronics, principally in the areas of capacitors and sensors. In this study, we examine the effect of pyrolysis temperature on the electrical conductive behavior and photosensitivity of a carbon-bas...

  • Article
  • Open Access
65 Citations
26,741 Views
11 Pages

Clean Hydrogen and Ammonia Synthesis in Paraguay from the Itaipu 14 GW Hydroelectric Plant

  • Massimo Rivarolo,
  • Gustavo Riveros-Godoy,
  • Loredana Magistri and
  • Aristide F. Massardo

This paper aims at investigating clean hydrogen production from the large size (14 GW) hydroelectric power plant of Itaipu, located on the border between Paraguay and Brazil, the two countries that own and manage the plant. The hydrogen, produced by...

  • Feature Paper
  • Article
  • Open Access
14 Citations
4,315 Views
16 Pages

Performance Evaluation of a Small-Scale Latent Heat Thermal Energy Storage Unit for Heating Applications Based on a Nanocomposite Organic PCM

  • Maria K. Koukou,
  • George Dogkas,
  • Michail Gr. Vrachopoulos,
  • John Konstantaras,
  • Christos Pagkalos,
  • Kostas Lymperis,
  • Vassilis Stathopoulos,
  • George Evangelakis,
  • Costas Prouskas and
  • Amandio Rebola
  • + 1 author

A small-scale latent heat thermal energy storage (LHTES) unit for heating applications was studied experimentally using an organic phase change material (PCM). The unit comprised of a tank filled with the PCM, a staggered heat exchanger (HE) for tran...

  • Article
  • Open Access
6 Citations
4,491 Views
20 Pages

An Engineering Toolbox for the Evaluation of Metallic Flow Field Plates

  • Uwe Reimer,
  • Dieter Froning,
  • Gert Nelissen,
  • Leonard F. J. M. Raymakers,
  • Shidong Zhang,
  • Steven B. Beale and
  • Werner Lehnert

Metallic flow field plates, also called bipolar plates, are an important component of fuel cell stacks, electrolyzers, hydrogen purification and compression stacks. The manufacturing of these plates by means of stamping or hydroforming is highly suit...

  • Article
  • Open Access
6 Citations
3,903 Views
9 Pages

Preliminary Study on the Application of Concentrated Solar Power in Metallurgy of Titanium

  • Jaroslav Kováčik,
  • Natália Mináriková,
  • Tomáš Dvorák,
  • Jose Rodríguez,
  • Inmaculada Cañadas,
  • Klaled Saleh Al-Athel,
  • Peter Šugár,
  • Jana Šugárová and
  • Štefan Emmer

The applicability of concentrated solar power for metallurgy of titanium is discussed based on preliminary experimental works performed at Plataforma Solar de Almeria Spain, using solar furnace SF40 under protective argon atmosphere. As a starting ma...

  • Review
  • Open Access
30 Citations
8,969 Views
19 Pages

Considering works published in the literature for more than a decade (period from January 2008 till June 2019), this paper provides an overview of recent applications of the so-called “solar furnaces”, their reactors, process chambers and...

  • Article
  • Open Access
2 Citations
5,598 Views
17 Pages

The growing demands for oleochemical products are expected to reach approximately RM 157.59 billion by 2026 due to an increased drive from the food and beverages, chemicals, and pharmaceutical industries. However, this will lead to an increase in ene...

  • Article
  • Open Access
9 Citations
7,138 Views
14 Pages

Conductivity, Viscosity, Spectroscopic Properties of Organic Sulfonic Acid solutions in Ionic Liquids

  • Anh T. Tran,
  • Jay Tomlin,
  • Phuoc H. Lam,
  • Brittany L. Stinger,
  • Alexandra D. Miller,
  • Dustin J. Walczyk,
  • Omar Cruz,
  • Timothy D. Vaden and
  • Lei Yu

Sulfonic acids in ionic liquids (ILs) are used as catalysts, electrolytes, and solutions for metal extraction. The sulfonic acid ionization states and the solution acid/base properties are critical for these applications. Methane sulfonic acid (MSA)...

  • Article
  • Open Access
9 Citations
5,882 Views
12 Pages

There has been an active interest in protecting metals and alloys using graphene coating. The mechanism by which corrosion protection occurs has not been well understood as the couple involved are both good electron conductors. In this work, we demon...

  • Article
  • Open Access
13 Citations
4,597 Views
12 Pages

The Effect of Cu and Ga Doped ZnIn2S4 under Visible Light on the High Generation of H2 Production

  • Ikki Tateishi,
  • Mai Furukawa,
  • Hideyuki Katsumata and
  • Satoshi Kaneco

A Cu+ and Ga3+ co-doped ZnIn2S4 photocatalyst (Zn(1−2x)(CuGa)xIn2S4) with controlled band gap was prepared via a simple one-step solvothermal method. Zn(1−2x)(CuGa)xIn2S4 acted as an efficient photocatalyst for H2 evolution under visible...

  • Article
  • Open Access
8 Citations
5,316 Views
19 Pages

Energy and Resource Efficient Production of Fluoroalkenes in High Temperature Microreactors

  • Konstantin Mierdel,
  • Andreas Jess,
  • Thorsten Gerdes,
  • Achim Schmidt and
  • Klaus Hintzer

Tetrafluoroethylene (TFE) and hexafluoropropylene (HFP) are the most common monomers for the synthesis of fluoropolymers at industrial scale. Currently, TFE is produced via multistep pyrolysis of chlorodifluoromethane (R22), resulting in a high energ...

  • Article
  • Open Access
5 Citations
3,507 Views
13 Pages

This study explores the concept of ecological limits (ELs) for determining the sustainable extraction of natural resources and sustainable discharge of emissions. ELs are expressed as limiting mass flowrates and equations are developed and presented...

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ChemEngineering - ISSN 2305-7084