Table of Contents
ChemEngineering, Volume 3, Issue 3 (September 2019) – 17 articles
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Cover Story (view full-size image) Separation is the most energetically demanding step in a carbon capture and utilization process. [...] Read more. Separation is the most energetically demanding step in a carbon capture and utilization process. Catalysts able to selectively fix carbon dioxide from unpurified CO2-rich mixtures would thus allow the cost of such a process to be decreased significantly. CO2 is an important byproduct in epoxide synthesis, accounting for 0.02% of worldwide greenhouse emissions. As a proof of concept, we report on the first metal–organic framework able to catalyze the cycloaddition of CO2 to ethylene and propylene oxides in the absence of a solvent or cocatalyst. View this paper.