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Inorganics, Volume 12, Issue 1

January 2024 - 35 articles

Cover Story: This study introduces Ba5Sb8, a novel binary compound within the Ba–Sb phase diagram, exemplifying the highest known member of the BanSb2n−2 (n ≥ 2) homologous series. It crystallizes in an orthorhombic space group (Fdd2) and is distinguished by its unique [Sb8]10− polyanionic fragments—a first in antimonides. These fragments, coupled with Ba2+ cations, comply with the Zintl–Klemm formalism, achieving a charge-balanced composition. Electronic structure calculations revealed an indirect narrow bandgap, highlighting the potential of the title phase in semiconductor applications and advancing our understanding of Zintl antimonides. View this paper
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Articles (35)

  • Article
  • Open Access
11 Citations
3,776 Views
23 Pages

Self-Cleaning and Charge Transport Properties of Foils Coated with Acrylic Paint Containing TiO2 Nanoparticles

  • Sanja J. Armaković,
  • Maria M. Savanović,
  • Mirjana V. Šiljegović,
  • Milica Kisić,
  • Maja Šćepanović,
  • Mirjana Grujić-Brojčin,
  • Nataša Simić,
  • Lazar Gavanski and
  • Stevan Armaković

The study comprehensively investigates the design and performance of self-cleaning surfaces fabricated by coating aluminum foil with an acrylic paint matrix enriched with different content of titanium dioxide (TiO2) nanoparticles. The main goal was t...

  • Review
  • Open Access
4 Citations
4,178 Views
24 Pages

Viruses rely on host cells to replicate their genomes and assemble new viral particles. Thus, they have evolved intricate mechanisms to exploit host factors. Host cells, in turn, have developed strategies to inhibit viruses, resulting in a nuanced in...

  • Article
  • Open Access
4 Citations
3,468 Views
12 Pages

Large Area Growth of Silver and Gold Telluride Ultrathin Films via Chemical Vapor Tellurization

  • Sara Ghomi,
  • Alessio Lamperti,
  • Mario Alia,
  • Carlo Spartaco Casari,
  • Carlo Grazianetti,
  • Alessandro Molle and
  • Christian Martella

Developing a method for the growth of ultrathin metal chalcogenides, potentially targeting the two-dimensional (2D) limit, has a pivotal impact on various nanotechnological device applications. Here, we employed a vapor deposition scheme, based on te...

  • Article
  • Open Access
2 Citations
2,811 Views
18 Pages

The organoplatinum chemistry of the ligands 2-C5H4N-CH2-NH-C6H3-2-OH-5-X (L1, X = H; L3, X = NO2) and 2-C5H4N-CH=N-C6H3-2-OH-5-X (L2, X = H; L4, X = NO2), which contain an appended phenol substituent, is described. Comparisons are made between the li...

  • Article
  • Open Access
5 Citations
3,687 Views
18 Pages

Deciphering Interactions Involved in Immobilized Metal Ion Affinity Chromatography and Surface Plasmon Resonance for Validating the Analogy between Both Technologies

  • Rachel Irankunda,
  • Jairo Andrés Camaño Echavarría,
  • Cédric Paris,
  • Katalin Selmeczi,
  • Loïc Stefan,
  • Sandrine Boschi-Muller,
  • Laurence Muhr and
  • Laetitia Canabady-Rochelle

Various peptides can be obtained through protein enzymatic hydrolysis. Immobilized metal ion affinity chromatography (IMAC) is one of the methods which can be used to separate metal chelating peptides (MCPs) in a hydrolysate mixture. In this context,...

  • Article
  • Open Access
21 Citations
3,344 Views
24 Pages

Safranine T dye causes health problems such as skin and respiratory irritations. Hence, the safranine T dye was efficiently removed from aqueous media employing a simply synthesized manganese ferrite (MnFe2O4) nanoadsorbent. The synthesis of manganes...

  • Review
  • Open Access
4 Citations
3,679 Views
28 Pages

Cancer is one of the leading causes of human death among all major diseases. Metal-based complexes are considered as the most promising vital part in the existing arsenal of cytotoxic candidates used in cancer therapy and diagnostics. The efforts of...

  • Article
  • Open Access
1 Citations
3,610 Views
13 Pages

Cobalt(II) thiocyanate-based tests are routinely used to screen cocaine products, with the formation of a blue species interpreted as a positive response. Two popular candidates for the origin of the blue color are an ionic coordination compound, fre...

  • Article
  • Open Access
1 Citations
2,905 Views
12 Pages

A Neutral Pyridine-Pyrazole-Based N^N*N^N Ligand as a Tetradentate Chromophore for Diverse Transition Metal Cations

  • Tobias Theiss,
  • María Victoria Cappellari,
  • Jutta Kösters,
  • Alexander Hepp and
  • Cristian A. Strassert

Herein, the synthesis and the structural as well as the photophysical characterization of five transition metal complexes bearing a neutral pyridine-pyrazole-based N^N*N^N ligand (L) acting as a tetradentate chelator are reported. The luminophore can...

  • Review
  • Open Access
5 Citations
4,080 Views
29 Pages

Exploring the Use of Intracellular Chelation and Non-Iron Metals to Program Ferroptosis for Anticancer Application

  • Oscar Claudio-Ares,
  • Jeileen Luciano-Rodríguez,
  • Yolmarie L. Del Valle-González,
  • Selene L. Schiavone-Chamorro,
  • Alex J. Pastor,
  • Javier O. Rivera-Reyes,
  • Carmen L. Metzler,
  • Lizandra M. Domínguez-Orona,
  • Brenda Lee Vargas-Pérez and
  • Rachid Skouta
  • + 1 author

The discovery of regulated cell death (RCD) revolutionized chemotherapy. With caspase-dependent apoptosis initially being thought to be the only form of RCD, many drug development strategies aimed to synthesize compounds that turn on this kind of cel...

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Inorganics - ISSN 2304-6740