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Separations, Volume 11, Issue 4

2024 April - 40 articles

Cover Story: Oil pollution, resulting from oil spills and large discharges of oily wastewater, poses a significant threat to the global ecological and economic environment. Recently, superwetting materials manufactured via ultrafast lasers for oil–water separation have garnered widespread attention due to their easy preparation strategies and excellent separation properties. This review makes progress in systematically discussing and comparing the preparation techniques of the superhydrophobic/superoleophilic, superhydrophilic/superoleophobic, and superamphiphilic or reversible-wettability materials with their corresponding separation performance, serving as a reference for the development of innovative superwetting materials for versatile oil–water separation in complex scenarios using ultrafast laser processing. View this paper
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Articles (40)

  • Article
  • Open Access
2 Citations
2,336 Views
27 Pages

The Removal of As(III) Using a Natural Laterite Fixed-Bed Column Intercalated with Activated Carbon: Solving the Clogging Problem to Achieve Better Performance

  • Régie Dimanche Ouedraogo,
  • Corneille Bakouan,
  • Abdoul Karim Sakira,
  • Brahima Sorgho,
  • Boubié Guel,
  • Touridomon Issa Somé,
  • Anne-Lise Hantson,
  • Eric Ziemons,
  • Dominique Mertens and
  • Jean-Michel Kauffmann
  • + 1 author

Natural laterite fixed-bed columns intercalated with two types of layers (inert materials, such as fine sand and gravel, and adsorbent materials, such as activated carbon prepared from Balanites aegyptiaca (BA-AC)) were used for As(III) removal from...

  • Review
  • Open Access
24 Citations
20,349 Views
21 Pages

Bioactives in Cocoa: Novel Findings, Health Benefits, and Extraction Techniques

  • Kristina Tušek,
  • Davor Valinger,
  • Tamara Jurina,
  • Tea Sokač Cvetnić,
  • Jasenka Gajdoš Kljusurić and
  • Maja Benković

Theobroma cacao L. seeds, commonly known as cocoa beans, are the foundation for cocoa and chocolate production. Following harvest, these beans undergo a multi-step processing chain including fermentation, drying, roasting, and grinding. This process...

  • Article
  • Open Access
1 Citations
2,697 Views
21 Pages

A rare medicinal fungus called Taiwanofungus camphoratus gives people resistance to illness. In order to effectively obtain high−quality T. camphoratus mycelia, we added Cymbopogon citratus (lemongrass) water extract (LWE), which was prepared u...

  • Review
  • Open Access
14 Citations
3,763 Views
24 Pages

Laser Manufacturing of Superwetting Oil–Water Separation Materials: A Review

  • Wei Xiong,
  • Linfeng Zhu,
  • Ruisong Jiang and
  • Chaolang Chen

The frequent occurrence of oil spills and the massive discharge of oily wastewater pose a significant threat to sustainable and healthy human development. Therefore, it is of importance to effectively separate oil–water mixtures. Inspired by na...

  • Article
  • Open Access
4 Citations
3,077 Views
19 Pages

Two aluminum-coated silica adsorbents were evaluated using silica sand and microcrystalline silica as aluminum-oxide-based adsorbents with different crystalline silica base materials. The aluminum coating contained mainly amorphous aluminum oxides fo...

  • Communication
  • Open Access
2 Citations
2,244 Views
10 Pages

The separation of Li+ and [Bmim]+(1-Butyl-3-methylimidazolium) using a cation exchange membrane in an electric field is studied in this work. The effects of the type of cation exchange membrane, current density, total cation concentration, temperatur...

  • Article
  • Open Access
5 Citations
3,766 Views
15 Pages

Extraction of Copper from Copper Concentrate by Indigenous Association of Iron-Oxidizing Bacteria

  • Arevik Vardanyan,
  • Ruiyong Zhang,
  • Anna Khachatryan,
  • Zaruhi Melkonyan,
  • Arshavir Hovhannisyan,
  • Sabine Willscher,
  • Andreas Kamradt,
  • Manuel Jost,
  • Yimeng Zhang and
  • Narine Vardanyan
  • + 1 author

Bioleaching of Cu from the copper concentrate of Armanis gold-bearing polymetallic ore (Armenia) was investigated. The main objective was revealing high active bacteria and their association, as well as optimizing the bioleaching process with their a...

  • Review
  • Open Access
18 Citations
10,763 Views
25 Pages

The Removal of Per- and Poly-Fluoroalkyl Substances from Water: A Review on Destructive and Non-Destructive Methods

  • Natalia Malouchi,
  • Stella Chatzimichailidou,
  • Athanasia K. Tolkou,
  • George Z. Kyzas,
  • Loris Calgaro,
  • Antonio Marcomini and
  • Ioannis A. Katsoyiannis

PFAS, or per- and poly-fluoroalkyl substances, are a broad group of man-made organic compounds that are very persistent, mobile, and tend to bioaccumulate. Their removal from different environmental media is becoming increasingly important because th...

  • Article
  • Open Access
3,854 Views
15 Pages

Industrial wastewater typically contains many organic and inorganic pollutants and is also contaminated by various microorganisms. Microbial species in industrial wastewater have not been extensively investigated. In this experiment, a Klebsiella pne...

  • Article
  • Open Access
1 Citations
3,487 Views
18 Pages

The characteristics of iron minerals in cyanidation tailings with a low iron grade were determined via chemical composition analysis, iron phase analysis, and mineral liberation analysis (MLA). The results showed that the cyanidation tailings contain...

  • Article
  • Open Access
3 Citations
4,215 Views
15 Pages

Combination of Natural Deep Eutectic Solvents and Nano-Liquid Chromatography towards White Analytical Chemistry: A Practical Application

  • Álvaro Santana-Mayor,
  • Giovanni D’Orazio,
  • Salvatore Fanali,
  • Miguel Ángel Rodríguez-Delgado and
  • Bárbara Socas-Rodríguez

In this work, a green and practical analytical method based on natural deep eutectic solvents (NADES) as extraction agents and nano-liquid chromatography as a separation technique was developed. To demonstrate the applicability of the methodology, al...

  • Article
  • Open Access
4 Citations
2,568 Views
22 Pages

Antioxidant and Hepatoprotective Activity of an Extract from the Overground Parts of Phlomis russeliana Lag. ex Benth

  • Magdalena Kondeva-Burdina,
  • Aleksandar Shkondrov,
  • Georgi Popov,
  • Vasil Manov and
  • Ilina Krasteva

An evaluation of the possible hepatotoxicity/hepatoprotective effects of a defatted extract of the above ground parts of Phlomis russeliana was conducted in vitro and in vivo. The extract was tested in vitro on hepatocytes alone and in a carbon tetra...

  • Article
  • Open Access
3 Citations
2,719 Views
13 Pages

The escalating demand for cobalt in modern industry necessitates the recycling or extraction of this resource for sustainable development. Despite the abundance of lignin in nature, its utilization remains low, highlighting the need to enhance its va...

  • Article
  • Open Access
17 Citations
5,600 Views
17 Pages

To implement sustainable water resource management, the industries that produce a huge amount of wastewater are aiming to recycle wastewater. Reverse osmosis (RO) is an advanced membrane process that can produce potable water from wastewater. However...

  • Article
  • Open Access
9 Citations
5,101 Views
14 Pages

As a traditional Chinese medicinal herb, ginseng (Panax ginseng C. A. Mey.) is commonly used to treat common diseases, for example, esophageal cancer and myasthenia gravis. Furthermore, ginseng is also processed into a functional food additive that i...

  • Article
  • Open Access
3 Citations
2,217 Views
16 Pages

Metabolic syndrome is an associated condition that occurs together and increases the risk of heart disease and diabetes. These conditions include high blood pressure, high blood sugar, and high body mass index (BMI) in terms of cholesterol and trigly...

  • Article
  • Open Access
3,141 Views
15 Pages

Enhanced Photocatalytic and Filtration Performance of TiO2-Ag Composite-Coated Membrane Used for the Separation of Oil Emulsions

  • Ákos Ferenc Fazekas,
  • Tamás Gyulavári,
  • Áron Ágoston,
  • László Janovák,
  • Judit Kopniczky,
  • Zsuzsanna László and
  • Gábor Veréb

Polyvinylidene fluoride (PVDF) membranes were coated with TiO2 and TiO2-Ag to enhance their efficiency for oil-in-water emulsion separation. The photocatalytic activities of the two modified membranes and their filtration performances were compared i...

  • Article
  • Open Access
2 Citations
2,702 Views
14 Pages

This study investigates and optimizes chromatographic separation in a Centrifugal Partition Chromatograph. Therefore, a model system is separated in a single-disc rotor. The occurring loss of the stationary phase lowers the separation efficiency over...

  • Article
  • Open Access
3 Citations
2,312 Views
12 Pages

Preparation of Polysilsesquioxane-Based CO2 Separation Membranes with Thermally Degradable Succinic Anhydride and Urea Units

  • Katsuhiro Horata,
  • Tsubasa Yoshio,
  • Ryuto Miyazaki,
  • Yohei Adachi,
  • Masakoto Kanezashi,
  • Toshinori Tsuru and
  • Joji Ohshita

New polysilsesquioxane (PSQ)-based CO2 separation membranes with succinic anhydride and monoalkylurea units as thermally degradable CO2-philic units were prepared by the copolymerization of a 1:1 mixture of [3-(triethoxysilyl)propyl]succinic anhydrid...

  • Article
  • Open Access
3 Citations
2,136 Views
13 Pages

Modulating Interfacial Charge Transfer Behavior through the Construction of a Hetero-Interface for Efficient Photoelectrochemical Water Splitting

  • Li Xu,
  • Jingjing Quan,
  • Li Xu,
  • Meihua Li,
  • Chenglong Li,
  • Saqib Mujtaba,
  • Xingming Ning,
  • Pei Chen,
  • Qiang Weng and
  • Xinbing Chen
  • + 1 author

Surface-coupled transition metal oxyhydroxide (TMOOH) on semiconductor (SC)-based photoanodes are effective strategies for improving photoelectrochemical (PEC) performance. However, there is a substantial difference between the current density and th...

  • Article
  • Open Access
4 Citations
2,630 Views
18 Pages

Carbon–Carbon Composite Membranes Derived from Small-Molecule-Compatibilized Immiscible PBI/6FDA-DAM-DABA Polymer Blends

  • Chamaal Karunaweera,
  • Nimanka P. Panapitiya,
  • Samitha Panangala,
  • Edson V. Perez,
  • Inga H. Musselman,
  • Kenneth J. Balkus and
  • John P. Ferraris

The use of immiscible polymer blends in gas separations is limited due to uncontrollable phase separation. In contrast, compatibilized immiscible polymer blends can be used as precursors with controlled morphologies that allow for a unique pore archi...

  • Article
  • Open Access
5 Citations
3,625 Views
14 Pages

Edible bird’s nests have a variety of biological activities, the main components of which are sialic acids. Sialic acids are a group of nine-carbon N-acetylated derivatives of neuraminic acid containing a keto group at position C2 and play impo...

  • Article
  • Open Access
12 Citations
4,890 Views
15 Pages

Industrial hemp (Cannabis sativa L.) is an attractive candidate for sustainable pest management due to its abundance of bioactive compounds with potential pesticidal properties. Solvent choice has a significant impact on the extraction efficiency of...

  • Article
  • Open Access
3 Citations
2,522 Views
13 Pages

Structural Characterization and Immunological Activity of Polysaccharide Degradation Products from Phlebopus portentosus

  • Dan Yu,
  • Xiaoming Cai,
  • Shuo Wang,
  • Yi Li,
  • Yuguang Du,
  • Zhuo A. Wang,
  • Siming Jiao and
  • Zhenquan Yang

Phlebopus portentosus is an edible and medicinal mushroom with a delicious taste and high nutritional value. The oligosaccharides derived from P. portentosus may be the material basis for its biological activity. The degradation of polysaccharide and...

  • Article
  • Open Access
2 Citations
2,110 Views
14 Pages

To establish a quality evaluation and identification method for Phyllanthi fructus (Yuganzi), the spectrum-effect relationship was explored. A high-performance liquid chromatography (HPLC) fingerprint was established using ultraviolet spectrophotomet...

  • Article
  • Open Access
2 Citations
2,205 Views
13 Pages

Rapid Determination of Taraxacum kok-saghyz Rubber Content Using a Pyrolyzer Hyphenated with a Miniaturized Mass Spectrometer

  • Shunkai Gao,
  • Minmin Guo,
  • Jiaqi Gao,
  • Zejian Huang,
  • Min Gan,
  • Jichuan Zhang and
  • Yiyang Dong

Taraxacum kok-saghyz (TKS), a rubber-producing plant with excellent potential, emerges as a viable substitute for rubber tree (Hevea brasiliensis). While natural rubber is a desirable material, conventional techniques for assessing rubber content hav...

  • Article
  • Open Access
8 Citations
2,768 Views
16 Pages

In the Azores Archipelago, Cryptomeria japonica is, currently, the most cultivated forestry tree for timber production, landscaping, and gardening, generating large amounts of foliage waste that is used for local essential oils (EOs) production. Howe...

  • Article
  • Open Access
5 Citations
2,808 Views
14 Pages

Recovery of Omega-3-Rich Lipids: Toward the Sustainable Valorization of Sea-Bass Industry Side Streams

  • Ioanna Semenoglou,
  • Maria Katsouli,
  • Maria Giannakourou and
  • Petros Taoukis

This study pertains to the selection of the appropriate process parameters of lipid extraction aimed at the valorization of sea-bass gutting and filleting side stream biomass. A comparative kinetic study between an environmentally friendly polar (eth...

  • Article
  • Open Access
6 Citations
2,656 Views
16 Pages

Detection and Comparison of Volatile Organic Compounds in Four Varieties of Hawthorn Using HS-GC-IMS

  • Lijun Zhu,
  • Feilin Ou,
  • Yun Xiang,
  • Bin Wang,
  • Yingchao Mao,
  • Lingfeng Zhu,
  • Qun Zhang and
  • Chang Lei

Hawthorn is a type of natural food with significant medicinal and nutritional properties; it has been listed in the “Both Food and Drug” list by the Chinese Ministry of Health Item List since 1997. However, hawthorn varieties have complex...

  • Article
  • Open Access
2 Citations
2,401 Views
16 Pages

Effects of Abelmoschus esculentus Extracts and Fractions on Embryos and Adult Individuals of Biomphalaria glabrata (Say, 1818) and on Schistosoma mansoni Cercariae

  • João Claudio Vitoria Atico Leite,
  • Leonardo da Silva Rangel,
  • Keyla Nunes Farias Gomes,
  • Ricardo Diego Duarte Galhardo de Albuquerque,
  • José Augusto Albuquerque dos Santos and
  • Robson Xavier Faria

Schistosomiasis is a neglected tropical disease caused by parasitic worms of the genus Schistosoma. In Brazil, there are reports of infection by the Schistosoma mansoni species, which has the Biomphalaria glabrata snail as one of its intermediate hos...

  • Article
  • Open Access
4 Citations
1,856 Views
19 Pages

Counteracting Bleeding in Centrifugal Partition Chromatography: Redosing of the Stationary Phase

  • Felix Buthmann,
  • Jan Hohlmann,
  • Sophia Volpert,
  • Mareen Neuwald,
  • Djamal Hamza and
  • Gerhard Schembecker

Centrifugal Partition Chromatography is a type of Liquid-Liquid Chromatography that offers several advantages compared to Liquid Chromatography. Two immiscible liquids are utilized, and one phase has to be immobilized to implement chromatographic sep...

  • Article
  • Open Access
13 Citations
4,972 Views
21 Pages

Essential Oil of Ocimum basilicum against Aedes aegypti and Culex quinquefasciatus: Larvicidal Activity of a Nanoemulsion and In Silico Study

  • Edla Lídia Vasques de Sousa dos Santos,
  • Jorddy Neves Cruz,
  • Glauber Vilhena da Costa,
  • Ester Martins Félix de Sá,
  • Alicia Karine Pereira da Silva,
  • Caio Pinho Fernandes,
  • Anna Eliza Maciel de Faria Mota Oliveira,
  • Jonatas Lobato Duarte,
  • Roberto Messias Bezerra and
  • Raimundo Nonato Picanço Souto
  • + 4 authors

Diseases transmitted by vectors such as Aedes aegypti and Culex quinquefasciatus (Diptera: Culicidae) have been responsible for endemics and epidemics in several countries, causing irreparable damage to human health. For this reason, vector control i...

  • Article
  • Open Access
8 Citations
5,972 Views
10 Pages

Nickel hydroxide (Ni(OH)2) is a valuable compound derived from nickel, widely utilized across various fields because of its versatile properties. This study aimed to characterize as-prepared β-Ni(OH)2 via chemical precipitation using various ana...

  • Article
  • Open Access
6 Citations
2,116 Views
14 Pages

Flotation Separation of Cassiterite from Calcite Using Low-Molecular-Weight Citrus Pectin as Depressant

  • Chenyang Yao,
  • Yachao Li,
  • Peng Li,
  • Xiaokui Che,
  • Guosheng Li,
  • Fanfan Zhang,
  • Weijun Peng,
  • Bozeng Wu and
  • Guixia Fan

This paper presents the development of an environmentally friendly, small molecular depressant citrus pectin for improving the recovery of cassiterite resources. Citrus pectin extracted from citrus peel was utilized as the depressant, and it demonstr...

  • Article
  • Open Access
3 Citations
3,630 Views
14 Pages

Optimized Centrifugal Partition Chromatography (CPC) Protocol for Isolation of Urease Inhibitors: Magnoflorine and Berberine from Berberis vulgaris Extracts

  • Sylwia Nakonieczna,
  • Katarzyna Susniak,
  • Anna Bozhadze,
  • Aneta Grabarska,
  • Anna Głowniak-Lipa,
  • Kazimierz Głowniak and
  • Wirginia Kukula-Koch

In recent years, an increasing interest in phytotherapy has been observed. Parallel to the research on the total extracts of plant material, numerous studies on the activity of single molecules derived from plants are being conducted to address their...

  • Article
  • Open Access
6 Citations
4,665 Views
16 Pages

The Extraction Mechanism of Zirconium and Hafnium in the MIBK-HSCN System

  • Jing Xiong,
  • Yang Li,
  • Xiaomeng Zhang,
  • Yong Wang,
  • Yanlin Zhang and
  • Tao Qi

The extraction of zirconium (Zr) and hafnium (Hf) in methyl isobutyl ketone (MIBK)—thiocyanic acid (HSCN) system has been widely used in the production of nuclear-grade zirconium and hafnium in industry, while the extraction mechanism was not a...

  • Article
  • Open Access
4 Citations
2,587 Views
15 Pages

Volatile Carbonyl Compounds Emission in Dry-Process Fibreboard: Identification through a Selective GDME-HPLC-DAD-MS/MS Method

  • Fátima Daniela Gonçalves,
  • Jorge M. Martins,
  • Luísa H. Carvalho,
  • José António Rodrigues and
  • Rui Miguel Ramos

This work presents a novel application of gas-diffusion microextraction (GDME) for the extraction and identification of volatile carbonyl compounds from a dry-process fibreboard (MDF) by combining high-performance liquid chromatography with diode arr...

  • Review
  • Open Access
19 Citations
7,367 Views
20 Pages

Gallium (Ga), indium (In), and germanium (Ge) play an important role in the modern high-tech material field. Due to their low content and scattered distribution in the crust, and the increasing demand for these metals in recent years, their supply ri...

  • Article
  • Open Access
8 Citations
3,626 Views
17 Pages

Comprehensive Analysis of Phytochemical Composition, Antioxidant Potential, and Antibacterial Activity of T. polium

  • Zineb Timizar,
  • Khalida Boutemak,
  • Amel Hadj Ziane-Zafour,
  • Nabil Touzout,
  • Hichem Tahraoui,
  • Bassem Jaouadi,
  • Meriem Zamouche,
  • Mohammed Kebir,
  • Jie Zhang and
  • Abdeltif Amrane

This study aims to thoroughly examine the chemicals and effects of the ethanol extract from T. polium’s upper parts. We used the Soxhlet method for extraction, resulting in an extract with a significant yield of 20.6%. Qualitative analysis iden...

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Separations - ISSN 2297-8739