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Chemosensors, Volume 8, Issue 4

2020 December - 47 articles

Cover Story: The review paper describes basic properties of novel fascinating two-dimensional nanomaterial MXene. Electrochemical impedance spectroscopy (EIS) was applied to better understand its rich surface chemistry, stability and modification by polymers. Moreover, EIS was applied as a detection tool for construction of ultrasensitive electrochemical sensors and biosensors. View this paper
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Articles (47)

  • Article
  • Open Access
10 Citations
4,496 Views
17 Pages

SnSe2-Zn-Porphyrin Nanocomposite Thin Films for Threshold Methane Concentration Detection at Room Temperature

  • Adam Lőrinczi,
  • Eugenia Fagadar-Cosma,
  • Gabriel Socol,
  • Andreea Mihăilescu,
  • Elena Matei,
  • Florinel Sava and
  • Mariana Ştefan

Nanocomposite thin films, sensitive to methane at the room temperature (25–30 °C), have been prepared, starting from SnSe2 powder and Zn(II)-5,10,15,20-tetrakis-(4-aminophenyl)- -porphyrin (ZnTAPP) powder, that were fully characterized by X...

  • Article
  • Open Access
27 Citations
3,861 Views
15 Pages

Simple Development of Novel Reversible Colorimetric Thermometer Using Urea Organogel Embedded with Thermochromic Hydrazone Chromophore

  • Tawfik A. Khattab,
  • Mehrez E. El-Naggar,
  • Meram S. Abdelrahman,
  • Ali Aldalbahi and
  • Mohammad Rafe Hatshan

Thermochromic urea (U) organogel immobilized with a thermochromic tricyanofuran hydrazone (TCFH) chromophore was developed. Thermochromic TCFH chromophore bearing two nitro functional groups on a hydrazone recognition unit was synthesized via an azo-...

  • Article
  • Open Access
27 Citations
5,333 Views
13 Pages

Paracetamol Sensing with a Pencil Lead Electrode Modified with Carbon Nanotubes and Polyvinylpyrrolidone

  • Piyanut Pinyou,
  • Vincent Blay,
  • Kantapat Chansaenpak and
  • Sireerat Lisnund

The determination of paracetamol is a common need in pharmaceutical and environmental samples for which a low-cost, rapid, and accurate sensor would be highly desirable. We develop a novel pencil graphite lead electrode (PGE) modified with single-wal...

  • Article
  • Open Access
7 Citations
3,826 Views
10 Pages

Flavylium Dye as pH-Tunable Fluorescent and CD Probe for Double-Stranded DNA and RNA

  • Ivo Crnolatac,
  • Letícia Giestas,
  • Gordan Horvat,
  • António Jorge Parola and
  • Ivo Piantanida

The interaction of 4′-(N,N-dimethylamino)-6-hydroxyflavylium cation with double stranded (ds-) DNA/RNA was studied by UV/Vis spectrophotometry, circular dichroism (CD), and also steady-state and time-resolved emission spectroscopies at neutral...

  • Article
  • Open Access
15 Citations
7,564 Views
20 Pages

Fabrication of a 3D-Printed Porous Junction for Ag|AgCl|gel-KCl Reference Electrode

  • Sarah May Sibug-Torres,
  • Lance P. Go and
  • Erwin P. Enriquez

Fused filament fabrication (FFF) is a 3D printing method that is attracting increased interest in the development of miniaturized electrochemical sensor systems due to its versatility, low cost, reproducibility, and capability for rapid prototyping....

  • Review
  • Open Access
6 Citations
6,154 Views
20 Pages

Passenger safety requires that in commercial airplanes hydraulic actuators be powered by fire-resistant hydraulic fluids. As a downside, such fluids are hygroscopic which means that these tend to accumulate humidity from the environment and that the...

  • Article
  • Open Access
24 Citations
4,034 Views
15 Pages

Two highly fluorescent calix[4]arene-containing phenylene-alt-ethynylene-carbazolylene polymers (Calix-PPE-CBZs) were used in the detection of explosives from the nitroaromatic compounds (NACs) family, in solution and in vapour phases. Both fluoropho...

  • Article
  • Open Access
10 Citations
4,477 Views
14 Pages

Electrochemical Evaluation of Laccase Activity in Must

  • Szilveszter Gáspár,
  • Elena Brinduse and
  • Alina Vasilescu

As laccase (produced by Botrytis cinerea) can significantly alter the properties of wine, winemakers frequently use commercially available colorimetric kits and spectrophotometers to measure the activity of this enzyme in grapes, must and wine. Altho...

  • Review
  • Open Access
64 Citations
10,944 Views
21 Pages

This review presents the basic characteristics of MXene, a novel 2D nanomaterial with many outstanding properties applicable to electrochemical sensing and biosensing. The second part deals with electrochemical impedance spectroscopy (EIS) and its be...

  • Article
  • Open Access
31 Citations
6,406 Views
14 Pages

Fully Printed Disposable IoT Soil Moisture Sensors for Precision Agriculture

  • Tomáš Syrový,
  • Robert Vik,
  • Silvan Pretl,
  • Lucie Syrová,
  • Jiří Čengery,
  • Aleš Hamáček,
  • Lubomír Kubáč and
  • Ladislav Menšík

Digitization of industrial processes using new technologies (IoT—Internet of Things, IoE—Internet of Everything), including the agriculture industry, are globally gaining growing interest. The precise management of production inputs is es...

  • Article
  • Open Access
26 Citations
5,319 Views
14 Pages

Pitfalls in Monitoring Mitochondrial Temperature Using Charged Thermosensitive Fluorophores

  • Dominique Chrétien,
  • Paule Bénit,
  • Christine Leroy,
  • Riyad El-Khoury,
  • Sunyou Park,
  • Jung Yeol Lee,
  • Young-Tae Chang,
  • Guy Lenaers,
  • Pierre Rustin and
  • Malgorzata Rak

Mitochondria are the source of internal heat which influences all cellular processes. Hence, monitoring mitochondrial temperature provides a unique insight into cell physiology. Using a thermosensitive fluorescent probe MitoThermo Yellow (MTY), we ha...

  • Article
  • Open Access
16 Citations
4,411 Views
12 Pages

A Naphthalimide–Sulfonylhydrazine Conjugate as a Fluorescent Chemodosimeter for Hypochlorite

  • Yasuhiro Shiraishi,
  • Rikako Nakatani,
  • Shunsuke Takagi,
  • Chiharu Yamada and
  • Takayuki Hirai

Hypochlorite anion (ClO) is a widely-used disinfectant and a microbicidal agent in the immune system. Accurate detection of ClO in environmental and biological samples by simply prepared chemosensors/chemodosimeters is important. Herein...

  • Article
  • Open Access
28 Citations
4,750 Views
19 Pages

An Impedance Based Electrochemical Immunosensor for Aflatoxin B1 Monitoring in Pistachio Matrices

  • Michail D. Kaminiaris,
  • Sophie Mavrikou,
  • Maria Georgiadou,
  • Georgia Paivana,
  • Dimitrios I. Tsitsigiannis and
  • Spyridon Kintzios

Aflatoxins are highly toxic fungal secondary metabolites that often contaminate food and feed commodities. An electrochemical immunosensor for the determination of aflatoxin B1 (AFB1) was fabricated by immobilizing monoclonal AFB1 antibodies onto a s...

  • Article
  • Open Access
21 Citations
5,584 Views
14 Pages

A new chemosensor UiO-66-N-Py (Py = 2-methinepyridine, N = imine nitrogen) based on isoreticular UiO-66 (University of Oslo) Metal–Organic Framework (MOF) containing 2-methinepyridine functionalized organic linker was solvothermally synthesized...

  • Communication
  • Open Access
47 Citations
5,903 Views
14 Pages

Manganese-Doped Zinc Oxide Nanostructures as Potential Scaffold for Photocatalytic and Fluorescence Sensing Applications

  • Deepika Thakur,
  • Anshu Sharma,
  • Abhishek Awasthi,
  • Dharmender Singh Rana,
  • Dilbag Singh,
  • Sadanand Pandey and
  • Sourbh Thakur

Herein, we report the photocatalytic and fluorescence sensing applications of manganese-doped zinc oxide nanostructures synthesized by a solution combustion technique, using zinc nitrate as an oxidizer and urea as a fuel. The synthesized Mn-doped ZnO...

  • Article
  • Open Access
2 Citations
3,290 Views
11 Pages

Label-Free Optical Biosensing Using Low-Cost Electrospun Polymeric Nanofibers

  • Paula Martínez-Pérez,
  • Salvador Ponce-Alcántara,
  • Nieves Murillo,
  • Ana Pérez-Márquez,
  • Jon Maudes,
  • Inés Peraile,
  • Laura González-López,
  • Matilde Gil-García,
  • Paloma Lorenzo-Lozano and
  • Jaime García-Rupérez

Polymeric nanofiber matrices are promising structures to develop biosensing devices due to their easy and affordable large-scale fabrication and their high surface-to-volume ratio. In this work, the suitability of a polyamide 6 nanofiber matrix for t...

  • Review
  • Open Access
28 Citations
6,909 Views
15 Pages

Biomarkers Determination Based on Surface-Enhanced Raman Scattering

  • Chao Song,
  • Shuang Guo,
  • Sila Jin,
  • Lei Chen and
  • Young Mee Jung

An overview of noteworthy new methods of biomarker determination based on surface-enhanced Raman scattering (SERS) is presented. Biomarkers can be used to identify the occurrence and development of diseases, which furthers the understanding of biolog...

  • Review
  • Open Access
151 Citations
17,474 Views
31 Pages

Nanomaterials for Diagnosis and Treatment of Brain Cancer: Recent Updates

  • Mahwash Mukhtar,
  • Muhammad Bilal,
  • Abbas Rahdar,
  • Mahmood Barani,
  • Rabia Arshad,
  • Tapan Behl,
  • Ciprian Brisc,
  • Florin Banica and
  • Simona Bungau

Brain tumors, especially glioblastoma, remain the most aggressive form of all the cancers because of inefficient diagnosis and profiling. Nanostructures, such as metallic nanostructures, silica nano-vehicles, quantum dots, lipid nanoparticles (NPs) a...

  • Article
  • Open Access
12 Citations
4,293 Views
12 Pages

Impedimetric Biosensor Based on a Hechtia argentea Lectin for the Detection of Salmonella spp.

  • Jorge Lopez-Tellez,
  • Irais Sanchez-Ortega,
  • Claudia Teresa Hornung-Leoni,
  • Eva Maria Santos,
  • Jose Manuel Miranda and
  • Jose Antonio Rodriguez

A sensitive electrochemical detection method for Salmonella spp. was described, based on the use of Hechtia argentea lectin immobilised on a screen-printed gold electrode. The lectin was extracted from Hechtia argentea, a plant belonging to the Brome...

  • Article
  • Open Access
10 Citations
4,046 Views
14 Pages

Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles

  • Bendix Ketelsen,
  • Patrick P. Tjarks,
  • Hendrik Schlicke,
  • Ying-Chih Liao and
  • Tobias Vossmeyer

This study presents a method for printing flexible chemiresistors comprising thin film transducers based on cross-linked gold nanoparticles (GNPs). First, interdigitated silver paste electrodes are printed onto polyimide (PI) foil via dispenser print...

  • Article
  • Open Access
14 Citations
4,628 Views
12 Pages

Optimizing Piezoelectric Cantilever Design for Electronic Nose Applications

  • Matiyas Tsegay Korsa,
  • Josep Maria Carmona Domingo,
  • Lawrence Nsubuga,
  • Jeanette Hvam,
  • Florian Niekiel,
  • Fabian Lofink,
  • Horst-Günter Rubahn,
  • Jost Adam and
  • Roana de Oliveira Hansen

This work demonstrates a method to optimize materials and dimensions of piezoelectric cantilevers for electronic nose applications via finite element analysis simulations. Here we studied the optimum piezoelectric cantilever configuration for detecti...

  • Article
  • Open Access
19 Citations
4,786 Views
18 Pages

This paper describes the sensitive properties of screen-printed carbon electrodes (SPCE) modified by using three different electroactive chemical compounds: Meldola’s Blue, Cobalt Phthalocyanine and Prussian Blue, respectively. It was demonstra...

  • Article
  • Open Access
12 Citations
3,513 Views
13 Pages

DFO@EVOH and 3,4-HP@EVOH: Towards New Polymeric Sorbents for Iron(III)

  • Giancarla Alberti,
  • Camilla Zanoni,
  • Lisa Rita Magnaghi,
  • Maria Amélia Santos,
  • Valeria Marina Nurchi and
  • Raffaela Biesuz

The paper presents the synthesis and preliminary characterization of two novel solid-phase sorbents for iron(III), resulting from the functionalization of ethylene-vinyl alcohol copolymer (EVOH) with deferoxamine, DFO (DFO@EVOH), and a novel tripodal...

  • Article
  • Open Access
6 Citations
2,854 Views
13 Pages

Sensing and Interaction of His-Tagged CA19-9 Antigen with Graphene-Modified Electrodes

  • Mihaela Mic,
  • Codruta Varodi,
  • Florina Pogacean,
  • Crina Socaci,
  • Maria Coros,
  • Raluca-Ioana Stefan-van Staden and
  • Stela Pruneanu

The electrochemical oxidation of CA19-9 tagged with L-Histidine (CA199-His) was investigated for the first time with screen-printed electrodes (DS) modified with graphene oxide (DS/GO) or thermally reduced graphene oxide (DS/TRGO). Successive cyclic...

  • Article
  • Open Access
6 Citations
3,254 Views
12 Pages

Ginkgo biloba is one of the most important sources of active compounds, mainly flavonoids and phenolic compounds. Due to its importance related to pharmaceutical practice, the making of a qualitative and quantitative method for the detection and quan...

  • Article
  • Open Access
27 Citations
5,115 Views
15 Pages

Facile Synthesis of Silver-Doped Zinc Oxide Nanostructures as Efficient Scaffolds for Detection of p-Nitrophenol

  • Deepika Thakur,
  • Anshu Sharma,
  • Dharmender Singh Rana,
  • Nagesh Thakur,
  • Dilbag Singh,
  • Tomas Tamulevicius,
  • Mindaugas Andrulevicius,
  • Sigitas Tamulevicius,
  • Sudheesh K. Shukla and
  • Sourbh Thakur

In this paper, silver-doped zinc oxide nanoparticles were synthesized by using a solution combustion technique, in which zinc nitrate is used as an oxidizer and tartaric acid as a fuel. The phase composition, morphology and structural properties of t...

  • Article
  • Open Access
16 Citations
5,023 Views
14 Pages

Fumed SiO2-H2SO4-PVA Gel Electrolyte CO Electrochemical Gas Sensor

  • Yuhang Zhang,
  • Dongliang Cheng,
  • Zicheng Wu,
  • Feihu Li,
  • Fang Fang and
  • Zili Zhan

The conventional CO electrochemical gas sensor uses aqueous H2SO4 solution as electrolyte, with inevitable problems, such as the drying and leakage of electrolyte. Thus, research on new alternative electrolytes is an attractive field in electrochemic...

  • Article
  • Open Access
6 Citations
4,830 Views
10 Pages

Second-Generation Phosgene and Diphosgene Detection Tube

  • Vladimír Pitschmann,
  • Lukáš Matějovský,
  • Jiří Zeman,
  • David Vetchý,
  • Michal Dymák,
  • Martin Lobotka,
  • Sylvie Pavloková and
  • Zdeněk Moravec

We have developed a second-generation detection tube for colorimetric and fluorescence detection of phosgene and diphosgene in air. The tube is packed with pellets made of a mixture of microcrystalline cellulose and magnesium aluminum metasilicate tr...

  • Review
  • Open Access
28 Citations
16,354 Views
42 Pages

Low Energy Beta Emitter Measurement: A Review

  • Hara Kang,
  • Sujung Min,
  • Bumkyung Seo,
  • Changhyun Roh,
  • Sangbum Hong and
  • Jae Hak Cheong

The detection and monitoring systems of low energy beta particles are of important concern in nuclear facilities and decommissioning sites. Generally, low-energy beta-rays have been measured in systems such as liquid scintillation counters and gas pr...

  • Review
  • Open Access
45 Citations
8,638 Views
22 Pages

A Review of Nanostructured Resistive-Based Vanadium Oxide Gas Sensors

  • Vahid Amiri,
  • Hossein Roshan,
  • Ali Mirzaei and
  • Mohammad Hossein Sheikhi

Vanadium pentoxide (V2O5) is a transition metal oxide with features such as high availability, good catalytic activity, unique electrical properties and high conductivity which are appropriate for gas sensing applications. In this review, we discuss...

  • Article
  • Open Access
16 Citations
5,226 Views
19 Pages

Experimental Study and Mathematical Modeling of a Glyphosate Impedimetric Microsensor Based on Molecularly Imprinted Chitosan Film

  • Fares Zouaoui,
  • Saliha Bourouina-Bacha,
  • Mustapha Bourouina,
  • Albert Alcacer,
  • Joan Bausells,
  • Nicole Jaffrezic-Renault,
  • Nadia Zine and
  • Abdelhamid Errachid

A novel impedimetric microsensor based on a double-layered imprinted polymer film has been constructed for the sensitive detection of the herbicide, glyphosate (GLY), in water. It is based on electropolymerized polypyrrole films, doped with cobaltabi...

  • Article
  • Open Access
63 Citations
6,969 Views
11 Pages

Flexible Carbon Electrodes for Electrochemical Detection of Bisphenol-A, Hydroquinone and Catechol in Water Samples

  • Acelino C. de Sá,
  • Simone C. Barbosa,
  • Paulo A. Raymundo-Pereira,
  • Deivy Wilson,
  • Flávio M. Shimizu,
  • Maria Raposo and
  • Osvaldo N. Oliveira

The detection of pollutant traces in the public water supply and aquifers is essential for the safety of the population. In this article, we demonstrate that a simple electrochemical procedure in acidic solution can be employed for enhancing the sens...

  • Article
  • Open Access
24 Citations
4,251 Views
10 Pages

Novel 1D/2D KWO/Ti3C2Tx Nanocomposite-Based Acetone Sensor for Diabetes Prevention and Monitoring

  • Obinna Ama,
  • Mahek Sadiq,
  • Michael Johnson,
  • Qifeng Zhang and
  • Danling Wang

The acetone content in the exhaled breath of individuals as a biomarker of diabetes has become widely studied as a non-invasive means of quantifying blood glucose levels. This calls for development of sensors for the quantitative analysis of trace co...

  • Article
  • Open Access
23 Citations
4,656 Views
11 Pages

Sensitive Electrochemical Detection of Tryptophan Using a Hemin/G-Quadruplex Aptasensor

  • Ayemeh Bagheri Hashkavayi,
  • Jahan Bakhsh Raoof and
  • Ki Soo Park

In this study, we design an electrochemical aptasensor with an enzyme-free amplification method to detect tryptophan (Trp). For the amplified electrochemical signal, the screen-printed electrode was modified with dendritic gold nanostructures (DGNs)/...

  • Review
  • Open Access
15 Citations
6,497 Views
24 Pages

Semiconductor quantum dots (QDs) have become a unique class of materials with great potential for applications in biomedical and optoelectronic devices. However, conventional QDs contains toxic heavy metals such as Pb, Cd and Hg. Hence, it is imperat...

  • Article
  • Open Access
5 Citations
3,933 Views
16 Pages

Dipsticks with Reflectometric Readout of an NIR Dye for Determination of Biogenic Amines

  • Sarah N. Mobarez,
  • Nongnoot Wongkaew,
  • Marcel Simsek,
  • Antje J. Baeumner and
  • Axel Duerkop

Electrospun nanofibers (ENFs) are remarkable analytical tools for quantitative analysis since they are inexpensive, easily produced in uniform homogenous mats, and provide a high surface area-to-volume ratio. Taking advantage of these characteristics...

  • Article
  • Open Access
19 Citations
7,549 Views
19 Pages

A dip-and-read microfluidic paper-based analytical device (µPAD) was developed for the qualitative and quantitative detection of the total hardness of water. To create well-defined hydrophobic barriers on filter paper, a regular office printer...

  • Communication
  • Open Access
4 Citations
3,588 Views
12 Pages

Unmodified gold nanoparticles (AuNPs)-based aptasensing (uGA) assay has been widely implemented in the determination of many different targets, but there are few reports on protein detection using uGA. Here, we designed a uGA assay for protein detect...

  • Review
  • Open Access
49 Citations
6,445 Views
37 Pages

Advances in Electrochemical Aptasensors Based on Carbon Nanomaterials

  • Gennady Evtugyn,
  • Anna Porfireva,
  • Rezeda Shamagsumova and
  • Tibor Hianik

Carbon nanomaterials offer unique opportunities for the assembling of electrochemical aptasensors due to their high electroconductivity, redox activity, compatibility with biochemical receptors and broad possibilities of functionalization and combina...

  • Article
  • Open Access
16 Citations
4,201 Views
11 Pages

SOI-Nanowire Biosensor for the Detection of Glioma-Associated miRNAs in Plasma

  • Kristina A. Malsagova,
  • Tatyana O. Pleshakova,
  • Rafael A. Galiullin,
  • Andrey F. Kozlov,
  • Tatyana S. Romanova,
  • Ivan D. Shumov,
  • Vladimir P. Popov,
  • Fedor V. Tikhonenko,
  • Alexander V. Glukhov and
  • Yuri D. Ivanov
  • + 5 authors

Herein, we report the development of a highly sensitive nanotechnology-based system—silicon-on-insulator nanowire biosensor for the revelation of microRNAs (miRNAs), associated with the development of glioma in the human. In this system, a sens...

  • Article
  • Open Access
27 Citations
4,668 Views
14 Pages

Development of a NanoMIPs-SPR-Based Sensor for β-Lactoglobulin Detection

  • Roberta D’Aurelio,
  • Jon Ashley,
  • Thomas L. Rodgers,
  • Linda Trinh,
  • Jeff Temblay,
  • Mike Pleasants and
  • Ibtisam E. Tothill

Food manufacturers are aiming to manage the levels of cross-contamination of allergens within food processing plants and ultimately move away from precautionary labelling. Hence, the need for rapid methods to detect allergens cross-contamination. A s...

  • Article
  • Open Access
12 Citations
3,939 Views
12 Pages

Reliable, cost-effective, and robust screen-printed sensors were constructed and presented for Ca2+ ions determination. The sensors were based on the use of bilirubin (1,3,6,7-tetramethyl-4,5- dicarboxyethy-2,8-divinyl-(b-13)-dihydrobilenone) as a re...

  • Article
  • Open Access
9 Citations
3,363 Views
12 Pages

Ion mobility spectrometry instrumentation today is widespread in the area of transport security and counterterrorism. This method of detection of explosive substances is highly appreciated for the existence of portable detectors capable of detecting...

  • Article
  • Open Access
15 Citations
3,487 Views
14 Pages

Impedance-type humidity sensors were fabricated via one-step UV-irradiation photopolymerization of Ag microwires (Ag MWs), polypyrrole (PPy) and SnO2 ternary composite (Ag MWs/PPy/SnO2) films on an alumina substrate. X-ray diffractometry (XRD), Fouri...

  • Review
  • Open Access
6 Citations
3,214 Views
14 Pages

The terminology used in electrochemical methods which are used to generate the measured signal in antioxidant/oxidant activity (AOA/OA) sensors is briefly considered. The review presents a hybrid version of electrochemical methods for the determinati...

  • Article
  • Open Access
26 Citations
3,474 Views
19 Pages

TiO2 nanoparticles coating has been proven to be an extremely performing sensing material for relative humidity (RH) measurements. The chemical activity of TiO2 toward water vapor adsorption and the very large surface to volume ratio typical of nanos...

  • Article
  • Open Access
11 Citations
4,549 Views
13 Pages

Identification of Plastic Type and Surface Roughness of Film-Type Plastics in Water Using Kramers–Kronig Analysis

  • Boniphace Elphace Kanyathare,
  • Benjamin Asamoah,
  • Muhammad Umair Ishaq,
  • James Amoani,
  • Jukka Räty and
  • Kai-Erik Peiponen

The knowledge of the plastic type, thickness, and the nature of the surface is important towards the monitoring of microplastic pollution in water bodies, especially when vis-NIR spectroscopy is utilized. Factors such as complex environment and surfa...

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Chemosensors - ISSN 2227-9040