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Atoms, Volume 7, Issue 3

September 2019 - 34 articles

Cover Story: Quantum interference between the direct and looping reaction pathways determines the outcome of the ultracold O + OH → H + O2 reaction. In the ultracold regime, the interference can approach its maximal constructive or destructive values, effectively turning the reaction on or off (a quantum switch!). This is due to the unique properties of ultracold collisions, where the scattering phase shifts approach integer multiples of π (the integer corresponds to the number of bound states supported along each pathway). The geometric phase associated with the C2v conical intersection introduces an additional π-phase shift between the two interfering pathways, which reverses the nature of the interference (constructive ↔ destructive) and in this way controls the reaction. View this paper.
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Articles (34)

  • Article
  • Open Access
3 Citations
3,782 Views
9 Pages

Opacity Corrections for Resonance Silver Lines in Nano-Material Laser-Induced Plasma

  • Ashraf M. EL Sherbini,
  • Ahmed H. EL Farash,
  • Tharwat M. EL Sherbini and
  • Christian G. Parigger

31 July 2019

Q-switched laser radiation at wavelengths of 355, 532, and 1064 nm from a Nd: YAG laser was used to generate plasma in laboratory air at the target surface made of nano-silver particles of size 95 ± 10 nm. The emitted resonance spectra from th...

  • Article
  • Open Access
6 Citations
5,585 Views
16 Pages

Plasma Spectroscopy of Various Types of Gypsum: An Ideal Terrestrial Analogue

  • Abhishek K. Rai,
  • Jayanta K. Pati,
  • Christian G. Parigger and
  • Awadhesh K. Rai

21 July 2019

The first detection of gypsum (CaSO4·2H2O) by the Mars Science Laboratory (MSL) rover Curiosity in the Gale Crater, Mars created a profound impact on planetary science and exploration. The unique capability of plasma spectroscopy, which involv...

  • Article
  • Open Access
17 Citations
4,489 Views
11 Pages

Atomic and Molecular Laser-Induced Breakdown Spectroscopy of Selected Pharmaceuticals

  • Pravin Kumar Tiwari,
  • Nilesh Kumar Rai,
  • Rohit Kumar,
  • Christian G. Parigger and
  • Awadhesh Kumar Rai

19 July 2019

Laser-induced breakdown spectroscopy (LIBS) of pharmaceutical drugs that contain paracetamol was investigated in air and argon atmospheres. The characteristic neutral and ionic spectral lines of various elements and molecular signatures of CN violet...

  • Article
  • Open Access
29 Citations
4,538 Views
15 Pages

18 July 2019

Knowledge of the electronic structures of atomic and molecular systems deepens our understanding of the desired system. In particular, several information-theoretic quantities, such as Shannon entropy, have been applied to quantify the extent of elec...

  • Article
  • Open Access
12 Citations
3,546 Views
11 Pages

5 July 2019

Cross sections and thermal rate coefficients for rotational and vibration excitation of the four stable isotopologues of the 4 HeH + ion by electron impact are presented. The data are calculated using a previously developed theoretica...

  • Article
  • Open Access
9 Citations
4,486 Views
13 Pages

Geometric Phase Effects in Ultracold Chemical Reactions

  • Brian K. Kendrick and
  • N. Balakrishnan

3 July 2019

The role of the geometric phase effect in chemical reaction dynamics has long been a topic of active experimental and theoretical investigations. The topic has received renewed interest in recent years in cold and ultracold chemistry where it was sho...

  • Article
  • Open Access
6 Citations
3,884 Views
9 Pages

Soft X-Ray Spectroscopy of Rare-Earth Elements in LHD Plasmas

  • Chihiro Suzuki,
  • Fumihiro Koike,
  • Izumi Murakami,
  • Naoki Tamura,
  • Shigeru Sudo and
  • Gerry O’Sullivan

3 July 2019

Soft X-ray spectra from high Z rare-earth (lanthanide) elements have been systematically observed in optically thin, high-temperature plasmas produced in the Large Helical Device (LHD), a facility for magnetically confined fusion research. It has bee...

  • Article
  • Open Access
44 Citations
8,430 Views
14 Pages

2 July 2019

The famous Cowan’s book, “The Theory of Atomic Structure and Spectra”, published in 1981, and his suite of computer codes based on it, continue to be highly influential in atomic physics and many other research areas. As of September 2018, there have...

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Atoms - ISSN 2218-2004Creative Common CC BY license