The mixture powders were designed by adding 0 wt.%~1.0 wt.% CeO
2 into the 2205 duplex stainless steel (DSS) powders. The 2205 DSS cladding layer was prepared on the surface of Q345 steel by plasma arc cladding technology. The effects of different CeO
2 contents on the macro-morphology, microstructure composition, and corrosion resistance of the cladding layer were studied. The action mechanism of CeO
2 in the cladding layer was also discussed. The results showed that the addition of CeO
2 modified the appearance and decreased the defect of the cladding layer. Also, the austenite grains were refined, and the austenite proportion was increased under the action of CeO
2. When the CeO
2 content was 0.5 wt.%, the appearance of the cladding layer was optimum; the austenite proportion in the upper cladding layer and the lower cladding layer reached up to 52.6% and 55.5%, respectively, and the crystal changed from columnar to equiaxed. CeO
2 decomposes into Ce element and O element under the action of the plasma arc, after which Ce element is easily absorbed at the grain boundary to reduce the surface tension and improve the fluidity of the liquid metal so as to modify the appearance of the cladding layer. Meanwhile, Ce element primarily reacts with O, S, Al, and Si elements to form low-melting-point oxygen sulfides and are then removed, which eliminates the defect of the cladding layer. Moreover, the high melting point of CeO
2 acts as heterogeneous nucleation sites during solidification, thus improving the value of nucleation rate/growth rate of the grain and promoting the transformation from ferrite to austenite. According to the electrochemical corrosion testing result, Ce element inhibited the enrichment of Cr element at grain boundaries and promoted the formation of Cr
2O
3, which improved the corrosion resistance of the 2205 DSS cladding layer. It was optimum with the CeO
2 content of 0.5 wt.%.
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